Patents Assigned to Huntsman International LLC
  • Patent number: 8872034
    Abstract: Flame retardant thermoplastic composition comprising at least one thermoplastic polymer, preferably a thermoplastic polyurethane polymer, at least one conventional flame retardant and optionally at least one mineral filler together with modified polysiloxane in an amount of less than 1% by weight based on the total composition, preferably between 0.1 and 0.9% and most preferably between 0.25 and 0.75% by weight. The thermoplastic compositions are useful in applications where low flame properties are desirable, such as wire and cable applications.
    Type: Grant
    Filed: May 19, 2010
    Date of Patent: October 28, 2014
    Assignee: Huntsman International LLC
    Inventors: Anja Vanhalle, Hugo Verbeke, Sandra Marie Louise Meynen
  • Patent number: 8871979
    Abstract: A process for providing methylene-bridged polyphenyl polyamines from aniline and formaldehyde according to the invention comprises the subsequent steps of a) condensing aniline and formaldehyde; b) reacting, in a first catalytic reaction step, said condensate over a solid catalyst, whereby an intermediate mixture is provided; c) converting, in a subsequent catalytic reaction step, said intermediate mixture into methylene-bridged polyphenyl polyamines in presence of a subsequent solid catalyst, thereby providing said methylene-bridged polyphenyl polyamines.
    Type: Grant
    Filed: November 26, 2009
    Date of Patent: October 28, 2014
    Assignee: Huntsman International LLC
    Inventors: Christopher John Mitchell, Avelino Corma Canos, Robert Henry Carr, Pablo Botella Asuncion
  • Patent number: 8864850
    Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fiber materials, while at the same time exhibiting good build-up behavior, and yield dyeings of deep shade having good fastness properties.
    Type: Grant
    Filed: January 23, 2013
    Date of Patent: October 21, 2014
    Assignee: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen
  • Patent number: 8865315
    Abstract: The present invention is directed to a coating system deposited onto at least a portion of a substrate comprising: an inner coating layer deposited onto at least a portion of the substrate; a viscous gel coating layer deposited onto at least a portion of the inner coating layer wherein the viscous coating layer comprises: (A) the reaction product of: (i) at least one primary amine; (ii) a monofunctional surfactant; and (iii) a liquid polybutadiene; (B) optionally, a fatty acid; and (C) optionally, a secondary swelling agent; and an outer coating layer deposited onto a least a portion of the viscous coating layer; and an outer coating layer deposited onto a least a portion of the viscous coating layer.
    Type: Grant
    Filed: January 23, 2012
    Date of Patent: October 21, 2014
    Assignee: Huntsman International LLC
    Inventor: Ali Ozsahin
  • Publication number: 20140309324
    Abstract: Process for making a flexible polyurethane foam by reacting a polyisocyanate and a polyol composition in the presence of water, a reactive amine catalyst and a specific metal salt.
    Type: Application
    Filed: July 24, 2012
    Publication date: October 16, 2014
    Applicant: Huntsman International LLC
    Inventors: Johan Antoine Macken, Thomas Julien Joncheray, Jan Vandenbroeck
  • Patent number: 8852382
    Abstract: A thermosetting composition comprising (a) 97 to 40 percent by weight of at least one bis(dihydrobenzoxazine) prepared by the reaction of an unsubstituted or substituted bisphenol with at least one unsubstituted position ortho to each hydroxyl group, formaldehyde and a primary amine; and (b) 3 to 60 percent by weight of at least one bisphenol, wherein the percent by weight refer to the total amount of components (a) and (b), with the proviso that (a) and (b) add up to 100 percent by weight; and (c) optionally other components. Cured products made from these compositions have valuable chemical, physical and mechanical properties.
    Type: Grant
    Filed: January 30, 2008
    Date of Patent: October 7, 2014
    Assignee: Huntsman International LLC
    Inventor: Frans Setiabudi
  • Patent number: 8844574
    Abstract: An apparatus for mixing at least first and second fluid, comprising: (a) a first nozzle comprising a first flow duct defining a first flow chamber, and having a first nozzle tip having a first discharge opening; and (b) a second nozzle comprising a second flow duct defining a second flow chamber, and having a second nozzle tip having a second discharge opening; wherein said first flow duct and said second flow duct are spirally wrapped each over the other. The invention also provides a process for mixing fluids, especially adapted for the production of isocyanates, and that is notably carried out in the apparatus of the invention.
    Type: Grant
    Filed: March 6, 2006
    Date of Patent: September 30, 2014
    Assignee: Huntsman International LLC
    Inventors: Neal Anthony Grob, James LaVerne Allbright
  • Publication number: 20140259455
    Abstract: The present invention relates to a method of increasing the chlorine fastness of dyed synthetic polyamide fibre materials, which comprises treating the fibre material after dyeing with an aqueous liquor comprising a thiourea/formaldehyde/bisphenol condensate or a thiourea/polyisocyanate adduct.
