Abstract: The invention relates to a method for replacing tubes in a hydrocarbon-vapor reforming unit, that comprises before launching any new production campaign: measuring the expansion of the tube diameters; taking X-ray photographs of the tubes; realizing replicas of the surfaces of the tubes; wherein a tube is replaced when it fulfills at least one of the following conditions; the diameter expansion is higher than 3%; the X-ray photograph includes at least one crack; the replica shows a sufficient thermal ageing and/or creep deformation.

Abstract: A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic material and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic material. The fiber is made by extruding a core suspension of particles of the first ceramic material, a polymeric binder, and a solvent and a sheath suspension of particles of the second ceramic material, a polymeric binder and a solvent, respectively, from a spinnerette and coagulating the nascent hollow fiber to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binders are burned off. Second, the sheath is densified and the second ceramic material is sintered without fully sintering the first ceramic material. The first ceramic material of the core suspension has a median particle size greater than that of the second ceramic material of the sheath suspension.

Abstract: A compressed air stream is cooled in an exchanger to form a compressed cooled air stream. The stream is then cryogenically compressed in a first compressor to form a first pressurized gas stream. The first pressurized gas stream is further cooled in the exchanger, cryogenically compressed in a second compressor, and then it is cooled and partially liquefied. The cooled and partially liquefied product is then fed to a system of distillation columns. A liquid product is removed from the system of distillation columns. This product is then pressurized, vaporized and warmed in the exchanger to yield pressurized gaseous product.

Abstract: The invention relates to a method for controlling a hydrocarbon vapor reforming reaction using a combustion chamber containing burners and tubes, said tubes being filled with catalysts and capable of being crossed by a mixture of hydrocarbons and vapor, the burners being arranged so as to transfer their combustion heat to the mixture of hydrocarbons and vapor through the walls of the tubes, wherein the temperature T of the wall of each tube is measured in the downstream part of the tube, and if for at least one tube, the measured temperature“is higher or equal to the MOT (DTT-15° C.), DTT being the design temperature of the measured tube, the functional parameters of the reforming method are then modified so as to decrease the measured temperature T of this tube down to a value lower than the MOT.

Abstract: The invention relates to a microbicidal use solution which comprises a) one or more isothiazolin-3-ones and b) one or two organic amines selected from N-dodecylpropane-1,3-diamine and bis(aminopropyl)-dodecylamine and optionally c) one or more oxidizing agents. The use solution is preferably in the form of technical and domestic products.

Abstract: A method for tracking the deterioration of the insulators in a rotating machine, a method for preventive maintenance of these machines using this tracking and devices using the tracking method is presented.

Abstract: (EN) The invention relates to a method for estimating the characteristic parameters of a cryogenic tank (1), in particular geometric parameters, including: a step comprising the measurement of the pressure differential between the upper and lower parts of the tank prior to filling DPmes—before; a step comprising the measurement of the pressure differential between the upper and lower parts of the tank after filling DPmes—after; a step comprising the determination of the mass of liquid delivered (mdelivered) during filling; and a step comprising the calculation of a first geometric parameter (R) of the tank, namely the radius (R) which is calculated from equation (I), wherein g is the Earth's gravitational acceleration and MAVO is a density coefficient that is a function of the density of the liquid and the gas in the tank and optionally in the pressure measuring pipes (11) when the pressure differential is measured by at least one remote pressure sensor connected to the upper and lower parts of the tank via r

Abstract: Methods and compositions for depositing metal films are described herein. In general, the disclosed methods utilize precursor compounds comprising gold, silver or copper. More specifically, the disclosed precursor compounds utilize neutral ligands derived from ethylene or acetylene.

Abstract: Techniques are disclosed for increasing the robustness of optimization solutions for bulk gas distribution, relative to uncertain events such as unexpected plant outages. The techniques actively consider different assumptions regarding unexpected plant outages while searching for a solution (i.e., when generating a delivery schedule). A robust solution (delivery schedule) is one on which a plant outage only has a limited impact. A computer-implemented delivery scheduling application may identify a robust solution that performs well with respect to a range of uncertain future conditions (e.g., a variety of plant outages), at the lowest additional cost to the producer/distributor relative to other solutions.

Abstract: The device according to the invention for the cooling of articles, comprising at least one channel which can be connected to a first coolant source such that a first stream of a first coolant can flow through the channel, the articles to be cooled being introducible into the stream, is distinguished in that at least one cross-sectional stabilizer for stabilizing the cross section of the at least one channel is formed. The device according to the invention advantageously allows the defined cooling of articles, in particular the freezing of drops of a liquid or pasty material, in particular of liquid or pasty foods. In particular, a deformation, such as warping, of the channels on account of pronounced temperature gradients and/or temperature transients is effectively reduced. Thus, even after cooling-down operations, uniform cooling conditions can be ensured.

