Patents Assigned to INEOS STYROLUTION GROUP GMBH
  • Patent number: 10525439
    Abstract: The invention relates to a process for the production of thermoplastic moulding compounds, in particular ABS, wherein at least a first reagent (11) and a second reagent (12) of the thermoplastic moulding compounds are fed to a gear pump (10) which comprises a housing and at least a first gear wheel that is rotatable relative to the housing about a first axis, and a second gear wheel that is rotatable relative to the housing about a second axis, wherein a loop conduit (29) is provided, and wherein the reagents (11, 12) are pressed in a loop through the loop conduit (29) and passing the gear wheels, whereby the reagents (11, 12) are dispersed to form a dispersion (15) in the gear pump (10). The invention also relates to a thermoplastic moulding compound that is produced by the inventive process.
    Type: Grant
    Filed: April 11, 2016
    Date of Patent: January 7, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: SangJun Ahn, Wolfgang Fischer, Norbert Niessner, Brian J. Banaszak, Roland Walker, Ula El-Jaby, Achim Stammer, Klaus-Dieter Hungenberg, Bernd Hisgen
  • Patent number: 10508180
    Abstract: The invention relates to a method for producing thermoplastic fibre composites made from a thermoplastic matrix (M) comprising a thermoplastic moulding compound (A) and reinforcing fibres (B). Said method has technical advantages when it comprises the following steps: i) a flat structure (F) made of reinforcing fibres (B) is provided, ii) the flat structure (F) is introduced into a matrix M, iii) functional groups of the matrix are reacted with polar groups of the reinforcing fibres (B), iv) the fibre composite materials is consolidated.
    Type: Grant
    Filed: April 22, 2016
    Date of Patent: December 17, 2019
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Norbert Niessner, Eike Jahnke
  • Publication number: 20190359800
    Abstract: A thermoplastic molding composition can be used for metal plating, in particular for electroplating, comprising the components A) to C): A) 20 to 55 wt. % of at least one graft rubber copolymer (A) B) 20 to 55 wt. % of at least one rubber free SAN copolymer, and C) 25 to 34% by weight of at least one aromatic polycarbonate; the metal-plated polymer composition can be used for automotive applications.
    Type: Application
    Filed: August 13, 2019
    Publication date: November 28, 2019
    Applicant: INEOS STYROLUTION GROUP GMBH
    Inventors: Frank EISENTRAEGER, Norbert NIESSNER, Eugen WIEDEL
  • Patent number: 10351679
    Abstract: A process produces a polymer composition (A) containing a styrene copolymer (a) and an impact modifier (b), comprising a copolymer (b1) as graft base and a graft (b2), where the steps of the process are: (1) providing a crosslinked copolymer (b1) made of: (b11) from 70 to 99.99% by weight of a conjugated diene or acrylate, (b12) from 0 to 29% by weight of another comonomer, (b13) from 0 to 10% by weight of crosslinking monomers, and (b14) from 0.01 to 0.7% by weight of a chain-transfer reagent; (2) applying, to the copolymer (b1), at least one graft (b2) comprising: (b21) from 65 to 95% by weight of a vinylaromatic monomer, (b22) from 5 to 35% by weight of acrylonitrile and/or methacrylonitrile, and (b23) from 0 to 30% by weight of monoethylenically unsaturated monomers, thus providing the impact modifier (b); (3) mixing the styrene copolymer (a) and the impact modifier (b), and thus leads to improved mechanical properties of the polymer composition (A).
    Type: Grant
    Filed: March 23, 2016
    Date of Patent: July 16, 2019
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Brian J. Banaszak, Roland Walker, Libor Seda, Johannes Barth, Gisbert Michels, Nikolaus Nestle
  • Patent number: 10329401
    Abstract: Deep black thermoplastic molding compositions having high gloss can be produced by mixing the following components: 90% to 99.5% by weight of one or more styrene copolymers as component A1, or 90% to 99.5% by weight of one or more polymethylmethacrylates (PMMA) and/or polyalkylmethacrylates as component A2, or 90% to 99.5% by weight of one or more polycarbonates (PC) and/or polyester carbonates as component A3, 0.01% to 5% by weight of a pigment black as component B, 0.1% to 1.5% by weight of at least two dyes soluble in the molding composition as component C, 0% to 5% by weight of one or more additives other than components B and C, as component D. These are found to be particularly weathering-resistant.