    Type: Application
    Filed: October 16, 2012
    Publication date: September 18, 2014
    Applicant: Huntsman International LLC
    Inventor: Philippe Ouziel
  • Patent number: 8829243
    Abstract: A method for removing methylene-bridged polyphenyl polyamines from an aqueous stream comprising said methylene-bridged polyphenyl polyamines according to the invention comprises the steps of Providing a pertraction equipment comprising a membrane with a first side and a second side opposite to said first side; Bringing an aqueous stream comprising methylene-bridged polyphenyl polyamines into contact with the first side of the membrane and bringing an organic stream into contact with the second side of the membrane, thereby causing the methylene-bridged polyphenyl polyamines to transfer from the aqueous stream through the membrane to the organic stream. The method further comprises, before bringing the aqueous stream and organic stream in contact with the membrane, the step of wetting the membrane with a liquid having a surface tension of less than 40 mN/m.
    Type: Grant
    Filed: July 22, 2010
    Date of Patent: September 9, 2014
    Assignee: Huntsman International LLC
    Inventors: Rabah Mouazer, Johannes Lodewijk Koole, Ramon Scheffer
  • Patent number: 8822729
    Abstract: A method for providing a secondary or tertiary amine with formula (R1R2NR3)2NR4 is provided, wherein each of R1 and R2 are chosen from the group consisting of a methyl group, an ethyl group, an iso-propyl group and an n-propyl group; R3 being an alkoxyalkyl group chosen from the group consisting of —CH2CH2OCH2CH2—, —CH2CH2OCH2CH2— and —CH2CH2CH2OCH2CH2CH2—; R4 is chosen from the group consisting of a hydrogen, a methyl group, an ethyl group, an iso-propyl group, an n-propyl group and a group with formula R1R2NR3. The method comprises the steps: (?) reacting R1R2NR3(OH) with ammonia, thereby providing a mixture comprising (R1R2NR3)2NR4; (?) separating (R1R2NR3)2NR4 from said mixture.
    Type: Grant
    Filed: December 12, 2013
    Date of Patent: September 2, 2014
    Assignees: Huntsman International LLC, Huntsman Corporation Hungary Zrt
    Inventors: Zsolt Gaspar, Heiko H. Humbert, Gabor Felber, Attila Gaspar, Robert A Grigsby, Jr., Imre Kordas, Petra Emma Vanderstraeten
  • Patent number: 8822595
    Abstract: Isocyanurate-reactive mixture obtained by reacting an anhydride and a polyol; process for making it; polyisocyanate composition comprising this mixture; binder composition comprising such a polyisocyanate composition; the use of such a polyisocyanate composition and/or binder composition for making a polyisocyanurate and such polyisocyanurates.
    Type: Grant
    Filed: July 30, 2009
    Date of Patent: September 2, 2014
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Johan Robert Derluyn, Eric Huygens, Hans Verbeke, Luthgarde Alberta Marcella Geeraerts, Mathias Johan Richard Devos, Kristin Guillemine Irène Devos
  • Patent number: 8809410
    Abstract: Flexible polyurethane foam having a density of 25-70 kg/m3 and a compression load deflection of 5-15 kPa. Process for making a flexible polyurethane foam and the use as plant growth medium and in green roofs and green walls.
    Type: Grant
    Filed: September 14, 2010
    Date of Patent: August 19, 2014
    Assignee: Huntsman International LLC
    Inventors: Johan Antoine Stefaan Macken, Herman Eugene Germain Moureau, Steven Ramsdonck, Annelies Vandevelde
  • Patent number: 8802890
    Abstract: The present invention relates to a process for manufacturing isocyanates from an amine compound. The process comprises the steps of a) Providing chlorine; b) Providing carbon monoxide; c) Reacting said chlorine and said carbon monoxide for providing phosgene, the carbon monoxide being provided in an adjustable molar excess; d) Providing an amine compound and phosgenating said amine compound using said phosgene thereby providing said isocyanate; the process further comprises adjusting said adjustable molar excess, i.e. the molar excess of carbon monoxide, for adjusting the color of the isocyanate.
    Type: Grant
    Filed: November 5, 2009
    Date of Patent: August 12, 2014
    Assignee: Huntsman International LLC
    Inventors: Robert Henry Carr, Johannes Lodewijk Koole, Udo Brian Dave Mike Rodger Bruinsma
  • Patent number: 8796345
    Abstract: A method to form a urethane material, the method comprises blending and reacting at least one isocyanate, at least one isocyanate reactive compound and a metallized polyhedral oligomeric silsesquioxane to provide said urethane material, the metallized polyhedral oligomeric silsesquioxane is a dimeric structure with general formula wherein M represents a metal providing a 6-coordinated metal center, x and y being 1, R1O and R2O represent an alkoxide bridging the 6-coordinated metal centers, R3OH and R4OH represent an alcohol ligand and each of R5, to R18 is selected from the group consisting of alkyl-, polyether- and polyester ligands.
