Abstract: Propylene is polymerized with an improved titanium chloride catalyst. The improved titanium chloride catalyst is prepared by treating TiCl.sub.4 with an aluminum alkyl and treating the resulting titanium chloride catalyst with carbon dioxide and a Lewis base, such as di(n-butyl) ether in a hydrocarbon medium at an elevated temperature.
Abstract: A novel class of compounds which are useful as plant growth regulators is disclosed, having the general structural formula: ##STR1## in which R.sup.1 is: C.sub.1 to C.sub.4 alkyl, nitro or halo and n is zero or an integer from 1 to 4R.sup.2 and R.sup.3 are: H or C.sub.1 to C.sub.4 alkyl, or benzyl andAr is: adamantyl, C.sub.3 to C.sub.4 alkyl or alkenyl, benzyl, halobenzyl, naphthyl, phenyl or phenyl bearing thereon from one to three of the substituents: cyano, benzyloxy, nitro, bromo, chloro, trifluoromethyl and C.sub.1 to C.sub.4 alkyl, alkenyl, alkoxy, alkylthio and alkyl-substituted amino.
Abstract: Hot melt adhesive compositions are provided which contain (a) about 10-30 weight % of an alkenyl succinic anhydride, (b) about 20-60 weight % of an ethylene copolymer, and (c) about 10-40 weight % of a tackifying resin which is a rosin ester.
Type:
Grant
Filed:
January 29, 1981
Date of Patent:
April 20, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Vikramkumar Acharya, Pallavoor R. Lakshmanan
Abstract: Intimate fusion blends of 100 parts of an ionomer resin and about 5 to 900 parts of an alkenyl succinic anhydride (the alkenyl group containing about 16 to 52 carbon atoms) are provided. The compositions can be heated with aqueous alkaline solutions to form stable dispersions useful as coating compositions.
Abstract: Hot melt adhesive compositions are provided which contain (a) about 10-30 weight % of an alkenyl succinic anhydride, (b) abut 20-60 weight % of an ethylene copolymer, and (c) about 10-40 weight % of a tackifying resin which is a terpene-phenolic resin.
Type:
Grant
Filed:
January 28, 1981
Date of Patent:
April 13, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Vikramkumar Acharya, Pallavoor R. Lakshmanan
Abstract: Conversion of raw coal to distillate liquid and gaseous hydrocarbon products by solvent liquefaction in the presence of molecular hydrogen employing recycle of mineral residue is commonly performed at a higher thermal efficiency than conversion of coal to pipeline gas in a gasification process employing partial oxidation and methanation reactions. The prior art has disclosed a combination coal liquefaction-gasification plant employing recycle of mineral residue to the liquefaction zone wherein all the normally solid dissolved coal not converted to liquid or gaseous products in the liquefaction zone is passed to a gasification zone for conversion to hydrogen. In the prior art plant the amount of normally solid dissolved coal passed to the gasification zone is just sufficient to enable the gasification zone to produce the entire process hydrogen requirement.
Abstract: A novel class of compounds which are useful as plant growth regulators has the general structural formula ##STR1## in which R is H or CH.sub.3, R' is halogen, trifluoromethyl, cyano or C.sub.1 to C.sub.3 alkyl or alkoxy and n is zero or an integer from 1 to 2.The compounds are synthesized by reacting a compound of the formula ##STR2## with an isocyanate of the formula ##STR3## under basic conditions in a non-reactive, polar organic solvent.
Abstract: Ethylene or propylene polymers are dyed by dispersing a small quantity of a copolymer of a C-14 or higher alpha-olefin and maleic anhydride therein and subsequently treating the composition with an aqueous solution of a basic dye stuff such as Malachite Green.
Abstract: Improved ethylene polymer fibrils are provided which are characterized in having:(a) a melt temperature of at least about 137.degree. C.,(b) a molecular weight of at least 250,000,(c) at least about 1.2 weight % of polyvinyl alcohol sorbed thereon, and(d) a zero-span breaking length of at least about 25,000.
Type:
Grant
Filed:
December 12, 1980
Date of Patent:
March 16, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Jin K. Kim, Clarence R. Murphy, Edward W. Smith
Abstract: Hot melt adhesive compositions are provided which contain (a) about 10-30 weight % of an alkenyl succinic anhydride, (b) about 20-60 weight % of an ethylene copolymer, and (c) about 10-40 weight % of a tackifying resin which is a terpene-urethane resin.
Type:
Grant
Filed:
January 28, 1981
Date of Patent:
March 16, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Vikramkumar Acharya, Pallavoor R. Lakshmanan
Abstract: A class of novel compounds is disclosed which has utility as plant growth regulators, having the general formula: ##STR1## in which X is O or S,Y is one of the group: ##STR2## R is H or CH.sub.3, Q is phenyl or chlorophenyl whenQ' is hydrogen, or Q and Q' together may form the remainder of a benzene ring.
