Patents Assigned to L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés George Claude
  • Publication number: 20230363334
    Abstract: A method for using hydrogen-rich water to increase the content of aromatic substances in fruits and vegetables comprises the step of keeping an outlet hydrogen concentration of hydrogen-rich water no lower than a set value within a period of time for which a filed is irrigated with hydrogen-rich water.
    Type: Application
    Filed: September 13, 2021
    Publication date: November 16, 2023
    Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, NANJING AGRICULTURAL UNIVERSITY
    Inventors: Webiao SHEN, Yan ZENG, Longna LI, M. SUNDAR, Shu WANG, Xu CHENG, Yuhao LIU
  • Patent number: 11815309
    Abstract: A method including, compressing a first hydrogen stream, and expanding a portion to produce a hydrogen refrigeration stream, cooling a second hydrogen stream thereby producing a cool hydrogen stream, wherein at least a portion of the refrigeration is provided by a nitrogen refrigeration stream, further cooling at least a portion of the cool hydrogen stream thereby producing a cold hydrogen stream, and a warm hydrogen refrigeration stream wherein at least a portion of the refrigeration is provided by the hydrogen refrigeration stream, compressing the warm hydrogen refrigeration stream, mixing the balance of the compressed first hydrogen stream with a high-pressure gaseous nitrogen stream to form an ammonia synthesis gas stream, and wherein the first hydrogen stream and the warm hydrogen refrigeration stream are compressed in the same compressor.
    Type: Grant
    Filed: November 7, 2018
    Date of Patent: November 14, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Mike Turney, Alain Guillard, Alexander Roesch
  • Patent number: 11813603
    Abstract: The invention relates to a reformer furnace for catalytic reforming of a carbon-containing input material with steam. The reformer furnace has a steel construction which serves as a framework for a refractory lining and for the fastening of burners, reformer tubes and supply and discharge lines. The burners and reformer tubes are arranged in rows, parallel to one another and in alternating fashion. The steel construction includes a plurality of main carrier units, wherein each main carrier unit has at least two vertically extending supports and a horizontally extending main carrier which connects the supports. This type of steel construction makes it possible to achieve uniform spacing of the reformer tubes and burners over the entire reformer furnace. This results in advantages in terms of the maximum operating temperature of the reformer tubes, thereby extending their service life.
    Type: Grant
    Filed: November 30, 2020
    Date of Patent: November 14, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Antonio Coscia, Ingo Gammel
  • Patent number: 11815295
    Abstract: Low-temperature refrigeration device arranged in a frame and comprising a working circuit forming a loop and containing a working fluid, the working circuit forming a cycle comprising in series: a compression mechanism, a cooling mechanism, an expansion mechanism and a heating mechanism, the device comprising a refrigeration heat exchanger intended to extract heat from at least one member by exchanging heat with the working fluid, the mechanisms for cooling and reheating the working fluid comprising a common heat exchanger in which the working fluid transits in counter-flow in two separate transit portions of the working circuit, the compression mechanism comprising at least two compressors and at least one motor for driving the compressors, the working fluid expansion mechanism comprising at least one rotary turbine, the device comprising at least one drive motor comprising a drive shaft, one end of which drives a compressor and the other end of which is coupled to a turbine, the motor being attached to the
    Type: Grant
    Filed: July 8, 2020
    Date of Patent: November 14, 2023
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Fabien Durand, Guillaume Delautre
  • Publication number: 20230357095
    Abstract: A method for irrigation of a crop capable of producing Cannabidiol (CBD) comprises irrigating the crop with a nanobubble hydrogen rich water (HRW-nano), whereby a concentration of CBD in the crop increased as a result of irrigating with the HRW-nano, compared to irrigation with an irrigation water having the same composition except without added hydrogen (control irrigation).
    Type: Application
    Filed: September 13, 2021
    Publication date: November 9, 2023
    Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, American Air Liquide, Inc.
    Inventors: Rovshan MAHMUDOV, Shu FANG, Yan ZENG
  • Patent number: 11808407
    Abstract: The invention relates to a pressurized gas container, in particular a gas cylinder, having an internal volume for gas storage, a fluid-distributing valve, a pressure sensor and microprocessor-based control means. The microprocessor-based control means are configured to detect filling of the gas container with gas, by comparing said at least one pressure value measured by the pressure sensor with at least one predefined and stored reference pressure threshold value; then to initiate a timer on the basis of a detection of filling of the gas container with gas; and to trigger a warning when the timer exceeds a given period calculated from the initiation of the timer.
    Type: Grant
    Filed: March 4, 2021
    Date of Patent: November 7, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Sofia Andre Dias, Federica Bellingeri
  • Patent number: 11806677
    Abstract: A preprocessing method comprises a sintering step of heating a solid material container filled with a solid material using a temperature which is lower than either the melting point or sublimation of the solid material, whichever is lower, and crystallizing at least part of the solid material, and an impurity removal step of heating the solid material container filled with the solid material using a temperature which is lower than either the melting point or sublimation of the solid material, whichever is lower, and removing at least part of the impurities included in the solid material.
