Patents Assigned to L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés George Claude
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Publication number: 20230213278Abstract: An integrated industrial unit is provided, which can include: a nitrogen source comprising an air separation unit that is configured to provide pressurized gaseous nitrogen and liquid nitrogen; a hydrogen source; a hydrogen liquefaction unit, wherein the hydrogen liquefaction unit comprises a precooling system, and a liquefaction system; and a liquid hydrogen storage tank, wherein the precooling system is configured to receive the gaseous hydrogen from the hydrogen source and cool the gaseous hydrogen to a temperature between 70K and 100K, wherein the precooling system comprises a primary refrigeration system and a secondary refrigeration system, wherein the liquefaction system is in fluid communication with the precooling system and is configured to liquefy the gaseous hydrogen received from the precooling system to produce liquid hydrogen, wherein the liquid hydrogen storage tank is in fluid communication with the liquefaction system and is configured to store the liquid hydrogen received from the liquefactType: ApplicationFiled: December 16, 2022Publication date: July 6, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Michael A. TURNEY, Alain GUILLARD, Bobby CHAN
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Publication number: 20230211281Abstract: A single compressor is used to separately compress permeate from cascaded first and second gas separation membrane-based separation units and residue from a fourth gas separation membrane-based separation unit in order to avoid too high a CO2 partial pressure in the compressed permeate. After the permeates from the first and second stages are compressed, the compressed stream is fed to a third gas separation membrane-based separation unit.Type: ApplicationFiled: December 31, 2021Publication date: July 6, 2023Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLCInventors: Sandeep KARODE, Paul TERRIEN, Cyril DEFAYE
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Publication number: 20230212007Abstract: A method for producing hydrogen in a steam methane reformer with reduced carbon emissions that can include the steps of: heating a feed stream comprising methane in a first heat exchanger to produce a heated feed stream, wherein the heated feed stream is at a temperature above 500° C.Type: ApplicationFiled: December 23, 2022Publication date: July 6, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Alexander ROESCH, Richard DUBETTIER, Dieter ULBER, Florian PONTZEN, Guillaume LODIER, Michael LUTZ
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Publication number: 20230211293Abstract: A CMS membrane module includes plurality of hollow fiber CMS membranes that are enclosed within an open cylindrical shell whose ends are embedded in tubesheets. The shell is concentrically disposed within an open cylindrical pressure vessel whose open ends are covered by and secured by end caps. The shell includes a feed fluid inlet formed therein between the tubesheets and a retentate outlet in between one of the tubesheets and an adjacent end cap. A retentate seal is formed between the shell and the pressure vessel at a position between the tubesheets. A permeate seal is formed between the pressure vessel and the tubesheet that is adjacent a permeate port of the module. A structure made up of the CMS membranes, shell, tubesheets, and seals is slidable within the pressure vessel and not fixed in place in relation to the pressure vessel and end caps.Type: ApplicationFiled: December 31, 2021Publication date: July 6, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Tao LI, Raja SWAIDAN, Robert A. GAGLIANO
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Publication number: 20230212006Abstract: An apparatus for producing hydrogen in a steam methane reformer with reduced carbon emissions, the apparatus comprising: a first heat exchanger configured to heat a feed stream comprising methane to produce a heated feed stream that is at a temperature above 500° C.Type: ApplicationFiled: December 23, 2022Publication date: July 6, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Alexander ROESCH, Richard DUBETTIER, Dieter ULBER, Florian PONTZEN, Guillaume LODIER, Michael LUTZ
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Publication number: 20230213148Abstract: Heat is transferred from a flow of liquid hydrogen to a flow of a heat transfer fluid at a first heat exchanger to produce a warmed flow of pressurized hydrogen and a cooled flow of heat transfer fluid. Heat is also transferred at a second heat exchanger, to the cooled flow of heat transfer fluid, from a flow of pressurized hydrogen that is derived from one or more buffer vessels filled by the warmed flow of pressurized hydrogen and/or the warmed flow of pressurized hydrogen from the first exchanger to produce a cooled flow of pressurized hydrogen that is used to fill tanks of fuel cell electric vehicles.Type: ApplicationFiled: September 15, 2022Publication date: July 6, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Vincent FAIRY, Anh Thao THIEU
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Publication number: 20230213274Abstract: A hydrogen feed stream is introduced into a primary refrigeration system of a precooling system and cooling the hydrogen stream to a first precooling temperature. From there, the precooled hydrogen stream is then introduced to a secondary refrigeration system of the precooling system and cooling the precooled hydrogen stream to a second temperature. Next, the cooled hydrogen stream is then liquefied in the liquefaction system to produce liquid hydrogen. The refrigeration is provided by expansion of a pressurized gaseous nitrogen stream and vaporization of a liquid nitrogen stream that is sourced from a nearby air separation unit.Type: ApplicationFiled: December 16, 2022Publication date: July 6, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Michael A. TURNEY, Alain GUILLARD, Bobby CHAN
