Patents Assigned to ENI
  • Patent number: 7235113
    Abstract: Use of a liquid oxygenated product with a cetane number higher than 50, consisting of one or more compounds selected from dialkyl-polyformals represented by the formula RO(CH2O)mR wherein R is an alkyl chain CnH2n+1, m is an integer equal to or higher than 2, n is an integer between 1 and 10, as a substitute of gas oil in diesel engines.
    Type: Grant
    Filed: November 20, 2003
    Date of Patent: June 26, 2007
    Assignees: ENI S.p.A., Snamprogetti S.p.A.
    Inventors: Domenico Sanfilippo, Renata Patrini, Mario Marchionna
  • Publication number: 20070135527
    Abstract: Process for the running of a reactor in which reactions take place in multiphase systems, wherein a gaseous phase prevalently consisting of CO and H2 is bubbled into a suspension of a solid in the form of particles (catalyst) in a liquid (prevalently reaction product), according to the Fischer-Tropsch technology.
    Type: Application
    Filed: September 17, 2004
    Publication date: June 14, 2007
    Applicants: ENI S.p.A, INSTITUT FRANCAIS DU PETROLE, ENITECNOLOGIE S.p.A.
    Inventors: Cristina Maretto, Giovanni Pederzani
  • Publication number: 20070131414
    Abstract: A centralizer for an oil well drill casing including at least one strip of ceramic or plastic material applied onto an outer wall of the casing.
    Type: Application
    Filed: February 12, 2007
    Publication date: June 14, 2007
    Applicant: ENI S.p.A.
    Inventors: Angelo CALDERONI, Fabrizio Zausa
  • Patent number: 7220349
    Abstract: The invention concerns a process for producing middle distillates from an effluent produced by a Fischer-Tropsch unit, comprising optional fractionation to obtain at least one heavy fraction with an initial boiling point in the range 120-200° C., said heavy fraction or said effluent optionally being hydrotreated, then bringing it into contact with a first amorphous hydrocracking/hydroisomerization catalyst that contains at least one noble group VIII metal, the effluent obtained is distilled, then the residual fraction boiling above the middle distillates and/or a portion of the middle distillates is brought into contact with a second amorphous hydrocracking/hydroisomerization catalyst containing at least one noble group VIII metal. The invention also concerns a unit.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: May 22, 2007
    Assignees: Institut Francais du Petrole, AGIP Petroli S.p.A., ENI S.p.A., EniTecnolgie SpA
    Inventors: Eric Benazzi, Christophe Gueret
  • Publication number: 20070105962
    Abstract: Partial oxidation process of liquid fuels, selected from hydrocarbon and/or oxygenated compounds, together with gaseous fuels, selected from hydrocarbon compounds, natural gas and LPG, by means of a suitable catalytic system comprising the following steps: premixing the reagents and possibly heating them to temperatures ranging from 25 to 400° C., said reagents consisting of said liquid fuels, said gaseous fuels and oxygen or air or oxygen enriched air, optionally in the presence of vapour and/or CO2; reacting the mixture of reagents in the catalytic zone, at inlet temperatures ranging from 50 to 500° C. and space velocities ranging from 1,000 to 1,000,000 Nl reagents/L cat×h, reaching temperatures ranging from 450 to 1350° C.
    Type: Application
    Filed: September 9, 2004
    Publication date: May 10, 2007
    Applicants: ENI S.p.A., Enitecnologie S.p.A.
    Inventors: Luca Basini, Andrea Bartolini, Giancarlo Lupi, Gabriele Clerici
  • Patent number: 7195730
    Abstract: Method for the centralization of drill casings in a tight borehole, both vertical and deviated, comprising the following operations: Application on the casing section in question, of an adherence strip equipped with one or more housings and rapid adjustable lever closure; Insertion of suitable molds in the housings of which the strip is equipped; Injection into the molds of plastic material characterized by a high mechanical resistance, a high degree of surface adhesion and resistance to abrasion by friction, and also in-place elasticity, higher than the elasticity of the casings; Removal of the adherence strip once the hardening of the plastic material in the shape of the mold, has been completed.
