Patents Assigned to Midwest Research Institute
  • Patent number: 6518086
    Abstract: A two-stage method of producing thin-films of group IB-IIIA-VIA on a substrate for semiconductor device applications includes a first stage of depositing an amorphous group IB-IIIA-VIA precursor onto an unheated substrate, wherein the precursor contains all of the group IB and group IIIA constituents of the semiconductor thin-film to be produced in the stoichiometric amounts desired for the final product, and a second stage which involves subjecting the precursor to a short thermal treatment at 420° C.-550° C. in a vacuum or under an inert atmosphere to produce a single-phase, group IB-III-VIA film. Preferably the precursor also comprises the group VIA element in the stoichiometric amount desired for the final semiconductor thin-film. The group IB-IIIA-VIA semiconductor films may be, for example, Cu(In,Ga)(Se,S)2 mixed-metal chalcogenides. The resultant supported group IB-IIIA-VIA semiconductor film is suitable for use in photovoltaic applications.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: February 11, 2003
    Assignee: Midwest Research Institute
    Inventors: Markus E. Beck, Rommel Noufi
  • Patent number: 6509184
    Abstract: A process for production of an alkaline tolerant dextranase enzyme comprises culturing a dextran-producing microorganism Streptomyces anulatus having accession no. ATCC PTA-3866 to produce an alkaline tolerant dextranase, Dex 1 wherein the protein in said enzyme is characterized by a MW of 63.3 kDa and Dex 2 wherein its protein is characterized by a MW of 81.8 kDa.
    Type: Grant
    Filed: August 24, 1999
    Date of Patent: January 21, 2003
    Assignee: Midwest Research Institute
    Inventors: Stephen R. Decker, William S. Adney, Todd B. Vinzant, Michael E. Himmel
  • Patent number: 6498029
    Abstract: Strains of the yeast Pichia stipitis NPw9 (ATCC PTA-3717) useful for the production of ethanol using oxygen for growth while fermenting normally toxic lignocellulosic prehydrolysates.
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: December 24, 2002
    Assignee: Midwest Research Institute
    Inventors: Fred A. Keller, Jr., Quang A. Nguyen
  • Patent number: 6487859
    Abstract: A hybrid high-temperature solar receiver is provided which comprises a solar heat-pipe-receiver including a front dome having a solar absorber surface for receiving concentrated solar energy, a heat pipe wick, a rear dome, a sidewall joining the front and the rear dome, and a vapor and a return liquid tube connecting to an engine, and a fossil fuel fired combustion system in radial integration with the sidewall for simultaneous operation with the solar heat pipe receiver, the combustion system comprising an air and fuel pre-mixer, an outer cooling jacket for tangentially introducing and cooling the mixture, a recuperator for preheating the mixture, a burner plenum having an inner and an outer wall, a porous cylindrical metal matrix burner firing radially inward facing a sodium vapor sink, the mixture ignited downstream of the matrix forming combustion products, an exhaust plenum, a fossil-fuel heat-input surface having an outer surface covered with a pin-fin array, the combustion products flowing through the
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: December 3, 2002
    Assignee: Midwest Research Institute
    Inventors: Mark S. Mehos, Kenneth M. Anselmo, James B. Moreno, Charles E. Andraka, K. Scott Rawlinson, John Corey, Mark S. Bohn
  • Patent number: 6468886
    Abstract: Method and apparatus for producing purified bulk silicon from highly impure metallurgical-grade silicon source material at atmospheric pressure. Method involves: (1) initially reacting iodine and metallurgical-grade silicon to create silicon tetraiodide and impurity iodide byproducts in a cold-wall reactor chamber; (2) isolating silicon tetraiodide from the impurity iodide byproducts and purifying it by distillation in a distillation chamber; and (3) transferring the purified silicon tetraiodide back to the cold-wall reactor chamber, reacting it with additional iodine and metallurgical-grade silicon to produce silicon diiodide and depositing the silicon diiodide onto a substrate within the cold-wall reactor chamber. The two chambers are at atmospheric pressure and the system is open to allow the introduction of additional source material and to remove and replace finished substrates.
