Patents Assigned to Metallgesellschaft Aktiengesellschaft
  • Patent number: 6238547
    Abstract: This invention concerns a process in which gases or gas mixtures are reacted in the presence of an ion-conductive liquid in an electro-chemical cell. The cell has at least one anode (2) and at least one cathode (3) to which an external electrical constant potential is applied so that a direct current flows through the ion-conducting liquid. In the lower region of the cell a sump (4) of ion-conductive liquid is located into which the electrodes are partially immersed. At least 20% of the entire surface of at least one of the electrodes is located outside the sump in an upper region through which gas flows. This upper region of the cell is sprayed or irrigated with the ion-conductive liquid and the electrode surface at least partially wet. During this wetting process, the gas flows across the electrode surface.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: May 29, 2001
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Nikola Anastasijevic, Stefan Laibach, Dietrich Werner
  • Patent number: 6237368
    Abstract: A method for regulating or controlling the content of NOx in the exhaust gases of a glass-melting furnace having several burners operated in alternation, wherein both the beginning and the end of a combustion break (FP+, FP−) are supplied to a binary signal generator (8) which passes a signal to a regulator (4) with a time delay and upon receipt of the time-regulator (4), and the amount of NH3 supplied to the denitrating plant is adjusted to a lower constant fixed value F1 via a control, and by means of a memory element (7) a higher constant fixed value F2 is calculated as amount of NH3 and supplied to the regulator (4), whereupon as soon as the regulator (4) has received the signal of the time-delayed end of a combustion break, the fixed value F1 is adjusted to the fixed value F2 via a control, and subsequently the regulation is directly continued.
    Type: Grant
    Filed: August 30, 1999
    Date of Patent: May 29, 2001
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Hans Beisswenger, Klaus Hasselwander, Hansjörg Herden, Gernot Mayer-Schwinning, Gurudas Samant, Peter Ludwig
  • Patent number: 6238639
    Abstract: Nitrosylsulphuric acid is mixed in a mixing reactor with sulphuric acid saturated with SO2. The acid mixture is led into a saturating reactor into the bottom region of which water and an SO2-containing gas are introduced. The gas partially serves as stripping gas inside the saturating reactor. SO2-saturated, Nox-free sulphuric acid with 5 to 60 wt % H2SO4 is removed from the bottom region of the saturating reactor and part thereof is mixed with nitrosylsulphuric acid in the mixing reactor.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: May 29, 2001
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Georg Schmidt, Egon Winkler, Hartmut Wagner, Ronald Apel, Roland Fach, Dieter Knoblich, Peter-Bernhard Stougie
  • Patent number: 6224720
    Abstract: An electrolytic cell is disclosed which comprises: (a) an electrolyte; and (b) a plurality of bipolar electrodes surrounded by the electrolyte and electrically connected in series during operation of the cell, the bipolar electrodes each comprising a cathode side, an anode side, and an electrically conductive connection between the cathode side and the anode side, wherein the cathode side and the anode side of at least one of the bipolar electrodes are movable and mechanically separable with respect to each other so that one of the two electrode sides can be removed from the cell, while the other electrode side remains in the cell.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: May 1, 2001
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Nikola Anastasijevic, Stefan Laibach, Dietrich Werner, Jean-Paul Nepper, Holger Langschied, Heinrich Cieslak
  • Patent number: 6191295
    Abstract: The invention relates to stable trimer isopropoxyalane of composition H5Al3(OiPr)4, wherein iPr is a (CH3)2CH radical. The invention also relates to a method for producing stable trimer isopropoxyalane, wherein AlH3 is reacted with Al(OiPr)3 or isopropanol in a molar ratio of 5:4 or 3:4 in a solvent or solvent mixture. The stable trimer isopropoxyalane is particularly suitable for use as a reducing agent in organic and inorganic synthesis, as a source for aluminium or aluminium oxide in the electronics or ceramics industry or to produce pigments.
