Patents Assigned to L'Exploitation Des
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Patent number: 9962659Abstract: A gas separation membrane module includes a seal between a higher pressure gas and a lower pressure gas. The seal includes a compressible sealing member in between sealing surfaces. At least one of the sealing surfaces has corrosion-resistant cladding provided over either low alloy steel or high alloy steel. The cladding reduce the possibility of a seal failure due to corrosion of low alloy or high alloy steel exposed to acid gases or condensed moisture containing acid gases dissolved therein while at the same not requiring that all surfaces of the membrane module exposed to acid gases be provided with cladding.Type: GrantFiled: June 28, 2016Date of Patent: May 8, 2018Assignees: AIR LIQUIDE ADVANCED TECHNOLOGIES U.S. LLC, L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE, SAUDI ARABIAN OIL COMPANYInventors: Sudhir S. Kulkarni, Karl S. Beers, Jean-Pierre R. Ballaguet, Milind M. Vaidya, Sebastien A. Duval
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Patent number: 9964354Abstract: A method is provided for production of gaseous oxygen at high pressures by splitting a main air feed into at least three separate streams, with the first stream being fed to a heat exchanger and then a column system for rectification; the second stream being further compressed in a warm booster, partially cooled in the heat exchanger, expanded in a turbine coupled to the warm booster and then fed to the column system; the third stream being expanded in a warm expander before being introduced to the heat exchanger and introduced to the column system. In certain embodiments, substantially all of the main air feed is eventually introduced to the column system for rectification, resulting in reduced sizing of a main air compressor and improved product recoveries.Type: GrantFiled: January 19, 2016Date of Patent: May 8, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventor: Paul Musicus
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Publication number: 20180112914Abstract: A method of transporting at least one panel intended to form part of a distillation apparatus in which a first, possibly partial, enclosure is built to contain an element of a distillation apparatus that is to operate at a temperature other than ambient temperature, at least one panel is attached to the first enclosure, the first enclosure attached to the at least one panel is transported to an erection site, the at least one panel is detached from the first enclosure and used to finish building the first or to build the second enclosure or to build a completely different element of the plant.Type: ApplicationFiled: October 18, 2017Publication date: April 26, 2018Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Patrice CAVAGNE, Franck LEMAIRE, Jean-Marc PEYRON
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Patent number: 9950274Abstract: In a method for cooling a flow containing at least 35% carbon dioxide and at least 0.2 ?g/Nm3 of mercury, the mercury being in liquid and/or gas form, the flow is cooled in a first brazed aluminum plate-fin heat exchanger from a first temperature to a second temperature higher than ?38.6° C. to form a cold flow at the second temperature, and the flow cooled to the second temperature is cooled in a second heat exchanger, which is a tube and shell heat exchanger, to a third temperature lower than ?38.6° C.Type: GrantFiled: July 12, 2013Date of Patent: April 24, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Alain Briglia, Arthur Darde, Ludovic Granados, Mathieu Leclerc, Frederick Lockwood, Xavier Traversac
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Publication number: 20180106534Abstract: The invention relates to a heat exchanger comprising parallel plates and spacers arranged in parallel and defining i) rough primary channels and ii) secondary channels arranged so as to exchange heat. Said heat exchanger comprises a primary liquid inlet to be fluidically connected to a primary liquid dispenser. Each rough primary channel has the shape of a prism having a polygonal cross-section and consisting of a plurality of essentially flat faces. The primary channels comprise rough primary channels. Each rough primary channel has microstructure elements which are distributed along the entire length of the channel and have dimensions of between 1 ?m and 300 ?m.Type: ApplicationFiled: April 13, 2016Publication date: April 19, 2018Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Centre National De La Recherche ScientifiqueInventors: Erwan LE GULUDEC, Clement LIX, David QUERE, Quentin SANIEZ, Bernard SAULNIER, Evan SPRUIJT, Marc WAGNER