    Type: Grant
    Filed: November 15, 2001
    Date of Patent: March 27, 2007
    Assignee: ENI S.p.A.
    Inventors: Angelo Calderoni, Fabrizio Zausa
  • Publication number: 20070066690
    Abstract: Process for the charging of a catalyst and for the running of a reactor in which reactions take place in multiphase systems, wherein a gaseous phase prevalently consisting of CO and H2 is bubbled into a suspension of a solid in the form of particles (catalyst) in a liquid (prevalently reaction product), according to the Fischer-Tropsch technology.
    Type: Application
    Filed: September 17, 2004
    Publication date: March 22, 2007
    Applicants: ENI S.p.A., INSTITUT FRANCAIS DU PETRROLE, ENITECHNOLOGIE S.p.A.
    Inventors: Cristina Maretto, Giovanni Pederzani
  • Publication number: 20070066855
    Abstract: Process for the production of dimethyl ether and the co-production of H2O, starting from methanol, substantially comprising a dehydration reaction of methanol carried out in a reactive distillation column with a packing of the re-active, structured and distillation type.
    Type: Application
    Filed: September 14, 2006
    Publication date: March 22, 2007
    Applicant: ENI S.p.A.
    Inventors: Alberto Malandrino, Marco Di Stanislao, Giuseppe Bellussi, Stefano Rossini
  • Patent number: 7188673
    Abstract: A process is described for reducing the production of water in oil wells which comprises the injection into the formation around the well of an aqueous solution of one or more polymers selected from those having general formula (I), wherein: n ranges from 0.70 to 0.98; m ranges from 0.30 to 0.02; n+m=1; X1 and X2, the same or different, are selected from H and CH3; R1, R2, R3, the same or different, are selected from C1–C10 monofunctional hydrocarbyl groups; and x ranges from 2 to 5.
    Type: Grant
    Filed: March 14, 2006
    Date of Patent: March 13, 2007
    Assignees: Eni S.p.A., Enitechnologie S.p.A.
    Inventors: Luisa Chiappa, Maria Andrei, Thomas Paul Lockhart, Giovanni Burrafato, Giuseppe Maddinelli
  • Publication number: 20070048087
    Abstract: Process for the disposal of sulfur in the liquid state which comprises: a) transforming elemental sulfur into sulfanes having the general formula H2Sn+1, wherein n is a number from 1 to 7; b) optionally mixing elemental sulfur in powder form with the liquid sulfanes, up to such a concentration as to guarantee the pumpability of the mixture; c) injecting the sulfanes liquid at room temperature into geological formations having a temperature lower than 150° C.
    Type: Application
    Filed: July 6, 2004
    Publication date: March 1, 2007
    Applicants: ENI S.P.A., ENITECHNOLOGIE S.P.A.
    Inventors: Alberto De Angelis, Paolo Pollesel, Giuseppe Bellussi, Thomas Lockhart
  • Publication number: 20070042899
    Abstract: The present invention regards a catalytic composition comprising gallium, at least one element chosen in the group of the lanthanides, and a zeolite belonging to the MFI, MEL or MFI/MEL families, the crystal lattice of which is made up of silicon oxide and at least one metal oxide chosen from among aluminum oxide, boron oxide and gallium oxide. Preferably, in the catalytic compositions of the present invention a zeolite is used belonging to the MFI family characterized by crystallites which for at least 90% have diameters smaller than 500 ? and which can form agglomerates of submicron dimensions characterized by possessing at least 30% of the extrazeolitic porosity in the region of the mesopores. The catalytic compositions of the present invention can, in addition, contain rhenium. These catalytic compositions are useful in processes of aromatization of hydrocarbons containing from 3 to 6 carbon atoms, preferably, hydrocarbon mixtures containing olefins.
    Type: Application
    Filed: October 24, 2006
    Publication date: February 22, 2007
    Applicants: ENI S.p.A., ENICHEM S.p.A., ENITECHNOLOGIE S.p.A.
