Abstract: The present invention relates to dye mixtures comprising one or more disazo dyes conforming to the formula (1) and one or more monoazo dyes corforming to the formula (2)
wherein the variables are described in the specification.
Abstract: Disclosed are dye mixtures comprising yellow dyes of the formulae indicated and defined in claim 1 which are useful for dyeing hydroxyl- and/or carboxamido-containing material, especially fiber material, such as cellulose fibers, for example cotton and filament viscose, and wool and also synthetic polyamide fibers.
Type:
Grant
Filed:
November 4, 1999
Date of Patent:
May 29, 2001
Assignee:
DyStar Textilfarben GmbH & Co. Deutschland KG
Abstract: Dye mixtures comprising water-soluble fiber-reactive azo dyes, preparation thereof and use thereof
Described are dye mixtures comprising yellow dyes of the formulae indicated and defined in claim 1, which are useful for dyeing hydroxyl- and/or carboxamido-containing material, especially fiber material, such as cellulose fibers, for example cotton and filament viscose, and wool and also synthetic polyamide fibers.
Type:
Grant
Filed:
September 29, 1999
Date of Patent:
May 8, 2001
Assignee:
Dystar Textilfarben GmbH & Co. Deutschland KG
Inventors:
Bengt-Thomas Gröbel, Christian Schumacher, Gerhard Lippert, Mieke Schaffeld, Karl Krieger, Dierk Röhrig
Abstract: The present invention comprises a dye mixture comprising one or more, such as one, two or three, disazo dyes conforming to the general formula (1), one or more, such as one, two or three, dyes.
Type:
Grant
Filed:
December 7, 1999
Date of Patent:
February 20, 2001
Assignee:
DyStar Textilfarben GmbH & Co
Inventors:
Christian Schumacher, Uwe Reiher, Joachim Steckelberg, Werner Russ, Ronald Pedemonte
Abstract: Azo dyes of the formula
wherein the substituents are each as defined in the description, are useful for dyeing and printing synthetic textile materials.
Type:
Grant
Filed:
December 14, 1999
Date of Patent:
February 20, 2001
Assignee:
DyStar Textilfarben GmbH & Co. Deutschland KG
Abstract: Described are dye mixtures comprising one or more azo dyes (1) and one or more azo dyes (2) or (3) or (2) and (3), all these azo dyes containing a 1-(halotriazinylamino)-3,6- or -4,6-disulfo-8-naphthol coupling component and the third substituent in the triazine moiety of (1) and similarly of (2) and of (3) being an optionally alkyl- and/or phenyl-substituted amino radical or heterocyclic radical and the diazo component in (1) containing a fiber-reactive group of the vinyl sulfone series and being an optionally alkyl- and/or alkoxy-substituted phenyl or optionally sulfo-substituted naphthyl radical, in (2) being an optionally alkyl-, alkoxy-, chlorine-, bromine-, sulfo- and/or carboxyl-substituted phenyl or optionally sulfo-substituted naphthyl radical and in (3) being a sulfophenyl radical which, attached via an amino group, possesses a fiber-reactive halopyrimidine radical or a halotriazine radical having a fiber-reactive group of the vinyl sulfone series.
Type:
Grant
Filed:
July 19, 1999
Date of Patent:
February 6, 2001
Assignee:
Dystar Textilfarben GmbH & Co.
Inventors:
Werner Russ, Bengt-Thomas Gröbel, Christian Schumacher
Abstract: A dyestuff mixture containing one or more copper formazan dyestuffs of the formula (1), one or more disazo dyestuffs of the formula (2) and one or two monoazo dyestuffs of the formula (3)
Type:
Grant
Filed:
September 25, 1997
Date of Patent:
January 9, 2001
Assignee:
DyStar Textilfarben GmbH
Inventors:
Werner Hubert Russ, Andreas Von Der Eltz, Bengt-Thomas Gröbel, Daniele Negri
Abstract: Disclosed are dye mixtures comprising yellow dyes of the formulae indicated and defined in claim 1 which are useful for dyeing hydroxy- and/or carboxamido-containing material, especially fiber material, such as cellulose fibers, for example cotton and filament viscose, and wool and also synthetic polyamide fibers.
