Abstract: The invention relates to a primary amine component corresponding to formula I being (R1R2NR3)2NR4 wherein each of R1 and R2 are chosen from the group consisting of a methyl group, an ethyl group, an iso-propyl group and an n-propyl group; R3 being an alkoxyalkyl group chosen from the group consisting of —CH2CH2OCH2CH2—, —CH2CH2OCH2CH2CH2— and —CH2CH2CH2OCH2CH2CH2—; R4 is chosen from the group consisting of a hydrogen and —CH2CH2CH2NH2, and the use of said primary amine component corresponding to Formula I as a blowing catalyst of a catalyst system in a reaction of at least one polyisocyanate component and at least one isocyanate-reactive component, the catalyst system further comprising at least one gelling catalyst different from said component of formula I.
Type:
Grant
Filed:
November 22, 2011
Date of Patent:
July 5, 2016
Assignees:
Huntsman Corporation Hungary Zrt, Huntsman International LLC
Inventors:
Zsolt Gaspar, Heiko Heinrich Humbert, Gabor Felber, Attila Gaspar, Robert Allison Grigsby, Jr., Imre Kordas, Petra Emma Vanderstraeten
Abstract: Stable polyisocyanate composition comprising a compound comprising a group having the structure —CO—NH—O— in such an amount that the ratio of the number of —CO—NH—CO— groups to the number of isocyanate groups is at most equal to 1. Curable composition comprising this polyisocyanate composition, lithium halide, urea and an epoxy resin.
Type:
Grant
Filed:
November 30, 2012
Date of Patent:
July 5, 2016
Assignee:
Huntsman International LLC
Inventors:
Christian Esbelin, Hugo Verbeke, Hans Godelieve Guido Verbeke
Abstract: The present invention relates to azo dyes of formula (1), wherein R1 denotes C1-C12alkyl which is unsubstituted or substituted by one or more C1-C12alkoxy groups, hydroxyl groups, amino groups, cyano groups or halogen atoms and which may be interrupted one or more times by the radical —O—, —S—, —COO— or —OOC—: R4 is hydrogen or C1-C12alkyl; either R2 is cyano and R3 is halogen or R2 is halogen and R3 is cyano; and Ar represents a carbocyclic or heterocyclic aromatic radical, to the process for the preparation thereof, to mixtures containing said dyes and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fiber materials, more especially textile materials.
Abstract: Provided are processes for dyeing or printing fibre materials using reactive dye mixtures. The reactive dyes mixtures have been found to be suitable for dyeing or printing hydroxyl-group containing fibre materials or nitrogen-containing fibre materials. The dyeings or prints obtained according to such processes exhibit good all around fastness properties.
Abstract: The present invention relates to aqueous inks comprising (A) at least one dye of the formula (1) wherein R1 is C1-C12alkyl, or C2-C12alkyl interrupted by one or more oxygen atoms and/or —COO— groups, and R2, R3, R4 and R5 each independently of the others is hydrogen, C1-C12alkyl, chlorine, bromine, hydroxy or amino; (B) at least one dye of the formula (2) wherein R6 is hydrogen, bromine, chlorine or cyano, R7 is trifluoromethyl, bromine or chlorine, R8 is hydrogen, methyl or acetylamino, R9 and R10 each independently of the other is C1-C4alkyl unsubstituted or substituted by cyano or by acyloxy, one of the C1-C4alkyl radicals R9 and R10 is substituted by cyano or by acyloxy; and (C) at least one dye of the formula (3) wherein R11 is fluoro, trifluoromethyl, trifluoromethoxy, trifluoromethylsulfonyl or cyano, R12 and R13 each independently of the other represent hydrogen, C1-C12alkyl, C1-C12alkoxy, halogen, cyano, nitro, trifluoromethyl or —CO—OR16, wherein R16 is C1-C12alkyl unsubstituted or substituted by on
Type:
Grant
Filed:
August 12, 2013
Date of Patent:
June 21, 2016
Assignee:
Huntsman International LLC
Inventors:
Marc Burglin, Gilles Sperissen, Nathalie Stein, Mattia Perri
Abstract: A method to provide polyether polyols comprises the steps of •providing a crude polyether polyol mixture comprising polyether polyol and a base catalyst; •neutralizing said base catalyst; •removing, in a first dehydration step, at least part of the water from the neutralized polyether polyol; •redissolving at least part of the salt crystals obtained by removal of at least part of the water; •removing, in a second dehydration step, at least part of the water from the neutralized polyether polyol mixture, thereby providing salt crystals; •removing the salt crystals from the neutralized polyether polyol, thereby providing the polyether polyol mixture.
