Abstract: Ceramic green films having advantageous isotropic distribution of the inorganic pigment can be obtained by casting and drying a slip containing finely divided inorganic pigment, organic solvents, polyvinylbutyral, plasticizer and dispersing agent if compounds which contain in their molecules at least one structural unit of the formula Z ##STR1## in which A and B, which must be different, stand for either the oxyalkylene unit --C.sub.3-4 H.sub.6-8 O-- or the oxyalkylene unit --C.sub.2 H.sub.4 O-- and x and y, which can be identical or different, each denote a number from 1 to 200, are used as dispersing agents.Ceramic green films produced according to the invention can be converted to isotropic ceramic substrates by subsequent heat treatment and sintering.
Type:
Grant
Filed:
December 7, 1988
Date of Patent:
November 6, 1990
Assignee:
Hoechst AG
Inventors:
Hans D. Hermann, Dieter Grote, Karl Waldmann
Abstract: Electrodepositable stable coating preparation essentially comprising a synthetic resin (A), which contains amino groups and, if appropriate, hydroxyl groups, a hardener (B) which is capable of transesterification and/or transamidation, water as diluent (C), if appropriate, organic solvents (D), and also the conventional coating additives and, if appropriate, hardening catalysts (E), wherein the organic solvents content is a maximum of 10% by weight, relative to the solids content.The invention furthermore relates to a process for the preparation of this coating preparation, which is distinguished by a low organic solvents content with good storage stability.
Abstract: A rinsing composition free from phosphate contains as a builder a crystalline layer sodium silicate of the general formula NaMSi.sub.x O.sub.2x+1.y H.sub.2 O, in which M is sodium or hydrogen, x is a number of 1.9-4 and y is a number of 0-20, in admixture with a co-builder which is a polymeric and/or copolymeric carboxylic acid or a salt of said acid.
Abstract: A process for the preparation of methylamines by the reaction of amines, formaldehyde and hydrogen as starting materials on a fixed-bed catalyst in the liquid phase under pressure and preferably at elevated temperature. The starting materials contain a reduced percentage of water. They are heated to a predetermined temperature apart from each other, and then mixed with each other in the presence of the fixed-bed catalyst.
Abstract: The invention is directed toward a base material for aluminium offset printing plates having improved heat stability comprising an aluminum alloy consisting of from about 0.2 to about 0.6% by weight of iron, less than about 0.25% by weight silicon and copper combined, from about 0.1 to about 0.3% by weight manganese and the remainder being aluminum and trace production impurities, said base material further characterized as containing secondary precipitates in the form of phases of the Al Mn Si: Al Fe: Al Mn type which bear a ratio to one another of from about 1:1:2 to about 1:1:3, the mean particle size being from about 0.25 to about 0.010 micron with a maximum particle size of less than about 0.3 micron and further containing a precipitation structure with a degree of dispersion of less than about 50 phases per cubic micron and a process for producing such material. The sheet material according to this invention may be uniformly roughened in either HCl or HNO.sub.
Type:
Grant
Filed:
April 26, 1988
Date of Patent:
July 31, 1990
Assignees:
Hoechst AG, Vereinigte-Aluminum Werke AG.
Inventors:
Gerhard Sprintschnik, Walter Niederstaetter, Kurt Reiss, Wolfgang V. Asten, Gunther Scharf, Barbara Grzemba
Abstract: A curing agent (A) for resins (B) which can be cured by means of isocyanates, which has an amine number of 20 to 150 mg of KOH/g and an OH number of not more than 20 mg of KOH/g and which contains per molecule at least two masked isocyanate groups which are reactive under the conditions of curing, obtained by reacting(a) an amine which contains at least one .beta.-hydroxylalkyl group per molecule and has an OH number of 100 to 1,200 mg of KOH/g and an amine number of 100 to 1,200 mg of KOH/g and which, if appropriate, also contains NHCO groups, if appropriate as a mixture with another OH-functional and/or NH-functional compound, with(b) a partly masked isocyanate, if appropriate as a mixture with an at least difunctional, OH-reactive and/or NH-reactive compound.These curing agents are readily dispersible in aqueous systems, if appropriate after neutralization, and frequently increase stability in aqueous paint formulations.
