Abstract: Methods and compositions for depositing metal films are disclosed herein. In general, the disclosed methods utilize precursor compounds comprising gold, silver, or copper. More specifically, the disclosed precursor compounds utilize pentadienyl ligands coupled to a metal to increase thermal stability. Furthermore, methods of depositing copper, gold, or silver are disclosed in conjunction with use of other precursors to deposit metal films. The methods and compositions may be used in a variety of deposition processes.

Abstract: The present invention provides for an integrated valve regulator assembly that comprises an integral body having a base portion that includes an axis for mounting on and coaxially with the neck portion of a pressurized source vessel and an assembly outlet, a defined internal passage in the integral body that extends through and between the base portion of the integral body and the assembly outlet, a sub-atmospheric pressure regulator assembled within the integral body of the integrated valve regulator assembly, an isolation valve positioned within the defined internal passage of the integral body and located downstream from and in communication with the sub-atmospheric pressure regulator, and a filling port disposed between the axis for mounting on and coaxially with the neck portion of the pressurized source vessel and the sub-atmospheric pressure regulator.

Abstract: A jet of gas injected from a lance is fluidically deviated with a gas flowing in either the same or opposite direction as the jet of gas. The gas used to fluidically deviate the jet is the same as or different from the gas in the jet.

Abstract: The invention relates to a method for the deoxygenation in a chemical loop of smokes resulting from oxidation-combustion reactions, that comprises: a first step during which the smokes are stripped from their oxygen by trapping the same by the oxidation of an oxygen-carrier material, thus producing a main flow of smokes with a reduced oxygen content; and a second step for also producing smokes that can join the main smoke flow and during which the material oxidized during the first step is reduced and regenerated by reaction with the fuel in order to be used again during said step. The invention also relates to an apparatus for implementing said method.

Abstract: The present invention relates to a process for depositing films on a substrate by chemical vapour deposition (CVD) or physical vapour deposition (PVD), said process employing at least one boron compound. This process is particularly useful for fabricating photovoltaic solar cells. The invention also relates to the use of boron compounds for conferring optical and/or electrical properties on materials in a CVD or PVD deposition process. This process is also particularly useful for fabricating a photovoltaic solar cell.

Abstract: In a method for separating air in a column system, by cryogenic distillation, compressed, purified and cooled air is separated in the column system in order to form an oxygen-enriched flow and a nitrogen-enriched flow. At least one column of the column system contains a vaporizer-condenser for ensuring the vaporization of a liquid enriched in oxygen in relation to the air by means of heat exchange with a calorigenic fluid, the calorigenic fluid having been compressed upstream of the vaporizer-condenser in a compressor having a cryogenic inlet temperature, the calorigenic fluid being at least partially condensed in the vaporizer-condenser, and a cryogenic liquid is added to the calorigenic fluid upstream of the vaporizer-condenser.

Abstract: The invention relates to a method and device for supersonically injecting oxygen into a furnace, in particular a cupola furnace, in which the total oxygen required for the furnace operation is injected with the aid of two distinct circuits, i.e., the first circuit comprising at least one supersonic oxygen injecting nozzle and a second circuit which comprises additionally oxygen injecting means and is connected to the first circuit by pressure-sensitive means, such as a discharging device (or upstream pressure adjuster), in such a way that a stable pressure is obtained in the first circuit upon the attainment of the maximum flowrate thereof, wherein the first circuit can consists of several supersonic nozzle groups.

Abstract: This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 75%, and most preferably at least 90% of the carbon dioxide. The present invention further provides the design for capture of at least 80%, carbon dioxide from syngas that allows for the simultaneous production of medium to high amounts of hydrogen in the syngas as a part of the production of hydrogen in a hydrogen generation plant. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation units to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and two hydrogen membrane separation units are utilized.

Abstract: The invention relates to a composite pressurized gas tank including a sealed inner casing (12), comprising an opening (18) on one of the ends of the casing, and a base (13) attached to the opening (18) of the inner casing (12), the base (13) being provided so as to receive or have built therein a valve or faucet, the tank also including an outer mechanical reinforcement casing (11) that is placed on at least a portion of the inner casing (12). Said tank is characterized in that at least a portion of the gap (14), located between the inner casing (12) and the outer mechanical reinforcement casing (11), is connected to at least one area (15) for collecting the gas capable of accumulating in said gap (14). The at least one collecting area (15, 137) leads into a predetermined discharge area (16, 26, 23) that is located outside the gap (14).

Abstract: The present invention provides a process for recovering hydrogen and carbon dioxide from a process stream utilizing a carbon dioxide separation unit and two membrane separation units. The present invention further provides a process within a hydrogen generation plant to increase recovery of hydrogen and capture equal to or greater than 80% of the carbon dioxide in the syngas stream. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation unit to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and a hydrogen membrane separation unit are utilized.

