Patents Assigned to L'Exploitation Des
  • Patent number: 8636922
    Abstract: The present invention provides a process for recovering high purity gaseous hydrogen and high purity gaseous carbon dioxide from a syngas stream by utilizing a hydrogen selective membrane unit and a primary water gas shift reactor in combination with a cryogenic purification unit, a hydrogen recovery unit and a secondary water gas shift reactor or by utilizing a hydrogen membrane/water gas shift reactor in combination with a cryogenic purification unit, a hydrogen recovery unit and a secondary water gas shift reactor. Each of these embodiments may further include a sulfur recovery unit.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: January 28, 2014
    Assignee: L'Air Liquide Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Bhadra S. Grover, Paul Terrien
  • Patent number: 8636040
    Abstract: An installation for packaging a gaseous NO/N2 mixture into at least one container from a source (1) of gaseous NO and a source (2) of gaseous nitrogen is disclosed. The installation uses at least one filling system (3) comprising one or more filling stations (24) for gas containers (25). A first gas line (11) is fluidically connected to the source (1) of gaseous NO and to the filling system (3), and a second gas line (12) is fluidically connected to the source (2) of gaseous nitrogen and to the filling system (3). The first gas line (11) and the second gas line (12) each has a mass flow meter (4, 5), each mass flow meter (4, 5) being connected (14, 15) to a control device (6) collaborating with each mass flow meter (4, 5).
    Type: Grant
    Filed: May 30, 2012
    Date of Patent: January 28, 2014
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Philippe Deck, Luca Valsasina, Wilfried Legeron
  • Patent number: 8636845
    Abstract: Methods and compositions for depositing a metal containing film on a substrate are disclosed. A reactor and at least one substrate disposed in the reactor are provided. A metal containing precursor is provided and introduced into the reactor, which is maintained at a temperature of at least 100° C. A metal is deposited on to the substrate through a deposition process to form a thin film on the substrate.
    Type: Grant
    Filed: June 25, 2009
    Date of Patent: January 28, 2014
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Julien Gatineau, Kazutaka Yanagita, Shingo Okubo
  • Patent number: 8639549
    Abstract: Techniques are disclosed for designing a supply chain distribution network. A network design tool may be configured to facilitates strategic decision making for a producer/distributor of a commodity products (e.g., molecular gas mixtures stored in cylinders) by incorporating transportation costs (i.e., operational decisions) into the strategic decision making process. Further, the network design tool may also integrate investment decision costs, which are usually considered ‘tactical decisions’, into the strategic decision process (e.g., which filling tools are assigned to which plant/hub location). The network design tool implements different algorithm approaches allowing a user to obtain optimal, near-optimal, and approximate solutions.
    Type: Grant
    Filed: October 28, 2010
    Date of Patent: January 28, 2014
    Assignee: L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Sujata S. Pathak, Philippe Briet, Franck Mornet, Nicoleta Neagu, Tejinder Pal Singh
  • Patent number: 8636827
    Abstract: A method of operating a mixed ionic-electronic conducting ceramic membrane having an oxidizing side and a reducing side, said method comprising a start-up phase and a production phase, for producing a gas stream, characterized in that the start-up phase comprises a step of introducing, on the oxidizing side and the reducing side of the membrane respectively, first and second gas mixtures not capable of chemically degrading the membrane; and a step of establishing a stream of oxygen through the membrane.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: January 28, 2014
    Assignee: L'Air Liquide Société Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Nicolas Richet, Cédric Delbos, Gilles Lebain
  • Patent number: 8632621
    Abstract: A simple, compact burner achieves a more optimal melting of a solid charge followed by performance of combustion under distributed combustion conditions. The burner achieves this by fluidically bending the flame towards the solid charge during a melting phase with an actuating jet of oxidant, redirecting the flame in a direction away from the charge, and staging injection of oxidant among primary and secondary portions during a distributed combustion phase.
    Type: Grant
    Filed: December 31, 2010
    Date of Patent: January 21, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Vivek Gautam, Kenneth Kaiser, Luc Jarry, Remi Pierre Tsiava
  • Patent number: 8632686
    Abstract: An apparatus and method to remove water content in organic solvents characterized in that it comprises treatment tank 10 to which organic solvent is introduced, solvent inlet section 1 that introduces the organic solvent, solvent outlet section 2 from which the treated organic solvent is discharged, inert gas inlet section 3 from which inert gas is introduced, treatment gas outlet section 4 from which gas is discharged, cooling treatment tank 20 in which the treatment gas is cooled and the gas and liquid are separated, treatment gas inlet section 5 from which the treatment gas is introduced, recovered liquid outlet section 6 from which the separated liquid organic solvent is discharged, and waste gas outlet section 7 from which the separated gas is discharged, and that the water content in the organic solvent is removed by having the inert gas flow over the entire liquid surface of the organic solvent inside treatment tank 10.
