Abstract: A process for extracting a phosgene compound, comprising providing a membrane extracting unit comprising at least one extracting cell that comprises at least one membrane contactor module having at least two sides, a gas side and a liquid side; letting an initial gas stream comprising a phosgene compound flow on the gas side of the membrane contactor module; and letting an extractant liquid stream, suitable for dissolving a phosgene compound, flow on the liquid side of the membrane contactor module so that the extractant liquid stream absorbs the phosgene compound from the initial gas stream and provides a second extractant liquid stream enriched with the phosgene compound.
Type:
Grant
Filed:
February 10, 2015
Date of Patent:
September 5, 2017
Assignee:
HUNTSMAN INTERNATIONAL LLC
Inventors:
Rabah Mouazer, Arend-Jan Zeeuw, Robert Henry Carr
Abstract: The present invention relates to a tin-free composition comprising at least one silylated polymer and at least one tin-free polyhedral oligomeric metallo silsesquioxane. The present invention also relates to a process of curing a composition comprising a silylated polymer comprising the step of: contacting a silylated polymer with a tin-free polyhedral oligomeric metallo silsesquioxane.
Type:
Grant
Filed:
April 1, 2014
Date of Patent:
September 5, 2017
Assignee:
HUNTSMAN INTERNATIONAL LLC
Inventors:
Christopher Phanopoulos, Servaas Holvoet, Fabrice Desesquelles, Alexander Rene Klein
Abstract: A stable partly cured polyisocyanate composition is disclosed which comprises polyisocyanurate (intermediate polyisocyanurate comprising material) and which is further curable. Furthermore a process for making the intermediate (partly cured) polyisocyanurate comprising material and a process for further curing the partly cured polyisocyanurate composition is disclosed. Also polyisocyanurate comprising materials made or obtainable from partly cured intermediate polyisocyanurate comprising material are disclosed and processes for further curing a partly cured polyisocyanurate comprising composition (intermediate material).
Type:
Grant
Filed:
June 18, 2013
Date of Patent:
April 25, 2017
Assignee:
HUNTSMAN INTERNATIONAL LLC
Inventors:
Christian Esbelin, Hugo Verbeke, Hans Godelieve Guido Verbeke
Abstract: An embodiment of a closed-cell polymeric rigid foam may be made using a one-shot method and a reaction system that includes a hydrofluoroalkene physical blowing agent and a polyol mixture having an aminic polyol. The hydrofluoroalkene blowing agent has 3 to 5 carbon atoms and a boiling point between 10° C. and 40° C. at 1 atmosphere pressure. Embodiments of rigid foams may have high closed cell content and are particularly well suited for thermal insulation.
Type:
Grant
Filed:
December 10, 2015
Date of Patent:
March 7, 2017
Assignee:
HUNTSMAN INTERNATIONAL LLC
Inventors:
Sachchida N. Singh, Jinhuang Wu, Alan J. Hamilton
Abstract: The present disclosure provides a thermosetting resin composition including a benzoxazine component comprising two or more benzoxazine monomer compounds and at least one epoxy resin characterized in that a resultant cured product formed by curing the thermosetting resin composition possesses high heat resistance and low dielectric loss at high frequency. The thermosetting resin composition is especially suited for use in high speed printed circuit boards and semiconductor devices.
Abstract: Disclosed is the use of a curable composition for padding-free encapsulation of instrument transformers comprising (a) a cycloaliphatic epoxy resin, (b) a polyoxyalkylene diglycidylether (c) an OH-terminated polysiloxane, (d) a cyclic polysiloxane and (e) a non-ionic, fluoroaliphatic surface-active reagent, (f) a filler, (g) a hardener selected from anhydrides, (h) a curing accelerator selected from accelerators for anhydride curing of epoxy resins.
Abstract: The present disclosure relates to a curable system comprising at least two compositions (A) and (B) where composition (A) comprises an epoxy resin, an inorganic thixotropic agent, an organic gelling agent and a filler and composition (B) comprises a hardener, an inorganic thixotropic agent, an organic thixotropic agent and filler. The curable system may be used in the manufacture of components or parts of electrical equipment.
