Abstract: The present disclosure relates to a process for the deolefinization of hydrocarbon streams through an aromatic alkylation reaction by olefins, using a catalyst containing a framework-substituted zirconium and/or titanium and/or hafnium-modified ultra-stable Y (USY) type zeolite.
Type:
Grant
Filed:
December 16, 2019
Date of Patent:
August 3, 2021
Assignees:
Saudi Arabian Oil Company, JGC CATALYSTS AND CHEMICALS LTD., JAPAN COOPERATION CENTER, PETROLEUM
Inventors:
Omer Refa Koseoglu, Robert Peter Hodgkins, Mitsunori Watabe, Tomoyasu Kagawa, Koji Uchida
Abstract: A polishing composition comprising an abrasive grain; a modified microfibril cellulose in which at least a part of the cellulose units has a hydroxyl group at the C6 position oxidized to a carboxyl group; and a dispersion medium, wherein each content of Na and K is 100 ppm or less relative to the solids weight.
Abstract: The hollow particles according to the present invention has a balloon structure which includes a cavity inside a shell, and include convex portions with a size of 3 to 100 nm on the surface. The particles have a true specific gravity of 0.3 to 3.0 g/cm3, a specific surface area (m2/cm3) per unit volume calculated by a BET method of not less than 0.5 and less than 60, and an average particle diameter (d1) of 1 to 20 ?m. Cosmetics containing such hollow particles have a soft texture property similar to plastic beads.
Abstract: An adsorbent of the invention, which is an adsorbent for removing carbonyl sulfide in a stream containing an olefin, contains copper oxide and an aluminum compound, in which a content of the aluminum compound ranges from 10 mass % to 50 mass % in terms of Al, and an NH3 desorption in a temperature region ranging from 100 degrees C. to 200 degrees C. as measured by NH3-TPD measurement is more than 0.001 mmol/g and 1 mmol/g or less.
Abstract: Provided is a hydrodesulfurization catalyst for hydrocarbon oil, the catalyst comprising: an inorganic oxide carrier comprising Si, Ti and Al; and at least one metal component, carried on the inorganic oxide carrier, being selected from the group consisting of group 6 elements, group 8 elements, group 9 elements and group 10 elements, wherein the content of Al in the inorganic oxide carrier is 50% by mass or higher in terms of Al2O3; the content of Si therein is 1.0 to 10% by mass in terms of SiO2; and the content of Ti therein is 12 to 28% by mass in terms of TiO2; and in the inorganic oxide carrier, the absorption edge wavelength of an absorption peak from Ti is 364 nm or shorter as measured by ultraviolet spectroscopy.
Type:
Application
Filed:
March 9, 2018
Publication date:
April 29, 2021
Applicants:
JXTG Nippon Oil & Energy Corporation, JGC Catalysts and Chemicals Ltd.
Abstract: The invention relates to methods for hydrocracking or hydrotreating hydrocarbon containing feedstocks. This is accomplished via the use of a catalyst which comprises a ? zeolite of *BEA framework, where a portion of aluminum atoms in the *BEA framework have been substituted by from 0.1-5.0 wt % of each of Ti and Zr, calculated on an oxide basis.
Type:
Grant
Filed:
October 1, 2019
Date of Patent:
March 9, 2021
Assignees:
Saudi Arabian Oil Company, JGC Catalysts and Chemicals Ltd.
Inventors:
Robert Peter Hodgkins, Omer Refa Koseoglu, Koji Uchida, Tomoyasu Kagawa, Mitsunori Watabe
Abstract: A ceria composite particle dispersion has ceria composite particles having an average particle size of 50 to 350 nm and having the features described below. Each ceria composite particle has a mother particle, a cerium-containing silica layer on the surface thereof, and child particles dispersed inside the cerium-containing silica layer, the mother particles being amorphous silica-based and the child particles being crystalline ceria-based. The child particles have a coefficient of variation (CV value) in a particle size distribution of 14 to 40%. The ceria composite particles have a mass ratio of silica to ceria of 100:11-316. Only the crystal phase of ceria is detected when the ceria composite particles are subjected to X-ray diffraction. The average crystallite size of the crystalline ceria measured by subjecting the ceria composite particles to X-ray diffraction is 10 to 25 nm.
