Patents Assigned to L'Exploitation Des
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Patent number: 8460989Abstract: Disclosed are methods for forming a metal-containing layer on a substrate. A vapor comprising at least one precursor compound selected from the group consisting of (Cp)V(=NtBu)(NEt2)2; (Cp)V(=NtBu)(NMe2)2; (Cp)V(=NtBu)(NEtMe)2; (Cp)V(?NiPr)(NEt2)2; (Cp)V(?NiPr)(NMe2)2; (Cp)V(?NiPr)(NEtMe)2; (Cp)V(?NC5H11)(NEt2)2; (Cp)V(?NC5H11)(NMe2)2; (Cp)V(?NC5H11)(NEtMe)2; (Cp)Nb(=NtBu)(NEt2)2; (Cp)Nb(=NtBu)(NMe2)2; (Cp)Nb(=NtBu)(NEtMe)2; (Cp)Nb(?NiPr)(NEt2)2; (Cp)Nb(?NiPr)(NMe2)2; (Cp)Nb(?NiPr)(NEtMe)2; (Cp)Nb(?NC5H11)(NEt2)2; (Cp)Nb(?NC5H11)(NMe2)2; and (Cp)Nb(?NC5H11)(NEtMe)2 is provided. At least one reaction gas selected from the group consisting of ozone and water is provided. The vapor and the reaction gas react with the substrate according to a deposition process to form the metal-containing layer on at least one surface of the substrate.Type: GrantFiled: October 6, 2009Date of Patent: June 11, 2013Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des ProcedesInventors: Nicolas Blasco, Anthony Correia-Anacleto, Audrey Pinchart, Andreas Zauner
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Publication number: 20130139542Abstract: The invention relates to an apparatus for producing carbon dioxide-rich liquid, which includes a separation unit including a column for physically washing with a solvent and means for cooling a fluid of the separation unit, and a unit for compressing and liquefying a carbon dioxide-rich gas derived from the separation unit, including means for cooling the gas upstream and/or downstream from the compression operation, a single refrigerating cycle using carbon dioxide as the refrigerant, which is suitable for providing frigories to the means for cooling the fluid of the separation unit and to the means for cooling the gas upstream and/or downstream from the compression operation, and means for sending a portion of the liquid from the liquefaction unit to the refrigerating cycle.Type: ApplicationFiled: May 6, 2011Publication date: June 6, 2013Applicant: L'Air Liquide Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Alain Briglia, Alain Guillard
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Patent number: 8454351Abstract: The invention relates to a method for the combustion of a fuel and an oxidant, in which at least one jet of fuel and at least two jets of oxidant are injected. According to the invention, at least one first oxidant is injected at a distance I1, at most 20 cm, from the fuel injection point and at least one second oxidant is injected at a distance I2 from the fuel injection point, I2 being greater than I1. The aforementioned oxidants are injected in quantities such that the sum of the quantities thereof is at least equal to the stoichiometric quantity of oxidant necessary in order to ensure the combustion of the injected fuel. Moreover, the first oxidant is oxygen-enriched air having a temperature of at most 200 DEG C. and the second oxidant is air preheated to a temperature of at least 300 DEG C.Type: GrantFiled: December 6, 2004Date of Patent: June 4, 2013Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Remi Pierre Tsiava, Bertrand Leroux, Christian Imbernon
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Patent number: 8453688Abstract: The high-pressure output (2) of a donor container is coupled to a user system (11) by means of a main transfer tube (4) through a pilot valve (5) controllable by an auxiliary line (6) which is connected (12) to an auxiliary circuit of the system (11), extends along the main tube (15) and is fixed thereto by the reduced length thereof at several distinct points (S<SUB>i</SUB>). In such a way, the rupture or inflammable leakage of the tube (4) generates the tearing off or meting of the auxiliary line (6) in such a way that the output valve (5) is immediately closed. Said invention is particularly suitable for an inflammable gas supply to stationary plants.Type: GrantFiled: January 6, 2006Date of Patent: June 4, 2013Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Laurent Allidieres