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Publication number: 20230213272Abstract: A hydrogen feed stream is introduced into a primary refrigeration system of a precooling system and cooling the hydrogen stream to a first precooling temperature. From there, the precooled hydrogen stream is then introduced to a secondary refrigeration system of the precooling system and cooling the precooled hydrogen stream to a second temperature. Next, the cooled hydrogen stream is then liquefied in the liquefaction system to produce liquid hydrogen.Type: ApplicationFiled: August 26, 2022Publication date: July 6, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Michael A. TURNEY, Alain GUILLARD, Bobby Mon-Flan CHAN
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Patent number: 11691108Abstract: A CMS membrane module includes plurality of hollow fiber CMS membranes that are enclosed within an open cylindrical shell whose ends are embedded in tubesheets. The shell is concentrically disposed within an open cylindrical pressure vessel whose open ends are covered by and secured by end caps. The shell includes a feed fluid inlet formed therein between the tubesheets and a retentate outlet in between one of the tubesheets and an adjacent end cap. A retentate seal is formed between the shell and the pressure vessel at a position between the tubesheets. A permeate seal is formed between the pressure vessel and the tubesheet that is adjacent a permeate port of the module. A structure made up of the CMS membranes, shell, tubesheets, and seals is slidable within the pressure vessel and not fixed in place in relation to the pressure vessel and end caps.Type: GrantFiled: December 31, 2021Date of Patent: July 4, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Tao Li, Raja Swaidan, Robert A. Gagliano
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Patent number: 11692896Abstract: A method for calculating the autonomy of a gas distribution system assembly including a container containing gas and equipped with at least one gas filling indicator device and a gas flow rate indicator device at the output of the container. The method includes recovering at least one item of identification information on the container and/or the gas used. The method also includes acquiring at least one image to recover a first datum on a value indicated by the gas filling indicator device and a second datum on a value indicated by the flow rate indicator device. The method also includes communicating the at least one acquired image and the at least one recovered item of identification to a computation module configured to deduce therefrom a corresponding value of autonomy of the gas distribution assembly, the computation module including at least the ability to process images.Type: GrantFiled: November 23, 2020Date of Patent: July 4, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Michele Quattrone
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Publication number: 20230204159Abstract: This invention can provide a hydrogen refueling system capable to reduce waiting time for refueling H2 to vehicles. The system is designed and operated to acquire the residual pressure in the vehicle the that connects to the dispenser, then to calculate sufficient conditions to perform complete refueling of the connected vehicle (in particular minimum pressure in buffers), and then to start H2 transfer to the vehicle as soon as the conditions are met. Waiting time can be further reduced with minimum investment by having a H2 dispenser with two H2 refueling hoses which has only one H2 flow control valve and/or only one H2 cooling heat exchanger and/or only one H2 flow metering system.Type: ApplicationFiled: July 31, 2017Publication date: June 29, 2023Applicant: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Etienne WERLEN, Thibaut FRANCOIS
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Patent number: 11686471Abstract: A furnace for performing an endothermic process, comprising tubes containing catalyst for converting gaseous feed, wherein tubes are positioned inside the furnace in rows parallel to refractory walls along X axis, wherein burners are mounted either to the furnace floor or to the furnace ceiling, inner burners being mounted in rows between the rows of tubes and outer burners being mounted in rows between tubes rows and the wall along X axis, and close to said wall along X axis, wherein the outer burners are positioned such that the distance b2w between the outer burner and the wall along X axis is smaller than or equal to equivalent burner nozzle diameter øb of said outer burner (b2w/øb?1).Type: GrantFiled: May 17, 2018Date of Patent: June 27, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Diana Tudorache
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Publication number: 20230191359Abstract: The main subject of the present invention is a process for installing a section of packing in a casing by means of a device to assist installation of a section of packing, the casing comprising at least one tubular wall extending in a longitudinal direction (L) between two longitudinal ends, and an inner face of which participates in delimiting a receptacle for the section of packing, the tubular wall participating in delimiting an input opening at one of its longitudinal ends, the casing comprising a base wall positioned at the longitudinal end opposite the input opening, the casing being positioned horizontally during the process for installing the section of packing, the process comprising a step of fitting of the device to assist installation on the casing, during which the device to assist installation is secured in the vicinity of the input opening of the casing, a step of positioning of the section of packing relative to the device to assist installation and to the input opening, and at least one stepType: ApplicationFiled: December 19, 2022Publication date: June 22, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Vincent FAUCHER, Manuel DOS REIS, Vincent MARET, Luis TORBADO, Alain APPEL, Eric BIRET, Laurent LECLERC
