Patents Assigned to L'Air Liquide - Societe Anonyme a'Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes George Claude
  • Patent number: 7431272
    Abstract: An apparatus for stirring and injecting a gas into a liquid. A drive device, located above a container containing a liquid, is connected to a vertical output shaft. The shaft has a self-suction turbine at its. The turbine is made of two stacked disks where the surface area of the lower disk is less than the surface area of the upper disk.
    Type: Grant
    Filed: December 4, 2003
    Date of Patent: October 7, 2008
    Assignees: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude, Centre National de la Recherche Scientifique, Institut National Polytechnique de Toulouse
    Inventors: Stephane Melen, Catherine Xuereb, Martine Poux, Rodolphe Sardeing
  • Patent number: 7422623
    Abstract: This abstract discusses membranes needed to separate fluids for the production of oxygen-enriched air, nitrogen-enriched-air, for the separation of carbon dioxide from hydrocarbons, and the separation of hydrogen from various petrochemical and oil refining streams. Membranes are needed that provide a resistance to interaction with process components or contaminants, provide the mechanical strength required to withstand high membrane differential pressures and high process temperatures, and exhibit sufficient maximum strain such that membranes are not brittle and can easily be formed into desirable membrane forms. Membranes of polyimide polymers, particularly polyimide polymers sold under the trade name P-84, are annealed in a controlled annealing step to improve the mechanical properties of the polymers used to make separation membranes.
    Type: Grant
    Filed: March 2, 2005
    Date of Patent: September 9, 2008
    Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Okan Max Ekiner, John W. Simmons
  • Patent number: 7399393
    Abstract: The invention concerns an oxide ion conductive ceramic membrane, characterized in that it comprises a non-null finite volume with non-null total thickness E, comprising, a dense layer (CD) of a solid electrolyte, a so-called bonding layer (CA), of mixed conductive porous cathode (EP) and porous anode (EP?), a cathode current collector (CC) and an anode current collector (CC?), a coating porous layer (ER), and a coating porous layer (ER?), and characterized in that the volume E of said membrane, is equal to the sum of the thickness of said elements. The membrane is used for separating oxygen from air or from a gas mixture containing same and in particular for producing ultra-pure oxygen under high pressure in a closed chamber.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: July 15, 2008
    Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Christophe Chaput, Thierry Terracol, Gisèle Bach, Guylaine Gouriou, Pascal Del Gallo
  • Patent number: 7396392
    Abstract: An apparatus and method of use for treating at least one fluid, in a container that holds at least one mass of a particulate material between two perforated walls. Near the upper part of the mass, at least one deflector extends from the first wall towards the second wall. Fluid flows through the walls horizontally, and the deflector is positioned at an angle to this horizontal fluid flow direction. With this particular apparatus configuration, an area close to the second wall and opposite the adjacent end of the deflector is formed, which is generally free of particulate matter; thus, resulting in a more efficient treatment process.
    Type: Grant
    Filed: February 17, 2003
    Date of Patent: July 8, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Jean-Yves Lehman, Benoît Davidian, Philippe Fert
  • Patent number: 7393383
    Abstract: Membranes are used to separate fluids for the production of oxygen-enriched air, nitrogen-enriched-air, for the separation of carbon dioxide from hydrocarbons, and the separation of hydrogen from various petrochemical and oil refining streams. Membranes are discussed that provide a resistance to interaction with process components or contaminants, which can lead to plasticizing of the membrane, while providing the mechanical strength required to withstand high membrane differential pressures and high process temperatures. Membranes of blended polymers are used to improve the mechanical strength of the polymers used to make separation membranes. Specifically, polyimide polymers are combined with a blend polymer that is a polyamide and/or a polyamide-imde polymer. The resulting polymer mix is used to produce various forms of high strength, chemically resistant membranes, including hollow-fiber membranes that are suitable for high pressure, high temperature applications.
    Type: Grant
    Filed: January 14, 2005
    Date of Patent: July 1, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Okan Max Ekiner, John Warren Simmons
  • Patent number: 7393380
    Abstract: A method for guaranteeing at least one characteristic of a fluid used for producing food products. This method utilizes a system for piping and delivering the fluid, combined with means for producing the products, in order to use the fluid for producing the products; the measuring a value of the characteristic; the comparing the measured value with a predetermined threshold value; the act of executing an action if the measured value departs from the threshold value; the combining the measured value with first information for identifying at least one product; and then the storing the associated value and the associated information.
