Patents Assigned to J. M. Huber Corporation
  • Patent number: 7553416
    Abstract: New silica gel materials and novel methods of producing such are provided. The method itself entails a manner of mixing the reactants together in a one-pot process such that the time required for aging is reduced without compromising the ability to target pore size production. In such a way, the pH of the reaction drives pore size development, thereby permitting a more efficient process to be followed in terms of expensive drying/heating steps being reduced timewise, if not altogether. Furthermore, in one embodiment, the resultant gel materials exhibit a certain pore size minimum while simultaneously exhibiting a degree of softness heretofore unavailable. As such, not only is this novel method more efficient in silica gel manufacture, but the resultant materials are completely novel as well. The gel materials made therefrom may be utilized in a variety of different end uses, such as cooking oil filtration, soft skin cleansers, dental abrasives, and the like.
    Type: Grant
    Filed: June 27, 2007
    Date of Patent: June 30, 2009
    Assignee: J.M. Huber Corporation
    Inventors: Duen-Wu Hua, Michael C. Withiam, Francis R. W. Godwin, Fitzgerald A. Sinclair
  • Patent number: 7510602
    Abstract: An environmental control for use in air handling systems that are required to provide highly effective filtration of noxious gases is provided. In one embodiment, a filtration system utilizes a novel combination of at least one metal-doped silica-based gel and zeolite materials to trap and/or modify, and remove such undesirable gases (such as ammonia, ethylene oxide, formaldehyde, and nitrous oxide, as examples) from an enclosed environment. The gel component exhibits specific porosity requirements and density measurements; the zeolite component is generally acidic and is preferably not reacted with any salts or like substances. The novel combination of such gels and zeolites permits highly effective noxious gas filtration over a wide range of known toxic industrial chemicals such that excellent breakthrough results are attained, particularly in comparison with prior media filtration products.
    Type: Grant
    Filed: July 6, 2006
    Date of Patent: March 31, 2009
    Assignee: J.M. Huber Corporation
    Inventors: David K. Friday, Fitzgerald A. Sinclair, Michael C. Withiam
  • Patent number: 7455791
    Abstract: An aqueous chemical mechanical polishing slurry is provided that comprises precipitated amorphous silica abrasive particles treated with acidic aluminum. Also provided is a method of polishing an electronic component substrate comprising the steps of: a) obtaining an electronic component substrate, the electronic component substrate having an insulating film deposited over it, an interconnection pattern formed in the insulating film, and interconnection material deposited on the insulated film and in the interconnection pattern; and b) polishing the interconnection material until a surface of said insulating film is exposed by using an aqueous chemical mechanical polishing slurry comprising: precipitated amorphous silica abrasive particles treated with acidic aluminum.
    Type: Grant
    Filed: December 14, 2004
    Date of Patent: November 25, 2008
    Assignee: J.M. Huber Corporation
    Inventors: Duen-Wu Hua, Frands Nielsen
  • Patent number: 7438895
    Abstract: Precipitated silica comprising porous silica particles having a cumulative surface area for all pores having diameters greater than 500 ? of less than 6 m2/g, as measured by mercury intrusion, and a percentage cetylpyridinium chloride (% CPC) Compatibility of greater than about 85%. The precipitated silica product is especially well-adapted for use in dentifrices containing cetylpyridinium chloride, which do not attach to the low surface area silica product in a meaningful level and thus remain available for antimicrobial action. Processes for making the silica product including the introduction of sodium sulfate powder during different process steps in order to enhance such a compatibility with CPC are provided.
    Type: Grant
    Filed: December 27, 2006
    Date of Patent: October 21, 2008
    Assignee: J.M. Huber Corporation
    Inventor: Karl Gallis
  • Patent number: 7377965
    Abstract: The present invention relates generally to an environmental control unit for use in air handling systems that provides highly effective filtration of noxious gases (such as ammonia). Such a filtration system utilizes novel metal-doped silica-based gels to trap and remove such undesirable gases from an enclosed environment. Such gels exhibit specific porosity requirements and density measurements. Furthermore, in order for proper metal doping to take effect, such gels must be treated while in a wet state. The combination of these particular properties and metal dopant permits highly effective noxious gas filtration such that uptake and breakthrough results are attained, particularly in comparison with prior silica gel filtration products. Methods of using and specific filter apparatuses are also encompassed within this invention.
