Abstract: An aqueous coating composition is provided for thermoplastic films comprising(i) from 1 to 10 weight percent based upon the total weight of the coating composition, of a sulfonated copolyester consisting essentially of the polyester condensation product of the following monomers or their polyester-forming equivalents:(A) about 65 to 95 mole percent of isophthalic acid;(B) about 0 to 30 mole percent of at least one aliphatic dicarboxylic acid of the formula HOOC(CH.sub.2)--.sub.n COOH, wherein n ranges from about 1-11;(C) about 5 to about 15 mole percent of at least one sulfomonomer containing an alkali metal sulfonate group attached to a dicarboxylic aromatic nucleus; and(D) stoichiometric quantities of about 100 mole percent of at least one copolymerizable aliphatic or cycloaliphatic alkylene glycol having about from 2 to 11 carbon atoms,(ii) from 0.
Abstract: A polyester resin is disclosed which is resistant to splitting during transverse orientation during conventional film manufacturing. The polyester resin contains up to 7 weight percent, based uon the total weight of the resin, of(A) a dicarboxylic acid component consisting essentially of 1,4-cyclohexandeicarboxylic acid having a trans isomer content of at least 70%(B) a glycol component consisting essentially of(1) 1,4-cyclohexanedimethanol, and(2) from about 15 to about 50 weight percent, based on the weight of the polyesterether, of polytetramethyleneether glycol having a molecular weight of about 500 to about 1100 and(c) from about 0.1 to about 1.5 mole percent, based on the mole percentage of the acid or glycol component, of a branching agent having at least three COOH or OH functional groups and from 3 to 60 carbon atoms.
Abstract: This invention provides novel acrylic copolymers which exhibit nonlinear optical response, and which have utility as a transparent optical component in optical light switch and light modulator devices.
Type:
Grant
Filed:
October 3, 1986
Date of Patent:
April 10, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Ronald N. DeMartino, Hyun-Nam Yoon, James B. Stamatoff
Abstract: Moisture absorbing pellets useful as animal litter are made from a blend of bentonite clay and a solid water-swellable but water-insoluble organic polymeric hydrocolloid.
Abstract: A light-sensitive compound having the formula: ##STR1## wherein R.sub.3 is selected from the group consisting of phenyl and C.sub.1 to C.sub.4 alklyl substituted phenyl.--K-- is selected from the group consisting of ##STR2## --S--, --O--, and --CH.sub.2 --, or is absent; R.sub.1 and R.sub.2 are independently selected from the group consisting of C.sub.1 to C.sub.4 alkyl, methoxy, ethoxy, butoxy, and H;X-- is an anion; andR denotes a hydrogen atom or a C.sub.1 to C.sub.4 alkyl group.
Abstract: Polyamides having improved solubility and processing characteristics are provided having incorporated into the polymeric chain a novel aromatic diamine compound, 2-(3-aminophenyl)-2-(4-aminophenyl) hexafluoropropane (3-4'-6F Diamine). The polyamides are prepared by reacting the 3,4'-6F Diamine with an aliphatic or aromatic di-acid or acid halide. It has been found that the polyamides of this invention have improved solubility characteristics, low dielectric constants and improved thermal flow properties as a consequence of the meta/para positioning of the amino groups on the daimine, which renders these polymers more readily melt spinnable for the production of fibers. The polymers may also be compression molded and fabricated into composites at moderate temperatures and pressures.
Abstract: A die spool for the extrusion of thermoplastic materials includes an axially split elongate spool body so as to be separable into first and second spool segments. The spool segments collectively establish the spool body and also define an axially oriented extrusion cavity through which thermoplastic material is conveyed. An alignment system ensures that only a single orientation of the extrusion axis is possible when the die spool is coupled to another similar die spool (or to an extrusion die associated with an extruder). A die spool assembly may therefore be provided which is comprised of a number of individual die spools. Preferably, a decreasing temperature gradient is established within the extrusion cavity of the die spool assembly (as may be accomplished by controllably operating electrical resistive heater elements) so as to at least partially solidify the thermoplastic extrudate therewithin.
Abstract: This invention relates to water developable, negative working photosensitized sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to predict the image quality from a lithographic printing process. The invention provides both overlay and transfer type proofing sheets which have good fingerprint resistance.
Abstract: A developing and finishing composition for lithographic printing plates containing:a. a mono-, di-, or tri-sodium potassium or lithium phosphate; andb. benzyl alcohol, phenoxyethanol or phenoxypropanol; andc. polyvinyl pyrrolidone, dextrin, poly (methyl vinyl ether/maleic acid) or gum arabic; andd. citric acid or benzoic acid; ande. sodium or potassium octyl sulfate; andf. sodium, potassium or lithium benzoate; andg. sodium, potassium or ammonium citrate; andh. sodium, potassium or ammonium sorbate; andi. sufficient water to formulate an effective developer.
