Abstract: A composition capable of removing the non-image areas of an imagewise exposed photographic element, consisting essentially of in admixture:(a) from at least about 5% to about 30% by weight benzyl alcohol; and(b) from about 1% to about 20% by weight of one or more compounds selected from the group consisting of sodium xylene sulfonate and sodium cumene sulfonate; and(c) from about 5% to about 40% by weight potassium toluene sulfonate; and(d) water.
Abstract: Systems and methods for predetermining maximum pressure differentials for particular microporous hollow fiber membranes and essentially immiscible feed and extractant liquids to be employed in liquid-liquid extractions include a test module having a number of such fibers formed into a loop between the opposing ends thereof. A tubular sleeve element encompasses these opposing ends, and a potting compound positionally retains the opposing ends within the tubular sleeve. The hollow fiber lumens are fluid-connected to a reservoir containing a pressurized feed liquid, and the loops of hollow fiber are immersed in an essentially unpressurized extractant liquid. The pressure of the feed liquid is continually increased until there is an incipient presence of the feed liquid in the extractant liquid. The pressure of the feed liquid at that incipient presence may therefore be used to calculate a maximum pressure differential tolerated by the microporous hollow fibers for the feed and extractant liquids used.
Abstract: Methods for forming magnetic coatings on a nonmagnetic substrate include the application of a liquid film layer onto the substrate, the film layer being a dispersion of magnetic particles in a liquid resin binder solution which contains trioxane. The trioxane may or may not be removed from the cured layer. Thus, the trioxane may be present as a reactive solvent for the resin binder, in which case, a polymerization initiator for the trioxane is also present in the liquid film layer. The trioxane may then be polymerized in situ on the substrate to yield poly(oxymethylene).
Abstract: An aqueous sulfuric acid anolyte solution is circulated through the anode compartment of an electrolytic cell, and an aqueous NaHSO.sub.3 catholyte solution is circulated through its cathode compartment, while maintaining an anolyte and catholyte temperature range of 20.degree.-25.degree. C., a catholyte pH range of 4.6 to 5.8, and a reduction potential of -1.25 to -1.50 V versus Ag.degree./AgCl, to produce an aqueous solution of Na.sub.2 S.sub.2 O.sub.4. Optimum pH is maintained by small additions of an alkali to the catholyte solution for electrolysis and solution stability.
Type:
Grant
Filed:
September 12, 1989
Date of Patent:
December 11, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Leonard L. Diaddario, Jr., Mark A. Schroeder
Abstract: A composite membrane is disclosed having a microporous support which is coated with a UV curable polymer composition having a sufficiently high viscosity to prevent pore filling upon coating and curing. A process for making and a process for using the membrane is also disclosed.
Abstract: Cationic copolymerization of trioxane and 1,2,6-hexanetriol formal (HTF) or its ester derivatives yields acetal copolymers having pendant functional groups. The HTF formal or ester derivatives of HTF may therefore include functional groups selected from hydroxyl or ester moieties which are protected, and thus survive, the copolymerization with trioxane. These groups may then be present as functional reactive sites for the subsequent synthesis of block copolymers and/or to chemically bind modifiers to the acetal copolymer backbone, for example.
Type:
Grant
Filed:
May 12, 1989
Date of Patent:
December 4, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Jerry A. Broussard, Andrew B. Auerbach, James L. Paul
Abstract: Cationic polymerization of trioxane and a mixture of ester derivatives of .alpha.,.alpha.- and .alpha.,.beta.-isomers of glycerol formal yields acetal terpolymers having pendant functional groups (i.e., ester groups, or hydroxyl groups obtained by hydrolyzing ester groups, pendent from the polymer's backbone). The glycerol formal monomers employed in this invention may include functional groups selected from ester moieties which are protected from, and thus survive, the polymerization process with trioxane. These groups may then be present as functional reactive sites for the subsequent synthesis of block polymers and/or to chemically bind modifiers to the acetal terpolymer backbone, for example.
Type:
Grant
Filed:
May 12, 1989
Date of Patent:
December 4, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Nan L. Yang, Andrew Auerbach, Rose Pesce, Jerry A. Broussard, James L. Paul
Abstract: A method of producing a polyester filament which has a superior combination of tensile, dyeability and shrinkage properties. The method comprises forming a polyester-polyethylene glycol copolymer from a mixture consisting essentially of a terephthalic acid or dimethyl terephthalate, ethylene glycol, and polyethylene glycol, with the polyethylene glycol having an average molecular weight of between about 200 and 1500 grams per mole and being added in an amount sufficient to produce a polyester-polyethylene glycol copolymer in which the polyethylene glycol is present in an amount of between about 1.0 and 4 percent by weight of the copolymer formed; forming filament from the copolymer drawing the copolymer filament; and heat setting the drawn filament.
Abstract: There is disclosed a method for the production of dust-free sodium dithionite from the reaction of a alkaline formate sulfur dioxide and an alkaline metal agent in the presence of a thiosulfate reactive compound by introducing a water-soluble polymer having a molecular weight less than 60,000 and delaying the start of the alkaline metal agent until the sodium formate and the sulfur dioxide have begun to be introduced into the reactor.
Abstract: Stripper compositions for coatings comprise trioxane. An aromatic hydrocarbon and aliphatic alcohol can be added to improve solubility parameters. Xylene and methanol are the preferred co-solvents.