    Type: Grant
    Filed: October 4, 2010
    Date of Patent: January 21, 2014
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Terumasa Koura, Takashi Kameoka
  • Patent number: 8632821
    Abstract: The invention relates to a gaseous mixture containing oxygen (O2) and a volume proportion of 20 to 70% of xenon (Xe) for use as an inhalable drug for preventing or treating hypersensitivity to pain in humans or animals, in particular hypersensitivity to pain expressed as hyperalgesia or allodynia.
    Type: Grant
    Filed: July 13, 2010
    Date of Patent: January 21, 2014
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, Université Bordeaux Segalen
    Inventors: Baptiste Bessiere, Guy Simonnet
  • Publication number: 20140013798
    Abstract: In an air-distillation method, purified air is cooled in an exchange line and then sent to a distillation column of a system of columns, and oxygen- and nitrogen-rich fluids are extracted from a column of the system of columns only during the repressurization phase. A purified airflow, constituting between 3% and 20% of the air compressed in the compressor, is used to at least partially pressurize the adsorber completing the regeneration phase thereof, and the airflow compressed in the compressor during the adsorption phase is substantially equal to the airflow compressed in the compressor during the pressurization of the adsorber. A portion of the purified air is sent to a turbine where it is decompressed and then sent into the atmosphere an as to ensure that it is kept at least partially cold during the entire cycle, and the amount of decompressed airflow sent into the air during the pressurization of an adsorber is less than the amount sent into the air during the adsorption phase of the same adsorber.
    Type: Application
    Filed: March 21, 2012
    Publication date: January 16, 2014
    Applicant: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventor: Patrick Le Bot
  • Patent number: 8628708
    Abstract: The invention relates to a method for producing a packing structure, characterized in that it includes the following main steps: a) a step comprising the hydrothermal synthesis of the packing mass, performed using a mixture of quicklime and silica; and b) a step comprising the drying of the packing mass produced in step (a) at a temperature T2 of between 110° C. and 500° C., possibly with at least one intermediate stage performed at a temperature of between 111° C. and 350° C. over a period t2 selected such that the physisorbed water content of the packing mass is less than 0.5%.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: January 14, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Pascal Del-Gallo, Emmanuel Baune, Jerome Cantonnet
  • Patent number: 8622068
    Abstract: The invention relates to a device for the supply of special gas that can be mounted on a gas cylinder. The device comprises a multi-function unit housing a fluid circuit comprising a single high-pressure regulator; a purge system consisting of three low-pressure valves; a fluidic connection with the inner space of a cylinder; and an outlet enabling equipment to be supplied with gas. The invention is characterized in that the high-pressure regulator is arranged upstream of the purge system.
    Type: Grant
    Filed: November 19, 2008
    Date of Patent: January 7, 2014
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Cyril Bourasseau, Guillaume Rameau
  • Patent number: 8621878
    Abstract: The injection device according to the invention, intended to be attached to the wall of the bottom of a container containing a product to be cooled in bulk, includes a hollow cylindrical body in which a valve forced by a spring is inserted, a throughchannel appreciably parallel to said valve intended to be fed by pressurized cryogenic fluid, one end of said through-channel being connected to the cryogenic fluid feed system and the opposite end opening into the seat of the valve.
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: January 7, 2014
    Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Herve Flamant, Olivier Pouchain, Jacques Fouche, Jo Algoet
  • Publication number: 20140004469
    Abstract: Method of combusting a fuel with an oxidizer and corresponding burner assembly, whereby a jet of fuel and a jet of primary oxidizer are injected into a combustion zone in contact with one another so as to generate a primary fuel-rich flame, a swirling first peripheral gas jet is injected through a first passage around the fuel jet and primary oxidizer jets and a swirling second peripheral gas jet is injected through a second passage around the first peripheral gas jet and whereby a jet of secondary oxidizer is injected through a passage into the combustion zone between the first and second peripheral gas jets.
    Type: Application
    Filed: March 9, 2012
    Publication date: January 2, 2014
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes
    Inventors: Patrick Recourt, Remi Tsiava
  • Publication number: 20140004470
    Abstract: A stream of sub ambient oxygen from an ion transport membrane is injected into an ambient pressure or super ambient pressure oxygen-consuming process through an annular space in between concentrically disposed inner and outer tubes where a high velocity gas is injected into the process from the inner tube.