Type:
Grant
Filed:
November 5, 1999
Date of Patent:
January 2, 2001
Assignee:
Dystar Textilfarben GmbH & Co. Deutschland KG
Inventors:
Bengt-Thomas Gröbel, Christian Schumacher, Birgit Eden, Mieke Schaffeld, Karl Krieger, Dierk Röhrig
Abstract: Described are dye mixtures comprising dyes containing a coupling component comprising a 1-(chlorotriazinyl)amino-3,6-disulfo-8-naphthol radical, the dye or dyes of the one group of dyes containing an optionally loweralkyl-, loweralkoxy-, halogen, sulfo- and/or carboxy-substituted phenylamino or naphthylamino radical attached to the chlorotriazine radical and possessing a diazo component comprising an optionally loweralkyl-, loweralkoxy-, sulfo- and/or carboxy-substituted phenyl radical which is substituted by a fiber-reactive group of the vinyl sulfone series, and the dye or dyes of the other group of dyes containing attached to the chlorotriazine radical a phenylamino radical whose phenyl is substituted by a fiber-reactive group of the vinyl sulfone series and may be substituted by lower alkyl, lower alkoxy, sulfo and/or carboxy, and possessing a diazo component comprising a radical of benzene or naphthalene which may in each case be optionally substituted by lower alkyl, lower alkoxy, halogen, sulfo and/Qr
Type:
Grant
Filed:
November 9, 1999
Date of Patent:
December 26, 2000
Assignee:
Dystar Textilfarben GmbH & Co. Deutschland KG
Inventors:
Bengt-Thomas Grobel, Christian Schumacher, Mieke Schaffeld, Karl Krieger, Dierk Rohrig
Abstract: The present invention provides a dye mixture comprising one or more copper complex formazan dyes conforming to the formula (1) ##STR1## and one or more copper complex formazan dyes conforming to the formula (2) ##STR2## wherein R1, R2, Y1, Y2 and M are defined as given in claim 1, methods for preparing said dye mixtures and methods for dyeing and printing hydroxy- and/or carboxamido-containing materials using said dye mixtures.
Abstract: The present invention relates to dye mixtures comprising one or more azo dyes of the general formula (1) and one or more azo dyes of the general formula (2) ##STR1## where p is 1 or 2,R.sub.1, R.sup.1' and R.sup.2 are independently hydrogen or a group of the general formula SO.sub.3 M or OCH.sub.3,R.sup.5 and R.sup.6 are independently hydrogen or C.sub.1 -C.sub.4 alkyl,X.sup.1 and X.sup.2 are independently fluorine or chlorine or a grouping of the general formula NR.sup.3 R.sup.4 or OR.sup.3,R.sup.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or optionally substituted aryl,R.sup.4 has one of the meanings of R.sup.3 or is aryl or alkyl (which may be substituted by SO.sub.2 Y, SO.sub.3 M or OCH.sub.3), optionally substituted morpholino or pyrimidino or NHCN,Y, Y.sup.1 and Y.sup.2 are independently vinyl or a grouping of the general formula CH.sub.2 CH.sub.
Type:
Grant
Filed:
August 11, 1999
Date of Patent:
October 24, 2000
Assignee:
DyStar Textilfarben GmbH & Co. Deutschland KG
Inventors:
Ronald P. Pedemonte, Werner Russ, Joachim Steckelberg, Christian Schumacher
Abstract: Described are fiber-reactive, water-soluble monoazo compounds which conform to the hereinbelow indicated and defined general formula (1) and which are capable of dyeing hydroxy- and/or carboxamido-containing material, especially fiber material, such as cellulose fibers, for example cotton or regenerated cellulose fibers, and also wool and synthetic polyamide fibers in high color strength and good fastnesses. ##STR1## where M is hydrogen, an alkali metal or some other salt-forming, colorless metal, D is a 2-sulfophenyl radical which may be additionally substituted by alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, sulfo and/or carboxy or is a 1-sulfonaphth-2-yl radical which may be additionally substituted by sulfo and/or carboxy, and the group --SO.sub.2 --Y is a fiber-reactive group of the vinyl sulfone series.
Type:
Grant
Filed:
April 13, 1999
Date of Patent:
September 26, 2000
Assignee:
DyStar Textilfarben GmbH & Co. Deutschland KG
Abstract: Fiber-reactive, water-soluble monoazo compounds conforming to the hereinbelow indicated and defined general formula (1) are capable of dyeing hydroxyl- and/or carboxamido-containing material, especially fiber material, such as cellulose fibers, for example cotton, or regenerated cellulose fibers and also wool and synthetic polyamide fibers in red shades and in high color strength and good fastnesses. ##STR1## where M is hydrogen, an alkali metal or some other colorless salt-forming metal, R is hydrogen or optionally sulfo-, methoxy-, ethoxy-, hydroxyl-, sulfato-, phosphate-, acetyloxy- or propionyloxy-substituted alkyl of 1 to 4 carbon atoms, R.sup.1 is hydrogen, carboxyl, optionally substituted alkyl of 1 to 4 carbon atoms or alkoxy of 1 to 4 carbon atoms, m is zero or 1, n is zero, 1 or 2 and X is a fiber-reactive radical from the halopyrimidine, dichloroquinoxazoline or fluorotriazinylamino series.
Abstract: A dye mixture comprising one or more disazo dyes composed of 1-amino-3,6-disulfo-8-naphthol as the coupling component and of two diazo components of the aniline series containing each a fiber-reactive group of the vinylsulfone series, one or more monoazo dyes composed of a sulfo-substituted 2-amino-naphthalene as coupling component and a diazo component of the aniline series containing a fiber-reactive group of the vinylsulfone series, and optionally one or two monoazo dyes with 1-amino-3,6-disulfo-8-naphthol as a coupling component to which is coupled in the ortho-position to the amino group a diazo component of the aniline series substituted by a fiber-reactive group of the vinylsulfone series. The dye mixtures yield on hydroxy- and/or carboxamido-containing fiber materials, such as cellulose fibers, in particular cotton, or on, for example, wool and synthetic polyamide fibers, deep black dyeings.