    Type: Grant
    Filed: December 6, 2018
    Date of Patent: November 7, 2023
    Assignees: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation des Procedes Georges Claude, American Air Liquide, Inc.
    Inventors: Kohei Tarutani, Jean-Marc Girard, Nicolas Blasco, Stefan Wiese, Guillaume Husson
  • Publication number: 20230349513
    Abstract: Plant and method for storing and distributing pressurized liquefied cryogenic fluid, comprising a liquefied gas source and a distribution member, comprising a first fluid inlet connected to the liquefied gas source and a second end intended to be connected to a user of the pressurized liquefied gas supplied by the distribution member, the source comprising a first liquefied gas store configured to store and supply the liquefied gas to the distribution member at a first determined pressure, the source comprising a second liquefied gas store configured to store the liquefied gas at a second determined pressure which is lower than the first pressure, the plant comprising a connecting pipe having a valve assembly connecting the first and second liquefied gas stores, the plant comprising a filling pipe having a valve assembly and having a first end connected to the second liquefied gas store and a second end intended to be connected to a mobile store for supplying liquefied gas to fill the source.
    Type: Application
    Filed: December 11, 2020
    Publication date: November 2, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventor: Jean-Marc BERNHARDT
  • Patent number: 11802044
    Abstract: A process is proposed for producing pure hydrogen by steam reforming of a feed gas comprising hydrocarbons, preferably natural gas or naphtha, with a simultaneously low and preferably adjustable export steam flow rate. The process includes the steam reforming of the feed gas, for which the heat of reaction required is provided by combustion of one or more fuel gases with combustion air in a multitude of burners arranged within the reformer furnace. According to the invention, the combustion air, before being introduced into the burners, is heated by means of at least one heat exchanger in indirect heat exchange with the hot flue gas to temperatures of at least 530° C.
    Type: Grant
    Filed: September 23, 2021
    Date of Patent: October 31, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Swatantra Kumar Shrivastava, Dieter Ulber, Mirko Huebel
  • Patent number: 11794400
    Abstract: A method for manufacturing a composite pressurized-fluid vessel including winding a first polyolefin resin-based tape thereby forming a first layer of the vessel, depositing an intermediate second layer on the first layer, consisting of a material having variable permeability properties depending on the temperature and permeability below a pre-determined temperature threshold and non-permeability above the temperature threshold, winding a second resin-based tape on the intermediate second layer thereby forming a third layer, and cooling the intermediate second layer to a temperature below the temperature threshold while the first and third layers are each kept at a temperature above the melting temperature of their resin. Wherein the tape forming the third layer is based on a different resin from the first layer and during the step of depositing the intermediate second layer.
    Type: Grant
    Filed: November 2, 2020
    Date of Patent: October 24, 2023
    Assignee: L'Air Liquide, Société, Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventor: Philippe Papin
  • Publication number: 20230332299
    Abstract: The invention relates to an electrolysis device and method for producing molecular hydrogen, the device comprising a negative electrode compartment for reducing H2O into H2 and a positive electrode compartment comprising circulating supercapacitive particles in contact with a conductive substrate. Such a device or method advantageously comprises a power supply provided by one or more photovoltaic cells.
    Type: Application
    Filed: June 29, 2021
    Publication date: October 19, 2023
    Applicants: Centre national de la recherche scientifique, INSTITUT PHOTOVOLTAÏQUE D'ILE DE FRANCE (IPVF), L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE, ELECTRICITE DE FRANCE, TotalEnergies OneTech
    Inventor: David AYME-PERROT
  • Patent number: 11784041
    Abstract: The disclosed lanthanide precursor compounds include a cyclopentadienyl ligand having at least one aliphatic group as a substituent and at least one bidentate ligand. These precursors are suitable for depositing lanthanide containing films.
    Type: Grant
    Filed: February 8, 2022
    Date of Patent: October 10, 2023
    Assignees: L'Air Liquide, Sociéte Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc.
    Inventors: Daehyeon Kim, Junhyun Song, Wontae Noh, Venkateswara R. Pallem
  • Patent number: 11780730
    Abstract: A reformer tube for producing synthesis gas by steam reforming of hydrocarbon-containing input gases is proposed where an outer shell tube is divided by means of a separating tray into the reaction chamber and an exit chamber, a dumped bed of a steam-reforming-active, solid catalyst is arranged in the reaction chamber, at least one heat exchanger tube is arranged inside the reaction chamber and inside the dumped catalyst bed whose entry end is in fluid connection with the catalyst bed and whose exit end is in fluid connection with the exit chamber, wherein gas-contacted parts of the reformer tube, in particular the at least one heat exchanger tube, are fabricated from a nickel-based alloy and coated on their inside with an aluminum diffusion layer.
