Patents Assigned to L'Exploitation Des
  • Patent number: 9901867
    Abstract: The invention relates to an air-separation device comprising a generally cylindrical casing housing a filtration element including a bundle of hollow oblong fibers forming a membrane, the longitudinal axis of the fibers being parallel to the longitudinal axis (A) of the cylindrical casing, said casing comprising an air inlet at a first end and an outlet for purified gas at a second end. The device comprises a member for maintaining the fiber bundle in the casing, characterized in that the maintenance member comprises at least one spring member disposed inside the casing, said spring member being loaded between an end-stop formed by the casing and a longitudinal end of the fiber bundle in order to maintain the fiber bundle longitudinally in place while allowing it to dilate and contract.
    Type: Grant
    Filed: September 15, 2014
    Date of Patent: February 27, 2018
    Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Xavier Roussin-Bouchard, Aurelie Caillaud, Pierre Gianese, Elodie Dumont, Jean-Marc Dejonghe
  • Patent number: 9902659
    Abstract: A process for producing olefins from oxygenates includes the following steps: (i) heterogeneously catalyzed conversion of at least one oxygenate to a stream containing propylene, aromatics and cyclic olefins, (ii) at least partial hydrogenation of the aromatics and cyclic olefins to naphthenes, and (iii) at least partial recirculation of the naphthenes into the heterogeneously catalyzed conversion.
    Type: Grant
    Filed: February 4, 2014
    Date of Patent: February 27, 2018
    Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Martin Rothaemel, Roberta Olindo, Stephane Haag, Thomas Renner, Frank Castillo-Welter
  • Patent number: 9903646
    Abstract: The apparatus for liquefying a gaseous stream received from a pipeline that is comprised predominantly of ethane and a relatively small amount of other components by using a mixed refrigerant refrigeration cycle loop incorporating heavy hydrocarbons, as well as a distillation column to remove constituents lighter than ethane. Prior to cooling in a main heat exchanger, the gaseous stream is split into two fractions. The main heat exchanger is configured to cool the first fraction before heading to the distillation column for separation therein. An expansion device expands the second fraction to produce a two phase fluid, which is separated in a gas/liquid separator, with the liquid fraction being introduced to the distillation column below the first fraction, and the gas fraction being cooled and then introduced to the distillation column at a point above the first fraction.
    Type: Grant
    Filed: October 7, 2015
    Date of Patent: February 27, 2018
    Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Michael A. Turney, Paul Terrien, Yasser Jebbari
  • Patent number: 9903648
    Abstract: According to certain embodiments of the invention, a gas containing at least 50% of carbon dioxide is cooled in a first exchanger so as to produce a cooled fluid, a liquid derived from the cooled fluid is sent to a distillation column to be separated therein, a head gas is withdrawn from the distillation column and reheated in the first exchanger, a vat liquid, which is richer in carbon dioxide than the gas containing at least 50% of carbon dioxide, is withdrawn and at least a portion thereof is heated in the first exchanger, at least a first portion of the vat liquid is vaporized in the first exchanger in order to produce a vaporized portion, the vaporized portion is sent back to the column and an NOx removal column is supplied with the liquefied cycle gas produced by vaporizing and reliquefying the vat liquid from the column.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: February 27, 2018
    Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Alain Briglia, Arthur Darde, Frederick Lockwood, Xavier Traversac
  • Patent number: 9895653
    Abstract: In a process for the separation of a stream containing carbon dioxide, water and at least one light impurity including a separation step at subambient temperature, the feed stream is compressed in a compressor comprising at least two stages to form a compressed feed stream, the compressed feed stream is purified in an adsorption unit to remove water and form a dried compressed stream, the dried compressed stream or a stream derived therefrom is cooled to a subambient temperature and separated by partial condensation and/or distillation in a separation apparatus, liquid enriched in carbon dioxide is removed from the separation apparatus, the adsorption unit is regenerated using a regeneration gas and the regeneration gas is formed by separating, by permeation in a permeation unit, the dried compressed stream or a gas derived therefrom, the permeate of the permeation unit constituting the regeneration gas.
