Patents Assigned to L'Exploitation Des
  • Patent number: 7648562
    Abstract: In a PSA separation method with compression (C1, C2) of at least one offgas (3), in case of temporary shutdown of one of the compressors (C1, C2), the operating parameters of the PSA unit (S) are changed to increase the outlet pressure of the offgas (3), in order to maintain a production level above 50% with a single compressor (C1).
    Type: Grant
    Filed: August 8, 2006
    Date of Patent: January 19, 2010
    Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Christian Monereau, François Fuentes, Philippe Merino
  • Publication number: 20100009301
    Abstract: The invention relates to a staged oxyfuel combustion method in which a combustion chamber is injected with a jet of fuel inside a jet of primary oxygen gas which is introduced through a hole having a diameter D and a secondary oxygen gas which is introduced through a hole having a diameter d, which is positioned at a distance l from the hole for the primary oxygen gas. According to the invention, the jet of fuel emerges at a distance r set back from the wall of the combustion chamber. The oxygen-rich oxygen gas is pre-heated to a temperature of at least 300° C. The r/D ratio is between 5 and 20 or between 0.75 and 3 and the l/d ratio is at least 2.
    Type: Application
    Filed: December 18, 2006
    Publication date: January 14, 2010
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Bertrand Leroux, Gabriel Constantin, Christian Imbernon, Remi Tsiava
  • Patent number: 7645319
    Abstract: The invention relates to a method for renovating a combined system consisting of a blast furnace supplied with an oxidant fluid received at least partly from an air/gas separation unit (ASU). The method consists in injecting, before renovation, at least 50% of the flow rate of the blower feeding the blast furnace into an ASU to produce oxygen whose purity is greater than 90% by volume of O2 which feeds the blast furnace, in controlling the blower airflow rate and the pressure of the air derived therefrom by a regulator which measures the flow rate and/or pressure at the input and/or output of a cleaning stage which is mounted upstream of the separation unit to control the flow rate and pressure of the air derived from the blower. The fluid feeding the blast furnace consists of pure oxygen or diluted by air produced by the cryogenic separation unit.
    Type: Grant
    Filed: February 11, 2005
    Date of Patent: January 12, 2010
    Assignee: L'Air Liquide Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Richard Dubettier-Grenier, Michel Devaux, Jean-Marc Peyron
  • Publication number: 20100000446
    Abstract: The invention relates to a process for manufacturing clinker from a raw mix, implementing the following: preheating of the raw mix by combustion flue gases; precalcination of the raw mix; and calcination of the precalcined raw mix in a rotary kiln, in which process the precalcination and the calcination in the rotary kiln produce combustion flue gases that contain CO2, in which the combustion flue gases created by the precalcination undergo a CO2-removal treatment without said flue gases mixing with the combustion flue gases created by the calcination in the rotary kiln.
    Type: Application
    Filed: October 22, 2007
    Publication date: January 7, 2010
    Applicant: L'Air Liquide Soceiete Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Erwin Penfornis, Guillaume De Smedt
  • Patent number: 7641719
    Abstract: The gas separation apparatus comprises a flexible wall which is maintained in a placed position on an upper end of an adsorbant material; the volume between the wall and an upper dome communicates with one of inner and outer chambers on both sides of the adsorbant (4). The invention can be used to separate air components.
    Type: Grant
    Filed: June 18, 2004
    Date of Patent: January 5, 2010
    Assignee: L'Air Liquide - Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Jérôme Bres, Xavier Vigor, Sylvain Fourage, Anne Barbier
  • Patent number: 7638972
    Abstract: A system for monitoring a group of electrochemical cells (C1, . . . , Ci, . . . , Cn) arranged in series, wherein each cell (Ci) is provided for outputting a DC voltage (Vi) greater than a minimum value (Vmin). According to the invention, said monitoring system includes a corresponding set of n electronic components (D1, . . . , Di, . . . , Dn) arranged in series, wherein each component (Di) is biased by the DC voltage (Vi) of a corresponding cell (Ci) by means of a low-frequency connecting element (Li), and has a conductivity threshold voltage (Vs) no lower than said minimum value (Vmin); and a means (D) for measuring a high-frequency conductivity parameter of all of said components. The system is useful in fuel cells.
    Type: Grant
    Filed: May 17, 2005
    Date of Patent: December 29, 2009
    Assignee: L'Air Liquide - Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventor: Pierre Charlat
  • Publication number: 20090314010
    Abstract: The injection device according to the invention, intended to be attached to the wall of the bottom of a container containing a product to be cooled in bulk, comprises a hollow cylindrical body in which a valve forced by a spring is inserted, a through-channel appreciably parallel to said valve intended to be fed by pressurized cryogenic fluid, one end of said through-channel being connected to the cryogenic fluid feed system and the opposite end opening into the seat of the valve.
