Patents Assigned to Lubrizol Advanced Materials, Inc.
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Publication number: 20160017070Abstract: A process for preparing a vinyl acetate rich polymer for formulating surfactant containing compositions comprising at least one anionic surfactant and having yield stress properties without a significant increase in viscosity, low turbidity, and the ability to suspend insoluble materials in the form of particulates and/or droplets that require suspension or stabilization is disclosed.Type: ApplicationFiled: March 5, 2014Publication date: January 21, 2016Applicant: LUBRIZOL ADVANCED MATERIALS, INC.,Inventors: Murat Kadir, Shui-Jen Raymond Hsu, Krishnan Chari
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Publication number: 20160015622Abstract: A conditioning and cleansing composition comprising at least one detersive surfactant, a silicone conditioning agent and a nonionic, amphiphilic polymer that mitigates the loss silicone deposition on keratinous substrates is disclosed. The nonionic, amphiphilic polymer is prepared by polymerizing a monomer composition comprising: a) from about 55 to about 95 wt. % of at least one vinyl amide monomer (based on the weight of the total monomers present); b) from about 5 to about 45 wt. % of at least one vinyl ester of an aliphatic carboxylic acid containing an acyl moiety having 2 to 22 carbon atoms (based on the weight of the total monomers present); c) from about 0 to about 1 wt. % of at least one polyunsaturated crosslinking monomer containing at least two polymerizable ethylenically unsaturated moieties (based on the total dry weight of the polymer); d) from about 0 to about 10 wt.Type: ApplicationFiled: March 3, 2014Publication date: January 21, 2016Applicant: LUBRIZOL ADVANCED MATERIALS INC.Inventors: Denise W. Rafferty, Brian D. Figura, Wei-Yeih Yang, Krishnan Chari
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Publication number: 20160009953Abstract: Polymers are disclosed that incorporate large portions of elastomeric polyamide oligomers connected with polyisocyanates. These polymers have enhanced properties over similar polyurethanes due to better hydrolysis resistance of polyamides over polyesters and better UV resistance of polyamides over polyethers. Polyurea linkages can also improve properties over polyurethane linkages. Composites and hybrids of these polymers and other polyamides with vinyl polymers are also disclosed and claimed.Type: ApplicationFiled: February 3, 2014Publication date: January 14, 2016Applicant: Lubrizol Advanced Materials, Inc.Inventors: Gabor Erdodi, Naser Pourahmady, John Ta-Yuan Lai, Anthony D. Pajersky
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Publication number: 20160002403Abstract: Low glass transition temperature polyamide oligomers or telechelic polyamides are formed from monomers forming tertiary amide linkages. These polyamides can be used with co-reactants to form high molecular weight or crosslinked polymers with desirable polyamide properties.Type: ApplicationFiled: February 3, 2014Publication date: January 7, 2016Applicant: Lubrizol Advanced Materials, Inc.Inventors: Gabor Erdodi, Naser Pourahmady, John Ta-Yuan Lai
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Publication number: 20150376325Abstract: This invention relates to polymers made from low molecular weight polyamide oligomers and telechelic polyamides (including copolymers) containing N-alkylated amide groups in the backbone structure. The described telechelic polyamides are used as the soft segment in the described TPU. These telechelic polyamides are unique in that they have an unexpectedly low glass-transition (desirably 30 degrees C. or lower) which makes them suitable for further reaction and polymerization, allowing for the formation of the described TPU. The resulting TPU can provide improved hydrolytic, oxidative and/or thermal stability as well as improved adhesion to other materials, especially polar materials.Type: ApplicationFiled: February 4, 2014Publication date: December 31, 2015Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: Naser Pourahmady, Umit G. Makal, Gabor Erdodi, John Ta-Yuan Lai
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Publication number: 20150374604Abstract: A composition and a process for straightening hair are disclosed. The process includes coating keratin fibers with a composition comprising a thermally-activated agent and contacting the coated keratin fibers with a heating device at a temperature of at least 185° C. for sufficient time to modify the keratin fibers. The thermally-activated agent comprises a heterocyclic compound containing two heteroatoms selected from nitrogen and oxygen in a 5 or 6-membered ring, such as a cyclic alkylene carbonate.Type: ApplicationFiled: February 3, 2014Publication date: December 31, 2015Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: Murat KADIR, Mark J. MC GUINESS
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Publication number: 20150342858Abstract: A conditioning cleansing composition comprising at least one detersive surfactant, a silicone conditioning agent and a crosslinked acrylic copolymer stabilizer/thickener that mitigates the loss silicone deposition on keratinous substrates is disclosed. The crosslinked acrylic copolymer is prepared by polymerizing a monomer composition comprising: a) from about 5 to about 50 wt. % of carboxyethyl acrylate and/or oligomers thereof; b) from about 30 to about 95 wt. % of a monomer selected from ethyl acrylate, vinyl acetate, or mixtures thereof; c) from about 0 to about 50 wt. % of (meth)acrylic acid; and d) from about 0.001 to about 5 wt. % of a polyunsaturated crosslinking monomer containing at least two polymerizable ethylenically unsaturated moieties.Type: ApplicationFiled: December 11, 2013Publication date: December 3, 2015Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: Krishnan Tamareselvy, Deborah S. Filla, Denise W. Rafferty, Carole A. Lepilleur, David L. Dashiell
