Patents Assigned to JGC Catalysts and Chemicals Ltd.
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Publication number: 20190248668Abstract: A ceria composite particle dispersion has ceria composite particles having an average particle size of 50 to 350 nm and having the features described below. Each ceria composite particle has a mother particle, a cerium-containing silica layer on the surface thereof, and child particles dispersed inside the cerium-containing silica layer, the mother particles being amorphous silica-based and the child particles being crystalline ceria-based. The child particles have a coefficient of variation (CV value) in a particle size distribution of 14 to 40%. The ceria composite particles have a mass ratio of silica to ceria of 100:11-316. Only the crystal phase of ceria is detected when the ceria composite particles are subjected to X-ray diffraction. The average crystallite size of the crystalline ceria measured by subjecting the ceria composite particles to X-ray diffraction is 10 to 25 nm.Type: ApplicationFiled: October 6, 2017Publication date: August 15, 2019Applicant: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Michio KOMATSU, Yuji TAWARAZAKO, Shinya USUDA, Kazuhiro NAKAYAMA, Shota KAWAKAMI
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Publication number: 20190240648Abstract: An object of the present invention is to provide a chabazite zeolite which does not easily peel from a substrate such as a honeycomb body even when the substrate has been coated therewith, while exhibiting excellent durability. The present invention relates to a chabazite zeolite for substrate coating, which includes (i) to (iv) below. (i) Si and Al are contained, (ii) an SiO2/Al2O3 molar ratio is in a range of 5<SiO2/Al2O3<10, (iii) an average crystal size is in a range of 0.05 ?m< average crystal size <1 ?m, and (iv) in a spectrum measured by 27Al-NMR, a ratio (ANFA/ATotal) between an area (ATotal) of all peaks in the spectrum and an area (ANFA) of peaks assigned to Al other than tetracoordinated Al is in a range of 20%?(ANFA/ATotal)?70%.Type: ApplicationFiled: October 25, 2017Publication date: August 8, 2019Applicant: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Yoko YAMAGUCHI, Shunji TSURUTA, Akira NAKASHIMA
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Patent number: 10358353Abstract: Silica particles calcined in a calcination step are supplied in a swirling flow generated by a gas introduced in a disintegration container and disintegrated therein, whereby the silica particles can be easily disintegrated and there can be obtained disintegrated silica particles having both low hygroscopicity and high dispersibility in resin. In addition, the introduction of dehumidified air (gas) during the disintegration reduces hygroscopicity and greatly improves dispersibility in resin. Furthermore, performing heating treatment (calcination) again after the disintegration causes the surface modification of the disintegrated silica particles, greatly improving hygroscopicity and dispersibility in resin. The resin composition obtained in this manner including silica particles provides good injectability and filterability when used for an underfill material for semiconductors and an in-plane spacer or sealing spacer of liquid crystal displays.Type: GrantFiled: August 1, 2014Date of Patent: July 23, 2019Assignee: JGC Catalysts and Chemicals Ltd.Inventors: Ryo Muraguchi, Miki Egami, Mitsuaki Kumazawa, Masanobu Taniguchi, Tsuguo Koyanagi, Michio Komatsu, Kazutaka Egami
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Patent number: 10357761Abstract: The present invention relates to a catalyst for fluidized catalytic cracking of hydrocarbon oil containing a framework-substituted zeolite-1 in which zirconium atoms and/or hafnium atoms form a part of a framework of an ultra-stable Y-type zeolite.Type: GrantFiled: May 22, 2015Date of Patent: July 23, 2019Assignees: Saudi Arabian Oil Company, JGC Catalysts and Chemicals Ltd., Japan Cooperation Center PEtroleumInventors: Omer Refa Koseoglu, Bandar Hussain Alsolami, Masaru Ushio, Seiji Arakawa
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Patent number: 10314769Abstract: The present invention provides organic-inorganic composite particles having a suitable biodegradability. The organic-inorganic composite particles of the present invention include a silica component and a biodegradable plastic. The organic-inorganic composite particles have a mean particle diameter (d1) ranging from 0.5 ?m to 25 ?m, an absolute specific gravity greater than 1.0 g/cm3 and equal to or smaller than 2.0 g/cm3, and a contact angle with water of 90° or less. A cosmetic product including the organic-inorganic composite particles has good texture characteristics.Type: GrantFiled: March 29, 2018Date of Patent: June 11, 2019Assignee: JGC Catalysts and Chemicals Ltd.Inventors: Satoshi Watanabe, Naoyuki Enomoto, Ikuko Shimazaki