Type:
Grant
Filed:
March 25, 2010
Date of Patent:
January 17, 2017
Assignee:
Huntsman International LLC
Inventors:
Josef Grindling, Christian Beisele, Astrid Beigel, Cliff Beard, Ann Beard
Abstract: Provided are anthraquinone azo dyes and dye mixtures which are distinguished by a very good build-up capacity and which also yield tinctorially strong dyeings or prints in a golden-yellow to orange shade having all around good properties, especially high temperature light fastness properties.
Type:
Grant
Filed:
May 15, 2013
Date of Patent:
January 17, 2017
Assignee:
HUNTSMAN INTERNATIONAL LLC
Inventors:
Ralf Petermann, Urs Lauk, Kevin Murer, Yvonne Pesek
Abstract: A dye mixture, comprising at least one blue dyeing dye of the formula (1), wherein Q1 represents a bivalent radical of formula (4a), (4b) or (4c), wherein X1 denotes chlorine or fluorine, R1 is hydrogen or C1-C8 alkyl, R2 is hydrogen, C1-C8alkyl, C1-C4alkoxy or sulfo, Y1 is vinyl or a radical —CH2—CH2—U and U is a leaving group removable under alkaline conditions, R3 is hydrogen or C1-C8alkyl that is unsubstituted or substituted by hydroxy, sulfo, sulfato, cyano, carboxy, C1-C4alkoxy or phenyl, r and s are each independently of the other the number 0 or 1, and t is the number 0, 1 or 2, and the sum of r, s and t is 2 or 3 and at least one yellow or red dyeing reactive dye is suitable especially for the dichromatic or trichromatic dyeing or printing of natural or synthetic polyamide fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
Type:
Grant
Filed:
February 5, 2014
Date of Patent:
January 10, 2017
Assignee:
HUNTSMAN INTERNATIONAL LLC
Inventors:
Alexander Mueller, Rainer Hildebrand, Sandra Da Silva Saraiva, Wolfgang Mundle, Markus Kneubuehler
Abstract: A process according to the invention is a process to separate an initial fluid stream comprising phosgene and hydrogen chloride in at least a first and a second fluid stream, said first fluid stream being a hydrogen chloride enriched and phosgene depleted gaseous stream, said second fluid stream being a hydrogen chloride depleted and phosgene enriched stream. The separation is performed by feeding said initial fluid stream to a membrane separation unit, said membrane separation unit separating said initial fluid stream in a first and a second fluid stream.
Abstract: A process for hydrogenating an aromatic nitro compound according to the invention comprises providing a hydrogen gas stream and a liquid aromatic nitro compound stream; providing a fixed bed catalytic reactor having an inflow side and an outflow side; feeding to the inflow side, the hydrogen gas stream and the liquid aromatic nitro compound stream; converting the hydrogen gas and the aromatic nitro compound into an aromatic amine, thereby providing a reactor effluent comprising the aromatic amine and water; evacuating the reactor effluent from the reactor at the outflow side of the reactor; wherein an inert solvent or water is fed to the inflow side of the reactor at a molar ratio of moles inert solvent or water to moles hydrogen is more than 1.
Type:
Grant
Filed:
March 18, 2010
Date of Patent:
January 3, 2017
Assignee:
Huntsman International LLC
Inventors:
Christopher John Mitchell, Douglas Hyndman Stewart
Abstract: Adhesive prepared by reacting an organic polyisocyanate with a compound containing isocyanate-reactive hydrogen atoms in the presence of a trimerization catalyst. The softblock content of the adhesive is between 20 and 70 wt %.
Abstract: An embodiment of a closed-cell polymeric rigid foam may be made using a one-shot method and a reaction system that includes a hydrofluoroalkene physical blowing agent and a polyol mixture having an aminic polyol. The hydrofluoroalkene blowing agent has 3 to 5 carbon atoms and a boiling point between 10° C. and 40° C. at 1 atmosphere pressure. Embodiments of rigid foams may have high closed cell content and are particularly well suited for thermal insulation.
