Patents Assigned to Mitsubishi Chemical Industries Ltd.
  • Patent number: 3988462
    Abstract: 3-(5,7-Dimethyl-2-hydroxy-4-oxo-6,8-decadienyl)-glutarimide is prepared by cultivating Streptomyces pluricolorescens var. yamashitaensis (S-885) ATCC No. 21956 in an aqueous nutrient broth containing a carbohydrate and a source of organic nitrogen until said broth achieves substantial antiviral activity, and recovering said antibiotic from said culture broth. This antibiotic is effective against the viruses of polio and A-type influenza.
    Type: Grant
    Filed: August 25, 1975
    Date of Patent: October 26, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Nakao Ishida, Tsutomu Okada, Akira Kamata
  • Patent number: 3984435
    Abstract: A.DELTA..sup.1 - tetrahydrophthalic anhydride is reacted with an amine in the presence of lower fatty acid. Alternatively N-(4-hydroxyphenyl)-.DELTA..sup.1 -tetrahydrophthalimide or a salt thereof is reacted with an aralkyl halide. A N-substituted-.DELTA..sup.1 -tetrahydrophthalimide compound having herbicidal activity is produced. This compound has the formula ##EQU1## wherein R' is naphthyl; phenyl; phenyl substituted by 1-3 substituents selected from the group consisting of halogen, nitro, cyano, thiocyano, carboxyl, haloalkyl, lower alkyl and alkylthio; --CH.sub.2 Y wherein Y is phenyl, naphthyl or phenyl substituted by 1-5 substituents selected from the group consisting of halogen, nitro, lower alkyl and lower alkoxyl; or ##SPC1##Wherein Z is phenyl, naphthyl, or phenyl substituted by at least one substituent selected from the group consisting of halogen, nitro, lower alkyl and lower alkoxyl.
    Type: Grant
    Filed: February 10, 1975
    Date of Patent: October 5, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Kazuo Matsui, Hiroshi Kasugai, Kuni Matsuya, Hiroyasu Aizawa
  • Patent number: 3984437
    Abstract: A diazamethine cationic dyestuff is disclosed which is suitable for dyeing a synthetic fiber in yellow shade with good fastness to light and to heat.
    Type: Grant
    Filed: April 2, 1975
    Date of Patent: October 5, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Sadao Fujino, Yoshio Magara
  • Patent number: 3984572
    Abstract: A method of culturing monogastric animals which comprises feeding the animals a feed in which part of the protein is supplied by a urea-isobutyraldehyde condensate.
    Type: Grant
    Filed: July 14, 1975
    Date of Patent: October 5, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Yasuhiro Sakaki, Hiroshi Kawai
  • Patent number: 3983289
    Abstract: An electrically insulating prepreg which comprises a resin composition of an alicyclic epoxy compound prepared by the expoxidation of an alkadiene alcohol ester of an alicyclic polybasic carboxylic acid, a latent curing agent, and a solid substrate, wherein said resin composition, once it has been applied to the substrate, is in the B-stage cured state and is thereby acetone soluble, thermoplastic and nontacky.
    Type: Grant
    Filed: April 9, 1974
    Date of Patent: September 28, 1976
    Assignees: Mitsubishi Chemical Industries Ltd., Mitsubishi Denki Kabushiki Kaisha
    Inventors: Syunichiro Nishizaki, Hiroshi Teratani, Osamu Fujisawa, Jiro Fukushima, Makoto Tokizawa, Nobukatsu Wakabayashi, Takashi Saito
  • Patent number: 3981907
    Abstract: A 1,3-conjugated diene compound and a derivative of a butadiene dimer are subjected to an addition reaction over a rhodium compound. The 1,3-conjugated diene compound adds to the derivative in a molar ratio of 1:1. The derivative may be an ester, ether or alcohol. Said derivative is obtained either by reacting a carboxylic acid, an alcohol or a phenol with a butadiene over a palladium catalyst or by hydrolyzing the reaction product.
    Type: Grant
    Filed: March 18, 1975
    Date of Patent: September 21, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Saburo Hattori, Yoshiharu Morita, Yoshio Ihashi, Tadao Sato
  • Patent number: 3980616
    Abstract: Flame resistance is imparted to polyamide resins by the process which comprises melting said polyamide at a temperature between the softening point of the polyamide and 250.degree.C, and adding a flameproofing quantity of a flameproofing agent to said melt, and thereafter solidifying said melt whereby said polyamide is flameproofed to an extent of UL-94, said flame proofing agent being selected from the group consisting of ##EQU1## wherein R is the same or different and represents hydrogen or lower alkyl, formamide and mixtures thereof.