    Type: Grant
    Filed: November 21, 2017
    Date of Patent: October 10, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Dieter Ulber, Sebastien Doublet, Pascal Del-Gallo, Laurent Prost
  • Patent number: 11781082
    Abstract: The invention relates to a process and a plant for removing thiols from synthesis gas. Thiols and optionally thiophene and carbon disulfide are absorbed in a dedicated absorption stage with methanol as physical absorption medium. Methanol laden with at least thiols is freed of thiols in a stripping stage with methanol vapours as stripping gas and the methanol vapours-containing thiols are freed of methanol in a scrubbing stage. The process according to the invention minimizes methanol losses and the amounts of coolant required for the process.
    Type: Grant
    Filed: December 8, 2021
    Date of Patent: October 10, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Sophia Schmidt, Matthias Linicus, Hincal Leichner
  • Patent number: 11780859
    Abstract: Compounds and method of preparation of Si—X and Ge—X compounds (X?N, P, As and Sb) via dehydrogenative coupling between the corresponding unsubstituted silanes and amines (including ammonia) or phosphines catalyzed by metallic catalysts is described. This new approach is based on the catalytic dehydrogenative coupling of a Si—H and a X—H moiety to form a Si—X containing compound and hydrogen gas (X?N, P, As and Sb). The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—X products produced by dehydrogenative coupling are inherently halogen free. Said compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si-containing films.
    Type: Grant
    Filed: February 4, 2022
    Date of Patent: October 10, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Antonio Sanchez, Gennadiy Itov, Peng Zhang, Matthew Stephens, Manish Khandelwal
  • Patent number: 11773483
    Abstract: A cabinet for a solid material container comprises a main body having a top wall, a side wall, and a bottom wall; an entry/exit portion which is attached to a portion of the main body, for putting in and taking out the solid material container; an exhaust duct attached to a portion of the main body; a heating portion for heating the solid material container; a temperature measuring portion for measuring a temperature of the solid material container, or of the heating portion; and a cooling blower for blowing cooling air toward the solid material container.
    Type: Grant
    Filed: May 13, 2020
    Date of Patent: October 3, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventor: Terumasa Koura
  • Publication number: 20230304731
    Abstract: Certain embodiments of the invention relate to a facility for refrigerating a fluid to a cryogenic temperature, comprising a circuit for the fluid to be refrigerated, comprising an upstream end connected to a source and a downstream end connected to a refrigerated and/or liquefied fluid collection member, the facility comprising at least one exchanger for precooling the fluid leaving the upstream end, the precooling exchanger exchanging heat with a precooling circuit composed of a flow of vaporization gas from a user, the facility further comprising a heat exchanger assembly for cooling by heat exchange with the circuit of fluid to be cooled downstream of the precooling exchanger, the facility comprising a device for cooling by heat exchange with at least a part of the cooling heat exchanger assembly, said cooling device comprising a first refrigerator with a refrigeration cycle of a cycle gas in a working circuit, the cycle gas preferably comprising hydrogen and/or helium, the working circuit of the first re
    Type: Application
    Filed: June 28, 2021
    Publication date: September 28, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Pierre BARJHOUX, Golo ZICK
  • Publication number: 20230296314
    Abstract: An air separation apparatus is provided, including an air separation unit including a low-pressure column, a mixing column, and a pure nitrogen column, wherein the low-pressure column has a first nominal diameter, the pure nitrogen column has a second nominal diameter which is smaller than the first nominal diameter, wherein the mixing column has an open cylindrical shape, with the inner diameter nominally greater than the second nominal diameter, with the pure nitrogen column located within the mixing column interior.
    Type: Application
    Filed: July 22, 2020
    Publication date: September 21, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Alain BRIGLIA, Bowei ZHAO, Fengjie XUE
  • Patent number: 11761585
    Abstract: Device and method for filling pressurized gas tanks, comprising a fluid transfer circuit comprising an upstream end provided with a plurality of pressurized fluid sources and a downstream end comprising at least two distribution terminals each intended to be connected to separate tanks to be filled, each source comprising a first fluid outlet connected to a first respective outlet valve, each first outlet valve being connected to each of the at least two distribution terminals via parallel transfer ducts, each of the transfer ducts comprising at least one respective isolation valve, each of the distribution terminals being fluidly connected to each first outlet valve of a source via a first direct fluid path passing through a single transfer duct and via at least one second indirect alternative fluid path successively passing through a plurality of transfer ducts.
    Type: Grant
    Filed: August 3, 2022
    Date of Patent: September 19, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventor: Laurent Allidieres
  • Patent number: 11753298
    Abstract: The invention relates to a process for producing hydrogen from a light hydrocarbon source, in which a synthesis gas is generated by steam methane reforming after desulfurization and optionally pre-reforming of the feedstock. The synthesis gas is enriched with hydrogen by steam conversion of carbon monoxide, and is subsequently purified in a pressure swing adsorption unit to give a pure H2 product and a residual gas mixture containing CH4, CO, H2 and CO2; in accordance with the invention, the conversion step is performed in a cooled reactor in which the heat of the conversion reaction is transferred to a fluid which feeds the burners of the reformer, or to the gas for reforming.
    Type: Grant
    Filed: November 26, 2019
    Date of Patent: September 12, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Marie Basin, Daniel Gary, Jean-Philippe Tadiello