Patents Assigned to Lubrizol Advanced Materials, Inc.
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Patent number: 9174929Abstract: The present invention relates to a composition containing a particulate solid, a non-polar organic medium, and a compound obtained/obtainable by reacting an aromatic amine with hydrocarbyl-substituted acylating agent, wherein the hydrocarbyl-substituted acylating agent is selected from the group consisting of an oligomer or polymer from condensation polymerization of a hydroxy-substituted C10-30 carboxylic acid into a polyester, an optionally hydroxy-substituted C10-30 carboxylic acid, a C10-30-hydrocarbyl substituted acylating agent, and a polyolefin-substituted maleic anhydride. The invention further provides compositions for inks, thermoplastics, plasticizers, plastisols, crude grinding and flush.Type: GrantFiled: November 16, 2012Date of Patent: November 3, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Dean Thetford, Matthew D. Gieselman, Joanne L. Jones
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Publication number: 20150299948Abstract: An aqueous cationic polyurethane dispersion, coagulating acids, and a reactive crosslinking moiety are disclosed for use as pretreatment for digital printing on substrates such as textiles and garments. The pretreatment comprises a polyurethane having properly positioned tertiary amino groups, generally protonated or quaternized, in combination with a reactive crosslinker, coagulating acid, and some di- or polyvalent metal ions.Type: ApplicationFiled: August 26, 2013Publication date: October 22, 2015Applicant: Lubrizol Advanced Materials, Inc.Inventors: Yun-Long Pan, Gary A. Anderle, Alexander V. Lubnin, Stacey L Rohde
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Publication number: 20150299377Abstract: The present invention relates to novel thermoplastic polyurethane (TPU) compositions that have crystalline chain ends. The TPU compositions of the invention can provide improved resiliency, lower surface free energy, and/or reduced stickiness, while maintaining other desirable physical properties. The present invention also provides the described TPU compositions that are further grafted with vinyl alkoxysilane moieties allowing for crosslinked networks of the TPU compositions. The present invention also provides plasticizer-free, very soft TPU compositions without the processing difficulties often associated with such materials. The invention further provides means of reducing the surface tension of a TPU composition which can allow for improved blend compositions, and means of crosslinking the described TPU compositions.Type: ApplicationFiled: October 14, 2013Publication date: October 22, 2015Applicant: Lubrizol Advanced Materials, Inc.Inventors: Umit G. Makal, Bryce W. Steinmetz, Qiwei Lu, Roger W. Day
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Publication number: 20150291791Abstract: The invention provides a bioabsorbable blend of (i) a polymer component comprising polylactic acid (PLA), polyglycolic acid (PGA), a copolymer of PLA and PGA, or any combination thereof and (ii) thermoplastic polyurethane (TPU) tailored to a medical application, and a process for making the same. In some embodiments the TPU comprises units derived from a diol chain extender, a diisocyanate, and a polyol formulated to provide a set biodegradation rate in combination with at least one physical property. The blend of the invention provides useful materials for medical applications that have the individual benefits of polylactic acid and TPU while moderating each material's typical limitations.Type: ApplicationFiled: October 14, 2013Publication date: October 15, 2015Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: Umit G. Makal, Roger W. Day
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Publication number: 20150284554Abstract: CPVC pipe in diameters in the range from 15 mm (0.5 inch) to 15.24 cm (6 ins), to carry hot and cold aqueous streams under 690 KPa (100 psi) pressure and 82.2° C. (180° F.) in continuous service, is extruded from a compound in which the CPVC has a high Cl content in the range from 66.5%-70%, when modified with either of two specific impact high rubber modifiers in an amount greater than 5 parts but no more than 6 parts per 100 parts of CPVC. Extruded CPVC pipe provides a HDB measured according to ASTM D2837-01 which is 25% or more greater than that required for commercial pipe as specified in ASTM D2846. As a result, both SDR-11 and SDR-13.5 pipe are produced which provide a HDB of at least 1250 psi (8.62 MPa) at the 100,000 hr intercept.Type: ApplicationFiled: April 6, 2015Publication date: October 8, 2015Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: Arthur L. Backman, Rocco A. Mango, Robert S. Newby, Andrew M. Olah
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Patent number: 9139677Abstract: A polymerization process to copolymerize hydrophobic ethylenically unsaturated C4-C28 olefins with polar monomers such as acrylates utilizing a polymeric support resin to stabilize the polymerization product in an aqueous media is described. The copolymer shows excellent adhesion to a variety of polymeric and/or polar substrates such as polyolefins, acrylate coatings, wood, etc.Type: GrantFiled: June 30, 2010Date of Patent: September 22, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Robert J. Pafford, IV, James D. Burrington, Naser Pourahmady, Libin Du