    Type: Grant
    Filed: July 11, 2013
    Date of Patent: February 20, 2018
    Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Arthur Darde, Richard Dubettier-Grenier, David J. Hasse, Sudhir S. Kulkarni, Mathieu LeClerc, Paul Terrien
  • Patent number: 9895646
    Abstract: A pressure swing adsorption process for producing a gas stream enriched in a compound X from a feed gas stream is provided. The process includes at least 2 adsorbers, with each adsorber being subjected to a pressure cycle having a high pressure and a low pressure. The process includes adsorption at the high pressure with production of the gas stream enriched in compound X, depressurization to the low pressure with production of at least one portion of an elution gas, c) elution at the low pressure, and repressurization to the high pressure. The pressure cycle has a phase time corresponding to the duration of a pressure cycle divided by the number of adsorbers. The pressure of the pressure cycle is modified to keep the phase time of the PSA equal to or within ±5% of the nominal phase time.
    Type: Grant
    Filed: October 1, 2014
    Date of Patent: February 20, 2018
    Assignee: L'Air Liquide, SociétéAnonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Christian Monereau, Yann-Pierrick Lemaire, Louis Toulemonde, Paulo Silva
  • Patent number: 9889268
    Abstract: The invention relates to an on-site medical gas production plant (100) comprising a unit (50) for purifying gas, such as air, a first compartment (A) for storing purified gas, and a main gas line (10) fluidically connecting the gas purification unit (50) to the said first storage compartment (A). It furthermore comprises a three-way actuated valve (VA) arranged on the main gas line (10) upstream of the first storage compartment (A), and furthermore connected to the atmosphere (at 12) via a vent line (11), as well as an operating device (4) which controls at least the three-way actuated valve (VA), and at least a first gas analysis device (D1) of which a first measurement line (29) is fluidically connected (at 28) to the main line (10), upstream of the three-way actuated valve (VA), and which is electrically connected to the said operating device (4).
    Type: Grant
    Filed: May 16, 2017
    Date of Patent: February 13, 2018
    Assignee: L'Air Liquide, SociétéAnonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventor: Paul Edwards
  • Patent number: 9892932
    Abstract: Replacement chemistries for the cC4F8 passivation gas in the Bosch etch process and processes for using the same are disclosed. These chemistries have the formula CxHyFz, with 1 ?x<7, 1?y?13, and 1?z?13. The replacement chemistries may reduce RIE lag associated with deep silicon aperture etching.
    Type: Grant
    Filed: June 17, 2015
    Date of Patent: February 13, 2018
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc., Air Liquide Electronics U.S. LP
    Inventors: Peng Shen, Christian Dussarrat, Curtis Anderson, Rahul Gupta, Vincent M. Omarjee, Nathan Stafford
  • Patent number: 9889400
    Abstract: The invention relates to an on-site medical gas production plant (100) comprising a unit (50) for purifying gas, such as air, a first compartment (A) for storing purified gas, and a main gas line (10) fluidically connecting the gas purification unit (50) to the said first storage compartment (A). It furthermore comprises a three-way actuated valve (VA) arranged on the main gas line (10) upstream of the first storage compartment (A), and furthermore connected to the atmosphere (at 12) via a vent line (11), as well as an operating device (4) which controls at least the three-way actuated valve (VA), and at least a first gas analysis device (D1) of which a first measurement line (29) is fluidically connected (at 28) to the main line (10), upstream of the three-way actuated valve (VA), and which is electrically connected to the said operating device (4).
    Type: Grant
    Filed: May 30, 2017
    Date of Patent: February 13, 2018
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventor: Paul Edwards
  • Publication number: 20180038638
    Abstract: The method for producing liquid hydrogen can include the steps of: introducing pressurized natural gas from a high pressure natural gas pipeline to a gas processing unit under conditions effective for producing a purified hydrogen stream; and introducing the purified hydrogen stream to a hydrogen liquefaction unit under conditions effective to produce a liquid hydrogen stream, wherein the hydrogen liquefaction unit provides a warm temperature cooling and a cold temperature cooling to the purified hydrogen stream, wherein the warm temperature cooling is provided by utilizing letdown energy of a pressurized stream selected from the group consisting of a nitrogen stream sourced from a nitrogen pipeline, a natural gas stream sourced from the high pressure natural gas pipeline, an air gas sourced from an air separation unit, and combinations thereof, wherein the cold temperature is provided by utilizing letdown energy of the purified hydrogen stream.