    Type: Grant
    Filed: August 28, 2001
    Date of Patent: October 22, 2002
    Assignee: Midwest Research Institute
    Inventors: Tihu Wang, Theodore F. Ciszek
  • Patent number: 6468885
    Abstract: A method of fabricating device quality, thin-film a-Si:H for use as semiconductor material in photovoltaic and other devices, comprising in any order; positioning a substrate in a vacuum chamber adjacent a plurality of heatable filaments with a spacing distance L between the substrate and the filaments; heating the filaments to a temperature that is high enough to obtain complete decomposition of silicohydride molecules that impinge said filaments into Si and H atomic species; providing a flow of silicohydride gas, or a mixture of silicohydride gas containing Si and H, in said vacuum chamber while maintaining a pressure P of said gas in said chamber, which, in combination with said spacing distance L, provides a P×L product in a range of 10-300 mT-cm to ensure that most of the Si atomic species react with silicohydride molecules in the gas before reaching the substrate, to thereby grow a a-Si:H film at a rate of at least 50 Å/sec.
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: October 22, 2002
    Assignee: Midwest Research Institute
    Inventors: Archie Harvin Mahan, Edith C. Molenbroek, Alan C. Gallagher, Brent P. Nelson, Eugene Iwaniczko, Yueqin Xu
  • Patent number: 6458254
    Abstract: A method of making a low-resistance electrical contact between a metal and a layer of p-type CdTe surface by plasma etching and reactive ion etching comprising: a) placing a CdS/CdTe layer into a chamber and evacuating said chamber; b) backfilling the chamber with Argon or a reactive gas to a pressure sufficient for plasma ignition; and c) generating plasma ignition by energizing a cathode which is connected to a power supply to enable the plasma to interact argon ions alone or in the presence of a radio-frequency DC self-bias voltage with the p-CdTe surface.
    Type: Grant
    Filed: September 25, 1997
    Date of Patent: October 1, 2002
    Assignee: Midwest Research Institute
    Inventor: Timothy A. Gessert
  • Patent number: 6448068
    Abstract: Provided is a system for identifying a hydrogen gas producing organism. The system includes a sensor film having a first layer comprising a transition metal oxide or oxysalt and a second layer comprising a hydrogen-dissociative catalyst metal, the first and second layers having an inner and an outer surface wherein the inner surface of the second layer is deposited on the outer surface of the first layer, and a substrate adjacent to the outer surface of the second layer, the organism isolated on the substrate.
    Type: Grant
    Filed: March 14, 2001
    Date of Patent: September 10, 2002
    Assignee: Midwest Research Institute
    Inventors: Michael Seibert, David K. Benson, Timothy Michael Flynn
  • Patent number: 6441942
    Abstract: A display and projection apparatus includes an electrochromic material and a photoconductive material deposited in tandem used in conjunction with a light filtering means for filtering light transmitted through the electrochromic material. When an electric field is applied across the electrochromic material and the photoconductive material, light that is incident onto the photoconductive material through the surface of the projection apparatus causes the photoconductive material to conduct current locally in proportion to the amount of light incident on the photoconductive material. The flow of current causes the underlying portions of the electrochromic material to switch from an opaque state to a clear or transmissive state, thereby allowing back-light to propagate through the electrochromic material to create a visible image on the surface of the projection apparatus.
    Type: Grant
    Filed: September 25, 1998
    Date of Patent: August 27, 2002
    Assignee: Midwest Research Institute
    Inventors: Howard M. Branz, David K. Benson
  • Patent number: 6441896
    Abstract: A method and apparatus for measuring the spatial uniformity of the intensity of a radiation beam from a radiation source based on a single sampling time and/or a single pulse of radiation. The measuring apparatus includes a plurality of radiation detectors positioned on planar mounting plate to form a radiation receiving area that has a shape and size approximating the size and shape of the cross section of the radiation beam. The detectors concurrently receive portions of the radiation beam and transmit electrical signals representative of the intensity of impinging radiation to a signal processor circuit connected to each of the detectors and adapted to concurrently receive the electrical signals from the detectors and process with a central processing unit (CPU) the signals to determine intensities of the radiation impinging at each detector location.