Abstract: In one embodiment this invention provides a novel polymerizable quaternary ammonium carbonate corresponding to the formula: ##STR1## In another embodiment this invention provides a novel copolymer of the above represented methacrylamidopropyltrimethylammonium methyl carbonate and acrylamide, which exhibits a high level clay flocculation efficiency.
Abstract: A flame arresting method, conduit section and apparatus for the safe disposal of combustible waste gases from a source such as a reactor. The invention involves providing a waste gas conduit section with a flame-detecting chamber and one or more upstream snuffing chambers divided by flame arresting grid members, and automatically introducing snuffing gases to the snuffing chamber(s) whenever a flame is detected in the flame-detecting chamber. The outlet from the waste gas conduit section opens to a combustion chamber, for incineration purposes, or to a scrubber.
Abstract: A battery separator includes a porous substrate and a thermal fuse material adhered to at least one surface of said porous substrate. The thermal fuse material is adhered to the substrate surface in a predetermined geometric array thereupon so as to establish open areas of the at least one substrate surface to thereby allow ionic migration therethrough. The thermal fuse material forming the geometric array on the substrate surface may itself define open pores to further facilitate such ionic migration. The thermal fuse material melts at or near a predetermined threshold temperature so that the substrate's permeability irreversibly becomes significantly decreased and thus interrupts the chemical reaction in an electrochemical battery. In such a manner, batteries of improved safety may be provided using the separators of this invention.
Type:
Grant
Filed:
April 5, 1989
Date of Patent:
November 27, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Henry T. Taskier, Steven M. Mullins, Ellen A. Langford, Robert J. Fleming
Abstract: A filter for a smoking article includes: a flavorant; a hollow fiber made of a thermoplastic, the flavorant dispersed in the thermoplastic; and a filter plug in which the fiber is embedded. Additionally, the hollow fiber may be sheathed with a layer of cellulose acetate.
Abstract: Diaryl pigments having excellent dried ink transparency and improved process heat stability are prepared by carrying out the coupling of a bisdiazotized substituted 4,4' diaminobiphenyl with acetoacetanilides and/or pyrazolinones in the presence of an added quantity of one or more substituted aromatic amines containing at least one sulfonic or carboxylic acid substituent, or their salts. The pigments exhibit improved tolerance to variations in drying temperatures and to high drying temperatures, and have improved transparency when present in dried ink formulations.
Abstract: Photoresist compositions suitable for deep UV and excimer laser lithography are disclosed that are mixtures of a photoacid and a polymer having imide residues to which acid labile groups are attached. These compositions provide high resolution, high contrast and high sensitivity in the deep UV (wavelength of 250-300 nm), mid-UV (wavelength of 300-350 nm) or conventional (wavelength of 350-450 nm) exposure bands. The compositions are also suitable for exposure at wavelengths commonly associated with excimer laser sources (248, 308 nm) or for exposure by X-radiation.In the compositions disclosed, the imide group ##STR1## can be blocked with certain groups, X, to form compounds containing the structure ##STR2## which have solubility properties different from the unblocked imide. These groups, X, can be cleaved by acid under the proper conditions to regenerate the unblocked imide.
Type:
Grant
Filed:
June 6, 1989
Date of Patent:
November 6, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Chengjiu Wu, Anne M. Mooring, Michael J. McFarland, Christopher E. Osuch, James T. Yardley
Abstract: Black acid or the sulfuric acid residue obtained in the manufacture of ethyl acrylate by reaction of ethylene and acrylic acid in the presence of sulfuric acid is heated and distilled in a distillation zone in the presence of a solvent to form an overhead mixture comprising an organic phase containing ethyl acrylate and solvent, and an aqueous phase containing water, solvent and acrylic acid. The aqueous phase is recycled to the distillation zone for recovery of additional acrylic acid value from the organic phase.
Type:
Grant
Filed:
May 7, 1990
Date of Patent:
November 6, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Brad L. Smith, Adolfo Aguilo, Cecil D. Homer, Jr.
Abstract: This invention relates to positive working color proofing sheet construction which, upon exposure to an actinic radiation source through a screened image, can accuratley reprouce said image. The construction is useful as a color proofing film which can be employed to accurately predict the image quality from a lithographic printing process. The image is produced by forming a composite of a receiver base, diazo or diazide layer, photopolymerizable layer and cover sheet. Upon imagewise exposure, a positive image appears on the receiver base after dry peel apart development.
Abstract: An aromatic substituted glycoside is disclosed of the formula ##STR1## wherein the configuration of the substituted --OR on the anomeric carbon is alpha, n is an integer of 0 to 1, and R is a substituted aromatic radical selected from the group ##STR2## where R.sub.1 through R.sub.6 are independently halogen, NO.sub.2, SO.sub.3 H, ##STR3## where R.sub.7 is lower alkyl; and includes its stereoisomers, optical isomers and geometric isomers and mixtures of the foregoing isomers. These substrates are useful as direct substrates for alpha-amylases. A process for the preparation of the substrates and related substances is also described.
Type:
Grant
Filed:
September 4, 1987
Date of Patent:
October 16, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Rodrigo G. Chavez, Harold David, Ernest K. Metzner, Gerald F. Sigler, Emily S. Winn-Deen
Abstract: This invention provides novel side chain liquid crystalline polymers which exhibit nonlinear optical response, and which have utility as a transparent optical component in electrooptic light modulator devices.
Type:
Grant
Filed:
December 1, 1987
Date of Patent:
October 9, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Ronald N. DeMartino, Hyun-Nam Yoon, James B. Stamatoff, Alan Buckley