    Inventors: Angela Carati, Marco Tagliabue, Carlo Perego, Roberto Millini, Stefano Amarilli, Giuseppe Terzoni
  • Patent number: 7164052
    Abstract: Aromatic hydrocarbon compounds are produced by a process of contacting one or more aliphatic hydrocarbons containing from 3 to 6 carbon atoms with a catalytic composition comprising (i) gallium, (ii) at least one lanthanide element, and (iii) a zeolite selected from the group consisting of the MIF family of zeolites, the crystal lattice of which consists of silicon oxide and aluminum oxide in a molar ratio of silicon oxide to aluminum oxide which is greater than 20 and less than 500, and is comprised of crystallites, at least 90% of which have diameters smaller than 500 ?.
    Type: Grant
    Filed: February 13, 2004
    Date of Patent: January 16, 2007
    Assignees: ENI S.p.A., Enichem S.p.A., Enitecnologie S.p.A.
    Inventors: Angela Carati, Marco Tagliabue, Carlo Perego, Roberto Millini, Stefano Amarilli, Giuseppe Terzoni
  • Publication number: 20070010395
    Abstract: Amorphous porous solid of an acidic nature, with a controlled pore size, essentially consisting of a mixed oxide of silicon, aluminum and phosphorous, having a surface area of at least 200 m2/g, which can be used as a catalyst or active carrier of a catalyst for various industrial processes, such as, for example, alkylation, isomerization, hydro-dehydrogenation processes, with an improved activity and selectivity with respect to the traditional amorphous silica-alumina gels.
    Type: Application
    Filed: June 25, 2004
    Publication date: January 11, 2007
    Applicants: ENI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Vincenzo Calemma, Cristina Flego, Luciano Carluccio, Roberto Millini
  • Patent number: 7156978
    Abstract: A system comprising: a paraffin feed produced by the Fischer-Tropsch process is fractionable into at least three fractions: an intermediate fraction boiling between T1 and T2, T1 being in the range 120–200° C. and T2 being more than 300° C. and less than 410° C., a light fraction boiling below it and a heavy fraction boiling above it; at least a portion of the intermediate fraction is hydrotreated then at least a portion thereof is passed over an amorphous hydroisomerisation/hydrocracking catalyst; the heavy fraction is passed over an amorphous hydroisomerisation/hydrocracking catalyst with a conversion of 370° C.+ products into 370° C.? products of more than 80% by weight; the hydrocracked/hydroisomerised fractions are distilled to obtain middle distillates (kerosine, gas oil).
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: January 2, 2007
    Assignees: Institut Francais du Petrole, AGIP Petroli S.p.A., ENI S.p.A., EniTecnolgie SpA
    Inventors: Eric Benazzi, Christophe Gueret
  • Publication number: 20060278434
    Abstract: A device and the relative procedure are described, for the insertion of a new drilling string-element into a drilling-string essentially consisting of a short pipe-shaped body (C) having, at its ends, means suitable for screwing it onto drill pipes, in which two valves are housed, of which one (A) is radial to said short body, interceptable from the outside by means of an adaptor and equipped with a suitable safety plug, the other (B) axial to said body.
    Type: Application
    Filed: June 9, 2006
    Publication date: December 14, 2006
    Applicant: ENI S.p.A.