Type:
Grant
Filed:
August 14, 1980
Date of Patent:
March 9, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Loren W. Hedrich, Natu R. Patel, Joel L. Kirkpatrick
Abstract: A novel class of growth regulator compounds of the structural formula ##STR1## is disclosed, in which Y is --COOH or an agriculturally acceptable salt thereof, --COOR, --CH.sub.2 OH, --CHO, --R, --OR or halogen and R is C.sub.1 to C.sub.4 alkyl or alkenyl.
Abstract: Improved anaerobic adhesives are provided which contain two monomer types. The first is a polyacrylate terminated ester of 3,4,3',4'-benzophenone tetracarboxylic acid. The second is an acrylate terminated urethane prepolymer that is prepared in part from abietyl alcohol.
Type:
Grant
Filed:
June 20, 1980
Date of Patent:
January 5, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Thomas F. Huemmer, Pallavoor R. Lakshmanan
Abstract: Acrylate monomers useful as a component of U.V. curable resin compositions and anaerobic adhesive compositions are provided and have the structure: ##STR1## where the phenanthrene ring contains up to three (3) double bonds, where R.sub.1 is a divalent radical, where R.sub.2 is a divalent radical, and where R.sub.3 is a hydrogen atom or an alkyl group.
Type:
Grant
Filed:
June 20, 1980
Date of Patent:
January 5, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Thomas F. Huemmer, Pallavoor R. Lakshmanan
Abstract: Compounds of the general structural formula, ##STR1## in which R.sup.1 is C.sub.1 to C.sub.4 lower alkyl, cycloalkyl or alkylamino and R.sup.2 is H or lower N-alkylcarbamyl are made from corresponding m-aminophenylacetylenic compounds by conventional methods and are useful as selective herbicides.
Abstract: A group of heat curable resins are provided which have good physical properties, which properties are retained to a surprising degree after prolonged exposure to temperatures as high as 300.degree. C. The products are acetylene end-capped esterimides having the structure: ##STR1## where R is an arylene group or a group having the structure: ##STR2## where X is ##STR3## R.sub.1 is an alkyl group containing 1 or 2 carbon atoms and R.sub.2 is hydrogen or an alkyl group containing 1 or 2 carbon atoms; and where R' is a phenylene group.
Abstract: The products of the invention are partial acetylene end-capped oligomers which have the structure as shown in FIG. 3 in which terminal R" group is derived from a mixture consisting of about 14-40 mol % of an aromatic monoamine and the balance an acetylene substituted aromatic monoamine. The products are prepared from either of two (2) precursors. The first precursor has the structure shown in FIG. 2. The second precursor is a complex amine salt having the structure shown in FIG. 5.
Type:
Grant
Filed:
May 3, 1979
Date of Patent:
November 10, 1981
Assignee:
Gulf Oil Corporation
Inventors:
Patricia A. Antonoplos, William J. Heilman
Abstract: A method of regulating the growth of plants, including combating unwanted vegetation, comprises applying to the plants, either on seed, the soil or directly on the plants an effective amount of a novel compound of the class having the general structural formula ##STR1## in which one of Q.sub.1, Q.sub.2, Q.sub.3 or Q.sub.4 is N, X is --OH or --O--(C.sub.1 -C.sub.4 alkyl) and Y is H or X and Y together represent a bond between carbon and nitrogen atoms and R is H or one or two of the following substituents: --Br, --Cl, --F, --I, --CF.sub.3, --CH.sub.3, --NO.sub.2 or --C.tbd.N, or an agriculturally acceptable salt thereof.
Type:
Grant
Filed:
January 23, 1981
Date of Patent:
September 29, 1981
Assignee:
Gulf Oil Corporation
Inventors:
Jerry L. Rutter, Charles G. Gibbs, Loren W. Hedrich
Abstract: The products of the invention are vinyl end-capped oligomers which are prepared from 2,4-bis (p-aminobenzyl) aniline and a vinyl substituted aromatic monoamine, the principal component of which is the compound whose structure is shown in FIG. 3. The products are prepared from either of two (2) precursors. The first precursor is a compound whose structure is shown in FIG. 2 and which is prepared from 2,4-bis (p-aminobenzyl) aniline, a dianhydride of an aromatic tetracarboxylic acid such as 3,3'4,4'-benzophenonetetracarboxylic acid (BTDA) and a vinyl substituted aromatic monoamine, such as 3-aminophenyl-ethylene (APE). The second precursor is a complex amine salt having the structure shown in FIG. 6 and which is prepared from 2,4-bis-(p-aminobenzyl) aniline, a dialkyl ester of BTDA and APE.