Type:
Grant
Filed:
April 25, 2013
Date of Patent:
May 31, 2016
Assignee:
HUNTSMAN INTERNATIONAL LLC
Inventors:
Rene Den Heeten, Paul Anton Termorshuizen
Abstract: Reactive dyes of, for example, formula (101) especially suitable for dyeing synthetic polyamide fibre materials and which yield dyeings or prints having good wet-fastness properties, and a process for their preparation.
Type:
Grant
Filed:
April 25, 2013
Date of Patent:
May 24, 2016
Assignee:
Huntsman International LLC
Inventors:
Alexander Mueller, Kurt Plattner, Damien Schoehn, Rainer Hildebrand
Abstract: Adhesives, reaction systems, and processes for the production of lignocellulosic composites. The reaction system comprises a multi-component adhesive and a lignocellulosic substrate. The lignocellulosic substrate comprises a plurality of lignocellulosic adherends and is preferably a mass of wood particles. The multi-component adhesive comprises a multi-functional isocyanate, a hydrophilic polyahl, and an organotransition metal catalyst. The multi-component adhesive is characterized by being formulated into at least two mutually reactive chemical component streams. The process comprises the separate application of the mutually reactive chemical component streams of the multi-component adhesive to the lignocellulosic substrate, followed by forming and pressing the adhesive treated substrate under conditions appropriate for curing the adhesive and forming a lignocellulosic composite article.
Type:
Grant
Filed:
May 22, 2008
Date of Patent:
April 19, 2016
Assignee:
Huntsman International LLC
Inventors:
Christopher J. Moriarty, Sachchida N. Singh, Paul D. Coleman
Abstract: Lignocellulosic composites are made by pressing a mixture of a particulate lignocellulosic material with polymeric MDI, in the presence of a fatty amine ethoxylate anti-masking agent.
Type:
Grant
Filed:
June 15, 2010
Date of Patent:
April 5, 2016
Assignee:
Huntsman International LLC
Inventors:
Robert A. Grigsby, Jr., Christopher J. Moriarty, Sachchida N. Singh, George A. Smith
Abstract: The present invention relates to a highly durable, water resistant, and water and/or oil repellent outdoor textile fabric. The outdoor textile fabric may be prepared by treating the front surface of the textile fabric with an aqueous treatment composition containing a fluorochemical agent and applying a second treatment composition containing a polyurethane to the back surface of the textile fabric. The outdoor textile fabric may be used in a variety of outdoor applications including automotive and marine applications, as a cover, canopy or banner, in military applications, as an awning, tent, umbrella, or in casual outdoor furniture.
Type:
Grant
Filed:
October 21, 2009
Date of Patent:
March 15, 2016
Assignee:
Huntsman International LLC
Inventors:
Juergen Arnold, Betty Tilley, Ray Seals, Robert Manley
Abstract: Process for making a flexible polyurethane foam by reacting a polyisocyanate and a polyol composition in the presence of water, a reactive amine catalyst and a specific metal salt. The foams have a low level of volatile organic compounds (VOCs) and a desirable combination of mechanical and durability properties.
Type:
Grant
Filed:
July 24, 2012
Date of Patent:
March 15, 2016
Assignee:
Huntsman International LLC
Inventors:
Johan Antoine Macken, Thomas Julien Joncheray, Jan Vandenbroeck
Abstract: Crystalline foam and process for making it by first creating a crystalline arrangement of gas bubbles in curable composition and allowing this composition to cure subsequently.
Type:
Grant
Filed:
June 15, 2010
Date of Patent:
March 15, 2016
Assignee:
Huntsman International LLC
Inventors:
Thomas Julien Joncheray, Jan Marc Vandenbroeck
Abstract: An embodiment of a closed-cell polymeric rigid foam may be made using a one-shot method and a reaction system that includes a hydrofluoroalkene physical blowing agent and a polyol mixture having an aminic polyol. The hydrofluoroalkene blowing agent has 3 to 5 carbon atoms and a boiling point between 10° C. and 40° C. at 1 atmosphere pressure. Embodiments of rigid foams may have high closed cell content and are particularly well suited for thermal insulation.
