Patents Assigned to Mitsui Petrochemical Industries
  • Patent number: 5809048
    Abstract: A short wavelength light source mainly comprises a semiconductor laser for pumping a laser medium, a birefringence filter for controlling or stabilizing the waveform by applying an optical feedback to the semiconductor laser to feed back only light of specific wavelength, lens systems for focusing the pumping light, and an optical resonator composed of a laser medium formed of Nd:YAG doped with 1% of Nd and a nonlinear optical element formed of KNbO.sub.3. The birefringence filter is structured as a Lyot filter, and is composed of a birefringence element made of 2 mm thick non-doped YVO.sub.4, a polarizer, and a birefringence element made of 4 mm thick non-doped YVO.sub.4.This constitution realizes a short wavelength light source achieving a single longitudinal mode oscillation while maintaining a high output, small in size, superior in efficiency, and excellent in wavelength stability.
    Type: Grant
    Filed: July 9, 1997
    Date of Patent: September 15, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Shiro Shichijyo, Kiyofumi Muro
  • Patent number: 5804678
    Abstract: In a gas phase olefin polymerization, an olefin is continuously fed to a fluid bed reactor in which a metallocene catalyst is present. At least one compound selected from water, alcohols and ketones is added in a specified amount simultaneously with the feeding of the olefin. Thus, an olefin polymer having a satisfactory drop second count index as defined by the below indicated formula is produced: ##EQU1## wherein t.sub.0 and t respectively represent a flow time measured in the flow test according to ASTM D-1775 of the olefin polymer obtained when none of the water, alcohols and ketones is incorporated in the reactor, and when at least one compound of water, alcohols and ketones is incorporated in the reactor. The flowability of the polymer formed in the reactor is excellent, so that blocking, bridging and the like do not occur during the gas phase polymerization. Thus, it is feasible to stably produce a (co)polymer having excellent particle properties in high yield for a prolonged period of time.
    Type: Grant
    Filed: July 12, 1994
    Date of Patent: September 8, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yoshinori Morita, Hiroshi Nishikawa, Yutaka Haneda, Satoru Ohtani, Kenji Doi
  • Patent number: 5804517
    Abstract: A flexible nonwoven fabric comprising conjugate long fibers of sheath-core type comprising a core of a resin having a high melting point and a polyethylene sheath is provided. The fiber has a weight ratio of the resin of the high melting point to the polyethylene of from 5/95 to 20/80 and a fineness of up to 3.0 denier, and the nonwoven fabric has a sum of bending resistance in machine and transverse directions as measured by Clark method (method C in JIS L1096) of up to 80 mm. The flexible nonwoven fabric has excellent texture and frictional resistance. A laminate comprising such flexible nonwoven fabric and a gas-permeable film is also provided.
    Type: Grant
    Filed: September 24, 1997
    Date of Patent: September 8, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hiroshi Ishii, Kunihiko Takesue, Kunie Hiroshige
  • Patent number: 5799412
    Abstract: Drying of a solid polymer is disclosed in which a solid polymer obtained by polymerization (or a product of modification of the solid polymer) is contacted with a drying gas so that any solvent and/or unreacted polymerization feed materials remaining in the solid polymer are removed to thereby dry the solid polymer, and in which a gaseous polymerization feed material is used as the drying gas and contacted with the solid polymer to thereby dry the solid polymer (step i), and the resultant solid polymer is contacted with a drying gas which contains an inert gas (step ii). The drying gas can be recovered from the step (i) and part thereof can be recycled through a polymerization step as it is or be recycled, after cooling the drying gas to thereby remove any condensed components, to the step (i). Not only can the solid polymer be efficiently dried but also the solvent and unreacted polymerization feed materials recovered from the solid polymer can efficiently be recycled by the disclosed method.
    Type: Grant
    Filed: April 3, 1997
    Date of Patent: September 1, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Ryoichi Yamamoto, Satoru Ohtani, Toshimi Hachimori, Teruhisa Kojima, Takahiro Mamyoda
  • Patent number: 5795838
    Abstract: A solid olefin polymerization catalyst comprising: a fine particle carrier; (A) a transition metal compound of a Group IVB metal of the periodic table, containing a ligand having a cyclopentadienyl skeleton; (B) an organoaluminum oxy-compound; and optionally (C) an organoaluminum compound, wherein said organoaluminum oxy-compound has an alkyl to aluminum ratio of 1.3 to 2.1; said transition metal compound (A) and said organoaluminum oxy-compound (B) and said organoaluminum compound being supported on the fine particle carrier; and said solid catalyst having a bulk density of 0.3 g/cm.sup.3 to 0.5 g/cm.sup.3 and a fluidity index of 45 to 70 and an olefin polymerization process using the olefin polymerization catalyst; and an olefin prepolymerized catalyst obtained by prepolymerizing the catalyst, and an olefin polymerization process using the olefin prepolymerized catalyst.
