Abstract: A multicomponent product container includes two separate component compartments covered by a common pouring cap, individual pouring openings for the first and second components contained in the compartments, respectively, offset from one another relative to the longitudinal axis of the container and opening in the plane of an outer surface provided in said cap. The pouring openings are each juxtaposed in the pouring direction necessary to dispense the first and second components, by an individual pouring edge, which both rises beyond the outer surface of the cap, and projects beyond the associated pouring opening in the lateral or peripheral direction. Each pouring edge is shaped for providing in the tilted position of the container necessary for pouring via gravity said first and second components from said pouring openings, a sink formed in the region of the associated pouring opening.
Type:
Grant
Filed:
May 18, 1989
Date of Patent:
February 19, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Horst Bertram, Bernhard Bongers, Herbert Buecheler, Peter Kittscher
Abstract: Novel compounds with structures corresponding to the formula: ##STR1## in which n=0 or 1 and R.sup.1 is hydrogen, a C.sub.1 -C.sub.4 alkyl or hydroxyalkyl group, or an amino group, and salts of such compounds, are superior to previously known couplers for oxidation hair dyes to produce a variety of colors, especially reds, when used with standard developer components. With 2,4,5,6-tetraaminopyrimidine developer for example, these novel compounds produce red to brown hair colors and, with p-tolylenediamine developer, red to blue-violet hair colors.
Abstract: A heat-stable binder for use in the vulcanization of natural or synthetic rubber mixtures onto metallic or other substrates, comprising a mixture which is free from oxidizing agents that oxidize quinone dioxime and which contains chlorinated rubber, after-brominated dichloropolybutadiene, and quinone dioxime.
Abstract: In the cleaning and disinfection of endoscopes, the endoscope surfaces to be cleaned are successively(a) brought into contact with a cleaning solution which is heated to 55.degree. to 65.degree. C., kept at that temperature for 1 to 15 minutes and then drained off and which contains a low-foam nonionic surfactant, a proteolytic enzyme, at least one complexing agent and, optionally, other standard detergent constituents, and has a pH value of from 6 to 8;(b) brought into contact with a disinfectant solution which is heated to 55.degree. to 65.degree. C., kept at that temperature for 1 to 15 minutes and then separated off and which contains an aldehyde selected from the group consisting of formaldehyde and aliphatic C.sub.2 -C.sub.8 dialdehydes and at least one complexing agent, and has a pH value of from 6 to 8;(c) washed at least twice with water of which the pH value is adjusted to ph 6-8, the water being heated to 55.degree. to 65.degree. C.
Type:
Grant
Filed:
July 26, 1988
Date of Patent:
February 19, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Karlheinz Disch, Klaus Hachmann, Klaus Bansemir
Abstract: Isomeric formyl trimethylbicyclo[2.2.2]oct-7-enes, their use as perfumes, and a process for their preparation comprising a Diels-Alder reaction of acrolein with either 1,5,5-trimethylcyclohexa-1,3-diene, 3,5,5-trimethylcyclohexa-1,3-diene, 5,5-dimethyl-3-methylene-cyclohex-1-ene or mixtures thereof.
Type:
Grant
Filed:
May 5, 1989
Date of Patent:
February 12, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Klaus Bruns, Thomas Gerke, Michael Virnig
Abstract: Aqueous dispersions of thermoplastic polyamides based on dimeric fatty acids having melting points of at least 120.degree. C. or of mixtures of these thermoplastic polyamides, in which at least 20% of the polyamide has a melting point of at least 120.degree. C., and which contain salts of rosin derivatives having acid values of more than 120 as emulsifiers, show excellent properties as adhesives.
Type:
Grant
Filed:
February 1, 1989
Date of Patent:
February 12, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Wolfgang Klauck, Gerhard Gierenz, Juergen Wichelhaus
Abstract: Nitrogen-free thickeners in aqueous surfactant solutions comprising polyethoxylates of mono- and/or polyunsaturated C.sub.12 -C.sub.22 fatty alcohols having an average degree of ethoxylation of 2 to 5, which also contain 1 to 2 terminal propylene oxide groups attached by condensation instead of the corresponding number of ethylene oxide groups. The products may also be used in admixture with dissolved inorganic electroltye salts and with polyethoxylates of saturated fatty alcohols. These surfactant solutions are useful in the formulation of personal hygiene preparations such as hair shampoos, foam baths, shower baths, handwashing pastes and the like.
