Abstract: The present invention relates to a process for the preparation of benzodithiophene compounds which comprises reacting a derivative of 3,3?-bithiophene with at least one internal alkyne. Said benzodithiophene compounds can be suitably functionalized and polymerized to give electron-donor compounds which can be used in photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both rigid and flexible supports. Furthermore said benzodithiophene compounds can be advantageously used as spectrum converter in luminescent solar concentrators (LSCs). Said benzodithiophene compound can also be advantageously used as precursor of monomeric units in the preparation of semiconductor polymers.
Abstract: A process has been developed for producing diesel boiling range fuel or fuel blending component from renewable feedstocks such as plant oils and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating i.e. decarboxylating and/or hydrodeoxygenating to provide a hydrocarbon fraction useful as a diesel fuel. The hydrocarbon fraction is isomerized to improve cold flow properties. At least one interstage stream of the hydrogenating and deoxygenating reaction zone is heat exchanged with the feed to the isomerization reaction zone, and/or the effluent of the hydrogenating and deoxygenating reaction zone is heat exchanged with the feed to the isomerization reaction zone.
Type:
Grant
Filed:
February 17, 2011
Date of Patent:
October 7, 2014
Assignees:
UOP LLC, ENI S.p.A.
Inventors:
Tom N. Kalnes, John P. Brady, Marco Di Stanislao
Abstract: A catalytic system characterized in that it comprises: a first catalyst, having a hydrogenating function, consisting of solid particles of which at least 95% by volume having an equivalent diameter smaller than 20 ?m, containing one or more sulfides of metals of group VI and/or VIII B, possibly prepared starting from an oil-soluble precursor of the same; and a second catalyst, having a cracking function, consisting of solid particles of which at least 90% by volume having an equivalent diameter larger than 5 ?m and smaller than 5 mm, containing an amorphous silico-aluminate and/or a crystalline silico-aluminate and/or an alumina, the equivalent average diameter of the solid particles of the second catalyst being greater than the equivalent average diameter of the solid particles of the first catalyst.
Type:
Application
Filed:
September 6, 2012
Publication date:
October 2, 2014
Applicant:
Eni, S.P.A.
Inventors:
Daniele Molinari, Giuseppe Bellussi, Alberto Landoni, Paolo Pollesel
Abstract: The invention relates to a process for the production of middle distillates from a paraffinic feedstock that is produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one zeolite that has at least one series of channels of which the opening is defined by a ring with 12 oxygen atoms modified by a) a stage for introducing at least one alkaline cation that belongs to group IA or IIA of the periodic table, b) a stage for treatment of said zeolite in the presence of at least one molecular compound that contains at least one silicon atom, c) at least one stage for partial exchange of said alkaline cations by NH4+ cations such that the remaining content of alkaline cations in the modified zeolite at the end of stage c) is such that the alkaline cation/aluminum molar ratio
Abstract: The present invention relates to a process for selectively removing molybdenum from a solution which contains molybdenum, said process comprising the following steps: bringing the solution to an acid pH lower than or equal to 3, preferably lower than or equal to 2, even more preferably lower than or equal to 0.
Abstract: A method for detecting the geometry of underground fractures comprising: introducing a filling material (14) into an underground fracture (11) to form a pack of filling material (14); transmitting an electromagnetic field into the fracture (11); detecting at least one reflected signal of the electromagnetic field transmitted; and processing the at least one detected signal to reconstruct the geometric and dimensional characteristics of the pack of filling material (14); wherein the electromagnetic field transmitted into the fracture (11) has a frequency comprised in the range of between 30 megahertz and 250 megahertz and in that said filling material is not added with any additives; and a system for implementing the aforementioned method.
