Patents Assigned to INEOS STYROLUTION GROUP GMBH
  • Patent number: 10843384
    Abstract: The invention relates to a process for the production of thermoplastic moulding compounds, in particular for the production of acrylonitrile-butadiene-styrene (ABS), wherein at least a first reagent (11) and a second reagent (12) of the thermoplastic moulding compounds are fed to a loop conduit (29) which comprises a static mixer (36), wherein the reagents (11, 12) are pressed in loops through the loop conduit (29) and passing the static mixer (36), whereby the reagents (11, 12) are dispersed to form a dispersion (15) in the static mixer (36). The invention also relates to a thermoplastic moulding compound that is produced by the inventive process.
    Type: Grant
    Filed: June 9, 2016
    Date of Patent: November 24, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: SangJun Ahn, Wolfgang Fischer, Norbert Niessner, Brian J. Banaszak, Roland Walker, Ula El-Jaby, Achim Stammer, Klaus-Dieter Hungenberg, Bernd Hisgen
  • Patent number: 10815342
    Abstract: The invention relates to a process for producing a stabilizer dispersion S, wherein the stabilizer dispersion is an aqueous composition comprising at least one phenolic stabilizer A, at least one thio co-stabilizer B, at least one surfactant C and at least one silicon oil component D. Further the present invention is directed to a process for producing a thermoplastic moulding composition, in particular an composition based on acrylonitrile butadiene styrene copolymers (ABS), using the stabilizer dispersion S.
    Type: Grant
    Filed: June 6, 2017
    Date of Patent: October 27, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Gisbert Michels, Ulrich Jansen, Frank Eisentraeger, Stefan Kaminsky
  • Patent number: 10815367
    Abstract: Thermoplastic moulding composition for 3D printing containing a polymer mixture A made of components a and b: a being from 30 to 95% by weight of at least one vinylaromatic copolymer a with average molar mass Mw from 150 000 to 360 000 g/mol, b being from 5 to 70% by weight of at least one impact modifier b, where the viscosity of the moulding composition (measured in accordance with ISO 11443) at shear rates of from 1 to 10 l/sec and at a temperature of 250° C. is not higher than 1×105 Pa*s and the Melt Volume Rate (MVR, measured in accordance with ISO 1133 for 220° C. and 10 kg load) is more than 6 ml/10 min.
    Type: Grant
    Filed: December 18, 2014
    Date of Patent: October 27, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Norbert Niessner, Frank Eisentraeger, Stephanie Baumann, Itana Lohse, Hans-Werner Schmidt, Josef Meiners, Florian Wieberger
  • Publication number: 20200255628
    Abstract: The present invention relates to a fibre composite material W of increased translucency and/or mechanical strength, comprising a copolymer C encompassing monomers A-1, where A-1 form covalent bonds with functional groups B-1 on the surface of fibres B embedded in the fibre composite material W, and this fibre composite material W has greater translucency and/or mechanical strength than a fibre composite material Win which the copolymer C contains no A-1. The present invention further embraces a method for producing a fibre composite material W of increased translucency and/or mechanical strength.
    Type: Application
    Filed: January 14, 2020
    Publication date: August 13, 2020
    Applicant: INEOS STYROLUTION GROUP GMBH
    Inventors: Norbert NIESSNER, Philipp DEITMERG, Eike JAHNKE, Marko BLINZLER, Achim BERNHARDT, Tobias SCHULZ
  • Patent number: 10731031
    Abstract: The invention relates to a method for producing thermoplastic molding materials based on acrylonitrile-butadiene-styrene copolymers (ABS) having improved surface properties, in particular improved resistance of the surface quality to storage in a warm, humid environment, and having a reduced content of residual monomers. The invention further relates to the use of a fluid bed dryer and/or a flash dryer in the production of thermoplastic ABS molding materials in order to improve the surface quality. The invention further relates to the use of a fluid bed dryer and/or a flash dryer in the production of thermoplastic ABS molding materials having a reduced content of residual monomers. The invention further relates to ABS molding materials that can be produced by means of the method according to the invention and to molded parts (e.g., molded bodies, films, and coatings) that can be produced from the thermoplastic molding materials according to the invention.
