Patents Assigned to DyStar Textilfarben GmbH
  • Patent number: 6046311
    Abstract: Dyes containing a 5,6-difluoropyrimidin-4-yl radical as fiber-reactive group are useful for dyeing hydroxy- and/or carboxamido-containing material, including fiber material, for example cellulose fibers, wool and polyamide.
    Type: Grant
    Filed: March 19, 1998
    Date of Patent: April 4, 2000
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Wilfried Hansmann, Hermann Henk, Stefan Ehrenberg, Wolfram Reddig
  • Patent number: 6036732
    Abstract: The present invention is a dye mixture containing one or more disazo dyes conforming to the formula (1), one or more monoazo dyes conforming to the formula (2), and one or more dyes of the formulae (3) The invention further relates to a method for its preparation and a process for dyeing hydroxy- and/or carboxamido containing fiber material in which the inventive dye is applied to the material.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: March 14, 2000
    Assignee: Dystar Textilfarben GmbH & Co. Deuschland KG
    Inventors: Ron Pedemonte, Stefan Meier
  • Patent number: 6001995
    Abstract: Aminated cellulose fiber obtained by adding one or more starches etherified with C.sub.2 -C.sub.5 -alkylamines which may additionally be substituted in the alkyl moiety by 1 to 2 further hydroxyl and methoxy groups and whose amino group is a primary or C.sub.1 -C.sub.4 -alkyl-substituted secondary, tertiary or quaternary amino or ammonium group and having a degree of substitution between 0.1 and 3 to a viscose dope, an alkali cellulose or a cellulose solution and spinning fiber therefrom.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: December 14, 1999
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Andreas Schrell, Bernd Huber
  • Patent number: 5993492
    Abstract: A dye mixture comprising at least two dyes of the formula (1) ##STR1## in which: D is phenyl or naphthyl which is substituted by 1, 2 or 3, sulfo groupsR.sup.A is aminocarbonyl of the formula --CO--NH.sub.2 or is a group of the formula (2) ##STR2## in which X is fluoro or hydroxyl,R.sup.1 is hydrogen, methyl, ethyl, methoxy or chloro,R.sup.2 is hydrogen, methyl, ethyl, methoxy or ethoxy,Y is vinyl or is ethyl substituted in .beta.-position by a substituent which can be eliminated by the action of an alkali to form the vinyl group, or is .beta.-hydroxyethyl, andn is zero or 1 (and if n is zero this group is hydrogen).
    Type: Grant
    Filed: November 13, 1998
    Date of Patent: November 30, 1999
    Assignee: DyStar Textilfarben GmbH & Co. Duetschland KG
    Inventor: Uwe Reiher
  • Patent number: 5986087
    Abstract: Sulfonated regenerated cellulose fiber obtained by adding a modifier to a viscose dope or alkali cellulose or cellulose solution and spinning fiber therefrom, wherefor the modifier is a starch etherified with C.sub.2 -C.sub.5 -alkylsulfonic acid radicals and having a degree of substitution of 0.1 to 3, a starch admixed with vinylsulfonic acid or a styrenesulfonic acid, or a polymeric styrenesulfonic acid or polymeric vinylsulfonic acid.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: November 16, 1999
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Andreas Schrell, Bernd Huber
  • Patent number: 5981741
    Abstract: Disclosed are aminated acetate fiber comprising acetylcellulose and one or more water-insoluble quaternary starch ether esters, said starch ether esters containing ester groups of formulae --O--CO--CH.sub.3 and/or --O--CO--C.sub.2 H.sub.5 and ether groups of the general formula I--O--CH.sub.2 --X--CH.sub.2 --N.sup.+ R.sub.3 A.sup.- (I)whereX is a direct bond or --CH(OH)-- andA.sup.- is an anion or one equivalent of an anion, andR is hydrogen, methyl and/or ethyl,and the degree of substitution of said ether group being within the range from 0.002 to 0.8, the degree of substitution of said ester group being within the range from 0.7 to 2.998 and the overall degree of substitution being within the range from 1.5 to 3, its preparation and its use and also quaternary starch ether esters present therein.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: November 9, 1999
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Andreas Schrell, Jimmy G. Welborn
  • Patent number: 5972048
    Abstract: Fiber-reactive triphendioxazine dyes, preparation thereof and use thereof Novel triphenoxazine dyes of the formula (1) ##STR1## where M is hydrogen or an alkali metal, m and n are each 1 or 2 and Y is 2,4,6-trifluoropyrimidinyl or a radical of the formula (3) ##STR2## where Z is fluorine, --NH.sub.2, C.sub.1 -C.sub.4 -alkylamino which may be hydroxy- or sulfo-substituted, N,N-di(C.sub.1 -C.sub.4 -alkyl)amino which may be hydroxy- or sulfo-substituted, phenylamino which may be C.sub.1 -C.sub.4 -alkyl-, C.sub.1 -C.sub.4 -alkoxy-, halogen-, hydroxy-, ureido-, acetylamino-, carboxy-, sulfo- or sulfomethyl-substituted, N-(C.sub.1 -C.sub.4 -alkyl)-N-phenylamino, sulfonaphthylamino, cyanoamino or N-morpholino, are notable for high color strengths, high brilliance and high fastnesses.