Type:
Grant
Filed:
June 19, 1989
Date of Patent:
March 27, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Major S. Dhillon, Shane Hsieh, Douglas A. Seeley
Abstract: Photoresist compositions suitable for deep UV and excimer laser lithography are disclosed that are mixtures of a photoacid and a polymer having imide residues to which acid labile groups are attached.The imide group ##STR1## can be blocked with certain groups, X, to form compounds containing the structure ##STR2## which have solubility properties different from the unblocked imide. These groups, X, can be cleaved by acid under the proper conditions to regenerate the unblocked imide. Where the imide group is incorporated in a polymer, the polymer with blocked imide groups can be made to function as a resist when compounded with a substance capable of forming an acid upon exposure to radiation.Preferred polymers are those in which at least 80% of the imide groups are blocked. When less than 50% of the imide groups are blocked, performance in a photoresist becomes unacceptable.
Type:
Grant
Filed:
June 22, 1987
Date of Patent:
March 27, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Christopher E. Osuch, Michael J. McFarland
Abstract: Sinterd molded article having improved thermal resistance and strength formed from a homogeneous mixture comprising from about 5 to 75 percent by weight polybenzimidazole and from about 95 to 25 percent by weight of a polyaryleneketone.
Type:
Grant
Filed:
April 13, 1989
Date of Patent:
March 27, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Edwardo Alvarez, Lorenzo P. DiSano, Bennett C. Ward
Abstract: Polymers of 4-acetoxystyrene in finely divided particulate form are suspended in water, and while in suspension are hydrolyzed to polymers of 4-hydroxystyrene using aqueous nitrogen bases. Such polymers are useful in photoresists, as protective coatings for metal, in the manufacture of epoxy resins and epoxy resin curing agents.
Abstract: A blanket with a weighted perimeter and a method of its use are disclosed herein. This blanket is used as a safety device which can prevent injury to a person cutting baling straps, that surround baled materials and that are under tension, by dampening the whiplash of the straps when cut.
Abstract: This invention relates to positive-working, photopolymerizable containing sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image on conventional paper with an adhesive layer pretreatment. The construction is useful as a peel apart color proofing film which can be employed to accurately predict the image quality from a lithographic printing process.
Type:
Grant
Filed:
October 21, 1988
Date of Patent:
March 20, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Stephan J. W. Platzer, Timothy T. Hannigan
Abstract: .alpha.-chloro-.alpha.-oximino-4-hydroxyacetophenone is prepared by reacting 4-hydroxyacetophenone with an alkyl nitrite and hydrogen chloride wherein the amount of hydrogen chloride is carefully controlled to limit the amount thereof to about 0.1 to 6 moles of hydrogen chloride per mole of 4-hydroxyacetophenone until at least one equivalent of the alkyl nitrite is reacted. Subsequent to the reaction of the one equivalent of alkyl nitrite, at least 1 mole of hydrogen chloride per mole of initially charged 4-hydroxyacetophenone is added to the reaction medium.
Abstract: The present invention provides a highly elongated member of substantially uniform cross-sectional configuration which is capable of improved service as a stiffening support in an optical fiber cable. Such elongated member is the product of melt extrusion through an appropriate orifice of a thermotropic liquid crystalline polymer (as described). The resulting elongated member has been found to offer significant advantages when compared to stiffening supports heretofore proposed for use in optical fiber cables.
Abstract: Disclosed herein is a process for producing a polyhalogenated microporous film having a very narrow pore size distribution and good temperature and chemical resistance. The process involves blending a polyhalogenated copolymer having a very small particle size with a binder polymer utilizing a solvent which is a nonsolvent for the polyhalogenated copolymer but a solvent for the binder polymer, forming a film from the blend, drying the film, heating the film to a temperature at or above the melting point of the polyhalogenated copolymer and under conditions such that the microparticulate particles at their points of mutual contact will neck together to form a relatively continuous matrix and extracting the binder polymer from the film utilizing a solvent for the binder particle to form a microporous film.
Type:
Grant
Filed:
August 5, 1988
Date of Patent:
March 20, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Edward R. Kafchinski, Herman L. LaNieve, III, Gordon W. Calundann, Tai-Shung Chung
Abstract: In one embodiment this invention provides a novel polymerizable quaternary ammonium carbonate corresponding to the formula: ##STR1## In another embodiment this invention provides a novel copolymer of the above represented methacrylamidopropyltrimethylammonium methyl carbonate and acrylamide, which exhibits a high level clay flocculation efficiency.