Type:
Grant
Filed:
December 10, 2014
Date of Patent:
January 19, 2016
Assignee:
Huntsman International LLC
Inventors:
Sachchida N. Singh, Jinhuang Wu, Alan J. Hamilton
Abstract: An embodiment of a closed-cell polymeric rigid foam may be made using a one-shot method and a reaction system that includes a hydrofluoroalkene physical blowing agent and a polyol mixture having an aminic polyol. The hydrofluoroalkene blowing agent has 3 to 5 carbon atoms and a boiling point between 10° C. and 40° C. at 1 atmosphere pressure. Embodiments of rigid foams may have high closed cell content and are particularly well suited for thermal insulation.
Type:
Grant
Filed:
December 10, 2014
Date of Patent:
January 19, 2016
Assignee:
Huntsman International LLC
Inventors:
Sachchida N. Singh, Jinhuang Wu, Alan J. Hamilton
Abstract: Process for the production of di- and poly(diamino diphenyl methane) comprising the steps of (a) reacting aniline and formaldehyde in the presence of an acid catalyst to produce a reaction mixture containing di- and polyamines; (b) neutralizing the reaction mixture containing di- and polyamines; (c) separating the neutralized reaction mixture into an organic phase containing di- and polyamines and an aqueous phase; (d) further treating the organic phase separated off in step (c) by (d1) washing with water followed by (d2) separating the washed mixture into an organic phase and an aqueous phase and (d3) further fractionation of the organic phase to produce purified di- and polyamines on the one hand and aniline/water on the other hand; (e) further treating the aqueous phase separated off in step (c) by (e1) washing with aniline followed by (e2) separating the washed mixture into an aqueous phase and an organic phase and (e3) further treatment of the aqueous phase to remove the aniline thereby leaving an efflu
Type:
Grant
Filed:
August 28, 2008
Date of Patent:
December 22, 2015
Assignee:
Huntsman International LLC
Inventors:
Robert Carr, Johannes Lodewijk Koole, Willem Van Der Borden
Abstract: Reactive dyes of formula (1) wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, X is halogen, 3- or 4-carboxypyridin-1-yl, or 3- or 4-carbamoylpyridin-1-yl, Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, and q is the number 1 or 2, are suitable for dyeing and printing cellulosic or amide-group-containing fiber materials.
Type:
Grant
Filed:
May 24, 2013
Date of Patent:
November 24, 2015
Assignee:
Huntsman International LLC
Inventors:
Georg Roentgen, Jean-Christophe Graciet, Rainer Hildebrand, Laszlo Fekete, Marie Schmidlin, Hubert Jean-Luc Christnacher
Abstract: Nano-sized polyurea particles or a dispersion of polyurea particles suitable for improving the mechanical properties of a polyurethane material, said particles having at least equivalent diameter dimensions in the nanosize range of 50 nm up to 700 nm, a uniform equivalent diameter particle size distribution, an amount of urethane bonds calculated on the total amount of urea+urethane bonds in said particles of <1%, and a glass transition temperature (Tg) of >100° C., preferably Tg >120° C., more preferably >150° C. measured in a second heating cycle after heating to >220° C. at 20° per minute using Differential Scanning calorimetry.
Type:
Application
Filed:
June 28, 2013
Publication date:
October 15, 2015
Applicant:
Huntsman International LLC
Inventors:
Steve Andre Woutters, Christopher Ian Lindsay
Abstract: Nanodispersions of inorganic clays in isocyanate may be created via pre-exfoliation, delamination, or both of the clay and subsequent mixing with isocyanate. In an embodiment, such an isocyanate nanodispersion is reacted with an isocyanate-reactive material or substrate to form a polyurethane nanocomposite.
Type:
Grant
Filed:
May 6, 2009
Date of Patent:
September 15, 2015
Assignees:
Huntsman International LLC, Regents of the University of Minnesota
Inventors:
G. Harikrishnan, Christopher Ward Macosko, Christopher Ian Lindsay, Sachchida Nand Singh
Abstract: The present invention relates to a formulation comprising at least one thermoplastic polyurethane polymer and a flame retardant composition, the flame retardant composition comprising i) at least one metal or metalloid oxide particle selected from magnesium oxide, magnesium hydroxide, silicon oxide, or aluminium oxide; ii) at least one phosphate component selected from the group comprising ammonium polyphosphate (APP), melamine phosphate, melamine pyrophosphate and melamine polyphosphate or mixture thereof, and iii) at least one oligomeric phosphate ester.
Type:
Grant
Filed:
February 9, 2012
Date of Patent:
September 15, 2015
Assignee:
Huntsman International LLC
Inventors:
Anja Anneke Vanhalle, Hugo Verbeke, Giacomo Giannini, Sandra Meynen