    Type: Grant
    Filed: June 20, 2005
    Date of Patent: May 27, 2008
    Assignee: J.M. Huber Corporation
    Inventors: Michael C. Withiam, Fitzgerald A. Sinclair, David K. Friday
  • Patent number: 7377975
    Abstract: Pigment suitable for use in coating compositions for inkjet recording media. Surfaces of an inorganic particulate are interacted with a water-soluble polyvalent metal salt in an aqueous medium. The treated particle surfaces have a significant cationic surface charge imparted to them. The salt is a salt of a metal of Group II or Group III of the Periodic Table. Inkjet recording media treated with a coating composition containing the above pigment provide high density, fast-drying, and non-feathering ink images with suitable water fastness, while the coating compositions also offer cost advantages and improved rheology at higher pigment levels over coatings based on silica pigments.
    Type: Grant
    Filed: September 20, 2006
    Date of Patent: May 27, 2008
    Assignee: J.M. Huber Corporation
    Inventors: Ching-Yih Chen, Ricky L. Giddens, Richard D. Carter
  • Patent number: 7361324
    Abstract: A method for forming calcium carbonate is provided, the method comprising the steps of: (a) milling calcium hydroxide; (b) providing a reactor vessel containing a slurry of the milled calcium hydroxide; and (c) carbonating the slurry of the milled calcium hydroxide by introducing carbon dioxide into the reactor vessel to form basic calcium carbonate by a precipitation reaction, wherein the initial reaction temperature is from about 8° C. to about 15° C.
    Type: Grant
    Filed: June 21, 2004
    Date of Patent: April 22, 2008
    Assignee: J. M. Huber Corporation
    Inventors: Sung-Tsuen Liu, Michael Robert Hart
  • Patent number: 7306788
    Abstract: Unique abrasive and/or thickening materials that are in situ generated compositions of precipitated silicas and silica gels are provided. Such compositions exhibit different beneficial characteristics depending on the structure of the composite in situ generated material. With low structured composites (as measured via linseed oil absorption levels from 40 to 100 ml oil absorbed/100 g composite), simultaneously high pellicle film cleaning properties and moderate dentin abrasion levels are possible in order to accord the user a dentifrice that effectively cleans tooth surfaces without detrimentally abrading such surfaces. Increased amounts of high structure composite materials tend to accord greater viscosity build and thickening benefits together with such desirable abrasion and cleaning properties, albeit to a lesser extent than for the low structure types.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: December 11, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Patrick D. McGill, William C. Fultz
  • Patent number: 7303766
    Abstract: Coated particles of metal (such as calcium) silicate that exhibit excellent odor neutralization and sebum absorption properties when present within certain cosmetic and/or personal care formulations and suspensions are provided. Uncoated calcium silicate exhibits a high pH level that may have a deleterious effect upon such cosmetic and/or personal care compositions, thereby rendering the overall composition ineffective for its intended purpose, particularly if the calcium silicate is present in its usual state at high loading levels. Alternatively, if certain materials present within personal care compositions exhibit a sufficiently low pH level, the effectiveness of such calcium silicates may be compromised as well.
    Type: Grant
    Filed: February 3, 2005
    Date of Patent: December 4, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Michael C. Withiam, Donald P. Conley, Michael Simone
  • Patent number: 7303767
    Abstract: Coated particles of metal (such as calcium) silicate that exhibit excellent odor neutralization and sebum absorption properties when present within certain cosmetic and/or personal care formulations and suspensions are provided. Uncoated calcium silicate exhibits a high pH level that may have a deleterious effect upon such cosmetic and/or personal care compositions, thereby rendering the overall composition ineffective for its intended purpose, particularly if the calcium silicate is present in its usual state at high loading levels. Alternatively, if certain materials present within personal care compositions exhibit a sufficiently low pH level, the effectiveness of such calcium silicates may be compromised as well.