Abstract: A polishing composition that can not only achieve high polishing speed, but also can improve the surface smoothness (surface quality) of a polished substrate and reduce defects is provided. That is, provided is a polishing composition comprising silica particles and a water soluble polymer, wherein the contained silica particles satisfy the following requirements (a) to (c): (a) the primary particle diameter based on the specific surface area is 5 to 300 nm; (b) the coefficient of variation in the particle diameter is 10% or less; and (c) the Sears number Y is 10.0 to 12.0.
Abstract: Provided is a dispersion liquid of silica particles, comprising silica particles having an average particle diameter of 5 to 300 nm determined from an electron micrograph and a density of 1.20 g/cm3 or more determined from a specific surface area determined by a BET method using nitrogen adsorption, wherein the dispersion liquid has a pH of less than 8, a silica concentration of 12 to 40% by mass, and a viscosity in terms of a silica concentration of 20% by mass of 40 mPa·s or less. When this silica particle is used as an abrasive, it is possible to realize a sufficient polishing speed and a smooth polished surface on which occurrence of scratches is suppressed.
Abstract: Disclosed is a silica-based composite fine particle dispersion including a silica-based composite fine particle which comprises a mother particle containing amorphous silica as a main component with a child particle containing crystalline ceria as a main component on a surface thereof. Features of the silica-based composite fine particle include a silica to ceria mass ratio of 100:11 to 316, and when subjected to X-ray diffraction, only the crystalline phase of ceria is detected, and when subjected to X-ray diffraction for measurement, the crystalline ceria has a crystallite diameter of 10 to 25 nm.
Abstract: Provided is a dispersion containing high-purity silica particles and a method for producing the same. A first solution containing a silane alkoxide and a second solution containing fine bubbles having an average bubble diameter of 40 nm to 10 ?m are mixed. Thus, the silane alkoxide is hydrolyzed without using an alkaline catalyst in a liquid phase containing the fine bubbles, so that uniform silica particles having an average particle size of 3 to 10 nm are produced. Further, hydrolysis is carried out by adding a hydrolyzable metal compound to the dispersion containing the silica particles in the presence of the fine bubbles and the alkaline catalyst. Thus, the silica particles are grown, so that a uniform silica-based particle dispersion containing particles having an average particle size of more than 10 nm and 300 nm or less is produced.
Abstract: The invention relates to a reforming catalyst. The reforming catalyst comprises a reforming metal, such as Pt, a support, such as an alumina support, and a USY zeolite, which has had part of its aluminum framework substituted with Zr and Ti. The amount of USY zeolite does not exceed 5 wt %, and most preferably, contains 2-3 wt % USY zeolite.
Type:
Grant
Filed:
January 23, 2018
Date of Patent:
September 29, 2020
Assignees:
SAUDI ARABIAN OIL COMPANY, JGC CATALYST AND CHEMICALS, LTD.
Inventors:
Omer Refa Koseoglu, Robert Peter Hodgkins, Ali H. Alshareef, Koji Uchida, Mitsunori Watabe, Kenji Nita
Abstract: Provided is a dispersion containing high-purity silica particles and a method for producing the same. A first solution containing a silane alkoxide and a second solution containing fine bubbles having an average bubble diameter of 40 nm to 10 ?m are mixed. Thus, the silane alkoxide is hydrolyzed without using an alkaline catalyst in a liquid phase containing the fine bubbles, so that uniform silica particles having an average particle size of 3 to 10 nm are produced. Further, hydrolysis is carried out by adding a hydrolyzable metal compound to the dispersion containing the silica particles in the presence of the fine bubbles and the alkaline catalyst. Thus, the silica particles are grown, so that a uniform silica-based particle dispersion containing particles having an average particle size of more than 10 nm and 300 nm or less is produced.