Type:
Grant
Filed:
March 21, 1989
Date of Patent:
July 10, 1990
Assignee:
Hoechst AG
Inventors:
Michael Honel, Manfred Finke, Gerd Walz, Peter Ziegler
Abstract: Water-dilutable printing ink binder system based on a binder in the form of a clear, dilute, ammoniacal or amine-containing solution, the binder being a product of reacting a natural resin acid and formaldhyde in at least one stage, the amount of (100% strength) formaldehyde being 1 to 25% by weight, based on the natural resin acid, and the reaction having been carried out under atmospheric or superatmospheric pressure in the absence or in the presence of 0.1 to 2% by weight of a lewis catalyst. A variant comprises partially esterifying the natural resin acid/formaldehyde reaction product with at least one polycarboxylic acid unit of the group (a) an ethylenically unsaturated dicarboxylic acid and/or the anhydride thereof and (b) a hydroxycarboxylic acid. The binder system has added to it as solubilizers monohydric and/or polyhydric alcohols, and the pH value is preferably set to 7.5 to 10.
Abstract: In the novel process alkylene glycol monoalkyl ethers of the formula ##STR1## in which R.sup.1 is an alkyl radical having 1 to 25 carbon atoms, R.sup.2 is H, CH.sub.3 or C.sub.2 H.sub.5 and, within the chain of the polyoxyalkylene radical, arranged randomly or in blocks, can also assume all three meanings, R.sup.3 is CH.sub.3 or C.sub.2 H.sub.5 and n denotes 1 to 100, are hydrogenated to give the corresponding alkylene glycol dialkyl ethers in the presence of a supported nickel catalyst using hydrogen without pressure.
Abstract: Process for the preparation of 2-oxo-1,3-dioxolanes by reaction of epoxides with carbon dioxide in the presence of a catalyst, wherein at least one epoxy compound is mixed with at least one catalyst in the presence or absence of an inert solvent and is reacted at temperatures from 40.degree. to 180.degree. C. while introducing carbon dioxide at normal pressure or slightly increased pressure to form the corresponding organic carbonates. The 2-oxo-1,3-dioxolanes obtained are used to prepare synthetic resins containing urethane groups in the form of coatings and molded bodies.
Abstract: Coating composition comprising a reaction product of primary monoamines and cyclic monocarbonates in the molar ratio 1:0.8 to 0.8:1 as agent for the production of a constant coating thickness in cathodic electrocating and a process for the preparation of the coating composition in the form of coating pastes or dip baths.
Abstract: The invention relates to stable epoxy resin dispersions and also a process for the preparation thereof and the use thereof, in particular for coatings.
Abstract: Polyamines based on derivatives of 1,3-bissubstituted 2-propanol containing a multiplicity of amino groups, the latter containing at least one primary amino group and additionally further N-basic groupings, prepared by reacting 1,2,3-trisubstituted propane compounds with bis(primary amines or with monoamines and bis(primary amines).The polyamines according to the invention are clear to yellowish or yellow products which, at room temperature, form viscous to highly viscous liquids or may be paste-like or wax-like. They may be used, inter alia, advantageously as starting products for the preparation of thermosetting, in particular water-dispersible and cataphoretically depositable binders based on aminourethanes for coating solid substrates, in particular metals.
Type:
Grant
Filed:
December 22, 1987
Date of Patent:
December 5, 1989
Assignee:
Hoechst AG
Inventors:
Rudiger Lenz, Gerd Walz, Michael Honel, Peter Ziegler
Abstract: Non-crosslinked reaction products of compounds (A) which contain structural units carrying 1,3-dioxolan-2-one groups in random distribution and compounds (B) which contain at least one primary aliphatic or cycloaliphatic amino group and additionally at least one further basic amino group.These reaction products are suitable, if appropriate together with conventional curing agents, especially as binders for coatings, above all electrodip coatings.
Abstract: Use of finely divided aqueous cationic dispersions of synthetic resins obtainable by emulsion polymerization from suitable monomers and which contain cationic dispersion polymers, as impregnants and primers for consolidating and priming of porous absorbent substrates, preferably inorganic substrates such as, for example, masonry, concrete, plaster surfaces, gypsum surfaces, bricks or wood, by treating these substrates with the aqueous cationic dispersions whose polymer particles have mean particle diameters of 0.02 to 0.2 .mu.m.Aqueous cationic dispersions of synthetic resins exhibit a superior penetrating and permeating power, in particular on smooth plaster surfaces and smooth gypsum surfaces, compared with aqueous anionic or non-ionic dispersions of synthetic resins.