    Type: Grant
    Filed: January 12, 2000
    Date of Patent: February 20, 2001
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Andreas Schlegel, Heinrich Noeth, Peter Rittmeyer, Dieter Hauk, Ulrich Wietelmann
  • Patent number: 6184404
    Abstract: There is described a process for the enantioselective alkylation of aldehydes by means of organozinc compounds, of which a ligand of the zinc is transferred to the aldehyde, and the other ligand acts as so-called dummy ligand. As novel substances there are used zinc-organic compounds, which contain the neophyl residue as dummy ligand.
    Type: Grant
    Filed: March 1, 1999
    Date of Patent: February 6, 2001
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Paul Knochel, Christian Lutz
  • Patent number: 6136067
    Abstract: The filtering plant has a plurality of porous, gas-permeable filter elements with at least one raw gas side and at least one clean gas side. The gas to be cleaned (raw gas) flows towards the raw gas side, and the clean gas side is connected with a clean gas passage. Into the clean gas passage and into the filter elements, pulse gas coming from a pressure vessel is introduced for periodically detaching dust adhering at the raw gas side. Via a gas-permeable passage, the pressure vessel is connected with a measuring chamber having a smaller volume than the pressure vessel. While pulse gas flows out of the pressure vessel into the clean gas passage and to the filter elements, the pressure difference .DELTA.p=p1-p2 is measured and monitored, where p1 is the static pressure in the measuring chamber, and p2 is the static pressure in the pressure vessel. Expediently, an alarm signal is activated when the maximum of the pressure difference falls below a predetermined minimum value.
    Type: Grant
    Filed: November 13, 1998
    Date of Patent: October 24, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Gunter Dehn, Joachim Krein, Horst Moellenhoff, Joachim Schmitt
  • Patent number: 6099922
    Abstract: The metal surface protected against metal-dusting corrosion has an insulating layer of a gas-permeable, thermally insulating material. The side of the thermal insulating layer that is colder during operation is in direct vicinity of the metal surface, and the side of the insulating layer that is hotter during operation is heated by a gas stream containing carbon monoxide, which in addition contains hydrogen and/or steam and has a temperature in the range from 300 to 1700.degree. C. In the region between the metal surface to be protected and the hot side of the insulating layer a catalyst is provided for reacting carbon monoxide with hydrogen and/or steam.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: August 8, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Walter Boll, Friedrich Hohmann, Werner Roell
  • Patent number: 6087139
    Abstract: Citric acid and/or the salts thereof are produced from a raw material containing carbohydrates. An aqueous solution of the raw material is converted into a first solution containing citric acid by means of fermentation, and from the first solution a second solution containing citric acid is obtained by means of a cell separation. The second solution is subjected to a protein precipitation at temperatures of 2 to 70.degree. C., and protein is separated by filtration. From the filtration, a third solution containing citric acid is obtained, and the same is passed through a first anion exchanger. The solution containing citric acid, which is discharged from the first anion exchanger, is passed through a second anion exchanger, which is selectively charged with citric acid. The second anion exchanger charged with citric acid is eluted with hydroxide solution or water, and there is thus obtained a fourth solution, in which citrate or citric acid is dissolved.
    Type: Grant
    Filed: October 22, 1998
    Date of Patent: July 11, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Rudolf Boensch, Klaus Hohmann, Juergen Kuhn, Vaclav Cerny, Frantisek Hotek, Jiri Pendl
  • Patent number: 6077549
    Abstract: A process is for the continuous production of beer having a diacetyl content below 0.1 mg/l from a cooked, unfermented, fermentable wort with an oxygen content of 0.5 to 3.0 mg O.sub.2 per liter.