    Type: Grant
    Filed: December 8, 2010
    Date of Patent: August 5, 2014
    Assignee: Huntsman International LLC
    Inventors: Rene Alexander Klein, Christina Marinus, Chris Ian Lindsay, Hendrikus Abbenhuis, Jos Wilting, Gijsbert Gerritsen
  • Patent number: 8785570
    Abstract: A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate-reactive composition, wherein the reaction is conducted at an isocyanate index of 1600 to 100,000 and in the presence of a trimerization catalyst, wherein the polyisocyanate comprises a) 75-100% by weight of diphenylmethane diisocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4?-diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25° C.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: July 22, 2014
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Eric Huygens, Stijn Roekaerts, Marc Vandervesse, Hans Godelieve Guido Verbeke
  • Publication number: 20140196224
    Abstract: The present disclosure relates to a dye of formula (1a) and also to a process for its preparation and to its use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fibre materials, more especially textile materials.
    Type: Application
    Filed: March 18, 2014
    Publication date: July 17, 2014
    Applicant: Huntsman International LLC
    Inventors: Antoine Clement, Alfons Arquint, Urs Lauk
  • Patent number: 8779182
    Abstract: Process for the simultaneous and continuous production of two different mixtures of predominantly 4,4?-MDI and 2,4?-MDI in a single-step suspension melt crystallisation process whereby a mixed diisocyanate feed stream [MIx] is used to produce simultaneously two mixed diisocyanate streams [MIy] and [MIz] wherein x=80 to 92, y=97 to 99 and z=60 to 80 preferably x=82 to 88, y=97.2 to 98.5 and z=63 to 70 where x, y and z are percentages by weight of the 4,4?-MDI isomer contained in the diisocyanate isomer mixture.
    Type: Grant
    Filed: October 1, 2009
    Date of Patent: July 15, 2014
    Assignee: Huntsman International LLC
    Inventors: Johannes Lodewijk Koole, Adolf Daan Zijl, Robert Henry Carr
  • Publication number: 20140174011
    Abstract: The present invention is directed to a method of fabricating a wall structure that comprises a polyurethane backing. In certain embodiments, no additional layer is coated onto or disposed on the polyurethane backing that is formed through the process disclosed herein.
    Type: Application
    Filed: February 26, 2014
    Publication date: June 26, 2014
    Applicant: Huntsman International LLC
    Inventor: Jason Smith
  • Publication number: 20140173835
    Abstract: Dye mixtures comprising at least one reactive dye of the formula (1) together with at least one reactive dye of the formula (2), wherein one of the radicals A and B denotes NH2, and the other one of the radicals A and B denotes OH, D is a benzene or naphthalene radical, R1 is hydrogen, hydroxy, sulfo, C1-C4alkyl or C1-C4alkoxy unsubstituted or substituted in the alkyl moiety by hydroxy or by sulfato, R2 is hydrogen, C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino or ureido, R3 is C1-C4alkyl, (R4)0-2 denotes 0 to 2 identical or different substituents selected from the group C1-C4alkyl, C1-C4alkoxy or sulfo, X1 is halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Y1, Y2, Y3, Y4 and Y5 are each independently of the other vinyl or a radical —CH2CH2—U and U is a group removable under alkaline conditions, h, k, l, m and n are each independently of the other the number 0, 1 or 2, and p and q are each independently of the other the number 0 or 1, are suitable for dyeing and printing cellulosic or nitrogen-contai
    Type: Application
    Filed: June 19, 2012
    Publication date: June 26, 2014
    Applicant: HUNTSMAN INTERNATIONAL LLC
    Inventors: Georg Roentgen, Athanassios Tzikas, Hubert Jean-Luc Christnacher, Laszlo Fekete
  • Publication number: 20140155655
    Abstract: A method for providing a secondary or tertiary amine with formula (R1R2NR3)2NR4 is provided, wherein each of R1 and R2 are chosen from the group consisting of a methyl group, an ethyl group, an iso-propyl group and an n-propyl group; R3 being an alkoxyalkyl group chosen from the group consisting of —CH2CH2OCH2CH2-, —CH2CH2OCH2CH2- and —CH2CH2CH2OCH2CH2CH2-; R4 is chosen from the group consisting of a hydrogen, a methyl group, an ethyl group, an iso-propyl group, an n-propyl group and a group with formula R1R2NR3. The method comprises the steps: (?) reacting R1R2NR3(OH) with ammonia, thereby providing a mixture comprising (R1R2NR3)2NR4; (?) separating (R1R2NR3)2NR4 from said mixture.
    Type: Application
    Filed: December 12, 2013
    Publication date: June 5, 2014
    Applicants: Huntsman Corporation Hungary ZRt, Huntsman International LLC
    Inventors: Zsolt Gaspar, Heiko H. Humbert, Gabor Felber, Attila Gaspar, Robert A Grigsby, JR., Imre Kordas, Petra Emma Vanderstraeten