Abstract: The present invention relates to a process for the recovery of bitumen from an oil sand comprising the following phases in succession: (a) mixing an oil sand with a diluent capable of reducing the viscosity and density of the bitumen contained in said oil sand, obtaining a first mixture (slurry) comprising diluted bitumen; (b) mixing said slurry with a basic aqueous solution (BAS) possibly containing salts to increase its ionic strength, capable of removing said diluted bitumen from said oil sand containing it, obtaining a second mixture (BAS-slurry) which can be separated into (i) a liquid phase comprising said diluted bitumen, a fraction of oil sand free of the bitumen removed and water; (ii) a sediment comprising the remaining fraction of said oil sand free of the bitumen removed, water and residual hydrocarbons which can be eliminated by subsequent washings; (c) separating a liquid phase comprising said diluted bitumen removed, from said BAS-slurry mixture; (d) recovering, from said liquid phase separated
Type:
Application
Filed:
October 24, 2012
Publication date:
August 28, 2014
Applicant:
ENI S.p.A.
Inventors:
Maria Andrei, Lucilla Del Gaudio, Giulia Luisa Eleonora Bozzano, Andrea Sliepcevich
Abstract: Process for the preparation of a polymer containing benzohetero[1,3]diazole. units which comprises reacting at least one disubstituted benzohetero[1,3]diazole compound with at least one heteroaryl compound. Said polymer can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both a rigid and flexible support. Furthermore, said polymer can be advantageously used in the construction of Organic Thin Film Transistors (OTFTs), or of Organic Field Effect Transistors (OFETs).
Abstract: The present invention relates to a process for the preparation of benzodithiophene compounds which comprises reacting a derivative of 3,3?-bithiophene with at least one internal alkyne. Said benzodithiophene compounds can be suitably functionalized and polymerized to give electron-donor compounds which can be used in photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both rigid and flexible supports. Furthermore said benzodithiophene compounds can be advantageously used as spectrum converter in luminescent solar concentrators (LSCs). Said benzodithiophene compound can also be advantageously used as precursor of monomeric units in the preparation of semiconductor polymers.
Abstract: The present invention relates to a heat exchange system comprising:—a single apparatus (N) having an area immersed in a fluid bath (N2) and a free space (N1) at the head in which a vapour phase is accumulated,—at least one interspace (P) open at both ends, situated inside said apparatus and completely immersed in the fluid bath,—one or more heat exchange surface (s) (6, 7, 8, 9, 10, 11), said system characterized in that it contains all the heat exchange surfaces in a single apparatus and said surfaces are completely immersed in the fluid bath and are fluidly connected to the hot and cold sources, external to said system, through flows of matter. At least one of the heat exchange surfaces (6, 7, 8) is situated inside the interspace and at least another surface (9, 10, 11) is situated in the space between said interspace and the walls of the apparatus.
Type:
Application
Filed:
April 17, 2012
Publication date:
August 21, 2014
Applicant:
Eni S.P.A.
Inventors:
Luca Eugenio Basini, Alfred Joachim Wilhelm
Abstract: The present invention relates to new hybrid, organic-inorganic hybrid silicates and metal-silicates characterized by a crystalline structure containing structural units having formula (a), wherein R is an organic group possibly containing one or more element T selected from Group IIIB, IVB, VB and from transition metals. A process starting from cyclic trisilanes for the preparation of said materials, is also described. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the area of nanotechnology.
Abstract: A compact inertial gas-liquid separator including: a stratification mechanism including a first horizontal pipe and a second pipe having a larger diameter possibly slightly tilted with respect to the horizontal, for example of ?10°, connected to each other by a suitable connection gate; a cylindrical body with a vertical development, on which the stratification mechanism is tangentially inserted, wherein the inertial gas-liquid separation is performed, in whose upper part an arrangement of finishing elements can be optionally inserted for further separation of drops of liquid entrapped in the gaseous stream; two outlets for the liquid stream and for the gaseous stream.
Type:
Grant
Filed:
June 21, 2010
Date of Patent:
August 19, 2014
Assignee:
Eni S.p.A.
Inventors:
Lorenzo Di Berardo, Paolo Andreussi, Alberto Ansiati
Abstract: An autonomous underwater system for environmental monitoring including a multidisciplinary underwater station including onboard instrumentation, at least one autonomous modular underwater vehicle movable inside an area to be monitored along an assigned route, and at least one external instrumental modulus which can be connected to the vehicle, wherein the multidisciplinary underwater station includes a docking area, an interface system, an equipping system for supplying the vehicle with instrumental moduli, and a management system.