Type:
Grant
Filed:
September 9, 1988
Date of Patent:
February 12, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Holger Tesmann, Hermann Hensen, Wolfgang Hochschon, Uwe Ploog
Abstract: A process and circuitry for the electrolytic coloring of an anodized article of aluminum or aluminum alloy in a coloring bath containing at least one metal salt for coloring the article. The process comprises applying to the coloring bath a controllable, asymmetrical and substantially sinusoidal a.c. voltage of substantially constant frequency. The sinusoidal a.c. voltage is obtained from a voltage source supplying a symmetrical sinusoidal a.c. voltage and at least one of the two current paths is divided into two parallel main lines and fed to electrical components whereby the amplitude level of the positive half wave and the amplitude level of the negative half wave and the ratio of the amplitude level of the positive half wave to the amplitude level of the negative half wave of the a.c.
Type:
Grant
Filed:
January 10, 1990
Date of Patent:
February 12, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Dieter Brodalla, Werner Huppertz, Georg Wagner, James W. Costello, Karl-Heinz Munk
Abstract: In light colored surfactants produced by sulfonation of fatty acid alkyl esters with less than 2 moles of SO.sub.3 per mole of fatty acid alkyl ester and subsequent work-up of the crude sulfonate in aqueous medium to form salts, the content of .alpha.-sulfofatty acid disalts is regulated and reduced by transesterifying the sulfonation product before its treatment with an aqueous medium with at least about 0.5 mole equivalent of an alcohol, based on the SO.sub.3 which is not for .alpha.-sulfonation.
Type:
Grant
Filed:
June 18, 1987
Date of Patent:
February 5, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Robert Piorr, Guenter Panthel, Karl H. Schmid, Dietmar Colignon, Hans J. Rommerskirchen, Wolfgang Schmidt, Horst Ritterbex
Abstract: This invention is directed to an aerosol container system with two separate chambers, each of which contains a component to be mixed with the other component just prior to use.
Type:
Grant
Filed:
May 8, 1986
Date of Patent:
January 29, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Dieter Schrader, Karl Giede, Hans Schneider, Dietholf Mehl
Abstract: Undesired hydrophilic materials are readily removed from long chain hydrophobic alcohols, from long chain hydrophobic alcohol/glycoside surfactant mixtures and from solutions of glycoside surfactants in water immiscible solvents resulting from dissolving the glycoside surfactants in said solvents or mixing aqueous mixtures of glycoside surfactants with said solvents, by contacting the hydrophilic material containing hydrophobic composition with water in an amount, and for a time period sufficient, to extract at least a portion of the hydrophilic material from the hydrophobic composition and to form a separate aqueous phase and by separating the resulting aqueous phase from the hydrophobic composition.
Abstract: A process for book binding in which a block of pages, one of whose sides constitutes a book spine, is adhered to a book cover through the applicaiton of a polyurethane hot melt adhesive to the book cover and not to the spine, together with parallel side strips of adhesive.
Abstract: Alkoxylation products of organic compounds containing active H atoms with a narrow homolog distribution range is produced by using as a catalyst in the alkoxylation process a catalyst composition comprising:a. Esters of titanic and/or zirconic acid with monoalkanols containing 1 to 4 carbon atoms in combination with,b. sulfuric acid and/or alkanesulfonic acid containing 1 to 6 carbon atoms and/or hydroxyarylsulfonic acids as catalysts for the ethoxylation or propoxylation of compounds containing active H atoms provide the alkoxylation products with a narrow homolog distribution range.