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Patent number: 10301183Abstract: Producing a silica particle by inhibiting the generation of incompletely reacted materials such as oligomers which have not been grown to the silica particles having the intended particle size. A dispersion liquid of a silica particle is produced by simultaneously adding, to a liquid substantially consisting of an organic solvent, a liquid containing silane alkoxide and a liquid containing an alkali catalyst and water to cause hydrolysis and polycondensations to produce a silica particle. The variation rate of the mole ratio of the alkali catalyst to silane alkoxide in the reaction system for a period from the start to the end of the reaction relative to the initial mole ratio is 0.90 to 1.10; and the variation rate of the mole ratio of water to silane alkoxide for a period from the start to the end of the reaction relative to the initial mole ratio is 0.90 to 1.10.Type: GrantFiled: December 27, 2017Date of Patent: May 28, 2019Assignee: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Miki Egami, Mitsuaki Kumazawa, Hirotada Arakane, Ryo Muraguchi, Toshiharu Hirai
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Patent number: 10293332Abstract: The present invention relates to a hydrocracking catalyst for hydrocarbon oil comprising a support containing a framework-substituted zeolite-1 in which zirconium atoms and/or hafnium atoms form a part of a framework of an ultrastable y-type zeolite and a hydrogenative metal component carried thereon and a method for producing the same. The hydrocracking catalyst of the present invention makes it easy to diffuse heavy hydrocarbon oils such as VGO, DAO and the like into mesopores, is improved in a cracking activity and makes it possible to obtain a middle distillate at a high yield as compared with catalysts prepared by using zeolite comprising titanium and/or zirconium carried thereon.Type: GrantFiled: September 25, 2018Date of Patent: May 21, 2019Assignees: Saudi Arabian Oil Company, JGC Catalyst and Chemicals Ltd., Japan Cooperation Center, PetroleumInventors: Omer Refa Koseoglu, Adnan Al-Hajji, Ali Mahmoud Al-Somali, Ali H. Al-Abdul'Al, Mishaal Al-Thukair, Masaru Ushio, Ryuzo Kuroda, Takashi Kameoka, Koji Nakano, Yuichi Takamori
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Patent number: 10286386Abstract: Provided herein is a hydrotreating catalyst for hydrocarbon oil having high desulfurization activity, and high abrasion strength and high compressive strength. A process for producing the hydrotreating catalyst is also provided. The hydrotreating catalyst uses an alumina-phosphorus support. The support contains 0.5 to 2.0 mass % of phosphorus in terms of an oxide. The support loads a metal in Group 6A of the periodic table, and a metal in Group 8 of the periodic table. The hydrotreating catalyst has a specific surface area of 150 m2/g or more. The hydrotreating catalyst has a total pore volume of 0.40 to 0.75 ml/g as measured by a mercury intrusion method. The hydrotreating catalyst has two maximal peaks in a pore diameter range of 6 nm to 13 nm in a log differential pore volume distribution measured by a mercury intrusion method. The hydrotreating catalyst has an abrasion strength of 0.5% or less. The hydrotreating catalyst has a compressive strength of 15 N/mm or more.Type: GrantFiled: April 7, 2016Date of Patent: May 14, 2019Assignee: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Kenji Yamane, Shunsuke Ohashi
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Patent number: 10239759Abstract: A method of producing silica-based particles includes, when a dispersion liquid of composite oxide particles is prepared by simultaneously adding an aqueous silicate solution and/or an acidic silicic acid solution and an aqueous solution of an alkali-soluble inorganic compound in an alkali aqueous solution or in an alkali aqueous solution with seed particles dispersed therein, if required, the aqueous silicate solution and/or the acidic silicic acid solution and the aqueous solution of alkali-soluble inorganic compound are added so that the molar ratio of MOx/SiO2 are in a range from 0.01 to 2, herein MOx denoting an inorganic oxide other than silica and SiO2 denoting silica to prepare the dispersion liquid of composite oxide particles with an average diameter (Dp1) in a range from 3 to 300 nm.Type: GrantFiled: January 28, 2015Date of Patent: March 26, 2019Assignee: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Ryo Muraguchi, Mitsuaki Kumazawa, Toshiharu Hirai
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Patent number: 10236505Abstract: A cathode active material for a non-aqueous electrolyte secondary battery satisfies conditions (1) to (5): (1) the cathode active material contains Li, Mn, and Ni and has a spinel structure; (2) a molar ratio of Ni to Mn is in a range from 0.10 to 0.43; (3) a molar ratio of Li to Mn is in a range from 0.70 to 1.80; (4) the cathode active material has a peak in a range of 2?=19.7 to 22.5° in an X-ray diffraction pattern; and (5) the cathode active material has at least one peak in a voltage range of voltage V1 and at least two peaks in a voltage range of voltage V2 in an initial dQ/dV curve of a discharge measured when a half cell is prepared using the cathode active material, V1=2.72 to 2.90 [V] V2=4.50 to 4.80 [V].Type: GrantFiled: March 4, 2016Date of Patent: March 19, 2019Assignee: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Yasuhiro Suzuka, Mariko Hashimoto, Takahiro Yashima