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Publication number: 20150342860Abstract: The present invention provides mild cleansing and cleaning compositions and methods for mitigating irritation induced by harsh detersive surfactants. The invention relates to a method of reducing skin irritation associated with a cleansing composition comprising at least one surfactant, the method comprising combining an effective amount of at least one nonionic amphiphilic polymer with at least one detersive surfactant selected from anionic surfactants, amphoteric surfactants, nonionic surfactants and combinations of two or more thereof.Type: ApplicationFiled: December 12, 2013Publication date: December 3, 2015Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: Brian D. Figura, Krishnan Chari, Wei-Yeih Yang
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Publication number: 20150335565Abstract: The present invention provides mild cleansing and cleaning compositions and methods for mitigating irritation induced by harsh detersive surfactants contained therein. The invention relates to a method of reducing skin irritation associated with a cleansing composition comprising at least one surfactant, the method comprising combining an effective amount of at least one nonionic amphiphilic polymer with at least one detersive surfactant selected from anionic surfactants, amphoteric surfactants, nonionic surfactants and combinations of two or more thereof. The at least one nonionic amphiphilic irritation mitigating polymer is prepared from a free radically polymerizable monomer composition comprising at least one hydrophilic monomer and at least one hydrophobic monomer.Type: ApplicationFiled: December 12, 2013Publication date: November 26, 2015Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: Brian D. Figura, Krishnan Chari, Shui-Jen Raymond Hsu
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Patent number: 9187590Abstract: The present invention relates to hydrolytically stable multi-purpose polymers that are polymerized from a monomer mixture comprising: at least one amino-substituted meth(acrylate) (ASMA) monomer or salt thereof; and at least one nonionic vinyl (NIV) monomer, wherein the monomer mixture optionally comprises one or more of at least one vinyl associative (VA) monomer; at least one vinyl surfactant (VS) monomer; and/or at least one polymerizable silicone macromer (PSM) and wherein the monomer mixture further optionally comprises one or more of at least one crosslinking (XL) monomer; at least one chain transfer agent (CTA); and/or at least one polymeric stabilizer. The multi-purpose polymers of the present invention can also be prepared from monomer mixtures containing chain transfer agents or other functional components commonly utilized in polymerization process.Type: GrantFiled: December 1, 2010Date of Patent: November 17, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Krishnan Tamareselvy, Yanshi Zhang, Deborah S. Filla
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Patent number: 9180084Abstract: This invention relates to a cationically and amphiphilically modified polygalactomannan having repeating units with an average D-mannosyl to D-galactosyl residue ratio of at least 5 to 1 and to compositions containing same. A portion of the hydrogen atoms of hydroxyl groups situated on the mannosyl and galactosyl residues of the galactomannan are replaced with an amphiphilic and a cationic substituent.Type: GrantFiled: May 17, 2012Date of Patent: November 10, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Carole A. Lepilleur, Dennis Malaba, John J. Mullay, Denise W. Rafferty, Duane G. Krzysik, Xin Liu, Eric H. Anderson
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Patent number: 9174929Abstract: The present invention relates to a composition containing a particulate solid, a non-polar organic medium, and a compound obtained/obtainable by reacting an aromatic amine with hydrocarbyl-substituted acylating agent, wherein the hydrocarbyl-substituted acylating agent is selected from the group consisting of an oligomer or polymer from condensation polymerization of a hydroxy-substituted C10-30 carboxylic acid into a polyester, an optionally hydroxy-substituted C10-30 carboxylic acid, a C10-30-hydrocarbyl substituted acylating agent, and a polyolefin-substituted maleic anhydride. The invention further provides compositions for inks, thermoplastics, plasticizers, plastisols, crude grinding and flush.Type: GrantFiled: November 16, 2012Date of Patent: November 3, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Dean Thetford, Matthew D. Gieselman, Joanne L. Jones
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Publication number: 20150299377Abstract: The present invention relates to novel thermoplastic polyurethane (TPU) compositions that have crystalline chain ends. The TPU compositions of the invention can provide improved resiliency, lower surface free energy, and/or reduced stickiness, while maintaining other desirable physical properties. The present invention also provides the described TPU compositions that are further grafted with vinyl alkoxysilane moieties allowing for crosslinked networks of the TPU compositions. The present invention also provides plasticizer-free, very soft TPU compositions without the processing difficulties often associated with such materials. The invention further provides means of reducing the surface tension of a TPU composition which can allow for improved blend compositions, and means of crosslinking the described TPU compositions.Type: ApplicationFiled: October 14, 2013Publication date: October 22, 2015Applicant: Lubrizol Advanced Materials, Inc.Inventors: Umit G. Makal, Bryce W. Steinmetz, Qiwei Lu, Roger W. Day