    Type: Grant
    Filed: April 3, 1997
    Date of Patent: June 20, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Roland Bodmer, Rudolf Bonsch, Michael Eichelsbacher, Peter Mitschke, Thorsten Seiffert
  • Patent number: 6074456
    Abstract: The granular sponge iron is supplied to a roller press at temperatures of 600 to 850.degree. C. for molding the hot briquets. There is produced a strip structure of sponge iron containing formed hot briquets, which are arranged at a distance from each other. By smashing the strip structure, the hot briquets are separated from each other, so that fragments of the strip structure are obtained. The hot briquets and at least part of the fragments are cooled to temperatures in the range from 20 to 400.degree. C., and the cooled briquets and fragments are passed through a rotary drum. In the rotary drum, fine-grained fines of the briquets and fragments are produced. Subsequently, these fines are separated from the briquets and fragments, as they exhibit a pyrophoric behavior.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: June 13, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Jochen Freytag, Helmut Hausmann, Martin Hirsch, Siegfried Schimo, Michael Stroder, Peter Weber
  • Patent number: 6063345
    Abstract: Disclosed is a method of separating NaCl from a NaCl contaminated aqueous LiCl solution involving concentration of the solution, cooling of concentrated solution and separation of the crystallized NaCl. The method is characterized in that the concentration and cooling or cooling of the solution are carried out in the presence of a base, preferably in the presence of 0.3-5 wt % (related to LiCl) of at least one alkaline or alkaline earth hydroxide or at least one easily soluble and difficultly volatile amine.
    Type: Grant
    Filed: June 14, 1999
    Date of Patent: May 16, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Jurgen Deberitz, Klaus Kobele, Klaus Schade
  • Patent number: 6051155
    Abstract: Wax-containing preparation for treating wood and leather surfaces, comprising very fine transparent titanium dioxide particles with a crystallite size of between 5 and 50 nm offer long-term protection of wood and leather surfaces against the harmful effects of light at wavelengths between 280 and 800 nm.
    Type: Grant
    Filed: August 17, 1999
    Date of Patent: April 18, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Jorg Hocken, Wolf-Rudiger Karl, Klaus Schulte
  • Patent number: 6034041
    Abstract: Disclosed is a solid or aqueous lubricant concentrate used for the cold forming of metals, which, with reference to the solids content, including a) 20 to 50 parts by weight polyethylene with a softening point above 120.degree. C. and a particle size int he range between 0.1 and 50 .mu.m; b) 20 to 8 parts by weight polyacrylate with a molecular weight of 4,500 to 10,000 and c) 2 to 8 parts by weight styrene/acrylic acid copolymer with a molecular weight of 150,000 to 250,000 and a glass transition temperature of 45 to 55.degree. C., where, under the conditions of use, the acrylic acid component of the polymers in accordance with items b) and c) is predominantly present as salt of one or more inorganic cations, and the softening points of the individuals polymers are distributed over the temperature range defined by the limiting values of ambient temperature and 200.degree. C.
    Type: Grant
    Filed: August 20, 1998
    Date of Patent: March 7, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Klaus-Dieter Nittel, Norbert Schwinke-Kruse, Gunter Hesse
  • Patent number: 6030444
    Abstract: A mixture is proposed for treating substrates, in particular glass or ceramic material, containing silicon compounds. The proposed mixture consists of the following components: (a) component A, which is formed from at least the polysiloxane with Si--H bonds; (b) component B, which is formed from at least one bi-, tri- or tetrafunctional silane, an alkoxy or CH.sub.3 COO rest acting as the functional group; and (c) component C, which is formed from at least one strong, anhydrous organic or inorganic acid. The mixture can be applied to the substrate to particular advantage after being diluted with a solvent.
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: February 29, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventor: Andre Couttenier
  • Patent number: 6015539
    Abstract: A process is disclosed for preparing anhydrous alumina from aluminum hydroxide which comprises feeding aluminum hydroxide into a first suspension preheater and partially dehydrating the aluminum hydroxide with a hot exhaust gas, transporting the partially dehydrated aluminum hydroxide with said exhaust gas to a first separating means and separately withdrawing the exhaust gas and the partially dehydrated aluminum hydroxide, and dividing the partially dehydrated aluminum hydroxide into a first and second partial stream of solids. The process uses a circulating fluidized bed comprising a fluidized bed reactor, a recycle separator connected to the upper portion of said fluidized bed reactor, and a return line for leading solids from said recycle separator to the lower portion of said fluidized bed reactor. The second partial stream of solids is fed into a second suspension preheater and contacted with hot exhaust gas from the recycle separator.