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Patent number: 9945606Abstract: Methods and apparatus for cryogenic distillation of air. In a system of air separation columns, all the air is taken to a high pressure which is 5 to 10 bar greater than a medium pressure. A portion of air, between 10% and 50% of the high pressure air stream, is boosted in a cold booster. This boosted air is then sent to an exchanger and a portion of it liquefies at the cold end of the exchanger. Part of the air is sent to one column of the column system, and another fraction is partly expanded in a Claude turbine. After expansion in the turbine, the air is sent to a medium pressure column, and a liquid stream is withdrawn for one of the columns of the system. The withdrawn stream is pressurized and vaporizes in the exchange line. The cold booster is coupled to either an expansion turbine, an electric motor, or a combination of the two.Type: GrantFiled: April 6, 2004Date of Patent: April 17, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Patrick Le Bot, Olivier De Cayeux, Frédéric Judas
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Patent number: 9938591Abstract: The present application discloses a method for carbonation with CO2. The method now disclosed describes the use of a static or dynamic mixer to react the CO2 with the incoming of nation liquor to whom Ca(OH)2 was previously added and readily starts the precipitation of tiny carbonate crystals. This solution can be advantageously used to compensate the deficit of CO2 in the carbonation process. This method for carbonation can be applied for example in the sugar refining industry.Type: GrantFiled: May 15, 2015Date of Patent: April 10, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Carlos Alberto Correia Alves, Arnaldo Manuel Estima De Oliveira Araujjo
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Patent number: 9936569Abstract: Method for cooling soldered printed circuit board modules in a cooling zone of a soldering system, wherein at least one cooling gas comprising inert gas is introduced into the cooling zone, wherein the printed circuit boards are conveyed continuously from a soldering zone of the soldering system into the cooling zone, wherein the cooling gas is generated using liquid cooling gas. The method according to the invention and the device (1) according to the invention advantageously permit highly efficient cooling of printed circuit board modules after the soldering process. The cooling gas may advantageously be used for inerting the soldering system (2) after extraction from the cooling zone (15).Type: GrantFiled: October 22, 2012Date of Patent: April 3, 2018Assignee: L'Air Liquide, Soci§té Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Holger Liebert, Patrick Ridgeway, Andre Kast, Laurent Coudurier
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Patent number: 9932281Abstract: The present invention relates to a process for the production of olefins from oxygenates, comprising the following steps: (i) heterogeneously catalyzed conversion of methanol to a product stream containing a C3? and a C4+ fraction, (ii) distillation of the product stream for separating the C3? fraction from a bottom product, and (iii) distillation of the bottom product for separating a stream containing the C4+ fraction and dimethyl ether from a stream containing water and methanol. Furthermore, the invention also comprises a plant for carrying out this process.Type: GrantFiled: December 3, 2013Date of Patent: April 3, 2018Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges ClaudeInventor: Martin Rothaemel
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Patent number: 9919258Abstract: A pressure swing adsorption process for producing a gas stream enriched in a compound X from a feed gas stream is provided. The process includes at least 2 adsorbers, with each adsorber being subjected to a pressure cycle having a high pressure and a low pressure. The process includes adsorption at the high pressure with production of the gas stream enriched in compound X; then depressurization; then elution at the low pressure; and finally repressurization to the high pressure. The elution gas is made up fractions of gas stream resulting from the depressurization of an adsorber and the gas stream enriched in compound X. The pressure cycle has a phase time corresponding to the duration of a pressure cycle divided by the number of adsorbers and the fraction of the gas stream enriched in compound X is determined as a function of the phase time.Type: GrantFiled: September 30, 2014Date of Patent: March 20, 2018Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Christian Monereau, Yann-Pierrick Lemaire, Elise Renou, Louis Toulemonde