Abstract: Chabazite zeolites have a problem of low hydrothermal resistance. By steam treating a chabazite zeolite having a silica-alumina ratio and a crystallinity that are within certain ranges, a chabazite zeolite having a high crystallinity and a high hydrothermal resistance can be obtained.
Abstract: A subject of this invention is to provide a dispersion liquid of a silica-based composite particle, which can rapidly polish silica film, Si wafer or even hard-to-process material, can concurrently achieve high surface accuracy (less scratches, etc.), and can suitably be used for surface polishing of semiconductor devices including semiconductor substrate and wiring board, by virtue of its impurity-free nature. The subject is solved by a dispersion liquid of a silica-based composite particle that contains a silica-based composite particle that has a core particle mainly composed of amorphous silica, and bound thereto a ceria particle mainly composed of crystalline ceria, further has a silica film that covers them.
Abstract: A method for producing a dispersion liquid of silica particles, by simultaneously adding a liquid A containing silane alkoxide and a liquid B containing an alkali catalyst and water to a liquid I containing silica seed particles to cause the particles to grow, so as to produce silica particles; wherein the variation rate of the mole ratio of the alkali catalyst to silica components in the reaction system during a period from the start to the end of the addition relative to the initial mole ratio is 0.90 to 1.10; and the variation rate of the mole ratio of water to the silica components in the reaction system during a period from the start to the end of the addition relative to the initial mole ratio is 0.90 to 1.10.
Abstract: The hollow particles according to the present invention has a balloon structure which includes a cavity inside a shell, and include convex portions with a size of 3 to 100 nm on the surface. The particles have a true specific gravity of 0.3 to 3.0 g/cm3, a specific surface area (m2/cm3) per unit volume calculated by a BET method of not less than 0.5 and less than 60, and an average particle diameter (d1) of 1 to 20 ?m. Cosmetics containing such hollow particles have a soft texture property similar to plastic beads.
Abstract: Provided is a water-resistant sulfur compound adsorbent having a crushing strength that is less likely to be reduced even when used in a process including moisture. A certain amount of cellulose derivative is contained in the sulfur compound adsorbent containing a copper component for adsorbing a sulfur compound. This imparts water resistance to the adsorbent. As a result, it is possible to obtain the water-resistant sulfur compound adsorbent having the crushing strength that is less likely to be reduced even when used in the process including moisture.
Abstract: An object of the present invention is to provide a chabazite zeolite which does not easily peel from a substrate such as a honeycomb body even when the substrate has been coated therewith, while exhibiting excellent durability. The present invention relates to a chabazite zeolite for substrate coating, which includes (i) to (iv) below. (i) Si and Al are contained, (ii) an SiO2/Al2O3 molar ratio is in a range of 5<SiO2/Al2O3<10, (iii) an average crystal size is in a range of 0.05 ?m<average crystal size<1 ?m, and (iv) in a spectrum measured by 27Al-NMR, a ratio (ANFA/ATotal) between an area (ATotal) of all peaks in the spectrum and an area (ANFA) of peaks assigned to Al other than tetracoordinated Al is in a range of 20%?(ANFA/ATotal)?70%.
Abstract: An object of the present invention is to provide a nanobubble-containing inorganic oxide fine particle dispersion having excellent concentration stability in a process used as an abrasive. The object is achieved by the nanobubble-containing inorganic oxide fine particle dispersion including: inorganic oxide fine particles having an average particle size of 1 to 500 nm and containing fine particles containing Ce; and nanobubbles having an average cell size of 50 to 500 nm and being at least one non-oxidizing gas selected from a group consisting of N2 and H2.