Patents Assigned to L'Exploitation Des
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Patent number: 10344768Abstract: A process for compressing a gaseous fluid comprising a step (a) of injecting refrigerant during which a refrigerant substance is sprayed into the gaseous fluid to be compressed, and also a compression step (b), during which the passage of said gaseous fluid loaded with refrigerant substance is forced through said compressor in order to compress said gaseous fluid, the mass flow rate (Q3) of the refrigerant substance injected into the gaseous fluid represents between 1% and 5% of the mass flow rate of the gaseous fluid to be compressed, and the refrigerant substance is sprayed in the form of particles having a maximum dimension of less than or equal to 25 pm, and preferably less than or equal to 10 pm.Type: GrantFiled: December 2, 2014Date of Patent: July 9, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Guillaume Cardon, Antony Correia Anacleto, Benoit Davidian, Francois-Xavier Lemant, Quentin Saniez, Jean-Pierre Tranier
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Publication number: 20190201869Abstract: A solid adsorbent fiber includes a solid support fiber that is enveloped by a solidified polymeric binder and also adsorbent particles.Type: ApplicationFiled: December 21, 2018Publication date: July 4, 2019Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Philippe A. COIGNET, Dean W. KRATZER
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Patent number: 10337104Abstract: Group 4 transition metal-containing film forming compositions are disclosed comprising Group 4 transition metal precursors having the formula: wherein M is Ti, Zr, or Hf; each A is independently N, Si, B or P; each E is independently C, Si, B or P; m and n is independently 0, 1 or 2; m+n>1; each R is independently a H or a C1-C4 hydrocarbon group; each L is independently a ?1 anionic ligand selected from the group consisting of NR?2, OR?, Cp, amidinate, ?-diketonate, or keto-iminate, wherein R? is a H or a C1-C4 hydrocarbon group; and L? is NR? or O, wherein R? is a H or a C1-C4 hydrocarbon group. Also disclosed are methods of synthesizing and using the disclosed precursors to deposit Group 4 transition metal-containing films on one or more substrates via vapor deposition processes.Type: GrantFiled: December 30, 2016Date of Patent: July 2, 2019Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Satoko Gatineau, Wontae Noh, Daehyeon Kim, Julien Gatineau, Jean-Marc Girard
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Patent number: 10335617Abstract: Respiratory protection hood comprising a flexible envelope and a reservoir of pressurized oxygen comprising an outlet orifice that leads into the internal volume of the envelope, the outlet orifice being closed off by a removable stopper, characterized in that the reservoir of oxygen comprises, upstream of the orifice, a passage for the pressurized gas and a needle that is able to move in a given direction of displacement in said passage, the needle being subjected to two opposite forces in the direction of displacement, said forces being respectively generated on the one hand by the pressure of the gas in the reservoir and the other hand by a return member, the needle having a section with a defined profile that is variable in the direction of displacement in order to modify the degree of closure of the passage depending on the position of said needle relative to the passage so as to regulate the flow rate of gas allowed to escape via the passage towards the orifice as a function of time and the pressure ofType: GrantFiled: May 2, 2014Date of Patent: July 2, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Rachid Makhlouche, Jean-Michel Cazenave, Freddy Dumont, Christian Rolland, Vincent Perrard
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Patent number: 10337791Abstract: In a process for the cryogenic separation of a feed mixture of at least carbon monoxide, hydrogen and methane, the feed mixture is separated in a methane wash column fed by a liquid methane stream at the top of the methane wash column to produce a gas enriched in hydrogen, a liquid stream from the bottom of the methane wash column is treated to produce a mixture of carbon monoxide and methane, the mixture of carbon monoxide and methane is separated in a separation column to produce a gas enriched in carbon monoxide and a liquid methane flow at least part of which forms a purge stream, the purge stream being varied to take account of load variations.Type: GrantFiled: April 29, 2013Date of Patent: July 2, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Alain Briglia, Emmanuelle Brocheriou, Pascal Marty, Bhadri Prasad
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Patent number: 10329959Abstract: A method for generating electricity by means of a thermal power plant and a liquid vaporization apparatus involves producing heat energy by means of the power plant and using the heat energy to vaporize water or to heat water vapor, expanding the water vapor formed in a first turbine and using the first turbine to drive an electricity generator in order to produce electricity, vaporizing liquefied gas coming from a cryogenic storage in order to produce pressurized gas, reheating the pressurized gas with a part of the water vapor intended for the first turbine of the power plant and expanding the pressurized fluid in a second turbine to produce electricity.Type: GrantFiled: December 17, 2014Date of Patent: June 25, 2019Assignee: L'Air Liquide Societe Anonyme pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Benoit Davidian, Cyrille Paufique
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Patent number: 10329960Abstract: A method for generating electricity by means of a nuclear power plant and a liquid vaporization apparatus involves producing heat energy by means of the nuclear power plant and using the heat energy to vaporize water or to heat water vapor, expanding the water vapor formed in a first turbine and using the first turbine to drive an electricity generator in order to produce electricity, vaporizing liquefied gas coming from a cryogenic storage in order to produce a pressurized gas, reheating the pressurized gas with a part of the water vapor intended for the first turbine of the power plant and expanding the pressurized fluid in a second turbine to produce electricity.Type: GrantFiled: December 17, 2014Date of Patent: June 25, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploitation Des Procedes Georges ClaudeInventors: Benoit Davidian, Cyrille Paufique