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Patent number: 10190023Abstract: Provided is a silica-based polishing particle which can polish and flatten the surface of a substrate at a sufficient polishing rate with generation of scratches prevented, and successfully prevents generation of particle residues on a substrate after polishing. A silica-based polishing particle with a three-dimensional polycondensation structure containing an alkoxy group, wherein the particle has an average particle diameter (d) of 5 to 300 nm, an aspect ratio of 1.00 or more and 1.20 or less, and a carbon content of 0.005% by mass or more and less than 0.50% by mass.Type: GrantFiled: November 6, 2017Date of Patent: January 29, 2019Assignee: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Mitsuaki Kumazawa, Miki Egami, Hirotada Arakane, Ryo Muraguchi, Toshiharu Hirai
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Patent number: 10184069Abstract: Provided is a silica-based polishing particle, particularly suitable for primary polishing, which provides a high polishing rate on the surface of a substrate and which prevents particle residues on the substrate after polishing, and an abrasive including the silica-based polishing particle. A silica-based polishing particle with a three-dimensional polycondensation structure containing an alkoxy group, wherein the particle has an average particle diameter (d) of 5 to 300 nm, an aspect ratio of more than 1.20 and 5.00 or less, and a carbon content of 0.005% by mass or more and less than 0.50% by mass.Type: GrantFiled: December 1, 2017Date of Patent: January 22, 2019Assignee: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Mitsuaki Kumazawa, Miki Egami, Hirotada Arakane, Ryo Muraguchi, Toshiharu Hirai
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Patent number: 10160894Abstract: Provided is a non-spherical silica sol containing non-spherical silica fine particles dispersed in a dispersion medium, the non-spherical silica fine particles having an average particle diameter in a range of 3 to 150 nm as measured by dynamic light scattering, a minor-diameter/major-diameter ratio in a range of 0.01 to 0.8, and a specific surface area in a range of 10 to 800 m2/g, and also having a plurality of wart-like projections on the surfaces thereof, and a process for producing the non-spherical silica sol. The non-spherical silica fine particles contained in the non-spherical silica sol have a unique structure different from the structure of ordinary non-spherical silica fine particles.Type: GrantFiled: November 20, 2015Date of Patent: December 25, 2018Assignee: JGC Catalysts and Chemicals Ltd.Inventors: Hiroyasu Nishida, Kazuhiro Nakayama
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Patent number: 10143636Abstract: A porous silica particle optimized as the scrubbing agent is used for a cleansing cosmetic. The porous silica particle has an average circularity of 0.1 to 0.5, a pore volume of 1.0 to 2.0 ml/g, a mode diameter of 50 to 600 ?m, and a ratio of the maximum particle diameter to the mode diameter of 3.0 or less. The porous silica particle moreover has a median size of 0.5 to 25 ?m and the maximum particle diameter of 1 to 100 ?m, after rubbing with a load of 1.0 to 1.4 KPa for 30 seconds. With the cleansing cosmetic containing this particle, the skin is rubbed by the frictional force generated by the friction with the skin at the rubbing. Therefore, the mild peeling effect for the stratum corneum is obtained and the damage of the skin and the micro damage on the stratum corneum can be prevented.Type: GrantFiled: November 5, 2015Date of Patent: December 4, 2018Assignee: JGC Catalysts and Chemicals Ltd.Inventors: Satoshi Watanabe, Naoyuki Enomoto, Yasutaka Miyoshi, Michio Komatsu
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Patent number: 10081009Abstract: The present invention relates to a hydrocracking catalyst for hydrocarbon oil comprising a support containing a framework-substituted zeolite-1 in which zirconium atoms and/or hafnium atoms form a part of a framework of an ultrastable y-type zeolite and a hydrogenative metal component carried thereon and a method for producing the same. The hydrocracking catalyst of the present invention makes it easy to diffuse heavy hydrocarbon oils such as VGO, DAO and the like into mesopores, is improved in a cracking activity and makes it possible to obtain a middle distillate at a high yield as compared with catalysts prepared by using zeolite comprising titanium and/or zirconium carried thereon.Type: GrantFiled: November 3, 2015Date of Patent: September 25, 2018Assignees: Saudi Arabian Oil Company, JGC Catalyst and Chemical Ltd., Japan Cooperation Center PetroleumInventors: Omer Refa Koseoglu, Adnan Al-Hajji, Ali Mahmoud Al-Somali, Ali H. Al-Abdul'al, Mishaal Al-Thukair, Masaru Ushio, Ryuzo Kuroda, Takashi Kameoka, Koji Nakano, Yuichi Takamori