    Type: Grant
    Filed: December 17, 1999
    Date of Patent: August 27, 2002
    Assignee: Midwest Research Institute
    Inventor: Halden Field
  • Patent number: 6436305
    Abstract: The present invention provides a process for etching a corrosion layer, such as oxide or hydroxide, from and concomitantly forming a passivating layer on the surface of metallic nanoparticles. A reaction mixture is prepared by dispersing sodium hexafluoroacetylacetonate (Na(hfa)) and a metallic particle powder having oxide or hydroxide corrosion layers in hexane solvent. The mixture is allowed to react for a time sufficient to etch the oxide or hydroxide groups from the particulate surface and passivate the surfaces with (hfa). Hexane may be evaporated from the mixture and any excess Na(hfa) separated from the reaction mixture by sublimation or rinsing with a polar aprotic solvent. In an embodiment of the present invention, aluminum particles are first etched and passivated and then used to form ohmic contacts with p-type silicon. This etching/passivation improves the electrical properties of the contact.
    Type: Grant
    Filed: March 12, 2001
    Date of Patent: August 20, 2002
    Assignee: Midwest Research Institute
    Inventors: Douglas L. Schulz, Calvin J. Curtis, David S. Ginley
  • Patent number: 6423145
    Abstract: A modified dilute acid method of hydrolyzing the cellulose and hemicellulose in lignocellulosic material under conditions to obtain higher overall fermentable sugar yields than is obtainable using dilute acid alone, comprising: impregnating a lignocellulosic feedstock with a mixture of an amount of aqueous solution of a dilute acid catalyst and a metal salt catalyst sufficient to provide higher overall fermentable sugar yields than is obtainable when hydrolyzing with dilute acid alone; loading the impregnated lignocellulosic feedstock into a reactor and heating for a sufficient period of time to hydrolyze substantially all of the hemicellulose and greater than 45% of the cellulose to water soluble sugars; and recovering the water soluble sugars.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: July 23, 2002
    Assignee: Midwest Research Institute
    Inventors: Quang A. Nguyen, Melvin P. Tucker
  • Patent number: 6420071
    Abstract: The invention provides a method of protecting an ion insertion material from the degradative effects of a liquid or gel-type electrolyte material by disposing a protective, solid ion conducting, electrically insulating, layer between the ion insertion layer and the liquid or gel-type electrolyte material. The invention further provides liquid or gel-type electrochemical cells having improved durability having a pair of electrodes, a pair of ion insertion layers sandwiched between the pair of electrodes, a pair of solid ion conducting layers sandwiched between the ion insertion layers, and a liquid or gel-type electrolyte material disposed between the solid ion conducting layers, where the solid ion conducting layer minimizes or prevents degradation of the faces of the ion insertion materials facing the liquid or gel-type electrolyte material. Electrochemical cells of this invention having increased durability include secondary lithium batteries and electrochromic devices.
    Type: Grant
    Filed: March 21, 2000
    Date of Patent: July 16, 2002
    Assignee: Midwest Research Institute
    Inventors: Se-Hee Lee, C. Edwin Tracy, Hyeonsik M. Cheong
  • Patent number: 6378605
    Abstract: The heat exchanger includes a fin and tube assembly with increased heat transfer surface area positioned within a hollow chamber of a housing to provide effective heat transfer between a gas flowing within the hollow chamber and a fluid flowing in the fin and tube assembly. A fan is included to force a gas, such as air, to flow through the hollow chamber and through the fin and tube assembly. The fin and tube assembly comprises fluid conduits to direct the fluid through the heat exchanger, to prevent mixing with the gas, and to provide a heat transfer surface or pathway between the fluid and the gas. A heat transfer element is provided in the fin and tube assembly to provide extended heat transfer surfaces for the fluid conduits. The heat transfer element is corrugated to form fins between alternating ridges and grooves that define flow channels for directing the gas flow.
    Type: Grant
    Filed: December 2, 1999
    Date of Patent: April 30, 2002
    Assignee: Midwest Research Institute
    Inventors: Charles F. Kutscher, Keith Gawlik
  • Patent number: 6369934
    Abstract: A photoelectrochemical-electrochromic device comprising a first transparent electrode and a second transparent electrode in parallel, spaced relation to each other. The first transparent electrode is electrically connected to the second transparent electrode. An electrochromic material is applied to the first transparent electrode and a nanoporous semiconductor film having a dye adsorbed therein is applied to the second transparent electrode. An electrolyte layer contacts the electrochromic material and the nanoporous semiconductor film. The electrolyte layer has a redox couple whereby upon application of light, the nanoporous semiconductor layer dye absorbs the light and the redox couple oxidizes producing an electric field across the device modulating the effective light transmittance through the device.
