Abstract: One or more polymeric hollow fiber membranes are pyrolyzed to form one or more hollow fiber CMS membranes by directing a flow of pyrolysis gas through a polymeric membrane cartridge (including a porous center tube around which one or more green, polymeric, hollow fiber membranes is arranged) or a bundle of polymeric membranes (including a plurality of green, polymeric hollow fiber membranes oriented so that their ends are disposed with ends of the bundle) in a direction perpendicular to a length direction of the cartridge or bundle in order to sweep away off-gases that are formed during pyrolysis.

Abstract: A measured quantity of gas is introduced into a gas reservoir via a filling station including a flow meter. The quantity of gas transferred by the filling station to the reservoir is measured by the flow meter. The measured quantity of gas is reduced or increased by a predetermined corrective amount to yield a corrected gas quantity.

Abstract: In a process of the separation of a mixture of carbon monoxide, hydrogen and methane, the mixture is sent to a scrubbing column, a bottom liquid withdrawn at the bottom of the scrubbing column is depleted in hydrogen with respect to the mixture and is sent to a stripping column, a bottom liquid from the stripping column is sent to a separation column and a liquid enriched in methane withdrawn from the bottom of the separation column is vaporized in order to form a final product.

Abstract: One or more polymeric hollow fiber membranes are pyrolyzed to form one or more hollow fiber CMS membranes by directing a flow of pyrolysis gas through a bundle of polymeric membranes (including a plurality of green, polymeric hollow fiber membranes oriented so that their ends are disposed with ends of the bundle) in a direction perpendicular to a length direction of the bundle in order to sweep away off-gases that are formed during pyrolysis.

Abstract: Methods for forming a SiN-containing film are disclosed. The methods use film-forming compositions comprising Si—N containing precursors. Also disclosed are methods of synthesizing the same and methods of using the same for vapor deposition. In particular, a catalytic dehydrogenative coupling of carbosilanes with ammonia, amines and amidines produces the Si—N containing precursors.

Abstract: The invention relates to an apparatus for cryogenic separation of a mixture of carbon monoxide, hydrogen and nitrogen, including a stripping column and a denitrogenation column, a pipe for sending the mixture in liquid form to the head of the stripping column, a pipe for removing a liquid depleted of hydrogen connected to the stripping column, a pipe for removing a gas enriched with hydrogen from the stripping column, means for sending the liquid depleted of hydrogen or a fluid derived from said liquid to the denitrogenation column, a pipe for drawing a liquid enriched with carbon monoxide from the denitrogenation column, a pipe for drawing a gas enriched with nitrogen from the head of the denitrogenation column and means for sending at least one portion of the gas enriched with hydrogen to the denitrogenation column.

Abstract: In a method for regulating at least two fluids, a fluid feed flow Q is divided into n parts, the sum of the n parts being equal to Q, each of the n parts is sent to one of n processing units, each of the n processing units produces at least one processed flow, at least one processed flow of a first of the processing units is regulated by control means in order to keep the flow thereof constant at a value Q1 in nominal operation, at least one processed flow of a second of the processing units is regulated by control means in order to keep the pressure thereof constant in nominal operation and, in the event of a reduction of the feed flow Q, in reduced feed operation, if, preferably only if, the flow of the flow processed in the second processing unit of step v) drops and thus reaches a first minimum flow threshold, a processed flow in the first processing unit is regulated such that the processed flow having a value Q1 in nominal operation is reduced to a value less than Q1.

Abstract: A composite fiber comprising sorbent particles (at 50 wt %) in a polymeric matrix that comprises a polymer or blend of polymers including at least one thermoplastic polymer, the extrudates being produced by thermal-induced phase separation or diffusion-induced phase separation from a dope suspension of the thermoplastic polymer, an optional solvent and the sorbent particles. The polymer or blend of polymers is able to withstand exposure to temperatures at or above 220° C. without experiencing significant detrimental effects upon the sorbent capacity of the sorbent particles. The fiber exhibits an elongation at break of at least 5%.

Abstract: Methods for isotropic etching at least a portion of a silicon-containing layer on a sidewall of high-aspect-ratio (HAR) apertures formed on a substrate in a reaction chamber are disclosed. The HAR aperture formed by plasma etching a stack of alternating layers of a first silicon-containing layer and a second silicon-containing layer, the second silicon-containing layer is different from the first silicon-containing layer. The method comprising the steps of: a) introducing a fluorine containing etching gas selected from the group consisting of nitrosyl fluoride (FNO), trifluoroamine oxide (F3NO), nitryl fluoride (FNO2) and combinations thereof into the reaction chamber; and b) removing at least a portion of the second silicon-containing layers by selectively etching the second silicon-containing layers versus the first silicon-containing layers with the fluorine containing etching gas to produce recesses between the first silicon-containing layers on the sidewall of the HAR aperture.

Abstract: A plurality of extrudates comprises sorbent particles (at 50 wt %) in a polymeric matrix that comprises a polymer or blend of polymers including at least one thermoplastic polymer, the extrudates being produced by thermal-induced phase separation or diffusion-induced phase separation from a dope suspension of the thermoplastic polymer, an optional solvent and the sorbent particles. The polymer or blend of polymers is able to withstand exposure to temperatures at or above 220° C. without experiencing significant detrimental effects upon the sorbent capacity of the sorbent particles.

Abstract: The invention relates to a reactor for the catalytic production of methanol, in which at least two catalyst layers are arranged. The first catalyst layer is arranged upstream and the second catalyst layer is arranged downstream. The activity of the first catalyst layer is higher than the activity of the second catalyst layer.