Type:
Application
Filed:
May 15, 2012
Publication date:
August 14, 2014
Applicant:
ENI S.p.A.
Inventors:
Francesco Gasparoni, Mauro Favaretto, Tiberio Grasso
Abstract: A method of providing at least one projection (4) on a tubular body (1) of the type required by the oil and gas industry for use in recovery of and transporting of crude oil or gas, namely oil-country-tubular goods (OCTG), said projection (4) having a predetermined form such as a blade, ribbing, or the like stand-off projection, by providing materials capable of being moulded, applying a mould to a tubular (OCTG) body, and moulding said materials using said mould onto said tubular body (1).
Type:
Application
Filed:
December 6, 2013
Publication date:
August 14, 2014
Applicant:
ENI S.p.A.
Inventors:
Richard Ronald BAYNHAM, David Levie, Anatoly Baryshnikov
Abstract: Process for the preparation of a benzohetero[1,3]diazole compound disubstituted with heteroaryl groups which comprises reacting at least one benzohetero[1,3]diazole compound disubstituted with at least one heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of luminescent solar concentrators (LSC). Furthermore, said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both a rigid and flexible support. Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can also be advantageously used as a precursor of monomeric units in the preparation of semiconductor polymers.
Abstract: A process for converting a heavy charge such as a heavy crude oil, a tar from oil sand and a distillation residue, by combining a hydroconversion with catalysts in slurry phase process, a distillation or flash process, and a deasphalting process, wherein the three processes operate on mixed streams consisting of fresh charge and recycled streams.
Type:
Application
Filed:
November 18, 2013
Publication date:
July 17, 2014
Applicant:
ENI S.p.A
Inventors:
Mario MARCHIONNA, Alberto DELBIANCO, Nicoletta PANARITI, Romolo MONTANARI, Sergio ROSI, Sebastiano CORRERA
Abstract: An anchoring and expanding unit comprising an anchoring device (20, 20?) and an expanding device (30, 30?), reciprocally removably constrained, the anchoring device (20, 20?) being of the expandable type, wherein the expanding device (30, 30?) includes a series of expanding means (33a, 33b) which can be extracted and blocked in at least two different operative positions, wherein the expanding means (33a, 33b) protrude radially from the expanding device (30, 30?).
Abstract: An apparatus for measuring a multiphase fluid stream which flows in a pipe (2) comprising: a measuring unit (11), coaxial to the pipe, consisting of an isokinetic sampling device (1) suitably configured for allowing the equidistribution of the flow at the inlet in n channels (6) having an area A, of which m are sampling channels and a flow restriction (13) both equipped with differential pressure measuring means (12, 14), a phase separator (15), connected to the sampling device, measurers and regulation means downstream of said separator. A method in accordance with said apparatus which comprises: the isokinetic sampling of a portion q of the multiphase flow Q at the inlet, measuring the flow-rates of the liquid qL and gas qG of the portion sampled and calculating the liquid and gas flow-rates (QL and Q0) from the sampling sections according to the equations QG=n/tn qG and QL=n/m qL. The method provides isokinetic sampling for portions of flow removed ranging from 5% to 20%.
Abstract: The present invention relates to a risk assessment method and system for the security of an industrial installation of at least one company, wherein the method comprises the following phases: analyzing a first plurality of data for determining an index of potential threats to the security of the industrial installation; analyzing a second plurality of data for determining a vulnerability index for the security of the industrial installation; identifying a security risk value on the basis of the indexes of potential threats and vulnerability determined; the risk assessment method is characterized in that the phase of analyzing the first plurality of data comprises the following phases: receiving at least one piece of information in the form of textual data from at least one information storage unit; effecting a correspondence analysis between the textual data and a plurality of data included in a master database of the at least one company; assigning a first relevance value to the at least one piece of informa