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Patent number: 8454928Abstract: A process for depositing a tellurium-containing film on a substrate is disclosed, including (a) providing a substrate in a reactor; (b) introducing into the reactor at least one tellurium-containing precursor having the formula TeLn or cyclic LTe(-L-)2TeL, wherein at least one L contains a N bonded to one said Te, “n” is between 2-6, inclusive, and each “L,” is independently selected from certain alkyl and aryl groups. The process further includes (c) optionally, introducing at least one M-containing source, wherein M is Si, Ge, Sb, Sn, Pb, Bi, In, Ag or Se, or a combination of any of those; (d) optionally, introducing a hydrogen-containing fluid; (e) optionally, introducing an oxygen-containing fluid; (f) optionally, introducing a nitrogen-containing fluid; (g) reacting the precursor(s) and M-containing source(s), if any, in the reactor with the hydrogen-, oxygen- and/or nitrogen-containing fluid, if any; and (h) depositing a tellurium-containing film onto the substrate.Type: GrantFiled: September 17, 2008Date of Patent: June 4, 2013Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Christian Dussarrat
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Publication number: 20130134359Abstract: A catalytic water gas shift process at temperatures above about 450° C. up to about 900° C. or so wherein the catalyst includes rhenium deposited on a support, preferably without a precious metal, wherein the support is prepared from a high surface area material, such as a mixed metal oxide, particularly a mixture of zirconia and ceria, to which may be added one or more of a high surface area transitional alumina, an alkali or alkaline earth metal dopant and/or an additional dopant selected from Ga, Nd, Pr, W, Ge, Fe, oxides thereof and mixtures thereof.Type: ApplicationFiled: January 28, 2013Publication date: May 30, 2013Applicants: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, Clariant CorporationInventors: Jon P. Wagner, Michael W. Balakos, Chandra Ratnasamy
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Publication number: 20130125839Abstract: A vaporizer includes a plurality of U-shaped tubes contained in a vessel and are arranged in at least one plane. The vessel is closed at one end by a plate having openings adapted to mate with the end of the U-shaped tubes, and there is a dome covering the plate on the opposite side of the tubes. The dome is bounded by a wall forming an inlet chamber and an outlet chamber, the inlet chamber being split into two parts by a partition perpendicular to the plane of the tubes and to the wall to form a chamber for admitting liquid between the plate and the partition and an auxiliary chamber on the other side of the partition. The auxiliary chamber is configured to receive liquid from the admission chamber such that liquid from the outside arriving in the admission chamber enters the tubes via the bottom openings only.Type: ApplicationFiled: July 29, 2011Publication date: May 23, 2013Applicant: L'Air Liquide Societe Anonyme pour l'Etude et l' Exploitation des Procedes Georges ClaudeInventor: Jean-Marc Peyron
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Publication number: 20130125707Abstract: Process for melting scrap metal in a furnace comprising the steps of feeding a charge of solid scrap metal to the furnace, supplying fuel and an oxygen-rich oxidant to the furnace and combusting the fuel with the oxidant to generate heat inside the furnace, melting the charge of solid scrap metal in the furnace by means of the heat, withdrawing the molten metal from the furnace. Following the step of feeding the charge of solid scrap metal to the furnace, the fuel is combusted with the oxidant so as to generate one or more visible flames in the furnace above the charge and before the step of withdrawing the molten metal from the furnace, the fuel is combusted with the oxidant so as to generate flameless combustion in the furnace above the molten metal.Type: ApplicationFiled: July 28, 2011Publication date: May 23, 2013Applicant: L'Air Liquide Societe Anonyme Pour L'Elide Et L'Exploitation Des Procedes Georges ClaudeInventors: Luc Jarry, Remi Tsiava
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Patent number: 8444749Abstract: A fast gas is recovered from a feed gas containing a fast gas and at least one slow gas using a gas separation membrane. A controller may control a control valve associated with a partial recycle of a permeate gas from the membrane for combining with the feed gas. A controller may control a control valve associated with the backpressure of a residue gas from the membrane.Type: GrantFiled: July 14, 2009Date of Patent: May 21, 2013Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Edgar S. Sanders, Sarang Gadre, Michael D. Bennett, Ian C. Roman, David J. Hasse, Indrasis Mondal