Abstract: A manually operated appliance for the treatment of textile floor coverings with a foaming cleaning liquid, comprising a shaft-like handle with a bristled cleaning element attached thereto, a container for cleaning liquid replaceably mounted on the handle by means of a holding element, and a hose for connecting the container and cleaning element which is operatively connected to a dosing mechanism regulating the outflow of cleaning liquid from the container. The hose has a grooved internal profile and the cleaning element is a hollow brush having an inlet nozzle on its top surface for the hose level with a socket for fixing the handle. Outlet holes face the floor between rows of bristles arranged at the outer edges of the hollow brush, and a distributor plate covers the brush surface.
Abstract: Compounds corresponding to the following formulaR.sub.1 --(CH.sub.2).sub.m --O--(CH.sub.2 CH.sub.2).sub.n --R.sub.2in which R.sub.1 is the phenyl radical or a phenyl radical which is substituted by linear or branched alkyl radicals containing a total of from 1 to 18 carbon atoms, R.sub.2 is a C.sub.4 -C.sub.8 alkyl radical, m=0 or 1 and n=3 to 30, are used as dispersants with foam-inhibiting properties in aqueous polymer dispersions and latices.
Type:
Grant
Filed:
December 21, 1987
Date of Patent:
January 1, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Rainer Hoefer, Karl-Heinz Schmid, Adolf Asbeck, Uwe Held
Abstract: In the direct catalytic hydrogenation of glyceride oils, the glyceride oils are continuously reacted with hydrogen under pressures of from 20 to 300 bar and at temperatures of from 160.degree. to 250.degree. C. with molar ratios of hydrogen to fatty acid residues in the glyceride oil substrate of from 10:1 to 500:1, the reaction being carried out over catalysts which contain from 30 to 40% by weight copper, from 23 to 30% by weight chromium, from 1 to 7% by weight barium (% by weight, based in each case on oxidic catalyst mass) and, if desired, other transition metals in the form of their oxides and which, after calcination of the components forming the catalyst mass, are converted into shaped particulate and/or granulated elements with from 1 to 10% by weight, based on oxidic catalyst, of at least one binder, and which have been activated with hydrogen or a hydrogen-containing gas mixture.
Type:
Grant
Filed:
December 20, 1989
Date of Patent:
January 1, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Franz-Josef Carduck, Jurgen Falbe, Theo Fleckenstein, Joachim Pohl
Abstract: The sulfonation of epoxidized ricinoleic acid glycerides with a dry stream of gaseous sulfur trioxide diluted with a carrier gas, followed by a reaction of the sulfonated reaction product with nucleophiles, leads to salt-free and anhydrous products showing surface-active properties.
Type:
Grant
Filed:
September 2, 1988
Date of Patent:
January 1, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Bernd Fabry, Robert Piorr, Frank Clasen, Horst Ritterbex, Hans Bornmann
Abstract: Quaternary ammonium phosphates produced by reacting a dicarboxylic acid with an alkoxylated tertiary amine to prepare an amino-functional polyester, mixing the polyester in the presence of water with a phosphoric acid ester, and reacting the mixture with an alkylene oxide at elevated pressure and temperature. The quaternary ammonium phosphates are useful as anti-static agents for textile fiber materials.
Type:
Grant
Filed:
March 3, 1989
Date of Patent:
December 11, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Guenter Uphues, Uwe Ploog, Wolfgang Becker, Irmhild Goebel
Abstract: A process for the continuous transesterification of C.sub.6 -C.sub.22 fatty acid lower alkyl esters, particularly methyl esters, with polyhydric C.sub.2 -C.sub.5 alcohols, particularly glycerol, in a reaction column comprising a rectifying and reaction section, alkaline catalysts and polyhydric alcohol are introduced into the upper part of the reaction column and boiling fatty acid methyl ester is introduced into the middle part of the reaction column. The product collected in the sump of the column is removed, heated and returned to the lower part of the reaction column. Product is removed from the sump. Lower alkanols passing from the reaction column section to the rectifying section are rectified. The reaction column is operated in boiling equilibrium in its lower part and predominantly in an absorption/desorption equilibrium in its upper part.
Type:
Grant
Filed:
March 14, 1989
Date of Patent:
December 11, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Lutz Jeromin, Eberhard Peukert, Bernhard Gutsche, Gerhard Wollmann, Bernard Schleper