    Type: Grant
    Filed: May 27, 1998
    Date of Patent: October 26, 1999
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Uwe Reiher, Hans-Walter Stein
  • Patent number: 5951717
    Abstract: A dyeing process comprises continuous dyeing of cellulosic circular knit, which comprises impregnating a rope of said circular knit with an aqueous liquor comprising one or more dissolved and/or dispersed dyes, any necessary fixing alkali and optionally further assistants at a temperature between 20 and 95.degree. C., squeezing off said impregnated rope and subsequently feeding said squeezed-off rope without intermediary drying into an apparatus in which said rope is opened out into a crease-free state and said dye is fixed in an unsaturated steam/air mixture which is at 100 to 160.degree. C. at an autogenous wet temperature of the moist rope of between 50 and 95.degree. C. and a fixing time of at least 20 seconds.
    Type: Grant
    Filed: March 10, 1998
    Date of Patent: September 14, 1999
    Assignee: DyStar Textilfarben GmbH & Co.
    Inventors: Uwe Mrotzeck, Andreas Schrell, Thomas Nauroschat, Erol Ozcan, Alfred Tressel
  • Patent number: 5944854
    Abstract: According to the invention, a process for the preparation of triphendioxazines systemetrically or asymmetrically amidated on both sides comprises reducing a triphendioxazine chromophore, which is optionally already amidated on one side, to give the leuco form end amidating and re-oxidizing the leuco form. Products amidated on both sides are obtained in this manner with a high yield and product quality. Novel triphendioxazine dyestuffs are furthermore prepared in this manner.
    Type: Grant
    Filed: July 15, 1997
    Date of Patent: August 31, 1999
    Assignee: Dystar Textilfarben GmbH & Co.
    Inventors: Christian Schumacher, Karl-Josef Herd
  • Patent number: 5938796
    Abstract: Cellullosic textile materials are dyed by a pad or spraying process using a solution which contains 5-100 g/l of inorganic polyphosphate and has a pH of 10-13.5.
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: August 17, 1999
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Daniele Negri, Andreas Schrell
  • Patent number: 5931976
    Abstract: The present invention concerns orange dye mixtures of fiber-reactive azo dyes, suitable for dyeing hydroxy- and/or carboxamido-containing material, such as cellulose fibers, like cotton, or wool and nylon, which comprise one or more monoazo dyestuffs corresponding to the general formula (1) and one or more monoazo dyestuffs corresponding to the formula (2) ##STR1## in which D.sub.1 and D.sub.2 are each, independently from one another, a radical of a benzene or naphthalene nucleus, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each, independently from one another, hydrogen, methyl, ethyl, methoxy, ethoxy, sulfo or carboxy, M is hydrogen or an alkali metal and the groups Y.sub.1 --SO.sub.2 -- and Y.sub.2 --SO.sub.2 -- are each fiber reactive groups of the vinylsulfone series.
    Type: Grant
    Filed: August 11, 1998
    Date of Patent: August 3, 1999
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Ronald P. Pedemonte, Werner Russ
  • Patent number: 5931974
    Abstract: A dye mixture comprising one or more disazo dyes composed of 1-amino-3,6-disulfo-8-naphthol as the coupling component and of two diazo components of the aniline series containing each a fiber-reactive group of the vinylsulfone series, one or more monoazo dyes composed of a carboxy-substituted benzoylamino-sulfo-naphthol coupling component and a diazo component of the aniline series, containing a fiber-reactive group of the vinylsulfone series and optionally one or two monoazo dyes with 1-amino-3,6-disulfo-8-naphthol as a coupling component to which is coupled in the ortho-position to the amino group a diazo component of the aniline series substituted by a fiber-reactive group of the vinylsulfone series. The dye mixtures yield on hydroxy- and/or carboxamido-containing fiber materials, such as cellulose fibers, in particular cotton, or on, for example, wool and synthetic polyamide fibers, deep black dyeings.
    Type: Grant
    Filed: July 28, 1998
    Date of Patent: August 3, 1999
    Assignee: Dystar Textilfarben GmbH & Co.
    Inventor: Ronald P. Pedemonte
  • Patent number: 5926269
    Abstract: The invention relates to an ATR spectrometer, containing an optical probe having a sensor made of transparent material and a feed line and an exit line for light, wherein the sensor contains an optical polymer or a mixture of different optical polymers. The probe of the spectrometer according to the invention essentially has the advantages that it is inexpensive and extremely flexible, and that it can be matched to the concentration range of the solution to be examined, which makes it possible to fill the gaps in terms of measurable concentrations between conventional transmission spectroscopy and prior ATR spectroscopy.
    Type: Grant
    Filed: March 13, 1998
    Date of Patent: July 20, 1999
    Assignee: Dystar Textilfarben GmbH & Co.
