Abstract: The present invention relates to a process for recovering hydrogen along with high temperature high pressure carbon dioxide from one or more hydrocarbon gas streams by incorporating a carbon dioxide recovery unit which utilizes a fluidized magnesium based sorbent into a process that includes a gasification unit, an optional sulfur removal unit, a water gas shift reactor and a hydrogen pressure swing adsorption unit.
Type:
Application
Filed:
July 5, 2011
Publication date:
January 10, 2013
Applicant:
L' Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: The present invention provides for an energy efficient process of producing hydrogen/carbon monoxide gas mixtures from one or more hydrocarbon gas streams treated in a syngas producing unit by utilizing a carbon dioxide removal unit that contains sorbent beds in which a magnesium based sorbent is transported and cycled between different beds for sorption and desorption of carbon dioxide. The carbon dioxide recovered during the process is recovered at high temperature and high pressure therefore allowing for at least a portion of the carbon dioxide stream to be recycled for further treatment with little or no compression of the stream.
Type:
Application
Filed:
July 5, 2011
Publication date:
January 10, 2013
Applicant:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: The present invention provides a process for recovering hydrogen and high pressure high purity carbon dioxide from one or more hydrocarbon feed streams utilizing a carbon dioxide removal unit that contains sorbent beds of a magnesium based sorbent in a fluidized form.
Type:
Application
Filed:
July 5, 2011
Publication date:
January 10, 2013
Applicant:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: The present invention relates to a process for recovering hydrogen along with high temperature high pressure carbon dioxide from one or more hydrocarbon gas streams by incorporating a carbon dioxide recovery unit which utilizes a magnesium based sorbent into a process that includes a reformer unit, a water gas shift reactor and a hydrogen pressure swing adsorption unit.
Type:
Application
Filed:
July 5, 2011
Publication date:
January 10, 2013
Applicant:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: The present invention relates to a process for recovering hydrogen along with high temperature high pressure carbon dioxide from one or more hydrocarbon gas streams by incorporating a carbon dioxide recovery unit which utilizes a magnesium based sorbent into a process that includes a gasification unit, an optional sulfur removal unit, a water gas shift reactor and a hydrogen pressure swing adsorption unit.
Type:
Application
Filed:
July 5, 2011
Publication date:
January 10, 2013
Applicant:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: Compositions and methods for forming a metal-containing thin film on a substrate. A reactor and at least one substrate in the reactor are provided. A metal-containing bis-?-diketiminate precursor is introduced into the reactor. The reactor is maintained at a set temperature and pressure, and the precursor is contacted with the substrate to form a metal-containing film on the substrate.
Type:
Grant
Filed:
November 10, 2011
Date of Patent:
January 8, 2013
Assignees:
L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, American Air Liquide, Inc.
Inventors:
Clement Lansalot-Matras, Christian Dussarrat, Vincent M. Omarjee, Cheng-Fang Hsiao
Abstract: Embodiments of the invention generally provide apparatus and methods for vaporizing liquid precursors. In one embodiment, a bubbling system for supplying a vapor of liquid precursor is provided including a gas flow conduit having a first end and a second end, a nozzle structure connected to the second end of the gas flow conduit, and comprising one or more perforated conduits fluidly coupled with the second end of the gas flow conduit, and a plate disposed around the gas flow conduit and in a spaced relationship from the nozzle structure, wherein both the one or more perforated conduits and the plate extend radially from an axis of the gas flow conduit.
Type:
Grant
Filed:
March 10, 2010
Date of Patent:
January 8, 2013
Assignee:
L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The present invention provides molecules with high carbon content for Carbon-containing species implant in semiconductor material. The molecules can be used in various doping techniques such as ion implant, plasma doping or derivates methods.
Type:
Grant
Filed:
March 4, 2011
Date of Patent:
January 1, 2013
Assignees:
L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, American Air Liquide, Inc.
Inventors:
Vincent M. Omarjee, Christian Dussarrat, Jean-Marc Girard, Nicolas Blasco
Abstract: The invention concerns a method for melting a composition of raw materials including introducing the composition in an oven to form a layer (2) at the surface of the molten pool (4). An oxycombustion burner (10) is arranged above the pool and directed towards the composition layer (2) to produce a melting front (3). Parameters of the burner are adjusted to produce a large covering flame (12) causing an essentially radiation-based thermal transfer. Additionally, a plane containing a longitudinal section of the flame (Z-Z) and a horizontal direction perpendicular to the axis of the oven (X-X) intersects the melting front (3) at a height (h) included ranging between one third and half of the thickness of the composition (e). Such a method provides for a stable operation of the oven and is particularly adapted to a large-capacity oven.
Type:
Application
Filed:
September 4, 2012
Publication date:
December 27, 2012
Applicant:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: The invention relates to an apparatus for the distillation separation of a mixture containing, as the main components thereof, carbon dioxide and at least one other fluid selected from the group containing nitrogen, oxygen, argon, hydrogen, methane, carbon monoxide, said apparatus comprising a distillation column (8), a condenser (9), a reboiler (7, 11), means for conveying the mixture to be separated to the column or the condenser, means for conveying a head gas from the column to the condenser, and means for conveying a liquid condensed in the condenser into the head of the column. The condenser is formed by an exchanger with plates and blades made from brazed aluminum and having an exchange surface area per m3 of exchanger greater than 400 m2/m3, with ammonia being used as refrigerant.
Type:
Application
Filed:
February 11, 2011
Publication date:
December 27, 2012
Applicant:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Inventors:
Bruno Berthome, Laurent Perru, Fabrice Rivoal
Abstract: For a plant comprising a gas/air separation unit supplying a boiler and a boiler-fed unit for compression and/or purification of CO2, the quantity of fumes sent to the compression and/or purification unit is modified according to the sale price of the electricity generated and/or the cost of venting the fumes.