Type:
Grant
Filed:
April 5, 1988
Date of Patent:
October 3, 1989
Assignee:
Hoechst AG
Inventors:
Erhard Bister, Hans-Ullrich Huth, Werner Stelzel
Abstract: A reaction product of (A) compounds containing at least two R.sup.1 R.sup.2; C.dbd.CR.sup.3 --X groups (I) with (B) compounds which contain(a) at least two active H atoms or(b) at least two groups containing active H atoms of the type --AH-- (II) or(c) at least one active H atom and at least one group of the type (III),or which form the corresponding amount of this group (II), in which, the formula (I),X denotes --CO-- which is attached to a further R.sup.1 R.sup.2 C.dbd.CR.sup.3 group either directly or via the radical of a polyhydric alcohol or of an amine,R.sup.1 denotes hydrogen or a hydrocarbon radical having 1 to 10, preferably 1 to 4, carbon atoms, such as alkyl, phenyl, benzyl or naphthyl,R.sup.2 denotes hydrogen, a hydrocarbon radical having 1 to 10, preferably 1 to 4, carbon atoms, such as alkyl, phenyl, benzyl or naphthyl, an ester group containing the radical R.sup.4 of a monohydric alcohol having up to 12 carbon atoms, --CN, --NO.sub.2 or a CO--NHR.sup.1 or CO--R.sup.1 group, andR.sup.
Type:
Grant
Filed:
June 16, 1986
Date of Patent:
October 3, 1989
Assignee:
Hoechst AG
Inventors:
Gerhard Brindopke, Gerd Walz, Karl Waldmann, Manfred Schon, Hans-Jerg Kleiner
Abstract: A method for treating paper or other fibrous materials to improve the holdout characteristics of printing inks, lacquers and coating compositions. The method involves the application of an organophilic complex of(a) a water-insoluble hydrated cation-exchangeable film-forming smectitic layered silicate having an ion exchange capacity of at least 50 milliequivalents/100 g and(b) an organic radical derived from an onium compound attached thereto.The organophilic complex forms a barrier layer by reaction with the organic solvent contained in the printing ink, lacquer or other coating composition.
Abstract: Amino group containing curing component (A) for compounds (B) which contain epoxy or 1,3-dioxolan-2-one groups, comprising a reaction product of (a.sub.1) active CH alkyl esters of isocyanate adducts thereof with (a.sub.2) polyamines.Mixtures of (A) and (B) with or without diluents and additives give rapid curing even at low temperatures and high atmospheric humidity and are suitable in particular for paint formulations.
Type:
Grant
Filed:
April 7, 1988
Date of Patent:
August 22, 1989
Assignee:
Hoechst AG
Inventors:
Gerhard Brindopke, Claus Godau, Walter Weber
Abstract: A process for the purification of phenol-containing waters, in particular waste waters from phenolic resin production, where the term "phenol" is taken to mean all steam-volatile benzene derivatives according to DIN 38,409 H 16, by reaction of the phenol with formaldehyde in an alkaline environment at 50.degree. to 100.degree. C. to form those phenolformaldehyde condensates which, by subsequent acidification of the waste water, precipitate in filterable, granular and no longer sticky form and can be separated.
Type:
Grant
Filed:
April 8, 1988
Date of Patent:
August 15, 1989
Assignee:
Hoechst AG
Inventors:
Ulrich Hars, Rolf Staiger, Karl Westphal
Abstract: Curing component (A) based on polyisocyanates for binders (B) which contain groups containing active hydrogen, wherein the curing component (A) is a product of the reaction of (a1) polyisocyanates with (a2) .alpha.-hydroxyalkylpyridines.Mixtures of (A) and (B), and also, if appropriate, diluents (C) and additives (D), are stable on storage and give, even at temperatures of 120.degree.-140.degree. C., curing products which are sufficiently solvent-stable. They are suitable, in particular, for surface-coating preparations.
Type:
Grant
Filed:
July 22, 1988
Date of Patent:
July 11, 1989
Assignee:
Hoechst AG
Inventors:
Edgar Vorwerk, Manfred Finke, Rudiger Lenz
Abstract: A false twisted bulky synthetic multifilament yarn of a uniform polymer consisting of at least two filament bundles of different filament deniers, with the filaments in each of said bundles having the same denier per filament. The smaller denier per filament is less than 1 dtex, and the total denier of the texturized yarn is in excess of 100 times the finer filament denier. For the production of such a multifilament yarn, the draw ratios of both filament bundles are chosen such that the difference between both draw ratios is smaller than 0.1, and both bundles are drawtexturized simultaneously at a draw ratio corresponding to the draw ratio of the filament bundle having the coarser denier per filament. Preferred end uses of the yarn are water-repellent fabrics, dust proof fabrics, and the conductive component of sports wear.