    Type: Grant
    Filed: December 2, 2016
    Date of Patent: August 4, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Gisbert Michels, Norbert Niessner
  • Patent number: 10717911
    Abstract: Thermally conductive polymer (TCP) resin compositions are described, comprising: 50 to 75% matrix polymer (I) comprising styrenic polymers (?) such as ABS (acrylonitrile-butadiene-styrene) resins, ASA (acrylonitrile-styrene-acrylate) resins and elastomeric block copolymers of the structure (S-(B/S))n-S; and 25 to 50% thermally conductive filler material (II) (D50 0.1 to 200 ?m), consisting of carbonyl iron powder (11-1) in mixture with multi wall carbon nanotubes, silicon carbide, diamond, graphite, aluminosilicates and/or boron nitride (II-2); wherein the volume ratio of (ll-1)/(ll-2) is 15:1 to 0.1:1. Shaped articles made thereof can be used for materials with antistatic finish, electrical and electronic housings, toys and helmet inlays.
    Type: Grant
    Filed: October 6, 2016
    Date of Patent: July 21, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Janna Michaelis De Vasconcellos, Gisbert Michels, Norbert Niessner, Hans-Werner Schmidt, Florian Wieberger, Tristan Kolb
  • Patent number: 10710274
    Abstract: A method for producing a thermoplastic moulding compound by means of an extruder (10), which comprises at least one feed zone (20), at least one mixing section (30), at least one venting section (40) and at least one discharge zone (50), wherein in the at least one feed zone (20) a water-containing first component and a second component are supplied, in the at least one mixing section (30) the thermoplastic moulding compound is mixed and contained water is evaporated, in the at least one venting section (40) water vapour is removed from the moulding compound and in the at least one discharge zone (50) the moulding compound is discharged. At least one of the mixing housings (31, 32) is kept at a temperature that is equal to or lower than the temperature of the moulding compound within the mixing section (30).
    Type: Grant
    Filed: May 4, 2017
    Date of Patent: July 14, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventor: Wolfgang Fischer
  • Patent number: 10711126
    Abstract: Thermoplastic molding compositions can be used in hydrofluoro olefin containing areas, comprising components A, B, C and D: 10 to 35 wt.-% ABS graft rubber copolymer A obtained by emulsion polymerization; 50 to 70 wt.-% SAN copolymer B; 4 to 20 wt.-% elastomeric SBC block copolymer C, and 4 to 20 wt.-% ABS graft rubber copolymer D obtained by mass polymerization.
    Type: Grant
    Filed: April 18, 2017
    Date of Patent: July 14, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Janna Michaelis De Vasconcellos, Norbert Niessner, KwanHee Lee, Gisbert Michels
  • Patent number: 10711110
    Abstract: The invention relates to a method for producing a thermoplastic fibre composite containing a thermoplastic moulding compound (A) as a polymer-matrix (M), reinforcement fibres (B), and optionally additive (C). Said method comprises the following steps: i) flat structures (F) made from reinforcing fibres (B) treated with a silane sizing material are provided, ii) the flat structures (F) are placed in a thermoplastic molding compound (A) which comprises at least 0.3 mol %, with respect to components (A), of a chemically reactive functionality, iii) chemically reactive groups of the thermoplastic molding compound (A) are reacted in the polymer matrix (M) with the polar groups of the treated reinforcing fibres (B), iv) the at least one additive (C) is optionally incorporated v) cooling. Said method is particularly suitable for producing fibrous composites.
    Type: Grant
    Filed: April 22, 2016
    Date of Patent: July 14, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Norbert Niessner, Eike Jahnke
  • Patent number: 10683372
    Abstract: The invention relates to graft copolymers (B) composed of an agglomerated graft core (B1) and at least one graft shell (B2) and also to copolymers (C) having an agglomerating effect, a method for producing said graft copolymers (B), thermoplastic molding compositions and also the use of the thermoplastic molding compositions.