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Patent number: 9115259Abstract: The invention relates to a composition containing a particulate solid, plastic material (such as polyvinyl chloride), and a dispersant/agent comprising an oligomer from polymerizing a C7-20 hydroxycarboxylic acid optionally with a C1-6 hydroxycarboxylic acid or its corresponding lactone form.Type: GrantFiled: July 30, 2009Date of Patent: August 25, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Dean Thetford, Patrick J. Sunderland, Eric L. Rohr, Jatin S. Panchal, Shelly A. Barnhart, John D. Schofield, Peter E. Bloyce
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Patent number: 9096755Abstract: A stable, aqueous composition containing a crosslinked, nonionic, amphiphilic polymer capable of forming a yield stress fluid in the presence of a surfactant is disclosed. The yield stress fluid is capable of suspending insoluble materials in the form of particulates and/or droplets requiring suspension or stabilization.Type: GrantFiled: September 13, 2012Date of Patent: August 4, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Krishnan Chari, Shui-Jen Raymond Hsu, Wei-Yeih Yang, Prachur Bhargava, Murat Kadir
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Publication number: 20150203692Abstract: Non-halogenated monomers that can be polymerized into flame retardant polymers, and processes to produce the monomers and polymers is provided. In a simplest aspect, there is provided a monomer composition that can comprise a) a group derived from one of a (meth)acrylic acid, (meth)acrylamide, or vinylbenzene, b) a polyphosphate moiety, and c) an amine species. In the monomer composition, the ethylenically unsaturated monomer of (a) is covalently bonded directly or through a linking group to the moiety of b), forming a precursor monomer unit. The amine species of c) is in complex with the precursor monomer unit. The polymer can be a homopolymer of the monomer composition, or a copolymer of the monomer composition having varying a), b) and c). In one embodiment, the polymer can additionally comprise ethylenically unsaturated monomers not covalently bonded to a polyphosphate moiety.Type: ApplicationFiled: October 31, 2012Publication date: July 23, 2015Applicant: Lubrizol Advanced Materials, Inc.Inventors: John Ta-Yuan Lai, Ti Chou
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Patent number: 9079689Abstract: A flexibly multilayer composite comprising at least one barrier layer of high hardness TPU having a Shore D hardness of at least 80, a soft segment content of less than 5%, and a low gasoline vapor transmission rate of less than 1 g/M2/day. The composite also has at least one layer of soft TPU static dissipative polymer having a surface resistivity of less than 1.0×1012 ohms/square a Shore durometer of form 60 A to 60 D, and a gum residue of less than 20 mg per 100 ml of gasoline after 1 week exposure. The composite may have an optional third layer of an abrasion resistant TPU. The abrasion resistant TPU layer may contain reinforcement material, such as fabric.Type: GrantFiled: May 17, 2012Date of Patent: July 14, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Victor Leng, Qiwei Lu, Joseph J. Vontorcik, Jr.
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Patent number: 9074103Abstract: An aqueous ink jet ink is made by forming a mixture of a pigment, an optional dispersant if the pigment is not self-dispersing, dispersing, and a urethane polymer or prepolymer dispersion in water. This ink is useful in a variety of ink jet printing applications such as printing on wide format substrates and textiles.Type: GrantFiled: March 29, 2011Date of Patent: July 7, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Elizabeth A. Flores, Robert J. Pafford, IV, George E. Snow, Deverakonda S. Sarma
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Patent number: 9068148Abstract: Disclosed are blends of acrylic polymers comprising at least one crosslinked acrylic copolymer and at least one linear acrylic copolymer. The acrylic polymer blends surprisingly provide desirable rheological, clarity, and aesthetic properties in aqueous surfactant containing compositions, particularly at low pH.Type: GrantFiled: July 7, 2011Date of Patent: June 30, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Krishnan Tamareselvy, Denise W. Rafferty
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Patent number: 9068076Abstract: A catalyst masterbatch is disclosed, which when used with a rigid TPU polymer, will cause the rigid TPU to depolymerize during melt processing and repolymerize as the melt is being cooled. This feature is of particular interest in a pultrusion process to create TPU/fiber composites. The catalyst masterbatch contains a relative soft TPU polymer where the catalyst has been swelled or absorbed into the soft TPU polymer. A carrier, such as a plasticizer, can be used to aid the transport of the catalyst into the soft TPU polymer. The catalyst masterbatch is used as an additive to the rigid TPU in a pultrusion process to make the composites. The catalyst masterbatch can also be used in non-fiber reinforced rigid TPU compositions to increase the Mw of melt processed rigid TPU.Type: GrantFiled: May 20, 2009Date of Patent: June 30, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Jerome J. Blayne, Kemal Onder, Shane R. Parnell, Kimberly L. Young