    Type: Grant
    Filed: February 3, 2005
    Date of Patent: December 4, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Michael C. Withiam, Donald P. Conley, Michael Simone
  • Patent number: 7303742
    Abstract: Unique abrasive and/or thickening materials that are in situ generated compositions of precipitated silicas and silica gels are provided. Such compositions exhibit different beneficial characteristics depending on the structure of the composite in situ generated material. With low structured composites (as measured via linseed oil absorption levels from 40 to 100 ml oil absorbed/100 g composite), simultaneously high pellicle film cleaning properties and moderate dentin abrasion levels are possible in order to accord the user a dentifrice that effectively cleans tooth surfaces without detrimentally abrading such surfaces. Increased amounts of high structure composite materials tend to accord greater viscosity build and thickening benefits together with such desirable abrasion and cleaning properties, albeit to a lesser extent than for the low structure types.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: December 4, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Patrick D. McGill, William C. Fultz
  • Patent number: 7297318
    Abstract: Methods for the removal of lead from a metal silicate during the process of manufacturing of such a material are provided. With the reliance upon lower cost starting silicon dioxide starting materials that are known to exhibit elevated amounts of heavy metal therein for the purpose of producing metal silicates (such as sodium silicate, as one example), it has been realized that removal of significant amounts of such heavy metals is necessary to comply with certain regulatory requirements in order to provide a finished material that exhibits the same low level of heavy metal contamination as compared with finished materials that are made from more expensive, purer starting silicon dioxides. Two general methods may be followed for such decontamination purposes. One entails the introduction of a calcium phosphate material, such as dicalcium phosphate, tricalcium phosphate, and/or hydroxyapatite, to a formed metal silicate solution but prior to filtering.
    Type: Grant
    Filed: November 17, 2005
    Date of Patent: November 20, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Yung-Hui Huang, John V. Offidani
  • Patent number: 7273596
    Abstract: A new and useful method of simultaneously producing and granulating anhydrous dicalcium phosphate is provided. Such a method entails the reaction of concentrated phosphoric acid with a powdered material of lime and/or calcium carbonate in substantially equal stoichiometric amounts, with subsequent, mixing, drying, milling, and sieving to provide the correct target particle size range for the resultant granulated materials. Such specifically produced granulated anhydrous dicalcium phosphate materials exhibit very high available calcium levels, excellent flow characteristics, and very high capability for compression into tablets. Products including such particularly produced granulated anhydrous dicalcium phosphate materials are also encompassed within this invention.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: September 25, 2007
    Assignee: J.M. Huber Corporation
    Inventor: Sung-Tsuen Liu
  • Patent number: 7273521
    Abstract: A new and useful method of simultaneously producing and granulating composite materials for simultaneous internal delivery of high amounts of calcium and phosphate to a subject (person or animal) is provided. Such a method entails the dropwise addition of concentrated phosphoric acid within a specified amount of water into a vessel containing a powdered material of lime and/or calcium carbonate, with the lime and/or calcium carbonate present in an excessive amount of the phosphoric acid, with subsequent, mixing, drying, milling, and sieving to provide the correct target particle size range for the resultant granulated materials. Such specifically produced granulated calcium carbonate/dicalcium phosphate materials exhibit very high available calcium levels, very high available phosphate levels, excellent flow characteristics, and very high capability for compression into tablets. Products including such particularly produced composite materials are also encompassed within this invention.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: September 25, 2007
    Assignee: J.M. Huber Corporation
    Inventor: Sung-Tsuen Liu
  • Patent number: 7270803
    Abstract: Unique abrasive materials that are in situ generated compositions of precipitated silicas and silica gels are provided. Such compositions exhibit different beneficial, particularly simultaneously high pellicle film cleaning properties and moderate dentin abrasion levels. Such a result thus accords the user a dentifrice that effectively cleans tooth surfaces without detrimentally abrading such surfaces. Furthermore, the produced abrasive materials also exhibit very high and desirable brightness properties that permit easy incorporation and utilization within dentifrices for aesthetic purposes. Encompassed within this invention is a unique method for making such gel/precipitated silica composite materials for such a purpose, particularly under high shear conditions, as well as the different materials within the structure ranges described above and dentifrices comprising such.