    Type: Application
    Filed: June 28, 2007
    Publication date: December 24, 2009
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Herve Flamant, Olivier Pouchain, Jacques Fouche, Jo Algoet
  • Publication number: 20090311638
    Abstract: Fuel is combusted with an oxidizer and at least one mainly inert gas, where the mainly inert gas is injected in the form of a divergently swirled jet around the flame and a convergently swirled jet surrounding the divergently swirled jet.
    Type: Application
    Filed: July 10, 2007
    Publication date: December 17, 2009
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Guillaume De Smedt, Christian Imbernon, Jacques Mulon, Patrick Jean-Marie Recourt, Ivan Sanchez-Molinero, Remi Pierre Tsiava
  • Publication number: 20090311879
    Abstract: A method of forming on at least one support at least one metal containing dielectric films having the formula (M11-a M2a) Ob Nc, wherein: 0?a<1, 01 and M2 being metals Hf, Zr or Ti using precursors with pentadienyl ligands and/or cyclopentadienyl ligands.
    Type: Application
    Filed: June 2, 2006
    Publication date: December 17, 2009
    Applicant: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Nicolas Blasco, Christian Dussarrat
  • Patent number: 7632453
    Abstract: The invention relates to a gas quenching method of the type that makes use of (i) a quenching cell (V1) which is intended to receive objects to be quenched with a quenching gas and (ii) a buffer capacity (V2) which is designed to contain the quenching gas.
    Type: Grant
    Filed: August 10, 2004
    Date of Patent: December 15, 2009
    Assignee: L'Air Liquide-Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Florent Chaffotte, Nicolas Blanchard, Olivier Delobel, Linda Lefevre
  • Publication number: 20090301965
    Abstract: The process according to the invention for treating water in a treatment plant comprising a reaction chamber in which a biodegradable material present in the water is biodegraded at least partly by microorganisms, in the course of which, at least temporarily, water is transferred out of the reaction chamber into a separating chamber and the biodegradable material and the microorganisms are separated at least partly from the water therein, a return stream comprising biodegradable material and at least some of the microorganisms flowing out of the separating chamber into the reaction chamber via a recycle line, is characterized in that at least some of the following substances: a) the biodegradable material and b) the microorganisms are treated with ozone (O3), an amount of 15 to 150 milligrams of ozone per kilogram of dry substance of the biodegradable material and of the microorganisms being added per hour in the reaction chamber.
    Type: Application
    Filed: December 12, 2008
    Publication date: December 10, 2009
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Jörg SCHWERDT, Stefan Wolff, Jan Parmentier
  • Publication number: 20090302275
    Abstract: A catalytic composition comprising a catalytically active metal and a solid support, characterized in that a proportion of said catalytically active metal is dispersed on the outer surface of said support and another proportion is included into the core structure of said solid support, and said solid support is a refractory and ionic conductive oxide.
    Type: Application
    Filed: May 8, 2009
    Publication date: December 10, 2009
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Thierry Chartier, Cédric Delbos, Fabrice Rossignol, Pascal Del-Gallo, Daniel Gary, Nicolas Richet
  • Patent number: 7628843
    Abstract: A feedstock hydrogen-enriched gas (3) is supplied to a PSA purification unit (1) which delivers pure hydrogen at a production output (4) and a hydrogen-deficient gas at a residual output. Said hydrogen-deficient gas is compressed (9) and injected into a line (10) wherein a gaseous combustible mixture circulates whose part (12) is extracted upstream of the PSA unit (1), compressed (13) and reinjected into said feedstock of the PSA unit (1). Said invention is used, in particular for petrochemical sites.
    Type: Grant
    Filed: June 28, 2004
    Date of Patent: December 8, 2009
    Assignee: L'Air Liquide, Societe Anonyme A Directoire Et Conseil de Surveillance pour l'Etude Et l'Exploitation des Procedes Georges Claude
    Inventors: Christian Monereau, François Fuentes, Guillaume De Souza
  • Publication number: 20090291177
    Abstract: According to the invention the liquid to be treated is contacted with the gas mixture in a column which is traversed simultaneously by each of the two fluids.