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Patent number: 9068072Abstract: CPVC pipe in diameters in the range from 15 mm (0.5 inch) to 15.24 cm (6 ins), to carry hot and cold aqueous streams under 690 KPa (100 psi) pressure and 82.2° C. (180° F.) in continuous service, is extruded from a compound in which the CPVC has a high Cl content in the range from 66.5%-70%, when modified with either of two specific impact high rubber modifiers in an amount greater than 5 parts but no more than 6 parts per 100 parts of CPVC. Extruded CPVC pipe provides a HDB measured according to ASTM D2837-01 which is 25% or more greater than that required for commercial pipe as specified in ASTM D2846. As a result, both SDR-11 and SDR-13.5 pipe are produced which provide a HDB of at least 1250 psi (8.62 MPa) at the 100,000 hr intercept.Type: GrantFiled: October 29, 2008Date of Patent: June 30, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Arthur L. Backman, Rocco A. Mango, Robert S. Newby, Andrew M. Olah
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Patent number: 9062131Abstract: This invention related to a cationically and hydrophilically modified polygalactomannan having repeating units with an average D-mannosyl to D-galactosyl residue ratio of at least 5 to 1 and to compositions containing the same. A portion of the hydrogen atoms of hydroxyl groups situated on the mannosyl and galactosyl residues of the galactomannan are replaced with a hydrophilic and a cationic substituent.Type: GrantFiled: December 14, 2010Date of Patent: June 23, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Carole A. Lepilleur, Dennis Malaba, John J. Mullay, Denise W. Rafferty, Eric H. Anderson, Xin Liu, Cory G. Miller, Duane G. Krzysik, Christopher D. Kolp
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Patent number: 9044720Abstract: The invention relates to a composition containing a particulate solid, an organic medium, and a (meth)acrylic polymer. The invention further relates to novel compounds, and the use of the (meth)acrylic polymer as a dispersant, typically a pigment dispersant.Type: GrantFiled: April 21, 2011Date of Patent: June 2, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Patrick J. Sunderland, Dean Thetford, John D. Schofield
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Patent number: 9034979Abstract: A composition comprising particulate solid (typically a pigment or filler), an organic medium (typically the organic medium may be a plastics material or an organic liquid) and a polyacrylic copolymer.Type: GrantFiled: October 25, 2012Date of Patent: May 19, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Patrick J. Sunderland, Dean Thetford, Elliot Coulbeck, Stuart N. Richards
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Patent number: 9029443Abstract: Flame retardant thermoplastic polyurethane (TPU) compositions are disclosed having a flame retardant package comprising an organo-phosphinate component, an organo-phosphate component, and a polyhydric alcohol. The flame retardant components may be present in an amount from about 5 to about 40 weight percent of the phosphinate compound; from about 5 to about 20 weight percent of the phosphate compound, and from about 0.1 to about 15 weight percent of the polyhydric alcohol, based on the total weight of the TPU composition. Processes are disclosed to make the TPU compositions and to make wire and cable constructions employing the TPU compositions as the jacket of the wire and cable constructions. The TPU compositions exhibit excellent flame retardant capabilities as measured by Limited Oxygen Index testing and/or UL 94 Vertical Burn tests.Type: GrantFiled: April 30, 2014Date of Patent: May 12, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Sridhar K. Siddhamalli, Carl A. Brown
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Publication number: 20150118428Abstract: The disclosed technology relates to a compound suitable for preparing articles, such as pipe, with good physical properties, such as impact strength, and resistance to environmental stress cracking (ESC). In particular, the technology relates to a vinyl chloride copolymer resin, such as chlorinated polyvinyl chloride or polyvinyl chloride, herein collectively referred to as CPVC that maintains suitable processability at molecular weights above which other vinyl chloride polymer resins will not flow. Furthermore, the invention relates to vinyl chloride copolymer compounds containing the vinyl chloride polymer resin, and articles made from such compounds, which compounds meet 23447 cell classifications under ASTM D1784.Type: ApplicationFiled: May 1, 2013Publication date: April 30, 2015Applicant: Lubrizol Advanced Materials, Inc.Inventors: Christopher D. Zook, Robert G. Vielhaber
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Patent number: 9018288Abstract: The invention relates to a composition containing a particulate solid, a plastic material (such as a thermoplastic polymer) and a compound capable of having dispersant properties. The compound may be obtained/obtainable by reacting (i) a carboxylic acid or anhydride thereof with (ii) an amine or an aminoalcohol, to form a product, wherein the carboxylic acid contains a lipophilic group R containing six or more carbon atoms; and wherein the product formed is derived from a molar ratio of (i) to (ii) is either: (a) 1:1 or greater when (i) is a carboxylic acid anhydride, or (b) ratio of greater than 1:1 when (i) is a carboxylic acid. The invention further relates to novel compounds, and the use of the compound as a dispersant.Type: GrantFiled: July 31, 2008Date of Patent: April 28, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Patrick J. Sunderland, Dean Thetford