Type:
Application
Filed:
March 11, 2011
Publication date:
December 27, 2012
Applicant:
L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGE CLAUDE
Abstract: A method of purifying or separating a gas using a number of adsorbers on phase-shifted cycles, and more particularly to the purification of atmospheric air, prior to cryogenic separation of the said air by cryogenic distillation is provided. More specifically still, it relates to the purification of air with a TSA cycle using radial adsorbers.
Type:
Grant
Filed:
December 27, 2007
Date of Patent:
December 25, 2012
Assignee:
L'Air Liquide Societe pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The invention relates to a method for melting vitrifiable materials in a low-capacity oven, wherein at least part of the melting energy is supplied by two oxy-burners projecting into the melting chamber through the upstream wall and arranged on opposite sides of a vertical plane in which a longitudinal axis of the melting chamber is situated, in such a way as to create two flames, the respective injection axes thereof crossing at a distance from the upstream wall, between ? and ¾ of the length L of the melting chamber.
Type:
Grant
Filed:
July 10, 2008
Date of Patent:
December 25, 2012
Assignee:
L'Air Liquide Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Philippe Beaudoin, Gabriel Constantin, Pascal Duperray, Son Ha Giang, Benoit Grand, Luc Jarry, Robert Kalcevic, Bertrand Leroux, Alban Poirier, Rémi Tsiava
Abstract: A method of preparing a composite includes the following steps. A powder blend is sintering while an oxygen partial pressure (pO2) of a gaseous atmosphere surrounding the powder blend is controlled. Before the sintering, a shape is formed from the powder blend. After the forming and before the sintering, binder is removed from the powder blend. The powder blend comprises binder, a mixed electronic/oxygen O2? anionic conducting compound (C1) and a compound (C2) chosen from MgO and BaTiO3. The resultant composite comprises at least 75 vol % of compound (C1), from 0.01 to 25 vol % of compound (C2), and from 0 vol % to 2.5 vol % of compound (C3).
Type:
Grant
Filed:
June 2, 2011
Date of Patent:
December 25, 2012
Assignee:
L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: Process and apparatus for melting raw material in an electric arc furnace using a flame of variable direction, the apparatus comprising a burner and a lance whereby the lance outlet opening and the burner outlet opening are not concentric and are located at a distance from one another, and whereby the lance axis forms an angle with the burner axis in the range from 10° to 40.
Type:
Grant
Filed:
January 6, 2009
Date of Patent:
December 18, 2012
Assignee:
L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Michael G. K. Grant, Fabien Januard, Youssef Joumani, Bernard Labegorre, Jacky Laurent
Abstract: The invention relates to a laser machining equipment including a laser oscillator (1) for generating a laser beam, a laser head (3) through which the laser beam passes, an optical path (2) for conveying the laser beam between the laser oscillator (1) and the laser head (3), and a gas source (9) fluidly connected to the laser head (3) via a main gas pipe (8). In addition, a second pipe (18) fluidly connects the gas source (9) to the laser oscillator (1). The equipment therefore comprises a common gas source for the laser oscillator (1) and head (3). The gas is preferably nitrogen.
Type:
Application
Filed:
January 21, 2011
Publication date:
December 13, 2012
Applicant:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: In one embodiment, a method for generating heat energy includes injecting a stream having a concentration of at least 50% oxygen (O2 stream) into a primary gas stream through a mixer, the mixer discharging the O2 stream as two or more spaced jets traversing the primary stream, thereby enriching the primary gas stream. The method further includes mixing fuel with the enriched primary gas stream, thereby forming a fuel stream; and combusting the fuel stream, thereby forming a flue gas stream.
Type:
Application
Filed:
August 21, 2012
Publication date:
December 13, 2012
Applicant:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Inventors:
M. Usman GHANI, Florian GAUTIER, Rajani K. VARAGANI, Susie LEVESQUE, Bernard LABEGORRE, Frederic CAMY-PEYRET, Sylvain GRILLON, Pavol PRANDA
Abstract: The invention pertains to a method for packaging a gaseous NO/N2 mixture into a container comprising the steps of introducing into a container a gaseous premix formed of NO and of N2 containing an NO content of less than 10% by volume so as to reach a first pressure P1 with P1>1 bar, then introducing into the container containing the NO/N2 premix at the first pressure P1, gaseous nitrogen so as to obtain a final gaseous NO/N2 mix containing an NO content of less than or equal to 1200 ppm by volume and a second pressure P2 lying between P1 and 800 bar. The final NO/N2 gaseous mixture contains an NO content of less than or equal to 1000 ppm by volume.
Type:
Application
Filed:
May 29, 2012
Publication date:
December 13, 2012
Applicants:
Air Liquide Santé (International), L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Inventors:
Pierre DE VILLEMEUR, Celso Zerbinatti, Joël Samirant
Abstract: A apparatus for substantially dehumidifying an insulating annular space (108) is provided. This apparatus includes an insulated surrounding envelope (106), an inner cylindrical device (107) and a partial annular cylinder (100) comprising at least two porous zones. This apparatus positions the partial annular cylinder (100) within the insulating annular space (108) that is formed by the inner cylindrical device (107) positioned within the insulated surrounding envelope (106). This partial annular cylinder (100) holds adsorbent.
Type:
Grant
Filed:
September 25, 2008
Date of Patent:
December 11, 2012
Assignee:
L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The present invention relates to a process for manufacturing an agglomerate in the form of beads made up of microcapsules of a phase change material, the process comprising wet-granulation and fluidized-bed drying.
Type:
Grant
Filed:
September 25, 2009
Date of Patent:
December 11, 2012
Assignee:
L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Vincent Gueret, Christian Monereau, Pluton Pullumbi