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: July 1, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Jean-François Vie, Henry Ledon, Philippe Girardon, Christel Girault
  • Patent number: 7385158
    Abstract: A method and an apparatus for welding with a laser beam. A shielding gas mixture of nitrogen and helium is used and the proportions of the component gases are modified depending on the laser beam's power or power density. Plasma formation in the shield gas is minimized by increasing the proportion of helium as the laser beam's power or power density increases.
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: June 10, 2008
    Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Francis Briand, Karim Chouf, Philippe Lefebvre
  • Patent number: 7380414
    Abstract: Methods and apparatus for treating a liquid bath of oxygen. A liquid bath of at least 70 mol % of oxygen is located at the base of a cryogenic distillation column. The bath is continuously boiled by an aluminum reboiler. A portion of the liquid bath is purged to prevent a build up of inflammable impurities in the bath. A portion of the purge is sent to a second reboiler, which is less inflammable than the first reboiler. Oxygen boiled by the second reboiler is sent back to the column, and a portion of the oxygen rich liquid bath treated by the second reboiler is also purged. The invention also relates to an apparatus of carrying out this method.
    Type: Grant
    Filed: March 29, 2004
    Date of Patent: June 3, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Jean-Yves Lehman, Bernard Saulnier
  • Patent number: 7380413
    Abstract: A method for simultaneously producing hydrogen and carbon monoxide by subjecting synthesis gas to a decarbonation in a decarbonation unit, and to desiccation in a desiccation unit. After the decarbonation and the desiccation, the remaining synthesis gas components are cryogenically separated and a hydrogen-enriched gas is recycled upstream from the decarbonation unit and downstream from synthesis gas producing unit.
    Type: Grant
    Filed: April 14, 2003
    Date of Patent: June 3, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Eric Dumont, Antoine Hernandez
  • Patent number: 7370494
    Abstract: A process and apparatus for highly efficient production of industrial gases by the cryogenic distillation of air, wherein a feed stream of compressed air, is supercharged to high pressure, cooled, and mixed with various recycle streams of supercharged air, to regulate the expander turbine operating temperature. The need for pre-cooling equipment downstream of the supercharger, which is widely employed in industry to manage the temperature of the incoming compressed air stream, is eliminated.
    Type: Grant
    Filed: July 17, 2006
    Date of Patent: May 13, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Lasad Jaouani, Bao Ha, Ovidiu Balog, Maurice Grenier, Xavier Pontone
  • Patent number: 7351670
    Abstract: Silicon nitride film is formed on a silicon wafer mounted in a boat in an LPCVD tool by feeding a silicon source (SiH2Cl2, SiCl4, Si2Cl6, etc.) from an injector and feeding a mixed gas of monomethylamine (CH3NH2) and ammonia (NH3) as the nitrogen source from an injector. This addition of monomethylamine to the source substances for film production makes it possible to provide an improved film quality and improved leakage characteristics even at low temperatures (450-600° C.).
    Type: Grant
    Filed: December 23, 2004
    Date of Patent: April 1, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Takeshi Hoshi, Tsuyoshi Saito, Takako Kimura, Christian Dussarrat, Kazutaka Yanagita
  • Patent number: 7347054
    Abstract: The invention relates to a system for delivering gas stored in a vessel in liquefied form, said vessel having in its lower part a liquefied phase of said gas and in the upper part a gaseous phase of said gas, which vessel includes a means for connecting to a means for utilization as well as a means for heating the lower part of said vessel. In accordance with the invention, the liquefied gas and/or the shell of the vessel are electrically conductive elements and the means for heating comprises an electromagnetic induction means capable of producing an alternating magnetic field in the shell and/or the liquid so as to heat the shell in its lower part and/or the liquid in the vessel, all while limiting the heating of the gas by said means.
    Type: Grant
    Filed: December 2, 2004
    Date of Patent: March 25, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Guillaume Rameau, Valère Laurent, Thierry Breville
  • Patent number: 7341449
    Abstract: A method and apparatus for heat treating objects in an enclosure, where the enclosure has an inlet passage, an outlet passage, and a treatment zone. Gaseous first fluid is injected into the treatment zone and the objects to be treated are passed through the treatment zone. A second fluid, with a density greater than that of the first fluid, is injected near the inlet and outlet passages.