    Type: Grant
    Filed: September 12, 2014
    Date of Patent: June 25, 2019
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Philipp Boeckmann, Norbert Mosbach, Eike Jahnke
  • Patent number: 10280296
    Abstract: A process for producing a thermoplastic molding composition comprising: 10% to 40% by weight of a graft copolymer A comprising 50% to 70% by weight, based on A, of a graft base A1 formed from an elastomeric, crosslinked acrylic ester polymer and 30% to 50% by weight of a graft shell A2, 50% to 90% by weight of a hard matrix B formed from copolymers of styrene or ?-methylstyrene and acrylonitrile, 0% to 50% by weight of a further graft copolymer C, 0% to 15% by weight of additives D, wherein the reaction for preparation of the acrylic ester polymer A and/or the reaction for preparation of C is conducted in the presence of 0.01 to 4 times the molar amount of sodium carbonate, based on the sum total of the molar amount of initiator used in the preparation of the graft base and graft shell, leads to lower coagulate formation.
    Type: Grant
    Filed: March 26, 2015
    Date of Patent: May 7, 2019
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Philipp Boeckmann, Wolfgang Fischer, Hans-Juergen Hausser
  • Patent number: 10189932
    Abstract: The present invention relates to a process for the production of styrene graft copolymers comprising addition and graft copolymerization of styrene monomers A1 and vinyl cyanide monomers A2 to a graft base B where the ratio by mass of A1 to A2 in the monomer feed at the end of the monomer feed time is lower than the ration by mass integrated over the entire monomer feed time. The present invention further relates to a graft copolymer obtainable by a process according to the invention, a molding composition comprising such a graft copolymer, and a molding obtained from such a molding composition.
    Type: Grant
    Filed: April 24, 2015
    Date of Patent: January 29, 2019
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Roland Walker, Gisbert Michels, Brian J. Banaszak
  • Patent number: 10150830
    Abstract: A copolymer comprising (A) 20-50% (w/w) of methyl methacrylate (MMA), (B) 40-80% (w/w) of one or more vinylaromatic(s) and, optionally, (C) 0-10% (w/w) of one or more aliphatic vinyl(s) can be used in a polymer composition for generating translucent final products.
    Type: Grant
    Filed: February 9, 2015
    Date of Patent: December 11, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Thomas W. Cochran, Norbert Niessner
  • Patent number: 10138364
    Abstract: The invention relates to a thermoplastic composition containing the components A and B and optionally the additional components C and D, the sum of which equals 100 wt. %. The molding compound consists of: a) 60 to 75 wt. % of one or more styrene copolymers A, b) 25 to 40 wt. % of one or more graft copolymers B, c) 0 to 15 wt. % of a rubber C which is different from component B, and d) 0 to 5 wt. % of one or more additives D. The composition contains 0.2 to 3.0 wt. %, based on the total weight of the components A to D, of oligomers, can be readily processed, and leads to scratch-resistant molded parts.
    Type: Grant
    Filed: January 27, 2015
    Date of Patent: November 27, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Norbert Niessner, Philipp Boeckmann, Roland Walker, Marcus Reining
  • Patent number: 10131779
    Abstract: Polymer blend comprising 95 to 100% of a component A) and 0 to 5% of additives, where A) is consisting of polymers A1) to A4): A1) 50 to 75% of a star shaped block copolymer A1 which comprises at least 2 terminal vinylaromatic hard blocks S and diene soft blocks B, where the proportion of the hard blocks S is from 65 to 90%, and Mn of block S is 35000 to 200000; A2) 5 to 15% of block copolymer A2 which comprises 2 terminal vinylaromatic hard blocks S1 and S2 and random copolymer blocks (B/S) consisting of 20 to 60% vinylaromatic monomers, and 80 to 40% dienes where the proportion of blocks S1 and S2 is 40 to 60%; and Mn of blocks S1 is 35000 to 200000, and Mn of blocks S2 is 5000 to 30000 and the molar S1/S2 ratio is 1:0.