    Type: Application
    Filed: June 29, 2012
    Publication date: January 2, 2014
    Applicants: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, American Air Liquide, Inc.
    Inventors: Wei HUANG, Justin Jian Wang, Remi Pierre Tsiava
  • Patent number: 8617292
    Abstract: Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.
    Type: Grant
    Filed: July 1, 2010
    Date of Patent: December 31, 2013
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: David J. Hasse, Sudhir S. Kulkarni, Edgar S. Sanders, Jr., Jean-Pierre Tranier, Paul Terrien
  • Publication number: 20130344450
    Abstract: A method for producing a syngas stream for use in a blast furnace, including providing a hot air stream to an ion transport membrane, thereby producing a hot nitrogen rich stream and a hot oxygen rich stream, providing a methane stream to the ion transport membrane, wherein the methane reacts with the hot oxygen rich stream thereby producing a syngas containing stream, introducing the syngas containing stream into a CO2 removal unit, thereby producing a carbon dioxide rich stream, and a hydrogen rich stream, and introducing the hydrogen rich stream into a blast furnace, thereby replacing at least a portion of the natural gas fuel required therein.
    Type: Application
    Filed: June 21, 2012
    Publication date: December 26, 2013
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Bhadra S. Grover, Michael Garry Keith Grant
  • Publication number: 20130341839
    Abstract: The present invention is a method of integrating oxygen production with blast furnace operation. A heated air stream is introduced to an ion transfer membrane separator, producing a permeate and a retentate. The permeate and the motive stream are introduced into an ejector jet pump producing an oxygen enriched stream. The oxygen enriched stream is introduced into blast furnace. In another embodiment of the present invention, the permeate and a steam motive stream are introduced into an ejector jet pump. Heated air inlet stream is introduced into a cascading series of ion transfer membrane separators, producing a series of permeate streams and a series of retentate streams wherein each retentate stream acts as the input stream for the subsequent ion transfer membrane separator. Thereby producing a series of oxygen enriched streams which are combined and introduced into blast furnace.
    Type: Application
    Filed: June 21, 2012
    Publication date: December 26, 2013
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Bhadra S. Grover, Kenneth Kaiser, Michael Garry Keith Grant, Wei Huang
  • Patent number: 8613976
    Abstract: A method of forming a silicon oxide film, comprising the steps of: providing a substrate into a reaction chamber; injecting into the reaction chamber at least one silicon containing compound where the at least one silicon containing compound is bis(diethylamino)silane; injecting Oxygen into the reaction chamber and at least one other O-containing gas selected from ozone and water; reacting in the reaction chamber by chemical vapor deposition at a temperature below 400 C the at least one silicon containing compound and the at least one oxygen containing gas in order to obtain the silicon oxide film deposited onto the substrate.
    Type: Grant
    Filed: July 12, 2012
    Date of Patent: December 24, 2013
    Assignee: L'Air Liquide, SociétéAnonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Christian Dussarrat, Ikuo Suzuki, Kazutaka Yanagita, Julien Gatineau, Eri Tsukada
  • Patent number: 8615325
    Abstract: Embodiments of the invention provide an advanced control system for steam hydrocarbon reformer furnaces, especially steam methane reformer furnaces. As described herein, the advanced control system may improve the control quality and efficiency of adjusting steam hydrocarbon reformer furnaces operating coefficients. As a result, the steam hydrocarbon reformer furnace operations become more stable, resulting in energy savings and improved furnace yield.
    Type: Grant
    Filed: December 9, 2010
    Date of Patent: December 24, 2013
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Tong Li, Justin Jian Wang
  • Publication number: 20130331726
    Abstract: The invention relates to an apparatus (2, 4) for tracking a treatment for obstructive sleep apnea, including a gas passage (10) and a Venturi tube (16) having a cylindrical inlet (40) and outlet (42), said Venturi tube (16) being axially arranged in said gas passage (10), a first pressure sensor (101), and a second pressure sensor (102). The diameters (D1) of the inlet (40) and outlet (42) of the Venturi tube (16) are between 10 and 25 mm. The Venturi tube (16) includes, arranged in series between said inlet (40) and outlet (42), a convergent portion (44) having the shape of an arc (46, 48), a cylindrical neck (50), the diameter of which is smaller than the diameter (D1) of the inlet (40), and a divergent portion (52) characterized by an angle of divergence (?) of between 5° and 15°.
    Type: Application
    Filed: January 11, 2012
    Publication date: December 12, 2013
    Applicant: L'Air Liquide, Société Anonyme pour L'Etude et L'Exploitation des Procédés Georges Claude
    Inventor: Claude Weber