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Publication number: 20150299948Abstract: An aqueous cationic polyurethane dispersion, coagulating acids, and a reactive crosslinking moiety are disclosed for use as pretreatment for digital printing on substrates such as textiles and garments. The pretreatment comprises a polyurethane having properly positioned tertiary amino groups, generally protonated or quaternized, in combination with a reactive crosslinker, coagulating acid, and some di- or polyvalent metal ions.Type: ApplicationFiled: August 26, 2013Publication date: October 22, 2015Applicant: Lubrizol Advanced Materials, Inc.Inventors: Yun-Long Pan, Gary A. Anderle, Alexander V. Lubnin, Stacey L Rohde
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Publication number: 20150291791Abstract: The invention provides a bioabsorbable blend of (i) a polymer component comprising polylactic acid (PLA), polyglycolic acid (PGA), a copolymer of PLA and PGA, or any combination thereof and (ii) thermoplastic polyurethane (TPU) tailored to a medical application, and a process for making the same. In some embodiments the TPU comprises units derived from a diol chain extender, a diisocyanate, and a polyol formulated to provide a set biodegradation rate in combination with at least one physical property. The blend of the invention provides useful materials for medical applications that have the individual benefits of polylactic acid and TPU while moderating each material's typical limitations.Type: ApplicationFiled: October 14, 2013Publication date: October 15, 2015Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: Umit G. Makal, Roger W. Day
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Publication number: 20150284554Abstract: CPVC pipe in diameters in the range from 15 mm (0.5 inch) to 15.24 cm (6 ins), to carry hot and cold aqueous streams under 690 KPa (100 psi) pressure and 82.2° C. (180° F.) in continuous service, is extruded from a compound in which the CPVC has a high Cl content in the range from 66.5%-70%, when modified with either of two specific impact high rubber modifiers in an amount greater than 5 parts but no more than 6 parts per 100 parts of CPVC. Extruded CPVC pipe provides a HDB measured according to ASTM D2837-01 which is 25% or more greater than that required for commercial pipe as specified in ASTM D2846. As a result, both SDR-11 and SDR-13.5 pipe are produced which provide a HDB of at least 1250 psi (8.62 MPa) at the 100,000 hr intercept.Type: ApplicationFiled: April 6, 2015Publication date: October 8, 2015Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: Arthur L. Backman, Rocco A. Mango, Robert S. Newby, Andrew M. Olah
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Patent number: 9139677Abstract: A polymerization process to copolymerize hydrophobic ethylenically unsaturated C4-C28 olefins with polar monomers such as acrylates utilizing a polymeric support resin to stabilize the polymerization product in an aqueous media is described. The copolymer shows excellent adhesion to a variety of polymeric and/or polar substrates such as polyolefins, acrylate coatings, wood, etc.Type: GrantFiled: June 30, 2010Date of Patent: September 22, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Robert J. Pafford, IV, James D. Burrington, Naser Pourahmady, Libin Du
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Patent number: 9115259Abstract: The invention relates to a composition containing a particulate solid, plastic material (such as polyvinyl chloride), and a dispersant/agent comprising an oligomer from polymerizing a C7-20 hydroxycarboxylic acid optionally with a C1-6 hydroxycarboxylic acid or its corresponding lactone form.Type: GrantFiled: July 30, 2009Date of Patent: August 25, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Dean Thetford, Patrick J. Sunderland, Eric L. Rohr, Jatin S. Panchal, Shelly A. Barnhart, John D. Schofield, Peter E. Bloyce
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Patent number: 9096755Abstract: A stable, aqueous composition containing a crosslinked, nonionic, amphiphilic polymer capable of forming a yield stress fluid in the presence of a surfactant is disclosed. The yield stress fluid is capable of suspending insoluble materials in the form of particulates and/or droplets requiring suspension or stabilization.Type: GrantFiled: September 13, 2012Date of Patent: August 4, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Krishnan Chari, Shui-Jen Raymond Hsu, Wei-Yeih Yang, Prachur Bhargava, Murat Kadir
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Publication number: 20150203692Abstract: Non-halogenated monomers that can be polymerized into flame retardant polymers, and processes to produce the monomers and polymers is provided. In a simplest aspect, there is provided a monomer composition that can comprise a) a group derived from one of a (meth)acrylic acid, (meth)acrylamide, or vinylbenzene, b) a polyphosphate moiety, and c) an amine species. In the monomer composition, the ethylenically unsaturated monomer of (a) is covalently bonded directly or through a linking group to the moiety of b), forming a precursor monomer unit. The amine species of c) is in complex with the precursor monomer unit. The polymer can be a homopolymer of the monomer composition, or a copolymer of the monomer composition having varying a), b) and c). In one embodiment, the polymer can additionally comprise ethylenically unsaturated monomers not covalently bonded to a polyphosphate moiety.Type: ApplicationFiled: October 31, 2012Publication date: July 23, 2015Applicant: Lubrizol Advanced Materials, Inc.Inventors: John Ta-Yuan Lai, Ti Chou