Abstract: A method of processing a semiconductor assembly is presented. The method includes fabricating a photovoltaic module including a semiconductor assembly. The fabrication step includes performing an efficiency enhancement treatment on the semiconductor assembly, wherein the efficiency enhancement treatment includes light soaking the semiconductor assembly, and heating the semiconductor assembly. The semiconductor assembly includes a window layer having an average thickness less than about 80 nanometers, wherein the window layer includes cadmium and sulfur. A related system is also presented.
Type:
Grant
Filed:
February 11, 2016
Date of Patent:
November 8, 2016
Assignee:
FIRST SOLAR, INC.
Inventors:
Bastiaan Arie Korevaar, Jinbo Cao, Adam Fraser Halverson, Scott Daniel Feldman-Peabody, Mark Jeffrey Pavol, Douglas Garth Jensen
Abstract: An improved feeder system and method for continuous vapor transport deposition that includes at least two vaporizers couple to a common distributor through an improved seal for separately vaporizing and collecting at least any two vaporizable materials for deposition as a material layer on a substrate. Multiple vaporizer provide redundancy and allow for continuous deposition during vaporizer maintenance and repair.
Abstract: A method to improve CdTe-based photovoltaic device efficiency is disclosed, the method including steps for removing surface contaminants from a semiconductor absorber layer prior to the deposition or formation of a back contact layer on the semiconductor absorber layer, the surface contaminants removed using at least one of a dry etching process and a wet etching process.
Type:
Grant
Filed:
March 14, 2014
Date of Patent:
September 20, 2016
Assignee:
First Solar, Inc.
Inventors:
Scott Christensen, Pawel Mrozek, Gang Xiong, San Yu
Abstract: One aspect of the present invention includes method of making a photovoltaic device. The method includes disposing an absorber layer on a window layer, wherein the absorber layer includes a first region and a second region. The method includes disposing the first region adjacent to the window layer in a first environment including oxygen at a first partial pressure; and disposing the second region on the first region in a second environment including oxygen at a second partial pressure, wherein the first partial pressure is greater than the second partial pressure. One aspect of the present invention includes a photovoltaic device.
Type:
Grant
Filed:
June 21, 2011
Date of Patent:
September 20, 2016
Assignee:
First Solar, Inc.
Inventors:
James Neil Johnson, Bastiaan Arie Korevaar, Yu Zhao
Abstract: A completed photovoltaic device and method forming it are described in which fluxing of a window layer into an absorber layer is mitigated by the presence of a sacrificial fluxing layer.
Type:
Grant
Filed:
March 13, 2014
Date of Patent:
September 6, 2016
Assignee:
FIRST SOLAR, INC.
Inventors:
Daniel Damjanovic, Rick C. Powell, Jigish Trivedi, Zhibo Zhao
Abstract: Embodiments provided herein describe methods for forming cadmium-manganese-telluride (CMT), such as for use in photovoltaic devices. A substrate including a material with a zinc blend crystalline structure is provided. CMT is formed above the substrate. During the formation of the CMT, cation-rich processing conditions are maintained. The resulting CMT may be more readily provided with p-type dopants when compared to conventionally-formed CMT.
Type:
Grant
Filed:
December 26, 2013
Date of Patent:
August 30, 2016
Assignee:
First Solar, Inc.
Inventors:
Sergey Barabash, Amir Bayati, Dipankar Pramanik, Zhi-Wen Sun
Abstract: An apparatus and related process are provided for vapor deposition of a sublimated source material as a thin film on a photovoltaic (PV) module substrate. A deposition head is configured for sublimating a source material supplied thereto. The sublimated source material condenses onto a transport conveyor disposed below the deposition head. A substrate conveyor is disposed below the transport conveyor and conveys substrates in a conveyance path through the apparatus such that an upper surface of the substrates is opposite from and spaced below a lower leg of the transport conveyor. A heat source is configured adjacent the lower leg of the transport conveyor. The source material plated onto the transport conveyor is sublimated along the lower leg and condenses onto to the upper surface of substrates conveyed by the substrate conveyor.
Abstract: A photovoltaic device with a low-resistance stable electrical back contact is disclosed. The photovoltaic device can have a CuTex or CuTexNy layer.
Type:
Grant
Filed:
August 22, 2011
Date of Patent:
August 9, 2016
Assignee:
First Solar, Inc.