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Patent number: 10330391Abstract: The invention relates to a heat exchanger assembly having two exchangers, each comprising a stack of parallel plates defining a first connection surface and a second connection surface that are adjacent to each other. The heat exchanger assembly can also include an enclosure between the first connection surface and the second connection surface, primary compartments in the enclosure configured to channel primary fluid through the first connection surface and the second connection surface, and a secondary compartment in the enclosure for channeling secondary fluid.Type: GrantFiled: September 9, 2013Date of Patent: June 25, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Jean-Pierre Tranier, Marc Wagner
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Patent number: 10323796Abstract: The invention relates to a container/container support assembly, notably for a medical gas cylinder, comprising a gas container (11) comprising a protective cap (3) comprising a peripheral wall (3), and a container support (20) able and designed to accept and bear said gas container (11). The protective cap (3) of the gas container (11) comprises a fixing element (10) projecting from the surface of the peripheral wall (3), and said container support (20) comprises an attachment system (24) for fixing said container support (20) to a bearing structure (30), and a housing (22) able and designed to accept said fixing element (10) borne by the protective cap (3) of the gas container (11) so as to secure said gas container (11) to said container support (20) when said fixing element (10) is positioned in said housing (22) of the container support (20).Type: GrantFiled: December 1, 2014Date of Patent: June 18, 2019Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédeés Georges ClaudeInventors: Antoine Frenal, Renaud Ligonesche, Chiara Tarantello
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Patent number: 10317111Abstract: In a process for vaporizing a liquid stream rich in carbon dioxide wherein a liquid first stream rich in carbon dioxide is withdrawn from a chamber containing liquid rich in carbon dioxide and gas rich in carbon dioxide, the gas being at a pressure P1, the liquid first stream is sent to a heat exchanger where it is vaporized, all the liquid from the first stream is vaporized in the heat exchanger at a pressure or several pressures greater than P1, the vaporized first stream is extracted from the heat exchanger, expanded in a first expansion valve and sent to the heat exchanger where it is heated.Type: GrantFiled: July 5, 2013Date of Patent: June 11, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Alain Briglia, Arthur Darde, Ludovic Granados, Christophe Szamlewski
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Patent number: 10315184Abstract: A bead comprised of a matrix of at least 50 wt % adsorbent particles and a thermoplastic polymer or a blend of thermoplastic polymers, the thermoplastic polymer or blend of thermoplastic polymers exhibiting a Vicat softening temperature of at least 240° C.Type: GrantFiled: April 17, 2017Date of Patent: June 11, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Philippe A. Coignet, Dean W. Kratzer, Sudhir S. Kulkarni, Edgar S. Sanders, Jr.
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Patent number: 10317135Abstract: A device for separating a gas mixture containing at least 35 mol % carbon dioxide and also at least one gas lighter than carbon dioxide, comprising a first phase separator configured to receive a first partially condensed flow from an exchange line; a first phase separator configured to separate the gas phase from the liquid phase; a cooling means configured to receive the gas phase from the first phase separator and cool said gas phase to form a second partially condensed flow. The resulting liquid phase is then sent to a first valve and is expanded to a lower pressure that is at most 300 mbar lower in order to form a first expanded liquid, which is then mixed with a second liquid originating from the second phase separator in a mixing means that is located upstream of a third valve.Type: GrantFiled: February 20, 2014Date of Patent: June 11, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Alain Briglia, Mathieu Leclerc
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Publication number: 20190169025Abstract: A furnace for performing an endothermic process, comprising tubes containing a catalyst for converting a gaseous feed, wherein tubes are positioned in rows inside the furnace, wherein burners are mounted between the tubes and between the tubes and the furnace walls parallel to the tubes rows, and wherein the burners rows and the tubes rows are ended by end walls and are divided into sections with, on each row of tubes, the distance from a wall end tube to the end wall being T2W, the distance between two adjacent inner tubes in a section being T2T, and the distance between two symmetry end tubes of two adjacent sections being T2S, wherein the tubes in the rows are arranged in such a way that the ratios T2T/T2W and T2T/T2S are greater than 0.5 and smaller than 2 thus limiting the differences in the heat transfer to the outer tubes (wall end tubes and symmetry end tubes) with respect to the inner tubes and reducing the temperature difference between outer tubes and inner tubes.Type: ApplicationFiled: July 12, 2017Publication date: June 6, 2019Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Diana TUDORACHE
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Patent number: 10309010Abstract: Cobalt-containing compounds, their synthesis, and their use for the deposition of cobalt containing films are disclosed. The disclosed cobalt-containing compounds have one of the following formulae: wherein each of R1, R2, R3, R4 and R5 is independently selected from the group consisting of hydrogen and linear, cyclic, or branched hydrocarbon groups; provided that (a) R1?R2 and/or R3 when R1 and R2 and R3 are a hydrocarbon group; (b) R1 and R2 are a hydrocarbon group when R3 is H; or (c) R1 is a C2-C4 hydrocarbon group when R2 and R3 are H.Type: GrantFiled: January 31, 2014Date of Patent: June 4, 2019Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Satoko Gatineau, Changhee Ko, Jean-Marc Girard, Julien Gatineau