    Type: Grant
    Filed: September 2, 2015
    Date of Patent: November 20, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Michael Hamilton, Thomas W. Cochran, Norbert Niessner, Konrad Knoll
  • Publication number: 20180291195
    Abstract: Thermally conductive polymer (TCP) resin composition (i) or (ii) are described, comprising components (I) and (II): (i) 40 to 72% by volume of at least one matrix polymer (I); 28 to 60% by volume of a thermally conductive filler material (II) (D50 0.1 to 200 ?m) consisting of aluminosilicate (II-1) in combination with a further component (II-2) selected from: multi wall carbon nanotubes, graphite and and boron nitride, wherein the volume ratio (ll-1)/(ll-2) is 30:1 to 0.1:1; or (ii) 40 to 65% by volume of at least one matrix polymer (I); 35 to 60% by volume of aluminosilicate (II) (D50 0.1 to 200 ?m); wherein the matrix polymer (I) comprises styrenic polymers (I?) selected from: ABS resins, ASA resins, and elastomeric block copolymers. Shaped articles made thereof can be used as “Cool Touch” surfaces for automobile interior, motor housings, lamp housings and electrical and electronic housings and as heat sinks for high performance electronics or LED sockets.
    Type: Application
    Filed: October 6, 2016
    Publication date: October 11, 2018
    Applicant: Ineos Styrolution Group GmbH
    Inventors: Tobias SCHULZ, Norbert NIESSNER, Gisbert MICHELS, Janna MICHAELIS DE VASCONCELLOS, Hans-Werner SCHMIDT, Florian WIEBERGER, Tristan KOLB
  • Patent number: 10072140
    Abstract: Polymer blend comprising components A, B and C: A: 1 to 19.5% by weight of an elastomeric block copolymer A based on styrene (S-TPE); B: 0.5 to 8% by weight of a compatibilizer component B; and C: 80 to 98.5% by weight of at least one semi-crystalline olefin homo- or copolymer C. The invention further relates to a composition comprising thermoplastic elastomers based on styrene (S-TPE) for use as compatibilizer of S-TPE block copolymers and polyolefins, a process for the preparation of the polymer blend, a master batch for the preparation of the polymer blend, and single- and multilayer films comprising said polymer blend and their use for food packaging and as shrink hood.
    Type: Grant
    Filed: February 10, 2015
    Date of Patent: September 11, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Konrad Knoll, Andrea Colombo
  • Patent number: 10072145
    Abstract: The invention relates to a thermoplastic molding composition which comprises at least one copolymer component made of styrene monomers and nitrile monomers, and also at least one graft copolymer based on an acrylate rubber. The invention also relates to thermoplastic moldings produced from the thermoplastic molding composition, and the use thereof.
    Type: Grant
    Filed: November 19, 2014
    Date of Patent: September 11, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Philipp Boeckmann, Wolfgang Fischer, Maarten Staal
  • Patent number: 10072144
    Abstract: Polymer blends comprising (A) at least one polystyrene (co)polymer other than styrene methyl methacrylate copolymer (SMMA), (B) at least one poly(lactic acid) (PLA) and (C) at least one styrene methyl methacrylate copolymer (SMMA) have advantageous properties.
    Type: Grant
    Filed: February 9, 2015
    Date of Patent: September 11, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventor: Thomas W. Cochran
  • Patent number: 10059791
    Abstract: The invention relates to thermoplastic ABS molding compositions comprising components A) and B): A) from 5 to 80% by weight of a graft polymer A) having bimodal particle size distribution; and B) from 20 to 95% by weight of a thermoplastic polymer B) having a viscosity number VN of from 50 to 120 ml/g. The invention further relates to a process for the preparation of graft copolymer A and to the graft copolymer made by that process.