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Publication number: 20130115560Abstract: Fuel-fired furnace and a method for operating it, in which method: a main oxidizing agent is injected at a controlled flow rate into the combustion chamber of the furnace; the combustible material is burnt in the combustion chamber with the main oxidizing agent, producing thermal energy and flue gases at a temperature higher than 600° C.; the flue gases are removed via an exhaust duct, said removed flue gases possibly containing residual materials that could be oxidized, the exhaust duct being equipped with an inlet for a diluting oxidizing agent downstream of the combustion chamber; the residual materials that could be oxidized are burnt with the diluting oxidizing agent by means of a flame at the inlet for the diluting oxidizing agent; the flame intensity inside the exhaust duct is detected; and the flow rate at which the main oxidizing agent is injected into the combustion chamber is controlled according to the detected flame intensity.Type: ApplicationFiled: March 30, 2011Publication date: May 9, 2013Applicant: L'Air Liquide Societe Anonyme Pour L'Etude ET L'Exploitation Des Proceded Georges ClaudeInventors: Philippe Beaudoin, Benoit Loiselet
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Publication number: 20130112662Abstract: The invention relates to a ternary gaseous mixture formed from argon, helium and oxygen, characterized in that it is formed from between 19.5 and 20.5% of helium, between 2.7 and 3.3% of Oi, and argon for the remainder (volume %), and to the use thereof as gaseous protection in a method of electric arc welding of at least one steel part to carbon, using a fusible filler wire. Preferably, the welded parts overlap or cover each other and the rotary arc welding takes place where the parts overlap.Type: ApplicationFiled: July 4, 2011Publication date: May 9, 2013Applicant: L'AIR LIQUIDE, SOCIETE ANOYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Laurent Biskup, Gilles Boudet, Jean-Pierre Planckaert, Michel Saez
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Publication number: 20130105445Abstract: The invention relates to a method for electric arc welding, without a laser beam, one or more metal parts, in particular made of steel, including an aluminum surface coating, in particular a coating consisting of aluminum and silicon, using a protective gas, characterized in that the protective gas consists of a mixture of argon and/or helium, and additionally of nitrogen, in particular less than 30 volume % of nitrogen, typically 2 to 10 volume % of nitrogen.Type: ApplicationFiled: May 5, 2011Publication date: May 2, 2013Applicant: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Pascal Bertin, Olivier Dubet, Sebastien Gadrey, Frederic Richard
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Publication number: 20130098878Abstract: The invention relates to a hybrid laser/arc-welding method using an electric arc and a laser beam that are combined together within a single welding melt to which molten metal is supplied by melting a filler wire, wherein the welding melt is provided on at least one steel part including an aluminum surface coating, and a protective gas is used, characterized in that the filler wire contains at least 3 wt % of one or more gammagenic elements, in particular the gammagenic elements selected from C, Mn, Ni and N, and the protective gas consists of helium and/or argon with the addition of at least 10 vol % of nitrogen or oxygen. The method of the invention is particularly suitable for welding end-welded flanks used in the field of manufacturing automobiles or for tube welding.Type: ApplicationFiled: May 5, 2011Publication date: April 25, 2013Applicant: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Francis Briand, Olivier Dubet
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Patent number: 8427082Abstract: The invention relates to a method for absorbing the displacement, under the influence of an external force, of at least one plunger (10,20) in a linear electrodynamic motor comprising a least an induction coil (11, 21) magnetically coupled with the plunger. Said method comprises the steps of: detecting in said induction coil a current induced (I?ind) amplified relative to the induced current. The invention can be applied to cryogenic machines on board space ships.Type: GrantFiled: October 10, 2007Date of Patent: April 23, 2013Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Gerald Aigouy, Jonathan Buquet, Thierry Trollier