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Publication number: 20230194160Abstract: The invention relates to a liquefied gas storage facility, in particular for liquid hydrogen, comprising a liquefied gas tank intended to contain gas in liquid form and a gaseous phase, a device for cooling the contents of the tank, the cooling device comprising at least a first refrigerator with a cycle for refrigerating a cycle gas, said first refrigerator comprising, arranged in series in a cycle circuit: a member for compressing the cycle gas, a member for cooling the cycle gas, a member for expanding the second cycle gas and a member for reheating the expanded cycle gas, the cooling device comprising a first heat transfer fluid loop comprising a first end exchanging heat with a cold end of the first refrigerator and a second end comprising a first heat exchanger located in the tank, the first heat transfer fluid loop comprising a member for circulating the heat transfer fluid, characterized in that the first heat exchanger exchanges heat directly with the inside of the tank, that is to say that the firstType: ApplicationFiled: March 23, 2021Publication date: June 22, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Francois LAGOUTTE, Jean-Marc BERNHARDT, Remi NICOLAS
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Publication number: 20230194195Abstract: Method for cryogenic cooling of a first fluid by heat exchange with at least one second fluid in a heat exchanger, the first fluid and/or the second fluid being at a temperature between ?100° C. and ?273° C., wherein the heat exchanger is of the type with polymer microtubes, i.e. comprising a plurality of microtubes made of polymer and having a diameter of between 0.1 mm and 1 cm, one of the first and second fluids being circulated inside said microtubes while the other fluid is circulated around said microtubes.Type: ApplicationFiled: March 25, 2021Publication date: June 22, 2023Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLCInventors: Guillaume DELAUTRE, Loic JEUNESSE, Golo ZICK, Pierre BARJHOUX, Thomas GATES, James Timothy MACHERAS
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Publication number: 20230194159Abstract: A hydrogen liquefaction apparatus is provided. The apparatus can include: one or more precooling zones; a plurality of liquefaction zones; a precooling refrigeration cycle configured to provide refrigeration to the precooling zone; and a cold end refrigeration cycle configured to provide refrigeration to the plurality of liquefaction zones, wherein the cold end refrigeration cycle comprises a common recycle compression system, wherein there are M total one or more precooling zones and N total liquefaction zones, wherein M is less than N.Type: ApplicationFiled: August 25, 2022Publication date: June 22, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Michael A. TURNEY, Patrick LE BOT, Alain GUILLARD, Bobby Mon-Flan CHAN, Francois FUENTES
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Patent number: 11679156Abstract: The disclosure relates to a manufactured composition, material or device comprising at least two different nonradioactive isotope atoms. Each nonradioactive isotope atom is present in an amount sufficient to increase the total amount of the nonradioactive isotope atom above the total amount found in the manufactured composition, material or device in the absence of adding the nonradioactive isotope atom to increase said total amount. The ratio(s) of the at least two nonradioactive isotopes in the manufactured composition, material or device are measurably different than the ratio(s) found in the manufactured composition, material or device in the absence of adding the nonradioactive isotope atom to increase said total amount.Type: GrantFiled: November 1, 2018Date of Patent: June 20, 2023Assignees: American Air Liquide, Inc., Airgas, Inc., L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Tracey Jacksier, Mani Matthew, Anthony W. Reccek, Jr., Martin Vasarhelyi, Vincent M. Omarjee
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Patent number: 11680746Abstract: Process and plant for the production of liquid hydrogen with a liquefier that has a variable cooling power dependent on the electrical power consumed. The liquefier is supplied with electricity by a first source of electricity at least one additional source of electricity that provides an intermittent or variable amount of electricity over time. Liquid hydrogen is produced at first thermodynamic conditions when the liquefier is supplied with a predetermined nominal electrical energy level and produced at subcooled conditions, with respect to the first thermodynamic conditions, when electricity supplied to the liquefier exceeds the nominal level.Type: GrantFiled: July 8, 2020Date of Patent: June 20, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Laurent Allidieres, Gregoire Rigout, Pierre Barjhoux, Pierre-Germain Marlier
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Patent number: 11680747Abstract: In a process for the combined production of a) a hydrogen-enriched gas and a carbon monoxide-enriched gas and/or b) a mixture of hydrogen and carbon monoxide by cryogenic distillation and scrubbing, a still liquor is extracted from a scrubbing column and sent to a stripping column, a still liquor is extracted from the stripping column and sent to a separating column for carbon monoxide and methane and a cooling fluid is used at a pressure greater than that of the head of the separating column for cooling at least one fluid extracted at an intermediate level from the scrubbing column.Type: GrantFiled: November 16, 2017Date of Patent: June 20, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Jean Billy, Axelle Gaertner, Antoine Hernandez, Jean-Marc Tsevery, Marie-Pascal Victor
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Patent number: 11679355Abstract: An adsorber for purifying or separating a gas stream, wherein a granular-material filling system is made up of a cylinder that is perforated over all or part of its height, of the top end thereof of diameter Dext, and of the bottom end thereof. The distance Din-Dext is greater than twice the size of particles of the second granular material. A first granular material and the second granular material follow one another in the direction of circulation of the gas stream and are such that M>ADN. And, the second granular material is in contact both with at least a part of the outer surface of the granular-material filling system and at least a part of the inner surface of the domed top end.Type: GrantFiled: February 11, 2019Date of Patent: June 20, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Guillaume Rodrigues, Bernard Fraioli, Patrick Pereira, Patrick Le Bot, Benjamin Morineau