    Type: Grant
    Filed: October 8, 2004
    Date of Patent: March 11, 2008
    Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Claude Carsac, Joseph Paganessi, Jérôme Perrin, Patrick Kae-Nune
  • Patent number: 7337616
    Abstract: A system for sampling cryogenic liquids, and an air separation unit provided with at least one such system. The cryogenic liquid is introduced into a vaporizer, through heat exchange with the compressed air. The liquid passes through the vaporizer generally downwards. The walls of the vaporizer that are intended to come into contact with the cryogenic liquid are maintained at a temperature above the sublimation temperature or the boiling point of the least volatile impurity contained in this liquid. Downstream of the vaporizer, a gaseous phase coming from the vaporization of the cryogenic liquid is withdrawn and at least some of the gaseous phase is sent to an analyzer.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: March 4, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: David Meneses, Jean-Yves Thonnelier, Jean-Yves Lehman
  • Patent number: 7334708
    Abstract: Integral blocks, chemical delivery systems and methods for delivering an ultrapure chemical to a point of use or to another integral block are provided. More particularly, the integral blocks include a recharge container block, a pressurization gas block, a purge gas block, a waste recovery block, a vacuum block, a solvent supply block, a degas block, a control block, and a filtration block. Various integral blocks may be selected to form a chemical delivery system, which is particularly suited for a given application. A chemical delivery system will typically comprise a chemical container block, a chemical delivery block, and a point of use in line with the chemical container block and chemical delivery block, as well as one or more integral blocks.
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: February 26, 2008
    Assignees: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude, Air Liquide America Corporation, American Air Liquide, Inc.
    Inventors: Mindi Xu, Tay Sayasane, Joseph E. Paganessi, Gregory M. Jursich, Naoyuki Nakamoto, Yukinobu Nishikawa, Herve E. Dulphy, Guillaume Rameau, Lorrin Honda
  • Patent number: 7335304
    Abstract: Methods for treating aqueous effluent, which include reducing sludge formation during the biological treatment of an aqueous effluent. The sludge formation is reduced by injecting an ozone containing gas into an aeration tank which contains the effluent. The affluent is in contact with microorganisms in the tank at least once during the method. The ozone containing gas contains at least 2.5 mg of ozone per liter of the gas.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: February 26, 2008
    Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Philippe Campo, Jérôme Cluzeau, Christian Jalbert
  • Patent number: 7332108
    Abstract: There is disclosed a method for preparing a thin ceramic and/or metallic solid-state composition consisting of three phases: a material (A), a material (B) and pores. The concentration of each phase varies continuously from one face of the article to the other in a continuous and controlled gradient. The porous matrix of material (A) has a porosity gradient of 0% to about 80%, the pores being completely or partly filled with material (B). The concentration of material (B) in the article therefore varies from 80% to 0% of small thicknesses.
    Type: Grant
    Filed: May 16, 2002
    Date of Patent: February 19, 2008
    Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Thierry Chartier, François Guillotin
  • Patent number: 7330778
    Abstract: A method for determining the operating parameters of a system for cooling articles. The temperature of the articles, as they leave a chamber, is predicted. The prediction is made on the basis of operating parameters of the chamber, thermodynamic and physical characteristics of the chamber, and thermodynamic and physical characteristics of the articles. The method may be used to determine the operating parameters for food freezing tunnels.
    Type: Grant
    Filed: March 23, 2004
    Date of Patent: February 12, 2008
    Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour L'Etude et L'Exploitation des Procedes Georges Claude
    Inventors: Bernard Delpuech, Pascal Favier, Sylvain Fourage
  • Patent number: 7329827
    Abstract: The invention relates to a wire-guide/nozzle assembly (11, 13) for an electric arc welding torch, comprising at least one nozzle (11) for delivering gas and at least one wire-guide system (13) for guiding at least one consumable wire, characterized in that the downstream end (20) of the wire-guide system (13) runs into the nozzle (11). The peripheral wall of the nozzle (11) has at least one cut-out (10) through which the wire-guide system (13) passes. The wire-guide system (13) is fastened to the nozzle (11). The TIG welding torch comprises a wire-guide/nozzle assembly (11, 13).
    Type: Grant
    Filed: May 11, 2006
    Date of Patent: February 12, 2008
    Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: André Borne, Jean-Marie Fortain
  • Patent number: 7320337
    Abstract: An apparatus and a method for fluid distribution and control. A valve body defines at least two pairs of chambers which are each connectable to an external fluid circuit. A mobile structure, which moves according to a controlling unit, forms an internal penetrating passage. An internal bearing surface, which is located at the first end of the internal passage, is capable of cooperating in a sliding manner with a stationary piston head. The internal bearing surface may move beyond either side of the piston head. When the mobile structure is in an extreme position, an end chamber of the valve body is in fluid communication with the internal passage. When coupled with a PSA adsorber system, the system is capable of supplying oxygen enriched air to an occupant of an aircraft.
    Type: Grant
    Filed: March 25, 2005
    Date of Patent: January 22, 2008
    Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Jean Arnault, Stéphane Lessi