    Type: Grant
    Filed: March 23, 2006
    Date of Patent: September 18, 2007
    Assignee: J.M. Huber Corporation
    Inventor: Patrick D. McGill
  • Patent number: 7267719
    Abstract: The invention relates to a process for regulating the porosity and printing properties of paper, in particular uncoated wood-containing paper such as SC-paper, wherein a sufficient quantity of colloidal PCC having a BET surface area of 10-100 m2/g is used as a filler in the paper to achieve a desired porosity of the paper; as well as paper containing colloidal PCC as filler, and a pigment mixture suitable for paper manufacture and containing colloidal PCC.
    Type: Grant
    Filed: December 10, 2004
    Date of Patent: September 11, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Klaus Akilles Lunden, Ib Attrup, Jens Toftelund Madsen
  • Patent number: 7267814
    Abstract: Unique abrasive and/or thickening materials that are in situ generated compositions of precipitated silicas and silica gels are provided. Such compositions exhibit different beneficial characteristics depending on the structure of the composite in situ generated material. With low structured composites (as measured via linseed oil absorption levels from 40 to 100 ml oil absorbed/100 g composite), simultaneously high pellicle film cleaning properties and moderate dentin abrasion levels are possible in order to accord the user a dentifrice that effectively cleans tooth surfaces without detrimentally abrading such surfaces. Increased amounts of high structure composite materials tend to accord greater viscosity build and thickening benefits together with such desirable abrasion and cleaning properties, albeit to a lesser extent than for the low structure types.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: September 11, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Patrick D. McGill, William C. Fultz
  • Patent number: 7262233
    Abstract: Disclosed is a silica substrate treated with a polysiloxane, and an organosilane, wherein the organosilane is described by the formula: RSi(R?)x(OR?)3-x; wherein R is a long-chain hydrocarbon group having between about 8 to about 30 carbon atoms, which may also contain organofunctional groups such as vinyl, methacryl, amino, sulfur, and epoxy groups; R? and R? are independently selected from a methyl and ethyl group; and X is either 0 or 1. The optimal use for the treated silica substrate is as a rheology modifier in epoxy polymer materials, however, the silica substrate could also be used in other chemical compositions such as polyurethanes, polyesters, silicones, and hydrocarbon oils.
    Type: Grant
    Filed: December 28, 2004
    Date of Patent: August 28, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Aleksey Isarov, Thomas J. Lynch
  • Patent number: 7255852
    Abstract: Precipitated silica comprising porous silica particles having a cumulative surface area for all pores having diameters greater than 500 ? of less than 8 m2/g, as measured by mercury intrusion, and a percentage cetylpyridinium chloride (% CPC) Compatibility of greater than about 55%. The precipitated silica product is especially well-adapted for use in dentifrices containing cetylpyridinium chloride, which do not attach to the low surface area silica product in a meaningful level and thus remain available for antimicrobial action. Processes for making the silica product are also provided.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: August 14, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Karl W. Gallis, Mark E. Wozniak, John A. Kostinko
  • Patent number: 7201885
    Abstract: Methods for the removal of lead from a metal silicate during the process of manufacturing of such a material are provided. With the reliance upon lower cost starting silicon dioxide starting materials that are known to exhibit elevated amounts of heavy metal therein for the purpose of producing metal silicates (such as sodium silicate, as one example), it has been realized that removal of significant amounts of such heavy metals is necessary to comply with certain regulatory requirements in order to provide a finished material that exhibits the same low level of heavy metal contamination as compared with finished materials that are made from more expensive, purer starting silicon dioxides. Two general methods may be followed for such decontamination purposes. One entails the introduction of a calcium phosphate material, such as dicalcium phosphate, tricalcium phosphate, and/or hydroxyapatite, to a formed metal silicate solution but prior to filtering.
    Type: Grant
    Filed: November 17, 2005
    Date of Patent: April 10, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Yung-Hui Huang, John V. Offidani