Abstract: A method for depolluting and regenerating a catalytic fuel-cell electrode, the reaction of the fuel of the cell and capture of at least one polluting species occurring on the catalytic electrode, comprises: a decrease, at a constant first reference current density, in fuel flow, relative to a nominal fuel flow, for a first length of time, leading to a value for the stoichiometric coefficient of fuel lower than 1, to increase oxidation potential on the catalytic electrode and reach oxidation potential of the polluting species, to eliminate it; a cut-off of current for a cut-off time; an increase in flow above nominal flow, leading to a value of stoichiometric coefficient higher than or equal to 1; and an increase in current density until a second current density chosen by operator and possibly identical to or different from the initial reference current density, is reached.

Abstract: “A hydrogen purification process is provided. This process includes separating hydrogen from a hydrogen containing stream in at least two sequential palladium membrane purification zones, wherein each purification zone has a permeate side, wherein the permeate side pressure of purification zones are not the same.

Abstract: The invention concerns the use of the ruthenium-containing precursor having the formula (Rn-chd)Ru(CO)3, wherein: (Rn-chd) represents a cyclohexadiene (chd) ligand substituted with n substituents R, any R being in any position on the chd ligand; n is an integer comprised between 1 and 8 (1?n?8) and represents the number of substituents on the chd ligand; R is selected from the group consisting of C1-C4 linear or branched alkyls, alkylamides, alkoxides, alkylsilylamides, amidinates, carbonyl and/or fluoroalkyl for R being located in any of the eight available position on the chd ligand, while R can also be oxygen O for substitution on the C positions in the chd cycle which are not involved in a double bond for the deposition of a Ru containing film on a substrate.

Abstract: An improved refrigeration cycle is provided. The cycle provides for improved thermal performance by incorporating a refrigerant makeup tank that introduces liquid refrigerant with expanded refrigerant upstream of the heat exchanger, thereby providing a savings in either electricity costs or refrigerant.

Abstract: The motion of the magnetized movable masses of a bilinear electrodynamic motor comprising two movable masses moving in opposite senses parallel to the axis (x-x) of the motor is balanced. At least one first magnetic sensor and at least one second magnetic sensor are provided which are able to deliver respectively a first electrical signal (s1(t)) and a second electrical signal (s2(t)) respectively representative of the motion of a first and of a second movable mass. An error signal (?s(t)) equal to the difference between the said first (s1(t)) and second (s2(t)) electrical signals is recorded. A harmonic analysis of the error signal performed. A sinusoidal excitation signal (e1(t)) at a given frequency f0 is applied to the first movable mass.

Abstract: The invention relates to a catalytic reactor including: a reaction chamber; at least one catalytic structure made up of at least one catalytic cell-like architecture having outer dimensions at most 10% smaller than the inner dimensions of the reaction chamber; an annular space between the inner wall of the reaction chamber and the cell-like architectures; and at least one second structure positioned in the annular space, selected from among: a) a fibrous structure, or b) a structure including at least one metal collar clasping at least one portion of the cell-like architectures and supporting metal fins.

Abstract: A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic compound and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic compound. The fiber is made by extruding first and second suspensions of the first and second ceramic compounds in polymeric binders and solvent from a spinnerette and coagulating the nascent hollow fiber to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binder is burned off. Second, the sheath is densified and the second ceramic compound is sinter without fully sintering the first ceramic compound. The first ceramic compound has a melting point higher than that of the second ceramic compound.

Abstract: Process for producing hydrogen from a gas mixture comprising hydrogen, CO2, CO, CH4 and water, employing a CO2 PSA unit, a cryogenic unit and an H2 PSA unit, in which process: a) said gas mixture is introduced into the CO2 PSA unit, producing a CO2-enriched fraction and CO2-depleted fraction; b) CO2-enriched fraction is introduced into the cryogenic unit, producing a CO2-enriched fraction and an H2-enriched fraction; c) the H2-enriched fraction is recycled upstream of the H2 PSA unit; and d) the CO2-depleted fraction coming from step b) is introduced into the H2 PSA unit, producing a hydrogen-enriched stream and a waste gas.

Abstract: A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic material and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic material. The fiber is made by extruding core and sheath suspensions from a spinnerette. The core suspension includes particles of the first ceramic material, a polymeric binder, a solvent, and a pore former material insoluble in the solvent. The sheath suspension includes particles of the second ceramic material, a polymeric binder and a solvent. The nascent hollow fiber is coagulated in a coagulant bath to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binders and pore former material are burned off. Second, the sheath is densified and the second ceramic material is sintered without fully sintering the core.

Abstract: Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.