Type:
Grant
Filed:
August 27, 1998
Date of Patent:
August 22, 2000
Assignee:
Dystar Textilfarben GmbH & Co. Deutschland KG
Abstract: Described are dye mixtures of dyes of the general formulae (1) and (2) ##STR1## where M is hydrogen, an alkali metal or the equivalent of an alkaline earth metal, R.sup.1, R.sup.2 and R.sup.3 are independently hydrogen or sulfo, X.sup.1 and X.sup.2, are independently chlorine, fluorine, hydroxy, alkoxy of 1 to 4 carbon atoms, optionally substituted phenyl, optionally substituted morpholino, optionally substituted pyrimidino, cyanoamino or an amino group of the formula --NR.sup.4 R.sup.5, where R.sup.4 is hydrogen, alkyl of 1 to 4 carbon atoms, unsubstituted or sulfo-substituted phenyl or unsubstituted or sulfo-substituted naphthyl, R.sup.5 is hydrogen, optionally substituted alkyl, which may be interrupted by oxy or amino, or optionally substituted phenyl or unsubstituted or sulfo-substituted naphthyl, or the group --NR.sup.4 R.sup.5 is the radical of an aliphatic heterocycle, the groups Y.sup.1 --SO.sub.2 --, Y.sup.2 --SO.sub.2 -- and Y.sup.3 --SO.sub.
Type:
Grant
Filed:
December 21, 1998
Date of Patent:
July 18, 2000
Assignee:
Dystar Textilfarben GmbH & Co. Deutschland KG
Inventors:
Joachim Steckelberg, Ronald P. Pedemonte
Abstract: Described are mixtures of dyes of the general formulae (1) and (2) ##STR1## where M is hydrogen, ammonium, an alkali metal or the equivalent of an alkaline earth metal, R.sup.1 is hydrogen or sulfo, R.sup.2 is hydrogen or sulfo, X.sup.1 and X.sup.2 are each fluorine, chlorine, amino, which may be mono- or disubstituted by lower alkyl or optionally substituted aryl and one of the radicals possesses a group of the formula --SO.sup.2 --Y.sup.1 or --SO.sub.2 --Y.sup.2, where Y.sup.1 and Y.sup.2 are each vinyl or ethyl substituted in the .beta.-position by an alkali-eliminable grouping, or X.sup.1 and X.sup.2 are each optionally substituted morpholino or pyrimidino, cyanoamino, hydroxyl, lower alkoxy or optionally substituted aryloxy and where the groups --SO.sub.2 --Y.sup.1 and --SO.sub.2 --Y.sup.2 are attached to the benzene nucleus meta or para to the azo or amino group.
Type:
Grant
Filed:
May 12, 1999
Date of Patent:
July 18, 2000
Assignee:
DyStar Textilfarben GmbH & Co. Deutschland KG
Abstract: The present invention comprises a dye mixture comprising one or more, such as one, two or three, disazo dyes conforming to the general formula (1), one or more, such as one, two or three, monoazo dyes conforming to the general formula (2), and one or more, such as one, two or three dyes of the general formulae (3) and (4) wherein the formulae (1) to (4) are defined as given in claim 1, a method for its preparation and a process for dyeing hydroxy- and/or carboxamido containing fiber material in which a inventive dye is applied to the material.
Type:
Grant
Filed:
March 9, 1999
Date of Patent:
July 11, 2000
Assignee:
Dystar Textilfarben GmbH & Co. Deutschland KG
Inventors:
Joachim Steckelberg, Werner Hubert Russ, Christian Schumacher, Ron Pedemonte
Abstract: Process for reacting fluorine-substituted heterocycles with amines in the presence of phase transfer catalysts The reaction of an amino compound with a fluorine-substituted triazine or pyrimidine group is carried out in the presence of a phase transfer catalyst, preferably of the formula (4a), (4b) or (4c) ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and are each alkyl having from 1 to 20 carbon atoms which may be substituted by phenyl, or are phenyl.
Type:
Grant
Filed:
October 14, 1998
Date of Patent:
June 27, 2000
Assignee:
DyStar Textilfarben GmbH & Co. Deutschland KG
Abstract: Process for continuous dyeing of cellulosic circular knits composed of natural or modified hydroxy-containing or natural, modified or synthetic carboxamido-containing fiber materials with water-soluble dyes comprises initially impregnating the material with an aqueous dye solution, optionally comprising auxiliaries, in the course of the dyeing step, reducing the liquor content to 400% by weight, based on weight of fiber, by squeezing means customary for tubular material, and subsequently subjecting the liquor-comprising material to a leveling and fixing step for the dye applied to the material by transporting the rope of material continuously through the machine unit by means of the flowing dyeing liquor at a liquor ratio of up to 10:1.
Type:
Grant
Filed:
November 5, 1998
Date of Patent:
April 4, 2000
Assignee:
Dystar Textilfarben GmbH & Co Deutschland KG