    Type: Application
    Filed: January 24, 2017
    Publication date: February 8, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Alain GUILLARD, Pierre-Etienne FRANC, Michael A. TURNEY, Kirill ANDREEV, Alexander ROESCH
  • Publication number: 20180038643
    Abstract: An integrated method for the production of liquefied natural gas (LNG) and syngas is provided. The method can include the steps of: utilizing letdown energy of a high pressure natural gas stream that is withdrawn from a natural gas pipeline to provide a warm temperature cooling; utilizing a refrigeration cycle to provide a cold temperature cooling, wherein the refrigeration cycle comprises a refrigerant recycle compressor that is powered utilizing a steam turbine; and cooling a second high pressure natural gas stream using the warm temperature cooling and the cold temperature cooling to produce an LNG product stream. The second high pressure natural gas stream is withdrawn from the natural gas pipeline, and the steam turbine is powered by high pressure steam that is produced from a syngas production facility.
    Type: Application
    Filed: January 24, 2017
    Publication date: February 8, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Alexander ROESCH, Alain GUILLARD, Michael A. TURNEY
  • Publication number: 20180038644
    Abstract: A method for the liquefaction of an industrial gas by integration of a methanol plant and an air separation unit (ASU) is provided.
    Type: Application
    Filed: January 24, 2017
    Publication date: February 8, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Alain GUILLARD, Michael A. TURNEY, Alexander ROESCH
  • Publication number: 20180038639
    Abstract: A method for liquefaction of natural gas using refrigeration from a combination of sources including a refrigeration cycle and letdown energy of natural gas is provided. The natural gas to be liquefied (LNG) is boosted in pressure using a booster that is powered by expansion of a portion of the natural gas flow from the booster through a first natural gas turbine. A second flow of natural gas is expanded in a second natural gas turbine, and the resulting expanded stream, along with the natural gas expanded in the first natural gas turbine, are warmed against the natural gas to be liquefied. The flow rate of the natural gas in the second natural gas turbine is decoupled from the booster, thereby allowing for variation in flow rates and pressures while maintaining a constant production of LNG.
    Type: Application
    Filed: January 24, 2017
    Publication date: February 8, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Oriane FARGES, Michael A. TURNEY, Louis de BESOMBES
  • Publication number: 20180038642
    Abstract: It is proposed to integrate a gas processing unit with a liquefaction unit. The industrial gas stream may be but is not limited to air gases of oxygen, nitrogen argon, hydrocarbon, LNG, syngas or its components, CO2, or any other molecule or combination of molecules. It is proposed to integrate the underutilized process inefficiencies of a gas processing unit into the liquefaction unit to produce a liquid at a reduced operating cost. The gas processing unit may be any system or apparatus which alters the composition of a feed gas. Examples could be, but are not limited to, a methanol plant, steam methane reformer, cogeneration plant, and partial oxidation unit.
    Type: Application
    Filed: January 24, 2017
    Publication date: February 8, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Alexander ROESCH, Alain GUILLARD, Michael A. TURNEY
  • Publication number: 20180038641
    Abstract: A method for the liquefaction of an industrial gas by integration of a methanol plant and an air separation unit (ASU) is provided. The method can include the steps of: (a) providing a pressurized natural gas stream, a pressurized purge gas stream originating from a methanol plant, and a pressurized air gas stream comprising an air gas originating from the ASU; (b) expanding three different pressurized gases to produce three cooled streams, wherein the three different pressurized gases are the pressurized natural gas stream, the pressurized purge gas stream, and the pressurized air gas stream; and (c) liquefying the industrial gas in a liquefaction unit against the three cooled streams to produce a liquefied industrial gas stream. The industrial gas to be liquefied is selected from the group consisting of a first portion of the pressurized natural gas stream, a nitrogen gas stream, hydrogen and combinations thereof.