    Type: Grant
    Filed: April 16, 2014
    Date of Patent: August 28, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Norbert Niessner, SangJun Ahn, Rudy Verstraeten, Gisbert Michels, Florian Patcas, YoungHwa Hwang, Brian J. Banaszak, Roland Walker, Michel Pepers, Johannes Barth
  • Patent number: 10047220
    Abstract: A process for preparing a thermoplastic polymer composition or a thermoplastic polymer blend, comprising: —from 20 to 80% by weight of at least one water-moist elastomer component A containing up to 40%, preferably up to 30% by weight of residual water, —from 20 to 80% by weight of at least one thermoplastic polymer B, —from 0 to 40% by weight of at least one further polymer C, and —from 0 to 60% by weight of additive(s) D, by mixing the elastomer component A with the thermoplastic polymer B and, if present, the further polymer C and, if present, the additive(s) D in an extruder, comprising the steps of precipitating the elastomer component A, and mechanical dewatering of the elastomer component A leads to improved salt-free products.
    Type: Grant
    Filed: July 1, 2014
    Date of Patent: August 14, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Norbert Niessner, Brian Banaszak, Rudy Verstraeten, Gisbert Michels, Wolfgang Fischer, Christian Ruthard, Ulrich Jansen
  • Patent number: 10023676
    Abstract: Conjugated diene monovinylarene block copolymers containing an internal conjugated diene block and having superior kink resistance properties are disclosed. These copolymers can be used to produce tubing and other end-use articles, and can be a replacement for flexible PVC.
    Type: Grant
    Filed: August 3, 2016
    Date of Patent: July 17, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Jinping Joe Zhou, Walter H. Pace, David A. Young
  • Patent number: 9982123
    Abstract: The invention relates to a process for producing molding compositions containing: a) from 55 to 85% by weight of copolymer A composed of vinylaromatic monomer A1 and a,B-unsaturated monomer A2; b) from 15 to 45% by weight of graft copolymer B with particle size from 50 to 550 nm composed of: B1: from 60 to 80% by weight of rubbery graft base B1 composed of: B11: from 80 to 99% by weight of at least one C2-C8-alkyl acrylate, B12: from 0.5 to 2.5% by weight of cyclic crosslinking agent, B13: from 0 to 2% by weight of non-cyclic crosslinking agent, B2: from 20 to 40% by weight of at least one graft shell B2 composed of: B21: from 60 to 75% by weight of a styrene, B22: from 25 to 40% by weight of acrylonitrile, c) from 0 to 10% by weight of additives C; where the reaction time of the polymerization for producing the graft base B1 is in the range from 2 to 5 h, and the addition of the starting materials takes place over at least two chronological segments.
    Type: Grant
    Filed: April 1, 2015
    Date of Patent: May 29, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Jordan Kopping, Philipp Boeckmann, Norbert Niessner, Lydia Behring
  • Patent number: 9873784
    Abstract: The invention is directed to polymer compositions comprising components (a), (b), (c) and (d): (a) 80 to 97% by weight of component (a) comprising a copolymer (a1) of styrene (a11) and methyl methacrylate (a12), wherein the amount present of (a11) is from 70 to 90% by weight and the amount present of (a12) is from 10 to 30% by weight, based in each case on (a1), (b) 3 to 20% by weight of polyphenylene ether as component (b); (c) 0 to 2% by weight of polystyrene as component (c); (d) 0 to 17%, in particular 0 to 15% by weight of conventional additives as component (d), having improved heat resistance, surface hardness, depth of color and gloss.
    Type: Grant
    Filed: November 10, 2014
    Date of Patent: January 23, 2018
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventor: Thomas W. Cochran
  • Patent number: 9850377
    Abstract: The present invention relates to a polymer blend comprising 75-99.5% (w/w) of at least one polylactic acid) (PLA) and 0.5-25% (w/w) of at least one styrene butadiene copolymer containing at least 50% (w/w) styrene. The present invention further relates to the use of such polymer blend for producing products and to the resulting products. Moreover, an object of the present invention is the use of a styrene butadiene block copolymer having a dendrimer structure comprising 50-85% (w/w) styrene as an additive of polymer blends comprising at least 50% (w/w) of PLA and a method of producing the polymer blend according to the invention.
    Type: Grant
    Filed: November 11, 2014
    Date of Patent: December 26, 2017
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Thomas W. Cochran, Michael Hamilton