    Type: Grant
    Filed: August 1, 2000
    Date of Patent: April 9, 2002
    Assignee: Midwest Research Institute
    Inventors: Clemens S. Bechinger, Brian A. Gregg
  • Patent number: 6369603
    Abstract: An apparatus for measuring the minority carrier lifetime of a semiconductor sample using radio-frequency coupling. The measuring apparatus includes an antenna that is positioned a coupling distance from a semiconductor sample which is exposed to light pulses from a laser during sampling operations. A signal generator is included to generate high frequency, such as 900 MHz or higher, sinusoidal waveform signals that are split into a reference signal and a sample signal. The sample signal is transmitted into a sample branch circuit where it passes through a tuning capacitor and a coaxial cable prior to reaching the antenna. The antenna is radio-frequency coupled with the adjacent sample and transmits the sample signal, or electromagnetic radiation corresponding to the sample signal, to the sample and receives reflected power or a sample-coupled-photoconductivity signal back.
    Type: Grant
    Filed: July 14, 2000
    Date of Patent: April 9, 2002
    Assignee: Midwest Research Institute
    Inventors: Steven W. Johnston, Richard K. Ahrenkiel
  • Patent number: 6332967
    Abstract: Methods for preparing high quality superconducting oxide precursors which are well suited for further oxidation and annealing to form superconducting oxide films. The method comprises forming a multilayered superconducting precursor on a substrate by providing an electrodeposition bath comprising an electrolyte medium and a substrate electrode, and providing to the bath a plurality of precursor metal salts which are capable of exhibiting superconducting properties upon subsequent treatment. The superconducting precursor is then formed by electrodepositing a first electrodeposited (ED) layer onto the substrate electrode, followed by depositing a layer of silver onto the first electrodeposited (ED) layer, and then electrodepositing a second electrodeposited (ED) layer onto the Ag layer. The multilayered superconducting precursor is suitable for oxidation at a sufficient annealing temperature in air or an oxygen-containing atmosphere to form a crystalline superconducting oxide film.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: December 25, 2001
    Assignee: Midwest Research Institute
    Inventor: Raghu N. Bhattacharya
  • Patent number: 6300557
    Abstract: A low-bandgap, double-heterostructure PV device is provided, including in optical alignment a first InP1−yAsy n-layer formed with an n-type dopant, an GaxIn1−xAs absorber layer, the absorber layer having an n-region formed with an n-type dopant and an p-region formed with a p-type dopant to form a single pn-junction, and a second InP1−yAsy p-layer formed with a p-type dopant, wherein the first and second layers are used for passivation and minority carrier confinement of the absorber layers.
    Type: Grant
    Filed: October 8, 1999
    Date of Patent: October 9, 2001
    Assignee: Midwest Research Institute
    Inventor: Mark W. Wanlass
  • Patent number: 6295819
    Abstract: A thermoelectric heat pump fluid circuit apparatus (10) for alternately delivering hot and cold fluids to an end device (12) such as a therapeutic wrap or pad. The apparatus includes a heat pump (14), a fluid circuit (16) coupled with the heat pump and having a fluid contained therein, a pump (18) interposed in the fluid circuit for circulating the fluid therein, and a valve (20) interposed in the fluid circuit for selectively delivering fluid from the fluid circuit to a device coupled with the apparatus.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: October 2, 2001
    Assignee: Midwest Research Institute
    Inventors: Balakrishnan Mathiprakasam, Patrick J. Heenan
  • Patent number: 6282497
    Abstract: A computational modeling method for predicting the chemical, physical, and thermodynamic performance of a condenser using calculations based on equations of physics for heat, momentum and mass transfer and equations of equilibrium thermodynamics to determine steady state profiles of parameters throughout the condenser. The method includes providing a set of input values relating to a condenser including liquid loading, vapor loading, and geometric characteristics of the contact medium in the condenser. The geometric and packing characteristics of the contact medium include the dimensions and orientation of a channel in the contact medium. The method further includes simulating performance of the condenser using the set of input values to determine a related set of output values such as outlet liquid temperature, outlet flow rates, pressures, and the concentration(s) of one or more dissolved noncondensable gas species in the outlet liquid.
    Type: Grant
    Filed: April 15, 1999
    Date of Patent: August 28, 2001
    Assignee: Midwest Research Institute
    Inventors: Desikan Bharathan, Yves Parent, A. Vahab Hassani