    Type: Application
    Filed: January 24, 2017
    Publication date: February 8, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Alain GUILLARD, Michael A. TURNEY, Alexander ROESCH
  • Patent number: 9883671
    Abstract: Disclosed is an antimicrobial composition that includes a) one or more C3 to C5 alkane dioles-1,3, b) one or more aromatic alcohols and c) one or more C8 to C14 alkanols. A preferred component a) is propane diol-1,3. Preferred components b) are phenoxyethanol and phenethyl alcohol. A preferred component c) is undecanol-1. Optionally, an antioxidant c) is present, which is preferably Vitamin E. In a preferred embodiment the composition is a concentrate and is suitable for the antimicrobial finishing of dermatological, cosmetic and pharmaceutical products.
    Type: Grant
    Filed: June 26, 2013
    Date of Patent: February 6, 2018
    Assignee: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Ralf Gradtke, Klaus Weber, Wolfgang Beilfuss, Stefan Sakulowski
  • Publication number: 20180028961
    Abstract: A process for separating undesired, in particular acidic gas constituents from a raw gas, in particular raw synthesis gas, by absorption with cold methanol as physical detergent, wherein the methanol is cooled in a compression refrigeration machine by using a multi-component coolant. The use of the coolant according to the invention provides significant advantages with regard to the compressor capacity required in the compression refrigeration machine for the provision of a defined cooling capacity.
    Type: Application
    Filed: January 19, 2016
    Publication date: February 1, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Exploitation des Proceds Georges Claude
    Inventors: Lucie CHAUBET, Marc WAGNER
  • Patent number: 9878964
    Abstract: A process for producing olefins from oxygenates comprises the following steps: (i) heterogeneously catalyzed conversion of at least one oxygenate to an entire stream containing propylene, aromatics and cyclic olefins; (ii) olefin interconversion of at least a part of the entire stream; (iii) separation of a stream rich in aromatics from the reaction product of the olefin interconversion; and (iv) hydrogenation of the stream rich in aromatics.
    Type: Grant
    Filed: February 4, 2014
    Date of Patent: January 30, 2018
    Assignee: L'AIR LIQUIDE SOCIÉTÉ ANONYME POUR L'ÉTUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Martin Rothaemel, Roberta Olindo, Stephane Haag, Thomas Renner, Frank Castillo-Welter
  • Patent number: 9878962
    Abstract: A process for producing olefins from oxygenates comprises the following steps: (i) heterogeneously catalyzed conversion of at least one oxygenate to an entire stream containing liquid and gaseous organic compounds and water, and (ii) separating the entire stream in a first separating means into a fraction containing at least 90 vol-% of the gaseous organic compounds of the entire stream, into a fraction containing at least 90 wt-% of the liquid organic compounds of the entire stream, and into a fraction containing at least 90 wt-% of the water of the entire stream. Furthermore, the invention also comprises a plant for carrying out this process.
    Type: Grant
    Filed: December 3, 2013
    Date of Patent: January 30, 2018
    Assignee: L'AIR LIQUIDE SOCIÉTÉ ANONYME POUR L'ÉTUDE ET L'EXPLOITATION DES PROCEDES GEORGE CLAUDE
    Inventors: Bernd Ahlers, Martin Gorny, Hermann Bach
  • Patent number: 9878278
    Abstract: Entrained metal hydride particle are removed from a flow of hydrogen from a Mg-based hydride storage unit using not only a particle filter but improvements for reducing or eliminating drastic changes in flow. In addition to or alternative to removal of entrained metal hydride particles, methane produced by reaction of hydrogen with steel in a metal hydride system preferably operated above 350° C. is removed downstream of the Mg-based hydride storage unit using an adsorption cartridge, preferably containing activated carbon.
    Type: Grant
    Filed: April 30, 2016
    Date of Patent: January 30, 2018
    Assignee: L'AIR LIQUIDE SOCIÉTÉ ANONYME POUR L'ÉTUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Pascal Tessier, Philippe Coignet, Benjamin Jurcik, Ryan Adelman