    Type: Grant
    Filed: November 12, 1974
    Date of Patent: September 14, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Tsuneo Kimura, Katsuhisa Koyama
  • Patent number: 3978045
    Abstract: N.sup.2 -dansyl-L-arginine esters and amides having the formula ##SPC1##Or the acid addition salts thereof with a pharmaceutically acceptable acid, wherein R is selected from the group consisting of(1) alkoxy, alkenyloxy, alkynyloxy, and cycloalkoxy, respectively, containing not more than 10 carbon atoms, aralkyloxy of not more than 15 carbon atoms, tetrahydrofurfuryloxy, and alkoxy of not more than 10 carbon atoms substituted with an alkoxy group of not more than 10 carbon atoms, halogen or nitro; ##EQU1## wherein R.sub.1 and R.sub.
    Type: Grant
    Filed: August 13, 1974
    Date of Patent: August 31, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Shosuke Okamoto, Ryoji Kikumoto, Yoshikuni Tamao, Shinji Tonomura, Kazuo Ohkubo
  • Patent number: 3975461
    Abstract: A graft copolymer is provided which is characterized by excellent gas impermeability, transparency and impact strength, as well as good flowability, and hence good molding workability, by copolymerizing an olefinically unsaturated nitrile with an alkyl vinyl ether in the presence of a rubbery polymer, which contains at least 50% by weight of a conjugated diene; said olefinically unsaturated nitrile being present in an amount of from 60 to 95% by weight, based on the total weight of said olefinically unsaturated nitrile and said alkyl vinyl ether; and wherein said olefinically unsaturated nitrile and said alkyl ether are present in an amount of from 3 to 50 times by weight the quantity of said rubbery polymer.
    Type: Grant
    Filed: January 11, 1974
    Date of Patent: August 17, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Takeshi Yamawaki, Masahiro Hayashi, Kazuo Endo
  • Patent number: 3974031
    Abstract: L-cysteine and derivatives thereof of the formula (I): ##EQU1## wherein R is selected from the group consisting of hydrogen, C.sub.1 -C.sub.15 alkyl, C.sub.2 -C.sub.15 alkenyl, C.sub.6 -C.sub.15 aryl, C.sub.7 -C.sub.15 aralkyl, are prepared by a process which comprises reacting .beta.-substituted L-alanine having the formula (II): ##EQU2## wherein X is selected from the group consisting of halogen, --OR' and --SR'; wherein R' is selected from the group consisting of hydrogen, allyl, C.sub.1 -C.sub.15 alkyl, C.sub.6 -C.sub.15 aryl and C.sub.7 -C.sub.15 aralkyl, with a thiol, or hydrogen sulfide, of the formula (III):r -- sh (iii)wherein R is as defined above, ammonium hydrosulfide of a metal hydrosulfide of the formula (IV):r -- s --y (iv)wherein R is hydrogen, and Y is ammonium or a metal, in an aqueous medium, in the presence of cysteine desulfhydrase.
    Type: Grant
    Filed: May 6, 1975
    Date of Patent: August 10, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Hideaki Yamada, Hidehiko Kumagai, Haruyiki Ohkishi
  • Patent number: 3972979
    Abstract: Exhaust gas containing a halohydrocarbon having 1 - 10 carbon atoms and molecular oxygen is contacted with chromium oxide or a boehmite supported platinum at an elevated temperature to decompose the halohydrocarbon to carbon dioxide, water, hydrogen halide and free halogen.
    Type: Grant
    Filed: May 14, 1974
    Date of Patent: August 3, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventor: Yoichi Kageyama
  • Patent number: 3972885
    Abstract: An oxyquinophthalone coloring material having the general formula ##SPC1##Wherein X represents chlorine or bromine atom and Y.sub.1, Y.sub.2 and Y.sub.3 represent respectively hydrogen, chlorine, bromine, methyl, ethyl, methoxy or ethoxy group, at least one of Y.sub.1, Y.sub.2 and Y.sub.3 being chlorine or bromine and one of Y.sub.1, Y.sub.2 and Y.sub.3 being methyl, ethyl, methoxy and ethoxy group.
    Type: Grant
    Filed: August 23, 1973
    Date of Patent: August 3, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Yoshio Kimura, Kiyoshi Himeno
  • Patent number: 3970632
    Abstract: A polymer composition, which comprises a polymer containing a quinophthalone pigment having the formula ##SPC1##Wherein the quinoline ring can have a substituent selected from the group consisting of halogen, lower alkyl, lower alkoxy, and carboxyl, and the ring A is a benzene ring or a naphthalene ring which can have a substituent selected from the group consisting of halogen, and --COW wherein W represents hydroxyl, lower alkoxyl or amino; and 0.005-5% by weight of a piperidine type or imidazolidine type ultraviolet absorbing agent.