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Patent number: 9920077Abstract: Halogen free amine substituted trisilylamine and tridisilylamine compounds and a method of their preparation via de-hydrogenative coupling between the corresponding unsubstituted trisilylamines and amines catalyzed by transition metal catalysts is described. This new approach is based on the catalytic dehydrocoupling of a Si—H and a N—H moiety to form an Si—N containing compound and hydrogen gas. The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—N containing products are halide free. Such compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si containing films.Type: GrantFiled: September 19, 2014Date of Patent: March 20, 2018Assignee: L'Air Liquide, SociétéAnonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Antonio Sanchez, Jean-Marc Girard
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Patent number: 9920078Abstract: Compounds and method of preparation of Si—X and Ge—X compounds (X?N, P, As and Sb) via dehydrogenative coupling between the corresponding unsubstituted silanes and amines (including ammonia) or phosphines catalyzed by metallic catalysts is described. This new approach is based on the catalytic dehydrogenative coupling of a Si—H and a X—H moiety to form a Si—X containing compound and hydrogen gas (X?N, P, As and Sb). The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—X products produced by dehydrogenative coupling are inherently halogen free. Said compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si-containing films.Type: GrantFiled: August 24, 2016Date of Patent: March 20, 2018Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Antonio Sanchez, Gennadiy Itov, Peng Zhang, Matthew Damien Stephens, Manish Khandelwal
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Patent number: 9914142Abstract: The disclosure relates to a device for dispensing one or more jets of cryogenic fluid, particularly liquid nitrogen, comprising a fluid conveying pipeline feeding one or more fluid dispensing nozzles arranged at the downstream end of said pipeline, and a motor collaborating with the fluid conveying pipeline via a rotary transmission shaft and a transmission mechanism.Type: GrantFiled: June 24, 2010Date of Patent: March 13, 2018Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Jacques Quintard, Frédéric Richard, Charles Truchot
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Patent number: 9915484Abstract: Process for producing an element comprising a multilayer architecture, the layers of which comprise primary channels on their upper faces, said process comprising the following successive steps: (a) producing secondary channels on the lower faces of each layer, each secondary channel being intended to be facing a primary channel of the neighboring lower layer within the architecture, (b) depositing a coating that protects against oxidation at a temperature of between 500° C. and 1000° C. and against corrosion over all of the lower and upper surfaces of the layers, (c) sanding or mechanical cleaning of the surfaces intended to be assembled, and (d) assembling via superposition of the various layers so that each secondary channel of a lower face of an upper layer is facing and is centered on a primary channel of the neighboring lower layer, the width of each secondary channel being greater than the width of the primary channel which it is facing within the architecture.Type: GrantFiled: March 17, 2014Date of Patent: March 13, 2018Assignees: L'AIR LIQUIDE SOCIÉTÉ ANONYME POUR L'ÉTUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE DE LORRAINEInventors: Damien Sallais, Laurent Prost, Pascal Del-Gallo, Marc Wagner, Michel Vilasi, Thierry Mazet, Stephane Mathieu
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Patent number: 9907737Abstract: A composition which includes a) ferulic acid ethyl ester and b) one, two or more aryl alkanols. The combination of components a) and b) has an antimicrobial effect on products such as cosmetics.Type: GrantFiled: July 4, 2014Date of Patent: March 6, 2018Assignee: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Wolfgang Beilfuss, Klaus Weber, Peter Oltmanns, Sabine Herweg, Sarah Erichsen, Carsten Bungenstock, Sonja Luthje