    Type: Grant
    Filed: September 3, 1998
    Date of Patent: January 18, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Hans Werner Schmidt, Martin Rahn, Werner Stockhausen, Dietrich Werner, Martin Hirsch
  • Patent number: 6010565
    Abstract: This invention relates to a foamed material for fireproofing and/or insulating purposes, consisting of 30 to 90 parts by weight of a solution that contains 20 to 70 wt-% Al (H.sub.2 PO.sub.4).sub.3 and 30 to 80 wt-% water, 5 to 55 parts by weight of a mixture that contains 10 to 70 wt-% MgO, 0 to 70 wt-% mica, 0 to 70 wt-% aluminium hydroxide and 1 to 20 wt-% MnO.sub.2, as well as 1 to 30 parts by weight of a foaming agent that contains 3 to 33 wt-% H.sub.2 O.sub.2 and 67 to 97 wt-% water. In accordance with the invention, the term "insulating purposes" refers to the use of the inventive foamed material for heat and sound insulation.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: January 4, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Wolfgang Bastian, Horst Kempf, Jorg Lind, Thomas Schmidt-Hansberg
  • Patent number: 5993765
    Abstract: The process for dry desulfuration of a combustion gas includes providing an electrostatic precipitator (12) or an inertia force separator for dedusting; dedusting the combustion gas at temperatures of 100.degree. C. to 180.degree. C. in the electrostatic precipitator or at temperatures of 100.degree. C. to 700.degree. C. in the inertia force separator to form a partially dedusted combustion gas with a solids content of 5 to 40 g/Nm.sup.3 ; mixing the partially dedusted combustion gas with CaO and/or Ca(OH).sub.2 and optionally CaCO.sub.3 to form a gaseous mixture; providing a circulating fluidized bed device including a fluidized-bed reactor (8) and a downstream solids separator (7) with a return line (17) to the fluidized-bed reactor (8), the solids separator (7) being either another electrostatic precipitator or a bag filter; feeding the gaseous mixture and water into the fluidized-bed reactor (8); cooling the gaseous mixture in the fluidized-bed reactor (8) to a temperature of 50.degree. C. to 90.degree.
    Type: Grant
    Filed: December 1, 1997
    Date of Patent: November 30, 1999
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Hans Beisswenger, Bernhard Thone, Wolfram Klee
  • Patent number: 5981819
    Abstract: A feed mixture containing C.sub.4 -olefins to C.sub.7 -olefins is evaporated and mixed with steam in a weight ratio of H.sub.2 O:hydrocarbons in the range from 0.5:1 to 3:1. The steam containing feed mixture with an inlet temperature in the range from 380.degree. to 500.degree. C. is introduced into a reactor, which contains a bed of granular, form-selective zeolite catalyst. The zeolite is of the pentasil type and has an atomic ratio of Si:Al of 10:1 to 200:1. From the bed a product mixture is withdrawn whose temperature is 20.degree. to 80.degree. lower than the inlet temperature, and whose total content of propylene and butene isomers is at least 60 wt-% of the olefinic constituents of the feed mixture.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: November 9, 1999
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Friedrich-Wilhelm Moeller, Peter Koenig, Christopher Higman, Hans-Dieter Holtmann
  • Patent number: 5969044
    Abstract: Process for airtight and/or moisture-proof packaging of air-sensitive and/or moisture-sensitive materials for the introduction of the packaged materials in a chemical reactor. Described is a process for the airtight and/or moisture-proof packaging of air-sensitive and/or moisture-sensitive materials in a foil and a method for introducing the packaged materials in a reactor, whereby the polymer foil is dissolved in an organic solvent.
    Type: Grant
    Filed: April 8, 1998
    Date of Patent: October 19, 1999
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Serge Fritz, Reinhold Feldmann