Abstract: This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 75%, and most preferably at least 90% of the carbon dioxide. The present invention further provides the design for capture of at least 80%, carbon dioxide from syngas that allows for the simultaneous production of medium to high amounts of hydrogen in the syngas as a part of the production of hydrogen in a hydrogen generation plant. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation units to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and two hydrogen membrane separation units are utilized.

Abstract: The present invention provides a process for recovering hydrogen and carbon dioxide from a process stream utilizing a carbon dioxide separation unit and two membrane separation units. The present invention further provides a process within a hydrogen generation plant to increase recovery of hydrogen and capture equal to or greater than 80% of the carbon dioxide in the syngas stream. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation unit to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and a hydrogen membrane separation unit are utilized.

Abstract: This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 75%, and most preferably at least 90% of the carbon dioxide. The present invention further provides the design for capture of at least 80%, carbon dioxide from syngas that allows for the simultaneous production of medium to high amounts of hydrogen in the syngas as a part of the production of hydrogen in a hydrogen generation plant. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation units to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and two hydrogen membrane separation units are utilized.

Abstract: The present invention provides a process for recovering hydrogen and carbon dioxide from a process stream utilizing a carbon dioxide separation unit and two membrane separation units. The present invention further provides a process within a hydrogen generation plant to increase recovery of hydrogen and capture equal to or greater than 80% of the carbon dioxide in the syngas stream. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation unit to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and a hydrogen membrane separation unit are utilized.

Abstract: An air separation unit having a medium-pressure column, a low-pressure column, a chamber, a heat exchanger, a bottom condenser of the low-pressure column and a condenser placed in the chamber is provided. The air separation unit also includes an expansion device configured to expand oxygen-rich liquid from the bottom of the low-pressure column before the oxygen-rich liquid is introduced to the chamber and a compressor configured to compress the gas from the chamber, wherein the compressor is downstream of the chamber and upstream of the low-pressure column.

Abstract: The invention relates to a device for stirring a liquid in a reactor and for injecting a gas into the said liquid in order to form a gas-liquid dispersion, comprising a) a drive device (1) positioned above the reactor, provided with a vertical output shaft (2) fitted at its lower end with at least one axial flow rotor (4) immersed in the liquid, b) means for introducing gas (3 and 7) above the axial flow rotor (4), c) a deflector (5) placed above the axial flow rotor (4) preventing the gas-liquid dispersion from rising, and d) a deflector (6) placed below the axial flow rotor (4) converting the axial flow of the said axial flow rotor into a radial flow. This device may be used in shallow basins.

Abstract: An apparatus and method for the treatment of gaseous effluents involving contact with a liquid may include a gas/liquid contact chamber which can receive a liquid in the lower part thereof and which is topped with a gas cover, wherein the chamber allows a gas to be treated. The chamber may also release residual gases following treatment involving contact with the liquid. The apparatus may also include a turbine that includes one or more stages which ensure improved contact between the gas and the liquid, the upper part of the turbine being equipped with an opening for drawing the gas situated in the gas cover above the liquid; and, preferably, a sensor for measuring the pH of the liquid.

Abstract: Methods and apparatus for cleaning undesired substances from a surface in a semiconductor processing chamber. An cleaning gas mixture is formed onsite and stored in a buffer tank for a time, prior to its introduction into a semiconductor processing chamber, to remove an undesired substance from a surface in the chamber. The undesired substance is removed without the generation of a plasma in the chamber, and at a temperature of less than 300° C.

Abstract: The present invention provides a process for the deposition of a iridium containing film on a substrate, the process comprising the steps of providing at least one substrate in a reactor; introducing into the reactor at least one iridium containing precursor having the formula: XIrYA, wherein A is equal to 1 or 2 and i) when A is 1, X is a dienyl ligand and Y is a diene ligand; ii) when A is 2, a) X is a dienyl ligand and Y is selected from CO and an ethylene ligand, b) X is a ligand selected from H, alkyl, alkylamides, alkoxides, alkylsilyls, alkylsilylamides, alkylamino, and fluoroalkyl and each Y is a diene ligand, and c) X is a dienyl ligand and Y is a diene ligand; reacting the at least one iridium containing precursor in the reactor at a temperature equal to or greater than 100° C.; and depositing an iridium containing film formed from the reaction of the at least one iridium containing precursor onto the at least one substrate.

Abstract: The invention relates to a method of integrating a plurality of blast furnaces with a plurality of air gas separation units, in which the replacement blower available on the blast furnace site is used to feed compressed air into an air gas separation unit making it possible to enrich the blast-furnace blast with oxygen, this unit being stopped when one of the blowers of the blast furnaces has to be replaced with the blower used by the air gas separation unit.