Abstract: Refrigeration device comprising a working circuit in a loop for the working gas and comprising, in series: a compression station, a cold box, a system for the exchange of heat between the cooled working gas and a point of use, a system for the additional pre-cooling of the working gas leaving the compression station comprising an auxiliary cryogenic fluid volume, the cold box comprising a first cooling stage for the working gas comprising a first and a second heat exchanger, these being connected both in series and in parallel to the working circuit at the outlet of the compression station, the first cooling stage also comprising a third heat exchanger selectively exchanging heat with the auxiliary fluid, characterized in that the third heat exchanger is connected both in series and in parallel to the first and to the second heat exchangers, the working circuit comprising a recuperation pipe fitted with at least one valve and which connects the outlet of the third heat exchanger to the second heat exchanger.

Abstract: Disclosed is a method for producing a liquid hydrocarbon comprising dividing a feed gas into a first feed gas stream and a second feed gas stream, separating the first feed gas stream through a membrane separation unit into an acid gas-enriched permeate gas stream and a biphasic non-permeate stream of acid gas-reduced hydrocarbon-enriched gas and liquid, separating the biphasic non-permeate stream of acid gas-reduced hydrocarbon-enriched gas and liquid into a first liquid hydrocarbon stream and an acid gas-depleted methane-rich gas stream, expanding the second feed gas stream to produce a hydrocarbon gas stream containing the acid gas in equilibrium with a second liquid hydrocarbon stream with an expander, commingling the first liquid hydrocarbon stream with the second liquid hydrocarbon stream to produce the liquid hydrocarbons product, commingling the acid gas-enriched permeate gas stream with the hydrocarbon gas stream containing the acid gas and collecting the acid gas-depleted methane-rich gas stream.

Abstract: The object of the present invention is to provide a different solution for revamping existing producing apparatuses so as to increase the production of low pressure pure nitrogen while controlling as far as possible the capital and operation expenditures. The revamping solution comprises increasing the diameter and/or height of a pure nitrogen column to thereby improve the production capacity thereof; choosing to switch the conduits where the waste liquid nitrogen and pure liquid nitrogen are passed through in the subcooler according to the increment of the low pressure pure nitrogen production; adding an additional heat exchanger to conduct a heat exchange between a portion of the medium pressure air and the increased low pressure pure nitrogen; or simultaneously switching the main parts of the conduits which transfer the pure liquid nitrogen and waste liquid nitrogen from a first column of higher pressure to a second column of lower pressure while performing the above revamping.

Abstract: Full hood respirator comprising a fluidtight flexible bag intended to be slipped over the head of a user, the flexible bag being provided with a transparent window and comprising, in its lower part, a rigid base element of annular overall shape intended to be positioned around the neck of the user, the base element comprising a tubular oxygen reservoir of pressurized oxygen provided with a calibrated outlet orifice opening into the internal volume of the flexible bag, characterized in that the base element comprises at least two rigid parts connected by an articulation, the two parts being movable relative to one another between a furled first position that prevents a head from entering the hood through the base element and an unfurled position of use that allows a head to enter the hood through the base element.

Abstract: Halogen free amine substituted trisilylamine and tridisilylamine compounds and a method of their preparation via dehydrogenative coupling between the corresponding unsubstituted trisilylames and amines catalyzed by transition metal catalysts is described. This new approach is based on the catalytic dehydrocoupling of a Si—H and a N—H moiety to form an Si—N containing compound and hydrogen gas. The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—N containing products are halide free. Such compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si containing films.

Abstract: The invention relates to a microstructure of an alloy for a tube for reformers, having an austenitic matrix structure, characterised in that: i) primary micrometric precipitates in the form of M23C6-type carbides, where M=Fe, Ni or Cr, and/or M(C,N)-type carbides, where M==Nb or Ti, are formed during the solidification of the alloy; ii) secondary nanometric precipitates in the form of M23C6-type carbides, where M=Fe, Ni or Cr and/or M(C,N)-type carbides, where M==Nb or Ti, are formed during the activation of the tube; and iii) between 0.1 and 0.3% of Ni16Si7Nb6-type intermetallic precipitates is formed during the use of the tube.

Abstract: A radiative recuperator preheats oxidant and/or fuel for combustion at one or more burners of a furnace. The recuperator includes a duct, at least portions of which comprise a material having a thermal conductivity of greater than 1 W/(m·K), preferably greater than 3 W/(m·K), that receives hot flue gas produced by the burner(s). The duct radiatively transfers heat to oxidant or fuel (for preheating) flowing through one or more metallic pipes disposed in between the duct and an insulating wall.

Abstract: Compounds and method of preparation of Si—X and Ge—X compounds (X=N, P, As and Sb) via dehydrogenative coupling between the corresponding unsubstituted silanes and amines (including ammonia) or phosphines catalyzed by metallic catalysts is described. This new approach is based on the catalytic dehydrogenative coupling of a Si—H and a X—H moiety to form a Si—X containing compound and hydrogen gas (X=N, P, As and Sb). The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—X products produced by dehydrogenative coupling are inherently halogen free. Said compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si-containing films.

Abstract: The invention relates to a plant for production of hydrogen, and to a method for operating this plant, comprising a steam reforming reactor having a furnace, in which reactor water and at least one carbonaceous energy carrier are reacted to form a hydrogen-containing crude synthesis gas, and at least one cleaning device for purifying the crude synthesis gas, to which the crude synthesis gas is fed from the steam reforming via at least one feed line. According to the invention, upstream of one of the at least one cleaning devices at least one return line branches off from the feed line, through which the crude synthesis gas is at least in part recirculated into the furnace of the steam reforming reactor.