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Publication number: 20130092241Abstract: Embodiments of the invention generally provide apparatus and methods for vaporizing liquid precursors. In one embodiment, a bubbling system for supplying a vapor of liquid precursor is provided including a gas flow conduit having a first end and a second end, a nozzle structure connected to the second end of the gas flow conduit, and comprising one or more perforated conduits fluidly coupled with the second end of the gas flow conduit, and a plate disposed around the gas flow conduit and in a spaced relationship from the nozzle structure, wherein both the one or more perforated conduits and the plate extend radially from an axis of the gas flow conduit.Type: ApplicationFiled: December 5, 2012Publication date: April 18, 2013Applicant: L'Air Liquide, Societe Anonyme pour l'Elude et l'Exploitation des Procedes Georges ClaudeInventor: L'Air Liquide, Societe Anonyme pour l'Elude et Ex
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Publication number: 20130086940Abstract: An air separation plant is provided that includes a plurality of air compressors, a plurality of air purification units, and one or more cold boxes. In a first mode of operation, a first air compressor is configured to compress air to a higher pressure than a second air compressor. In a second mode of operation, the second air compressor is configured to compress air to a higher pressure than during the first mode of operation.Type: ApplicationFiled: June 17, 2011Publication date: April 11, 2013Applicant: L'Air Liquide Societe Anonyme pout l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Richard Dubettier-Grenier, Alain Guillard
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Publication number: 20130089679Abstract: The disclosure relates to a process for depositing a Manganese-containing film comprising the step of providing a metal guanidinate and/or metal amidinate precursor, suitable for plasma deposition at temperature equal or lower than 500 degrees C., to a plasma deposition process comprising a deposition temperature equal or lower than 500 degrees C.Type: ApplicationFiled: October 7, 2011Publication date: April 11, 2013Applicants: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, American Air Liquide, Inc.Inventors: Christian Dussarrat, Vincent M. Omarjee, Clement Lansalot-Matras
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Publication number: 20130081789Abstract: A method and installation using liquid CO2 as a cryogenic fluid for transferring cold energy to products, wherein liquid CO2 is sent into a heat exchanger system including first and second heat exchangers connected in series. The liquid CO2 is supplied to the first heat exchanger where it evaporates. Gaseous CO2 from the first exchanger is supplied to the second heat exchanger. The atmosphere surrounding the products is blown across the heat exchangers to provide a cooled atmosphere with which to cool the products. The latent heat of vaporization of the liquid CO2 in the first heat exchanger and the sensible heat of the gaseous CO2 in the second heat exchanger satisfies the cooling requirement of the products. The first exchanger is kept at a pressure higher than the triple point pressure for CO2, whereas the second exchanger is held at atmospheric pressure or at a pressure between the triple point of the fluid and atmospheric pressure.Type: ApplicationFiled: May 5, 2011Publication date: April 4, 2013Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Didier Pathier, Thierry Dubreuil, Mohammed Youbi-Idrissi
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Patent number: 8409504Abstract: The invention relates to a fluid analysis device that comprises an analyzer and a system for supplying an instrumentation gas to said analyzer, characterized in that the supply system includes at least one mixer generating said instrumentation gas, and at least one purifier located downstream from said at least one mixer and upstream from said analyzer.Type: GrantFiled: November 3, 2008Date of Patent: April 2, 2013Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Valerie Bossoutrot, Joerg Koppel, Severine Lepic, Herve Paoli
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Patent number: 8408247Abstract: The invention relates to an element for controlling filling and/or drawing of a pressurized gas, to be mounted in an opening of a tank (1), comprising a body (21) provided with at least one device (8) for controlling the circulation of gas placed between a first end, which has an opening (31) forming an inlet and/or an outlet for the gas with regard to the tank, and a second end for communicating with the inside of the tank.Type: GrantFiled: October 18, 2006Date of Patent: April 2, 2013Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Philippe Pisot