    Inventors: Andreas Von Der Eltz, Dirk Buchwald, Andreas Brockmeyer, Marion Walter
  • Patent number: 5917121
    Abstract: The present invention relates to the .beta. and .gamma. modifications of the dye of the formula (I) ##STR1## as well as to a process for their preparation and their use for dyeing and printing textile materials of polyester and/or cellulose esters or blended fabrics of these materials and wool or cellulose.
    Type: Grant
    Filed: September 5, 1997
    Date of Patent: June 29, 1999
    Assignees: Dystar Textilfarben GmbH & Co. Deutschland KG, Dystar Japan Ltd.
    Inventors: Ulrich Buhler, Hubert Kruse, Heinz G. Zorn, Klaus-Wilfried Wanken
  • Patent number: 5910624
    Abstract: Disperse Dyestuff Mixtures comprising C.I. Disperse Red 82 of the formula (I) ##STR1## and one or more dyestuffs which differ therefrom, of the formula (II) ##STR2## wherein D denotes the radical of a diazo component of the formula ##STR3## or D denotes the radical of a diazo component from the group consisting of 5,6-dichlorobenzothiazol-2-yl, 6,7-dichlorobenzothiazol-2-yl, 6-nitro-benzothiazol-2-yl or 5-nitrothiazol-2-yl, and the other substituents have the meaning given in the description,are stable to spray-drying and have outstanding use properties, in particular in the dyeing of hydrophobic fiber materials.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: June 8, 1999
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Klaus-Wilfried Wanken, Karl-Ulrich Buhler
  • Patent number: 5856472
    Abstract: Novel aluminum phthalocyanine reactive dyestuffs of the formula (1) ##STR1## in which x is Cl or OH;Z is vinyl or a group of the formula --CH.sub.2 CH.sub.2 --Y, in which Y is a substituent which can be eliminated under alkaline conditions,c is a number from 0.5 to 4;M is a hydrogen, an alkali metal or a substituted or unsubstituted ammonium ion; andR.sup.1 and R.sup.2 independently of one another are hydrogen, substituted or unsubstituted C.sub.1 -C.sub.6 alkyl, a C.sub.1 -C.sub.6 -alkyl which is substituted by one or two radicals of the formulae OH, SO.sub.3 M or OSO.sub.
    Type: Grant
    Filed: June 16, 1997
    Date of Patent: January 5, 1999
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Karl-Josef Herd, Klaus Saitmacher
  • Patent number: 5851239
    Abstract: Process for preparing colored regenerated-cellulose fiber, which comprises adding a formulation comprising a cationized polysaccharide and an anionic dye to a viscose dope, an alkali cellulose or a cellulose solution and spinning fiber by a viscose spinning process or from the cellulose solution.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: December 22, 1998
    Assignee: Dystar Textilfarben GmbH & Co.
    Inventors: Andreas Von Der Eltz, Andreas Schrell
  • Patent number: 5834601
    Abstract: Dyes of the formula (1) indicated and defined below, containing at least one sulfo group, which can be used for dyeing hydroxy and/or carboxamido-containing material, especially fiber material, for example cellulosic fiber materials, wool and synthetic polyamide. ##STR1## in which F is the radical of a dye molecule, n is the number 1 or 2, R.sup.A is hydrogen or substituted or unsubstituted lower alkyl, R.sup.B is hydrogen, unsubstituted or substituted lower alkyl or unsubstituted or substituted phenyl, X is halogen, R is hydrogen, lower alkyl, lower alkoxy halogen or sulfo, and G at the benzene ring forms the radical of a heterocycle which includes at least one carbonylamido group whose N atom can be substituted.
    Type: Grant
    Filed: October 17, 1997
    Date of Patent: November 10, 1998
    Assignee: Dystar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Stefan Ehrenberg, Christian Schumacher
  • Patent number: 5831039
    Abstract: Fiber reactive azo dyes of the Formula (1) ##STR1## wherein the variables are as defined in the specification are useful for the dyeing of hydroxy- and carboxamido-containing materials, especially textile fiber materials, in clear shades with a high degree of fixation.
    Type: Grant
    Filed: April 15, 1998
    Date of Patent: November 3, 1998
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Christian Schumacher
  • Patent number: 5810890
    Abstract: A process for dyeing synthetic polyamide fibers, in particular in form of micro fibers, is described comprising the use of polyamide fibers having an amino end group content of at least 60 gram equivalents per 1000 kilograms of polyamide polymer and using a dye composition of water-soluble dyes containing at least one dye having 1 or 2 vinylsulfonyl groups and at least 1 dye having 1 or 2 groups of the general formula (A)--SO.sub.2 --CH.sub.2 --CH.sub.2 --N(R)--V--X (A)(in which R is hydrogen or alkyl of 1 to 4 carbon atoms which may be interrupted by 1 or 2 hetero groups and substituted by sulfo, carboxy, hydroxy, sulfato, phosphato and/or lower alkanoylamino, V is a covalent bond or alkylene of 2 to 4 carbon atoms or a group of the formula --CO--NH--CH.sub.2 --CH.sub.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: September 22, 1998
    Assignee: Dystar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Werner Hubert Russ, Mike Elliott, Robert Dewhurst, Charles Richard Langrick, David John Marfell