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Patent number: 10302357Abstract: A process to produce at least carbon dioxide and carbon monoxide from a feed gas containing carbon dioxide, hydrogen and carbon monoxide; comprises separating at least part of the carbon dioxide from the compressed feed gas by partial condensation and/or distillation producing a carbon dioxide product and a carbon dioxide depleted stream, treating the carbon dioxide depleted stream in a treatment unit to produce a feed stream containing carbon monoxide and hydrogen, less rich in carbon dioxide than the carbon dioxide depleted stream and feeding at least part of the feed stream containing carbon monoxide and hydrogen to a separation unit operating at cryogenic temperatures to produce a carbon monoxide product.Type: GrantFiled: November 19, 2014Date of Patent: May 28, 2019Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Antoine Hernandez, Paul Terrien
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Patent number: 10302356Abstract: A method for the production of air gases by the cryogenic separation of air can include the steps of sending a purified and compressed air stream to a cold box under conditions effective for cryogenically separating the air stream into an oxygen product and nitrogen using a system of columns, wherein the purified and compressed air stream is at a feed pressure when entering the system of columns; withdrawing the oxygen product at a product pressure; delivering the oxygen product at a delivery pressure to an oxygen pipeline, wherein the oxygen pipeline has a pipeline pressure; wherein during the second mode of operation, the method can include monitoring the pipeline pressure; and reducing the difference between the pipeline pressure and the delivery pressure. By operating the method in a dynamic fashion, a power savings can be realized in instances in which the pipeline pressure deviates from its highest value.Type: GrantFiled: December 19, 2016Date of Patent: May 28, 2019Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Paul Kong, Minh Pham-Huy, Wendy Yip
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Patent number: 10294110Abstract: [Problem] To provide a novel production method for pentachlorodisilane and to obtain pentachlorodisilane having a purity of 90 mass % or more by carrying out this production method. [Solution] A production method provided with: a high-temperature reaction step in which a raw material gas containing vaporized tetrachlorosilane and hydrogen is reacted at a high temperature in order to obtain a reaction product gas containing trichlorosilane; a pentachlorodisilane generation step in which the reaction product gas obtained in the high-temperature reaction step is brought into contact with a cooling liquid obtained by circulative cooling of a condensate that is generated by cooling the reaction product gas, the reaction product gas is quickly cooled, and pentachlorodisilane is generated within the condensate; and a recovery step in which the generated pentachlorodisilane is recovered.Type: GrantFiled: September 25, 2015Date of Patent: May 21, 2019Assignees: DENKA COMPANY LIMTIED, L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Hiroyuki Yashima, Takahiro Kozuka, Seiichi Terasaki, Jean-Marc Girard
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Patent number: 10295253Abstract: The invention relates to a method for separating air by cryogenic distillation in a set of columns including a first column operating at a first pressure, a second column operating at a second pressure which is lower than the first pressure, and a third column operating at a third pressure, which is lower than the second pressure, wherein the third column includes first and second evaporator-condensers, and nitrogen from a cold compressor is sent to one of the evaporator-condensers.Type: GrantFiled: October 14, 2014Date of Patent: May 21, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Benoit Davidian
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Patent number: 10293132Abstract: The invention concerns a nasal cannula assembly (10) adapted to deliver gases to a patient comprising a first compartment (1) and a second compartment (2) separated by a separation wall (6); a pair of nasal prongs (5) in fluid communication with the first compartment (1); the first compartment (1) comprising a first inlet (11) for introducing a first gas into said first compartment (1); the second compartment (2) comprising a second inlet (2) for introducing a second gas into said second compartment (2); and the separation wall (6) comprising at least one flow restriction element (35) for controlling the passage of gas from the second compartment (2) to the first compartment (1).Type: GrantFiled: September 28, 2016Date of Patent: May 21, 2019Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Andrew Martin
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Patent number: 10288346Abstract: A method for the liquefaction of an industrial gas by integration of a methanol plant and an air separation unit (ASU) is provided. The method can include the steps of: (a) providing a pressurized natural gas stream, a pressurized purge gas stream originating from a methanol plant, and a pressurized air gas stream comprising an air gas originating from the ASU; (b) expanding three different pressurized gases to produce three cooled streams, wherein the three different pressurized gases are the pressurized natural gas stream, the pressurized purge gas stream, and the pressurized air gas stream; and (c) liquefying the industrial gas in a liquefaction unit against the three cooled streams to produce a liquefied industrial gas stream. The industrial gas to be liquefied is selected from the group consisting of a first portion of the pressurized natural gas stream, a nitrogen gas stream, hydrogen and combinations thereof.Type: GrantFiled: January 24, 2017Date of Patent: May 14, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Alain Guillard, Michael A. Turney, Alexander Roesch