    Type: Grant
    Filed: March 3, 2016
    Date of Patent: June 16, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Roland Walker, Gisbert Michels, Brian J. Banaszak, Norbert Niessner
  • Patent number: 10654249
    Abstract: The present invention relates to a composite film comprising a styrene copolymer layer (a), a metal layer (b), optionally a coloured layer (c), and a transparent polymer layer (d), wherein (b) is located between (a) and (d) and optionally (c) is located between (b) and (d). Moreover, the present invention refers to a method for producing a composite film and to the use of such composite film for laminating a surface or a part thereof. Finally, the present invention further relates to a product that is at least partly laminated by a composite film according to the present invention.
    Type: Grant
    Filed: May 15, 2015
    Date of Patent: May 19, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Jaehee Lee, JaeSung Han, Jong Hoo Lee
  • Patent number: 10633528
    Abstract: The invention relates to a styrene copolymer composition comprising a) 60 to 99.9% by weight of styrene-based polymer matrix component A, b) 0.1 to 5% by weight of PMMA-based, cross-linked polymer bead as light diffuser component B, wherein the polymer beads have an average particle diameter from 0.5 to 20 ??? and a refractive index ranging from 1.34 to 1.55, and c) 0 to 39.9% by weight of further component C, different to A and B, wherein the sum of components A) to C) is 100% by weight and the composition exhibits a light transmittance greater than 80%, a haze greater than 90% and a Yellowness Index less than 4.5.
    Type: Grant
    Filed: December 15, 2015
    Date of Patent: April 28, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Eike Jahnke, Ricardo Daniel Fajardo Figueroa
  • Patent number: 10619061
    Abstract: The invention relates to the use of a thermoplastic moulding compound for 3D Printing, made of a mixture of the following components A-E: A: 35-60 wt. % impact resistant modified polymer A comprising: 30-95 wt. % SAN-copolymer and 5-70 wt. % ABS-graft copolymer; B: 33-58 wt. % aliphatic polyamide B; C: 1-10 wt. % SANMSA-terpolymer C as a compatibilizing agent; D: 0.01-5 wt. % processing agent D; and E: 0-30 wt. % other additives E.
    Type: Grant
    Filed: March 16, 2017
    Date of Patent: April 14, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Stephanie Baumann, Frank Eisentraeger, Josef Meiners, Norbert Niessner, Hans-Werner Schmidt
  • Patent number: 10563046
    Abstract: The present invention relates to a fibre composite material W of increased translucency and/or mechanical strength, comprising a copolymer C encompassing monomers A-1, where A-1 form covalent bonds with functional groups B-1 on the surface of fibres B embedded in the fibre composite material W, and this fibre composite material W has greater translucency and/or mechanical strength than a fibre composite material Win which the copolymer C contains no A-1. The present invention further embraces a method for producing a fibre composite material W of increased translucency and/or mechanical strength.
    Type: Grant
    Filed: April 22, 2016
    Date of Patent: February 18, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Norbert Niessner, Philipp Deitmerg, Eike Jahnke, Marko Blinzler, Achim Bernhardt, Tobias Schulz
  • Patent number: 10550260
    Abstract: Polymer blends comprising components A), B) and C): A) 80 to 96% by weight of an impact modified styrenic polymer A), B) 1 to 7% by weight of a polymer blend B) comprising B1) 25 to 75% by weight of polyisobutylene and B2) 25 to 75% by weight of a polyolefin, C) 3 to 13% by weight of an elastomeric block copolymer C) of structure (A-(B/A))n-A, where A is a vinylaromatic block, (B/A) is a random copolymer block of vinylaromatic monomer and diene, and n is 1 to 10, exhibit improved environmental stress crack resistance properties in presence of hydrofluoro olefins.
    Type: Grant
    Filed: March 17, 2016
    Date of Patent: February 4, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Thomas W. Cochran, John A. Morris
  • Patent number: 10525439
    Abstract: The invention relates to a process for the production of thermoplastic moulding compounds, in particular ABS, wherein at least a first reagent (11) and a second reagent (12) of the thermoplastic moulding compounds are fed to a gear pump (10) which comprises a housing and at least a first gear wheel that is rotatable relative to the housing about a first axis, and a second gear wheel that is rotatable relative to the housing about a second axis, wherein a loop conduit (29) is provided, and wherein the reagents (11, 12) are pressed in a loop through the loop conduit (29) and passing the gear wheels, whereby the reagents (11, 12) are dispersed to form a dispersion (15) in the gear pump (10). The invention also relates to a thermoplastic moulding compound that is produced by the inventive process.