    Type: Grant
    Filed: November 27, 1974
    Date of Patent: July 20, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Hirohisa Yoshiura, Toshiharu Arai, Masao Miyake, Kiyoshi Enriki
  • Patent number: 3966853
    Abstract: A prilled ammonium nitrate containing 2 to 5 percent by weight water obtained by prilling an aqueous solution of 93 to 98 percent by weight ammonium nitrate is dried by: lowering the drying temperature of the ammonium nitrate to a temperature less than the III--IV crystalline transition temperature of ammonium nitrate at least once when the water content of the prilled ammonium nitrate is 0.3 to 1.5 percent by weight in the drying step; further drying at a temperature higher than the III--IV transition temperature; and adding an anti-caking agent to the dried prilled ammonium nitrate. The dried, prilled ammonium nitrate obtained is useful as an ammonium nitrate fuel oil explosive.
    Type: Grant
    Filed: September 25, 1974
    Date of Patent: June 29, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Naoto Osako, Katsumi Kozima, Hiroshi Shimizu, Kazumi Kimura
  • Patent number: 3963766
    Abstract: In a process for separating 19-nor-.DELTA..sup.4 -androstene-3,17-dione from a mixture of steroids which is obtained by the Birch reduction of an alkyl or an aralkyl ether of estrone acetal having the following formula (I), ##SPC1##wherein R is selected from the group consisting of an alkyl group containing 1 to 10 carbon atoms and an aralkyl group containing a side chain of 1 to 5 carbon atoms; X and Y are selected from the group consisting of O-alkyl and S-alkyl groups, respectively, containing 1 to 10 carbon atoms; or the following formula (II), ##SPC2##wherein R is as defined above; Z and W are selected from the group consisting of oxygen atom and sulfur atom; and n represents an integer of from 2 to 10; followed by the hydrolysis of the obtained reduction product of said Birch reduction, the improvement which comprises1. reacting said mixture of steroids containing 19-nor-.DELTA..sup.4 -androstene-3,17-dione with a secondary amine to form the C.sub.3 -enamine of 19-nor-.DELTA..sup.
    Type: Grant
    Filed: January 31, 1975
    Date of Patent: June 15, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Ken-ichi Wakabayashi, Susumu Kanno
  • Patent number: 3960976
    Abstract: Hydrocarbons are reacted with a tri-halogenoacetate of the formula ##EQU1## wherein X, Y and Z each represents a halogen atom and M represents a mono valent metal of group Ib to form the corresponding complexes, and then the thus formed complexes are decomposed to selectively separate the desired hydrocarbon components. The used tri-halogenoacetate also is recovered by the decomposition of the complexes.
    Type: Grant
    Filed: June 5, 1973
    Date of Patent: June 1, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Yoshiaki Suzuki, Hajime Mori, Takemi Nakanome
  • Patent number: 3959354
    Abstract: A phenyl ester and/or phenol is prepared by reacting benzene, a carboxylic acid and molecular oxygen in the presence of an improved catalyst comprising palladium metal, an antimony component and least one carboxylic acid salt of zinc, cadmium, lead or tin supported on a carrier.
    Type: Grant
    Filed: June 3, 1974
    Date of Patent: May 25, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Takeru Onoda, Keisuke Wada
  • Patent number: 3959465
    Abstract: Titanium minerals are concentrated by leaching with an acid leaching agent in the presence of a chelating agent, sulfonate surfactant or polyacrylamide surfactant, wherein the iron components are removed from the minerals.
    Type: Grant
    Filed: May 24, 1974
    Date of Patent: May 25, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Tokuzo Kurata, Satoshi Emi, Kunihiko Ofuchi, Tsutomu Takeuchi, Isamu Sone
  • Patent number: 3959352
    Abstract: A carboxylic ester is prepared by reacting a hydrocarbon selected from monoolefins having 2 to 6 carbon atoms, benzene, toluene and xylene with an aliphatic saturated carboxylic acid having 2 to 4 carbon atoms and molecular oxygen in the vapor phase in the presence of a supported solid catalyst of palladium metal, an antimony component and a carboxylic acid salt of alkali metal, alkaline earth metal, zinc, cadmium, lead or tin, with the improvement comprising: adding said antimony compound to the support of said catalyst by dipping a carrier into an aqueous solution of a water-soluble antimony compound selected from the group consisting of antimonic acid, antimonates and antimony complexes of organic acids.
    Type: Grant
    Filed: March 7, 1975
    Date of Patent: May 25, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Takeru Onoda, Keisuke Wada, Masayuki Otake
  • Patent number: 3950304
    Abstract: A curable composition used for electric insulating material comprises a polyhydroxy hydrocarbon polymer, carbon black and talc or clay.
    Type: Grant
    Filed: February 1, 1974
    Date of Patent: April 13, 1976
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Jihei Inomata, Susumu Michishima, Kanji Kasahara, Seiichi Hino, Satoru Igarashi, Tatsuo Tani