Patents Assigned to Hooker Chemicals & Plastics Corp.
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Patent number: 4292146Abstract: A porous polyfluoroalkylene sheet, very preferably of polytetrafluoroethylene, which is suitable for use as a separator in an electrolytic cell, such as one used for the electrolysis of brine, has a porosity in the range of 70 to 90%, a thickness in the range of 0.2 to 3.5 mm. and at least one of (a) an A X-ray ratio in the range of 0.1 to 0.35 and (b) a B X-ray ratio in the range of 0.75 to 0.98. Preferably the A X-ray ratio is in the range of 0.1 to 0.3, the B.sub.2 X-ray ratio is in the range of 0.75 to 0.98 and the B.sub.1 X-ray ratio is in the range of 0.1 to 0.32. The porous sheets are separators or diaphragms for electrolytic cells and the uses of such separators and cells in electrolysis processes, preferably in the electrolysis of brine, are described. Also known in the specification are a method for the manufacture of the porous sheets and a method for ascertaining which milled, sintered and leached porous sheets are more suitable for use in electrolytic processes.Type: GrantFiled: August 7, 1979Date of Patent: September 29, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: Eng-Pi Chang, Christine A. Lazarz, Edward H. Cook, Jr.
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Patent number: 4290744Abstract: An improved molding apparatus for injection-compression molding thermosetting materials is described. The apparatus comprises a stationary platen assembly, a moveable platen assembly and a feed nozzle assembly.The stationary assembly is comprised of a stationary platen member, a heated plate mounted on the support plate and a plurality of mold faces mounted on the heat plate.The movable assembly is comprised of a moveable platen member, a heated plate mounted thereon and a plurality of mold faces mounted on the heat plate aligned with the mold faces on the stationary assembly.The feed, or injection, nozzle assembly is comprised of a cylindrical nozzle member, having an internal temperature controlling means, and a plurality of feed outlets positioned on the periphery.Type: GrantFiled: February 5, 1980Date of Patent: September 22, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: W. Andrew Dannels, Robert W. Bainbridge
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Patent number: 4289600Abstract: Microporous membrane materials suitable for use in electrolytic cells, such as cells for the electrolysis of brine to produce chlorine, are formed from a mixture of polytetrafluoroethylene, a particulate pore forming material and an organic fluorinated lubricant. Such materials are preferably formed into a sheet, which is rolled to a desired thickness, sintered and subjected to leaching out of the pore forming material.Type: GrantFiled: August 7, 1979Date of Patent: September 15, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: Christine A. Lazarz, Edward H. Cook, Jr., Lesleigh V. Scripa
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Patent number: 4289546Abstract: A composition and a method for applying a lubricant coating to clean metal surfaces prior to subjecting them to metal forming operations. The composition comprises a concentrate which is adapted to be diluted with water, if desired, to produce an aqueous acidic operating bath containing a controlled effective amount of phosphate ions to form a phosphate coating on the clean metal surface in combination with an emulsified organic lubricant agent, an emulsifying agent and an aqueous soluble organic corrosion inhibiting agent. The coating composition may further optionally contain a controlled amount of heavy metal cations for activating the coating bath. The coating composition is applied to a clean metal surface such as by flooding, immersion, spraying, or the like, at temperatures from ambient up to about 200.degree. F. for a period of time sufficient to effect a desired coating magnitude whereafter the parts are dried, preferably at elevated temperatures before forming.Type: GrantFiled: July 24, 1980Date of Patent: September 15, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventor: Kenneth J. Hacias
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Patent number: 4289060Abstract: An improved assembly for mounting a part onto a base member is provided by incorporating a tubular insert having a hollow inner core in a mounting hole in the part. A fastener, such as a bolt, machine screw or rivet, may then be inserted through the insert in the mounting hole for attachment to the base member. The tubular insert has an integral flange on the end which engages the fastener. The flange functions as the "washer" in conventional fastener assemblies. When the assembly is subjected to axial compression by the fastener, the insert collapses uniformly in an axial direction to absorb a substantial amount of the total compressive load exerted upon tightening the fastener.Type: GrantFiled: October 1, 1979Date of Patent: September 15, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventor: John E. Emmett
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Patent number: 4289061Abstract: An improved assembly for mounting a part onto a base member is provided by incorporating a tubular insert having a hollow inner core in a mounting hole in the part. A fastener, such as a bolt, machine screw or rivet may then be inserted through the insert in the mounting hole for attachment to the base member. When the assembly is subjected to axial compression by the fastener, the insert collapses uniformly in an axial direction to absorb a substantial amount of the total compressive load exerted upon tightening the fastener.Type: GrantFiled: October 1, 1979Date of Patent: September 15, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventor: John E. Emmett