Inventors:
Pratima V. Addepalli, Sreenivas Jayaraman, Oleh P. Karpenko
Abstract: A support system for a solar panel includes a triangular truss with connection points for mounting a photovoltaic module, and a cradle structure that supports the triangular truss and is connected to at least two side supports of the triangular truss. The cradle structure may be driven for rotation about an axis for tracking the sun and several cradle structures can be linked together for tracking movement using a buried linkage system. The truss may also be foldable for ease of transportation and storage.
Abstract: A method to improve operation of a CdTe-based photovoltaic device is disclosed, the method comprising the steps of depositing a semiconductor absorber layer adjacent to a substrate, depositing a semiconductor buffer layer adjacent to the semiconductor layer, and annealing at least one of the semiconductor absorber layer and the semiconductor buffer layer with one of a laser and a flash lamp.
Type:
Grant
Filed:
June 27, 2014
Date of Patent:
August 2, 2016
Assignee:
First Solar, Inc.
Inventors:
Pratima Addepalli, Benyamin Buller, Markus Gloeckler, Akhlesh Gupta, David Hwang, Andrei Los, Rick Powell, Rui Shao, Gang Xiong, Ming Lun Yu, San Yu, Zhibo Zhao
Abstract: A method and apparatus provide for a roughened back surface of a semiconductor absorber layer of a photovoltaic device to improve adhesion. The roughened back surface may be achieved through an etching process.
Type:
Grant
Filed:
September 11, 2012
Date of Patent:
July 19, 2016
Assignee:
FIRST SOLAR, INC.
Inventors:
Jianjun Wang, Oleh P. Karpenko, Thomas A. Sorenson
Abstract: A support structure for orienting and supporting at least one solar panel includes a lock rail and a support rail that are engaged together through a locking mount. The locking mount has a retaining pin that permits the locking rail to be connected to the support rail without tools. The locking mount may provide a permanent or a releasable connection that retains the solar panel to the support structure.
Type:
Grant
Filed:
March 14, 2014
Date of Patent:
July 19, 2016
Assignee:
First Solar, Inc.
Inventors:
Joshua Conley, Thomas Truman, Eddie Bugg
Abstract: Disclosed embodiments provide laser object marking methods and devices in which multiple slidable mechanisms are used for holding respective laser heads.
Abstract: A method of measuring vapor flux density including directing a light beam through a vapor flux to a pixel array sensor and using the pixel array sensor to measure attenuation of the light beam.
Type:
Grant
Filed:
December 26, 2013
Date of Patent:
July 5, 2016
Assignee:
First Solar, Inc.
Inventors:
Markus E. Beck, Ulrich A. Bonne, Raffi Garabedian, Erel Milshtein, Ming Lun Yu
Abstract: Methods for treating a semiconductor layer including a semiconductor material are presented. A method includes contacting at least a portion of the semiconductor material with a passivating agent. The method further includes forming a first region in the semiconductor layer by introducing a dopant into the semiconductor material; and forming a chalcogen-rich region. The method further includes forming a second region in the semiconductor layer, the second region including a dopant, wherein an average atomic concentration of the dopant in the second region is greater than an average atomic concentration of the dopant in the first region. Photovoltaic devices are also presented.
Type:
Application
Filed:
March 1, 2016
Publication date:
June 23, 2016
Applicant:
First Solar, Inc.
Inventors:
Donald Franklin Foust, Hongbo Cao, Laura Anne Clark, Robert Andrew Garber, Scott Daniel Feldman-Peabody, Wyatt Keith Metzger, Yinghui Shan, Roman Shuba
Abstract: Methods for treating a semiconductor material, and for making devices containing a semiconducting material, are presented. One embodiment is a method for treating a semiconductor material that includes a chalcogenide. The method comprises contacting at least a portion of the semiconductor material with a chemical agent. The chemical agent comprises a solvent, and an iodophor dissolved in the solvent.
Abstract: An improved feeder system and method for a vapor transport deposition system that includes a carrier gas bypass flow line to allow for continuous carrier gas flow to a vaporizer unit when a vibratory unit which supplies powdered material and carrier gas to the vaporizer unit is out of service. A process gas flow line to the vibratory unit may be included when the powdered material contains a powdered dopant in the material mix.