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Patent number: 10040943Abstract: Hollow silica-based particles having cavities inside the outer shell having a low refractive index. The method of producing the silica-based particles comprises the following steps (a) and (b): (a) a step in which, when an aqueous silicate solution and/or an acidic silicic acid solution and an aqueous solution of an alkali-soluble inorganic compound are simultaneously added in an alkali aqueous solution to prepare a dispersion liquid of composite oxide particles, an electrolytic salt is added at the molar ratio of a mole number of the electrolytic salt (ME) versus that of SiO2 (MS) [(ME)/(MS)] in the range from 0.1 to 10, and (b) a step of furthermore adding an electrolytic salt, if necessary, to the dispersion liquid of composite oxide particles and then removing at least a portion of elements constituting the composite oxide other than silicon by adding an acid to prepare a dispersion liquid of silica-based particles.Type: GrantFiled: July 8, 2004Date of Patent: August 7, 2018Assignee: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Ryo Muraguchi, Mitsuaki Kumazawa, Toshiharu Hirai, Masafumi Hirai
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Publication number: 20180179076Abstract: Producing a silica particle by inhibiting the generation of incompletely reacted materials such as oligomers which have not been grown to the silica particles having the intended particle size. A dispersion liquid of a silica particle is produced by simultaneously adding, to a liquid substantially consisting of an organic solvent, a liquid containing silane alkoxide and a liquid containing an alkali catalyst and water to cause hydrolysis and polycondensations to produce a silica particle. The variation rate of the mole ratio of the alkali catalyst to silane alkoxide in the reaction system for a period from the start to the end of the reaction relative to the initial mole ratio is 0.90 to 1.10; and the variation rate of the mole ratio of water to silane alkoxide for a period from the start to the end of the reaction relative to the initial mole ratio is 0.90 to 1.10.Type: ApplicationFiled: December 27, 2017Publication date: June 28, 2018Applicant: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Miki EGAMI, Mitsuaki KUMAZAWA, Hirotada ARAKANE, Ryo MURAGUCHI, Toshiharu HIRAI
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Publication number: 20180155591Abstract: Provided is a silica-based polishing particle, particularly suitable for primary polishing, which provides a high polishing rate on the surface of a substrate and which prevents particle residues on the substrate after polishing, and an abrasive including the silica-based polishing particle. A silica-based polishing particle with a three-dimensional polycondensation structure containing an alkoxy group, wherein the particle has an average particle diameter (d) of 5 to 300 nm, an aspect ratio of more than 1.20 and 5.00 or less, and a carbon content of 0.005% by mass or more and less than 0.50% by mass.Type: ApplicationFiled: December 1, 2017Publication date: June 7, 2018Applicant: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Mitsuaki KUMAZAWA, Miki EGAMI, Hirotada ARAKANE, Ryo MURAGUCHI, Toshiharu HIRAI
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Publication number: 20180127627Abstract: Provided is a silica-based polishing particle which can polish and flatten the surface of a substrate at a sufficient polishing rate with generation of scratches prevented, and successfully prevents generation of particle residues on a substrate after polishing. A silica-based polishing particle with a three-dimensional polycondensation structure containing an alkoxy group, wherein the particle has an average particle diameter (d) of 5 to 300 nm, an aspect ratio of 1.00 or more and 1.20 or less, and a carbon content of 0.005% by mass or more and less than 0.50% by mass.Type: ApplicationFiled: November 6, 2017Publication date: May 10, 2018Applicant: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Mitsuaki KUMAZAWA, Miki EGAMI, Hirotada ARAKANE, Ryo MURAGUCHI, Toshiharu HIRAI
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Patent number: 9889072Abstract: A porous silica particle with the small specific surface area and large pore volume, which is contained as the scrubbing agent in the cleansing cosmetics is provided. The porous silica particle has high collapsibility, and therefore the damage of the skin can be prevented. A porous silica particle according to the present invention has: an average circularity of 0.1 to 0.5; a pore volume of 0.1?Pv<1.0 ml/g; a specific surface area of 5 to 60 m2/cm3; a median size of 100 to 1000 ?m; a ratio of a maximum particle diameter to the median size, of 3.0 or less; and a median size of 5 to 40 ?m and a maximum particle diameter of 15 to 200 ?m, after rubbing for 30 seconds with a load of 1.0 to 1.4 KPa.Type: GrantFiled: October 2, 2015Date of Patent: February 13, 2018Assignee: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Satoshi Watanabe, Naoyuki Enomoto, Yasutaka Miyoshi