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Patent number: 4289547Abstract: A composition and a method for applying a lubricant coating to clean metal surfaces prior to subjecting them to metal forming operations. The composition comprises a concentrate which is adapted to be diluted with water, if desired, to produce an aqueous acidic operating bath containing a controlled effective amount of phosphate ions to form a phosphate coating on the clean metal surface in combination with an emulsified organic lubricant agent, an emulsifying agent and an iron chelating agent. The coating composition may further optionally contain a controlled amount of a corrosion inhibiting agent and heavy metal cations for activating the coating bath. The coating composition is applied to a clean metal surface such as by flooding, immersion, spraying, or the like, at temperatures from ambient up to about 200.degree. F. for a period of time sufficient to effect a desired coating magnitude whereafter the parts are dried, preferably at elevated temperatures before forming.Type: GrantFiled: July 24, 1980Date of Patent: September 15, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: Peter F. King, George J. Beyer
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Patent number: 4289826Abstract: Aqueous compositions are employed to form a protective coating on metal surfaces, in particular, ferrous or tin surfaces, and are especially useful for the coating of blackplate or tin-plated cans. The compositions contain, in the form of an aqueous emulsion, an epoxy resin, an alkylated melamine-formaldehyde resin, an acid catalyst, a block copolymer of ethylene oxide and propylene oxide and water. The composition is applied to a clean metal surface by any conventional technique and even-cured to provide a protective, paint-receptive coating.Type: GrantFiled: December 22, 1978Date of Patent: September 15, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventor: John K. Howell, Jr.
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Patent number: 4288286Abstract: A cellulosic pulp and bleaching process is described. The process integrates two cycles, one is a digestor liquor cycle and the other is a sulfur cycle.The digestor liquor cycle comprises the steps of digesting a fibrous cellulosic feed to form a pulp, separating the pulp and bleaching it in at least one stage with chlorine dioxide, evaporating and burning the remaining waste liquor to form a smelt, dissolving the smelt to form a green liquor and utilizing the green liquor, after recausticizing, as at least a portion of the feed stock for the digestor step.The sulfur cycle of the present invention utilizes a portion of the green liquor of the digestor liquor cycle. The green liquor is carbonated to form a bicarbonate which is then stripped of H.sub.2 S. The H.sub.2 S is converted into H.sub.2 SO.sub.4 and utilized as a feed stock to a chlorine dioxide generator. The chlorine dioxide generator utilizes H.sub.2 SO.sub.4 as feed stock and produces Na.sub.2 SO.sub.4 as a by-product. The Na.sub.2 SO.sub.Type: GrantFiled: March 3, 1980Date of Patent: September 8, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventor: Willard A. Fuller
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Patent number: 4285795Abstract: An improved apparatus for the electrolysis of aqueous solutions of ionizable chemical compounds is disclosed including specifically an apparatus for the production of chlorine and caustic containing low concentrations of sodium chloride by the electrolysis of brine which comprises electrolyzing brine solutions in a cell equipped with a cathode and an anode separated by a cation-active permselective diaphragm.Type: GrantFiled: April 18, 1975Date of Patent: August 25, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventor: Edward H. Cook, Jr.
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Patent number: 4284549Abstract: This invention relates to polymer blends having improved hydrolytic stability, moldability and fire retardancy which comprise, in admixture, (1) a linear aromatic polyester prepared from an aromatic dicarboxylic acid and a bisphenol, and (2) polyphenylene sulfide.Type: GrantFiled: May 28, 1980Date of Patent: August 18, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventor: Gideon Salee
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Patent number: 4283287Abstract: A flowable, non-caking aqueous slurry of sodium chlorate and sodium chloride having a weight ratio of sodium chloride to sodium chlorate between about 0.55 and 0.65, and, more preferably, about 0.59, is described. The slurry contains a solid phase essentially entirely of sodium chloride. The slurries contain from about 28 to about 33% by weight sodium chlorate, from about 15 to about 21% by weight sodium chloride, and from about 45 to about 58% by weight water.The slurries are produced by forming an initial aqueous solution of sodium chlorate and sodium chloride containing from about 28 to about 50% by weight sodium chlorate and from about 0 to about 14% by weight sodium chloride and subsequently adding sufficient sodium chloride to obtain a slurry containing from about 28 to about 33% by weight sodium chlorate, from about 15 to about 21% by weight sodium chloride, and from about 45 to about 58% by weight water.Type: GrantFiled: December 13, 1979Date of Patent: August 11, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: Theodore H. Dexter, Willard A. Fuller