    Type: Application
    Filed: June 28, 2007
    Publication date: November 26, 2009
    Applicant: L'Air Liquide Societe Anonyme Pour L-Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Simon Jallais, Dominique Ibarra
  • Publication number: 20090283419
    Abstract: A catalyst assembly for catalyzing chemical reactions in a gas phase consists of a solid support, whose surface (S) is provided with an anchorage oxide (O) which is chemically different therefrom and is fixed thereto, wherein said anchorage oxide covers a non-zero area percentage of said solid support (S) surface and of a metal phase (M) catalytically active for the considered chemical reaction, is characterized in that said catalytically active metal phase (M) is anchored to said solid support (S) by means of the anchorage oxide (O) which is also grafted on the solid support (S).
    Type: Application
    Filed: November 30, 2006
    Publication date: November 19, 2009
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Pascal Del-Gallo, Nicolas Richet
  • Patent number: 7618477
    Abstract: The invention relates to an installation for separating or purifying gases comprising at least one gas treatment vessel, characterized in that the vessel comprises at least one plane structure comprising a matrix and at least one phase change material (PCM).
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: November 17, 2009
    Assignee: L'Air Liquide Societe Anonyme Pour l'Etude Et l'Exploitation des Procedes Georges Clauge
    Inventors: Pluton Pullumbi, Vincent Gueret, Maria-Eva Vidal-Prado
  • Patent number: 7617701
    Abstract: In a process for producing a mixture containing at least 10% carbon monoxide (73) by cryogenic separation of a feed gas containing at least carbon monoxide, hydrogen and methane, the feed gas (1) is separated to produce a first gas enriched in hydrogen (71), the feed gas is scrubbed in a methane wash column (7), a carbon monoxide enriched stream (13) from the bottom of the methane wash column is separated (19) to produce a stream further enriched in carbon monoxide (23), the stream further enriched in carbon monoxide is separated to form a carbon monoxide rich stream (31,49) and a liquid methane stream (27), at least part (72) of the carbon monoxide rich stream is mixed with the first gas enriched in hydrogen to form the mixture containing at least 10% carbon monoxide as a product stream.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: November 17, 2009
    Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Jean Billy, Natacha Haik-Beraud, Jean Gallarda, Franck Wegrzyn
  • Publication number: 20090277531
    Abstract: Method for filling at least one compressed gas tank with at least one gas, wherein a reference pressure gas tank is formed in which a measurement can take place of at least one measurement variable which is relevant for the state in the reference pressure gas tank, wherein the compressed gas tank and reference pressure gas tank are flow-connected at least at times, wherein each compressed gas tank and the reference pressure gas tank have in each case one opening through which a gas can be filled and extracted, wherein in a filling process, at least one gas is filled through the opening into the at least one compressed gas tank and at least at times into the reference pressure gas tank, is characterized in that a measuring sensor is inserted through the opening into the reference pressure gas tank, and at least one measurement variable is measured by the measuring sensor at least during a part of the filling process.
    Type: Application
    Filed: April 3, 2007
    Publication date: November 12, 2009
    Applicant: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Johann Pongraz, Ulrich Klebe, Randolph Kunkel
  • Publication number: 20090277188
    Abstract: The invention relates to a heat exchanger for a mobile refrigerated vehicle having a tank for liquefied gas comprising a pipe for accepting a flow of a liquefied gas and for the evaporation of at least one part of the liquefied gas, in conjunction with which the pipe, at least in sections, exhibits a longitudinal axis, and the heat exchanger comprises an inlet side for liquefied gas and an outlet side for at least partially evaporated gas, and in conjunction with which the outlet side is connected to an exhaust pipe in such a way as to permit a flow, in conjunction with which the pipe exhibits elements in its interior for the purpose of generating turbulences in the flow or a radial phase separation. The invention is characterized in that, with the help of the elements, the thickness of a gas interface layer on a wall of the pipe, which occurs as a result of vaporization of the gas, is reduced considerably, whereby the efficiency of the heat exchanger is increased considerably.
    Type: Application
    Filed: March 28, 2007
    Publication date: November 12, 2009
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Dirk Teegen, Franz Lurken, Helmut Henrich, Reinhard Kost
  • Publication number: 20090272943
    Abstract: A catalytic composition comprising a catalytically active metal and a solid support, characterized in that said catalytically active metal is included into the core structure of said solid support, and said solid support is a refractory and ionic conductive oxide, process for their preparation and its use as a catalyst in synthesis gas production.
    Type: Application
    Filed: May 8, 2009
    Publication date: November 5, 2009
    Applicant: L Air Liquide Societe Anonyme Pour L Etude Et L Exploitation Des Procedes Georges Claude
    Inventors: Thierry Chartier, Cédric Delbos, Fabrice Rossignol, Pascal Del-Gallo, Daniel Gary, Nicolas Richet