    Type: Grant
    Filed: April 11, 2016
    Date of Patent: January 7, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: SangJun Ahn, Wolfgang Fischer, Norbert Niessner, Brian J. Banaszak, Roland Walker, Ula El-Jaby, Achim Stammer, Klaus-Dieter Hungenberg, Bernd Hisgen
  • Patent number: 10508180
    Abstract: The invention relates to a method for producing thermoplastic fibre composites made from a thermoplastic matrix (M) comprising a thermoplastic moulding compound (A) and reinforcing fibres (B). Said method has technical advantages when it comprises the following steps: i) a flat structure (F) made of reinforcing fibres (B) is provided, ii) the flat structure (F) is introduced into a matrix M, iii) functional groups of the matrix are reacted with polar groups of the reinforcing fibres (B), iv) the fibre composite materials is consolidated.
    Type: Grant
    Filed: April 22, 2016
    Date of Patent: December 17, 2019
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Norbert Niessner, Eike Jahnke
  • Publication number: 20190359800
    Abstract: A thermoplastic molding composition can be used for metal plating, in particular for electroplating, comprising the components A) to C): A) 20 to 55 wt. % of at least one graft rubber copolymer (A) B) 20 to 55 wt. % of at least one rubber free SAN copolymer, and C) 25 to 34% by weight of at least one aromatic polycarbonate; the metal-plated polymer composition can be used for automotive applications.
    Type: Application
    Filed: August 13, 2019
    Publication date: November 28, 2019
    Applicant: INEOS STYROLUTION GROUP GMBH
    Inventors: Frank EISENTRAEGER, Norbert NIESSNER, Eugen WIEDEL
  • Patent number: 10351679
    Abstract: A process produces a polymer composition (A) containing a styrene copolymer (a) and an impact modifier (b), comprising a copolymer (b1) as graft base and a graft (b2), where the steps of the process are: (1) providing a crosslinked copolymer (b1) made of: (b11) from 70 to 99.99% by weight of a conjugated diene or acrylate, (b12) from 0 to 29% by weight of another comonomer, (b13) from 0 to 10% by weight of crosslinking monomers, and (b14) from 0.01 to 0.7% by weight of a chain-transfer reagent; (2) applying, to the copolymer (b1), at least one graft (b2) comprising: (b21) from 65 to 95% by weight of a vinylaromatic monomer, (b22) from 5 to 35% by weight of acrylonitrile and/or methacrylonitrile, and (b23) from 0 to 30% by weight of monoethylenically unsaturated monomers, thus providing the impact modifier (b); (3) mixing the styrene copolymer (a) and the impact modifier (b), and thus leads to improved mechanical properties of the polymer composition (A).
    Type: Grant
    Filed: March 23, 2016
    Date of Patent: July 16, 2019
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Brian J. Banaszak, Roland Walker, Libor Seda, Johannes Barth, Gisbert Michels, Nikolaus Nestle
  • Patent number: 10329401
    Abstract: Deep black thermoplastic molding compositions having high gloss can be produced by mixing the following components: 90% to 99.5% by weight of one or more styrene copolymers as component A1, or 90% to 99.5% by weight of one or more polymethylmethacrylates (PMMA) and/or polyalkylmethacrylates as component A2, or 90% to 99.5% by weight of one or more polycarbonates (PC) and/or polyester carbonates as component A3, 0.01% to 5% by weight of a pigment black as component B, 0.1% to 1.5% by weight of at least two dyes soluble in the molding composition as component C, 0% to 5% by weight of one or more additives other than components B and C, as component D. These are found to be particularly weathering-resistant.
    Type: Grant
    Filed: September 12, 2014
    Date of Patent: June 25, 2019
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Philipp Boeckmann, Norbert Mosbach, Eike Jahnke