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Patent number: 4283264Abstract: A separator for an electrolytic cell or similar cell is made of a porous polymeric material, preferably porous polytetrafluoroethylene, and comprises a plurality of tubular portions of such material with one or two flange(s) at end(s) thereof for sealing to other such flanges and to the cell. The flanges are so constructed that when being sealed in place they do not strain or tear and do not strain or tear the material of the tubular portions. The separator is especially useful as a replacement for deposited asbestos diaphragms in electrolytic cells for the manufacture of chlorine and caustic.Type: GrantFiled: September 14, 1979Date of Patent: August 11, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: Richard D. Darling, Christine A. Lazarz
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Patent number: 4283523Abstract: The invention relates to a linear aromatic polyester of enhanced hydrolytic stability comprising bisphenol and dicarboxylic acid monomer residues which contains carboxylate ester end groups derived from a fluoro aliphatic alcohol of 1 to 45 carbon atoms. The invention also includes the process of preparing the polyester.Type: GrantFiled: June 4, 1979Date of Patent: August 11, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: Gideon Salee, Jerold C. Rosenfeld
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Patent number: 4278785Abstract: There are described linear aromatic polyesters of a bisphenol and a dicarboxylic acid having terminal carboxylate ester substituents of an aliphatic monofunctional alcohol of 8 to 45 carbons. The polyesters have enhanced hydrolytic stability compared to conventional polyesters of bisphenol and a dicarboxylic acid. Low molecular weight polyesters of the invention have improved stability on processing compared to comparable conventional polyesters of a bisphenol and a dicarboxylic acid. Processes for preparing the polyesters are also disclosed.Type: GrantFiled: June 4, 1979Date of Patent: July 14, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventor: Jerold C. Rosenfeld
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Patent number: 4271319Abstract: The present invention relates to a novel organic compound, phenyl beta-chloro-alpha-hydroxy-beta-(3-trifluoromethylphenyl)ethyl ketone. This compound may be produced by:(a) condensing 3-trifluoromethylbenzaldehyde with acetophenone under basic conditions to form a substituted chalcone,(b) epoxidation of the substituted chalcone to produce the corresponding epoxide, and(c) converting the epoxide to a chlorohydrin, phenyl beta-chloro-alpha-hydroxy-beta-(3-trifluoromethylphenyl)ethyl ketone.Type: GrantFiled: May 14, 1979Date of Patent: June 2, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: David Y. Tang, Arthur M. Foster
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Patent number: 4269754Abstract: Phenolic resin particles which are useful as friction particles for use in friction elements such as brake linings, clutch facings or other braking devices are produced by dispersing a liquid, heat curable phenolic resin in a paraffinic oil having a viscosity of at least about 1,000 SUS at 100.degree. F. at a temperature of about 100.degree. to about 175.degree. C. Preferred friction particles are prepared from phenolic resins containing benzylic ether linkages in the presence of hot oil or by other heating methods. Friction elements containing such particles are also described.Type: GrantFiled: July 19, 1979Date of Patent: May 26, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: Edward J. Lang, Michael G. Dubenitz
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Patent number: 4268457Abstract: The compound p-phenoxybenzotrichloride, useful as an intermediate in the preparation of various pesticides and monomers for the production of polyketone polymers, is prepared by the light-catalyzed reaction of p-phenoxytoluene with chlorine.Type: GrantFiled: June 28, 1979Date of Patent: May 19, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: James G. Colson, Victor F. G. Cooke, F. Howard Day, Michael J. Fifolt
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Patent number: 4268687Abstract: The present invention provides a novel process for the production of methyl or ethyl ester of (3-trifluoromethylphenyl)-acetic acid. The process comprises the steps of:(a) converting (3-trifluoromethyl)-benzotrichloride to the corresponding benzoyl chloride,(b) cyanation of the benzoyl chloride to produce the corresponding benzoyl cyanide,(c) hydrolyzing the benzoyl cyanide to produce the corresponding keto-acid,(d) hydrogenating the keto-acid to produce (3-trifluoromethylphenyl)-alpha-hydroxyacetic acid,(e) hydrogenating (3-trifluoromethylphenyl)-alpha-hydroxyacetic acid in the presence of glacial acetic acid to produce the corresponding substituted acetic acid, and(f) esterifying the substituted acetic acid using an alcohol selected from the group consisting of methyl and ethyl to obtain the corresponding methyl or ethyl ester of (3-trifluoromethylphenyl)-acetic acid.Type: GrantFiled: November 7, 1979Date of Patent: May 19, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: David Y. Tang, Arthur M. Foster
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Patent number: 4267141Abstract: Phenolic novolak resins are described which are structurally characterized as having from about 55% to about 90% of the available theoretical paraphenyl linkages in the resin chain bridged to a phenyl group. The resin compositions of this invention provide extended resin stability at relatively low temperatures without significant adverse affect on the cure speed at the molding temperature. The resins are especially suited for use in runnerless injection or cold manifold molding processes, but can also be used in transfer, compression and injection molding processes.Type: GrantFiled: December 28, 1979Date of Patent: May 12, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventor: Myron C. Annis