Type:
Grant
Filed:
December 10, 2015
Date of Patent:
December 27, 2016
Assignee:
Huntsman International LLC
Inventors:
Sachchida N. Singh, Jinhuang Wu, Alan J. Hamilton
Abstract: The present invention typically provides one-component polyurethane grout compositions and more specially to grout composition useful for seepage control and quick stoppage of water leakage under high water pressure environment, wherein the composition comprises a isocyanate prepolymer and auxiliary components selected from a plasticizer, a silane coupling agent, a catalyst, a cell stabilizer, an anionic surfactant, a filler, a blowing agent or a mixture thereof. The invention also provides the isocyanate prepolymer composition, obtained by reacting a polyfunctional isocyanate, with a polyfunctional polyol comprising at least one polyether polyol containing relatively low amount of ethylene oxide units, and optionally other polyfunctional polyols such as polyester polyols, biorenewable polyols or a mixture thereof, and at least a monofunctional hydroxyl containing compound, wherein the NCO content of said prepolymer is 3%˜18%.
Abstract: External wall insulation system comprising a high efficient insulation layer of rigid polyurethane or polyisocyanurate foam provided on at least one side with a facing, preferably a gastight (aluminum) layer, and a base layer provided on at least one of the surfaces of the facing wherein said base layer is a polyurethane layer or a polyisocyanurate layer.
Abstract: The invention relates to an isocyanate-containing prepolymer obtainable by reacting at least one isocyanate with at least one first compound selected from the group comprising monohydric alcohols, thiols and secondary amines; wherein the ratio of the NCO value of the isocyanate-containing prepolymer, to the OH, SH or NH value, of said monohydric alcohol, thiol or secondary amine respectively ranges from 0.0005 to 1.0000 and wherein said at least one first compound is present in a total amount of at least 40% by weight based on the total weight of the isocyanate-containing prepolymer.
Abstract: An apparatus for mixing at least first and second fluid, comprising: (a) a first nozzle comprising a first flow duct defining a first flow chamber, and having a first nozzle tip having a first discharge opening; and (b) a second nozzle comprising a second flow duct defining a second flow chamber, and having a second nozzle tip having a second discharge opening; wherein said first flow duct and said second flow duct are spirally wrapped each over the other. The invention also provides a process for mixing fluids, especially adapted for the production of isocyanates, and that is notably carried out in the apparatus of the invention.
Type:
Grant
Filed:
August 26, 2014
Date of Patent:
November 22, 2016
Assignee:
Huntsman International LLC
Inventors:
Neal Anthony Grob, James LaVerne Allbright
Abstract: The invention relates to a formulation suitable to provide polyurethane, the formulation comprising (a) at least one polyurethane forming mixture; (b) at least one phosphate component selected from the group consisting of ammonium polyphosphate (APP) and melamine phosphates, and mixtures thereof, and; (c) at least one metal or metalloid oxide particle having a maximum particle size of less than 300 ?m, wherein the metal or metalloid is selected from the group consisting of Mg, and Al, and wherein said at least one phosphate component is present in an amount ranging from 20 to 45% by weight based on 100% by weight of the formulation.
Type:
Grant
Filed:
February 9, 2012
Date of Patent:
November 22, 2016
Assignee:
Huntsman International LLC
Inventors:
Serge Bourbigot, Sophie Duquesne, Fabienne Samyn, Maryska Muller, Chris Ian Lindsay, Rene Alexander Klein, Giacomo Giannini
Abstract: The invention relates to an isocyanate-containing prepolymer obtainable by reacting at least one isocyanate which comprises methylene diphenyl diisocyanate with at least one first compound selected from the group comprising monohydric alcohols, thiols and secondary amines and with at least one second compound selected from the group comprising monohydric alcohols, thiols and secondary amines.
Abstract: The invention relates to a process for the impregnation of air core reactors or parts of air core reactors and impregnated air core reactors or parts thereof obtainable by said process.
Type:
Grant
Filed:
June 27, 2012
Date of Patent:
August 2, 2016
Assignee:
HUNTSMAN INTERNATIONAL LLC
Inventors:
Astrid Beigel, Christian Beisele, Ulrich Massen