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Patent number: 9909716Abstract: A stopper for fluid coupling and including a self-locking sheath designed to be slipped onto a connector, the sheath extending about a central longitudinal axis and including on its inner surface and at a first end, a tapped portion designed to engage with a mating threaded portion formed on the outer surface of the connector where the tapped portion includes at least one recess parallel to the longitudinal axis, where the inner surface of the sheath includes, at a second end opposite the first end, a spindle extending inside the sheath in a direction parallel to the longitudinal axis towards the second end of the sheath as far as a free end located between the first and second ends of the sheath, the free end of the spindle being designed to form a protective cover for a surface of the connector designed to engage with a filling tool.Type: GrantFiled: March 18, 2013Date of Patent: March 6, 2018Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Antoine Frenal
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Patent number: 9909717Abstract: Device for supplying gas comprising a support frame (2) housing a plurality of pressurized-fluid cylinders (3) connected to a fluidic circuit (4, 5) for withdrawing from or filling the cylinders (3), said circuit (4, 5) comprising at least a first connection end (6) connected to the cylinders (3) via a first isolation valve (7) to allow filling of and withdrawal from the cylinders (3), the support frame (2) comprising a base (34) on which the cylinders (3) rest and a set of uprights (30) and transverse beams (31, 32, 33) defining a cage of parallelepipedal overall shape to hold the cylinders (3), the frame (2) comprising, on one of the lateral faces thereof referred to as the “front” face (35), an interface panel (20) comprising at least one opening (23, 24, 25) providing access to the circuit (4, 5), characterized in that the lateral face referred to as the “rear” face (36) of the frame (2), which face is situated opposite the front face (35), is delimited by uprights (30) longer than the uprights (30) of thType: GrantFiled: July 30, 2014Date of Patent: March 6, 2018Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Antoine Frenal, Denis Muller, Didier Robert
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Patent number: 9911590Abstract: Method of deposition on a substrate of a dielectric film by introducing into a reaction chamber a vapor of a precursor selected from the group consisting of Zr(MeCp)(NMe2)3, Zr(EtCp)(NMe2)3, ZrCp(NMe2)3, Zr(MeCp)(NEtMe)3, Zr(EtCp)(NEtMe)3, ZrCp(NEtMe)3, Zr(MeCp)(NEt2)3, Zr(EtCp)(NEt2)3, ZrCp(NEt2)3, Zr(iPr2Cp)(NMe2)3, Zr(tBu2Cp)(NMe2)3, Hf(MeCp)(NMe2)3, Hf(EtCp)(NMe2)3, HfCp(NMe2)3, Hf(MeCp)(NEtMe)3, Hf(EtCp)(NEtMe)3, HfCp(NEtMe)3, Hf(MeCp)(NEt2)3, Hf(EtCp)(NEt2)3, HfCp(NEt2)3, Hf(iPr2Cp)(NMe2)3, Hf(tBu2Cp)(NMe2)3, and mixtures thereof; and depositing the dielectric film on the substrate.Type: GrantFiled: January 17, 2017Date of Patent: March 6, 2018Assignee: L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Christian Dussarrat, Nicolas Blasco, Audrey Pinchart, Christophe Lachaud
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Patent number: 9908776Abstract: There is proposed a method for pre-reforming a hydrocarbonaceous feed stream into a pre-reforming product containing carbon oxides, hydrogen and hydrocarbons, in which the adiabatically operated pre-reforming reactor comprises at least two reaction zones designed as fixed beds in a common reactor vessel, which are in fluid connection with each other and are filled with beds of granular, nickel-containing catalyst active for pre-reforming, wherein the first reaction zone in flow direction is filled with a catalyst active for high-temperature pre-reforming and the last reaction zone in flow direction is filled with a catalyst active for low-temperature pre-reforming.Type: GrantFiled: April 15, 2014Date of Patent: March 6, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Ulrich Wolf, Philipp Marius Hackel, Mirko Hubel
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Patent number: 9903645Abstract: The process for liquefying a gaseous stream received from a pipeline that is comprised predominantly of ethane and a relatively small amount of other components by using a mixed refrigerant loop incorporating heavy hydrocarbons (butane, and/or pentane), as well as a distillation column to remove constituents lighter than ethane. Prior to cooling in a main heat exchanger, the gaseous stream is split into two fractions. The first fraction is cooled in the main heat exchanger and introduced to the distillation column. The second fraction is expanded to produce a two phase fluid, with the liquid fraction being introduced to the distillation column below the first fraction, and the gas fraction being cooled and then introduced to the distillation column at a point above the first fraction.Type: GrantFiled: October 7, 2015Date of Patent: February 27, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Michael A. Turney, Paul Terrien, Yasser Jebbari