    Inventors: Angelo Calderoni, Giorgio Girola
  • Publication number: 20060272982
    Abstract: Process for the conversion of heavy charge stocks selected from heavy and extra-heavy crude oils, distillation residues, heavy oils from catalytic treatment, thermal tars, bitumens from oil sands, carbons of different origins and other high boiling charges of a hydrocarbon origin known as “black oils”, by means of the combined used of at least the three following process units: solvent deasphalting (SDA), hydroconversion with slurry phase catalysts (HT), distillation or flash (D), characterized in that it comprises the following steps: sending the heavy charge stock to a deasphalting section (SDA) in the presence of solvents, obtaining two streams, one consisting of deasphalted oil (DAO), the other containing asphaltenes; mixing the stream consisting of deasphalted oil (DAO) with a suitable hydrogenation catalyst precursor and sending the mix obtained to a hydrotreating reactor (HT), introducing, into the same reactor, hydrogen or a mix containing hydrogen and H2S; sending the stream containing the product
    Type: Application
    Filed: December 20, 2005
    Publication date: December 7, 2006
    Applicants: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Romolo Montanari, Mario Marchionna, Sergio Rosi, Nicoletta Panariti, Alberto Delbianco
  • Patent number: 7144559
    Abstract: Installation for chemical conversion of a feedstock by Fischer-Tropsch reaction comprising a reactor that contains a slurry constituted by at least one suspension of at least one solid in a liquid, a gas feed, a circuit, external to the reactor, of continuous circulation of a stream of slurry, whereby said slurry is drawn off at least one point (A) and reintroduced at least in part at least one other point (B), a section for separation of at least one slurry fluid that passes through said external circuit, whereby said installation also comprises: means allowing to shut down the circulation of said slurry in said circuit, means for introducing under pressure at least one fluid for purging the slurry that is contained in the circuit, and means allowing the circulation of the slurry in said external circuit under conditions such that the Reynolds number is greater than 2,500.
    Type: Grant
    Filed: June 25, 2002
    Date of Patent: December 5, 2006
    Assignees: Institut Francais du Petrole, AGIP Petroli S.p.A, ENI S.p.A. division de AGIP
    Inventors: Jean-Marc Schweitzer, Eric Lenglet, Franck Gaviot-Blanc
  • Patent number: 7144924
    Abstract: Hydrocarbons are prepared, liquid at the reaction temperature, by feeding synthesis gas into three-phase turbulent reactors in which the solid phase, consisting of the catalyst in the form of particles, is kept in suspension in the liquid phase by the rising synthesis gas. The reaction product is separated/filtered in continuous from the catalyst dispersed therein by means of at least one filtration device consisting of a hydrocyclone over which there is a first hollow metal element in which a second hollow element is situated, coaxial with the first, made of a material having a porous structure, with an average pore diameter ranging from 0.002 to 0.1 micrometers, suitable for micro/ultrafiltration.
    Type: Grant
    Filed: June 18, 2004
    Date of Patent: December 5, 2006
    Assignees: ENI S.p.A., Institut Francais du Petrole, Enitechnologie S.p.A.
    Inventors: Gabriele Carlo Ettore Clerici, Giuseppe Belmonte
  • Patent number: 7128169
    Abstract: Method for the removal and recovery of the oily component from cuttings coming from the drilling of oil wells by treatment of the cuttings with a solvent, which can be compressed to the liquid state, at a pressure value ranging from 45 to 80 bar and a temperature corresponding to the saturation value.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: October 31, 2006
    Assignees: ENI S.p.A., Enitecnologie S.p.A.
    Inventors: Felicia Massetti, Alessandro Nardella, Raffaele Tomaciello, Alberto Guarneri
  • Publication number: 20060231460
    Abstract: Process for the contemporaneous production of fuels and lubricating bases from synthetic paraffinic mixtures, which includes a hydrocracking step in the presence of a solid bi-functional catalyst comprising: (A) a support of an acidic nature consisting of a catalytically active porous solid, including silicon, aluminum, phosphorus and oxygen bonded to one another in such a way as to form a mixed amorphous solid characterized by an Si/Al atomic ratio of between 15 and 250, a P/Al ratio of at least 0.1, but lower than 5, a total pore volume ranging from 0.5 to 2.0 ml/g, with an average pore diameter ranging from 3 nm. to 40 nm, and a specific surface area ranging from 200 to 1000 M2/g; (B) at least one metal with a hydro-dehydrogenating activity selected from groups 6 to 10 of the periodic table of elements, dispersed on said support (A) in an amount of between 0.05 and 5% by weight with respect to the total weight of the catalyst.
    Type: Application
    Filed: June 28, 2004
    Publication date: October 19, 2006
    Applicants: ENI S.p.A, INSTITUT FRANCAIS DU PETROLE
    Inventors: Vincenzo Calemma, Cristina Flego, Luciano Carluccio, Wallace Parker, Roberto Giardino, Giovanni Faraci