    Type: Grant
    Filed: August 9, 1995
    Date of Patent: August 18, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Masaaki Ohgizawa, Tetsuhiro Matsumoto, Junichi Imuta
  • Patent number: 5789484
    Abstract: A 4-methyl-1-pentene polymer composition is prepared by melt mixing (A) a 4-methyl-1-pentene polymer, (B) a 1-butene polymer, (C) a propylene polymer, and (D) a triblock copolymer of polystyrene/ethylene-butylene copolymer/polystyrene and/or a triblock copolymer of polystyrene/ethylene-propylene copolymer/polystyrene. The composition has improved gas permeability, flexibility, and mechanical properties and is formed into a film which is heat sealable.
    Type: Grant
    Filed: May 6, 1996
    Date of Patent: August 4, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Kojiro Kan, Akio Yamamoto
  • Patent number: 5789459
    Abstract: A surface-coated vessel or a surface-coated product having a hard coating layer is obtained, by coating a substrate of, for example, resin product with a resin composition for hard coating which comprises(a) a poly?(meth)acryloyloxyalkyl! (iso)cyanurate represented by the following general formula (1) or (2): ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3 are each an acryloyl group, methacryloyl group, hydrogen atom or an alkyl group, with a proviso that at least two of them are (meth)acryloyl groups, and R.sup.1, R.sup.2 and R.sup.3 are each an oxyalkylene group or a polyoxyalkylene group;(b) a poly(meth)acrylated polyoxyalkane polyol;(c) a photopolymerization initiator consisting of 2-methyl-1-?4-(methylthio)phenyl!-2-morpholino-1-propanone;(d) a photopolymerization initiator based on thioxanthone;(e) a UV-absorber based on monohydroxybenzophenone;(f) an organic solvent.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: August 4, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hajime Inagaki, Koji Yoshii
  • Patent number: 5786403
    Abstract: Disclosed is a foamable olefin thermoplastic elastomer composition comprising (A) a partially crosslinked thermoplastic elastomer composition, (B) long-chain branch-containing polypropylene and (C) a foaming agent. The partially crosslinked thermoplastic elastomer composition (A) is obtained by dynamically heat-treating a mixture in the presence of organic peroxide, said mixture comprising specific proportions of a peroxide-crosslinking type olefin copolymer rubber (a), which is an ethylene/.alpha.-olefin copolymer rubber composed of ethylene, an .alpha.-olefin of 3 to 20 carbon atoms and optionally a nonconjugated diene, and a peroxide-decomposition type olefin plastic (b), which is an .alpha.-olefin (co)polymer containing a specific amount of an .alpha.-olefin of 3 to 20 carbon atoms and having a specific MFR. Also disclosed is a foamed product obtained by heating the foamable olefin thermoplastic elastomer composition.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: July 28, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Keiji Okada, Hiroyasu Yamaoka, Akira Uchiyama
  • Patent number: 5783273
    Abstract: A press-through packaging or blister package having excellent moisture-proofness, transparency, and superior processibility by vacuum or pneumatic forming, comprising of a formed product having blisters thereon prepared by forming a sheet or film of a non-stretched layer made from one or more non-crystalline polyolefin resins selected from the group consisting ofa cycloolefin random copolymer obtained from a non-ring-opening polymerization of ethylene and a cycloolefin having a molecular structure represented by the general formula (1), with an intrinsic viscosity (.eta.) of 0.01-100 dl/g determined in decalin at 135.degree. C. and a softening temperature (TMA) of 50.degree.-200.degree. C., anda graft-modified product of said cycloolefin random copolymer, ##STR1## in which n is zero or 1, m is zero or any positive integer, q is zero or 1, R.sup.1 -R.sup.18 as well as R.sup.a and R.sup.
    Type: Grant
    Filed: May 13, 1993
    Date of Patent: July 21, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yohzoh Yamamoto, Shinji Ohsato, Shiro Honma
  • Patent number: 5780378
    Abstract: A solid titanium catalyst component comprising (a) magnesium, (b) titanium, (c) a halogen, (d) a polyether, (e) a hydrocarbon and (f) an electron donor other than the polyether (d) as essential components is provided. Also a process for preparing a solid titanium catalyst component for olefin polymerization, comprising the steps of contacting a halogenated magnesium compound with a compound selected from the group consisting of an alcohol, an ether and an ester in a hydrocarbon solvent to obtain a magnesium compound solution, contacting the magnesium compound solution with a polyether and contacting the resultant solution with a liquid titanium compound is provided. Further, a catalyst for olefin polymerization comprising the above-mentioned solid titanium catalyst component, an organoaluminum compound catalyst component and an electron donor, and a process for polymerizing an olefin using the catalyst for olefin polymerization are also disclosed.
    Type: Grant
    Filed: September 6, 1995
    Date of Patent: July 14, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Tetsuya Toida, Tetsunori Shinozaki, Mamoru Kioka
  • Patent number: 5770655
    Abstract: A polymer composition comprising ?A! a polymer selected from a copolymer of .alpha.-olefin having at least 2 carbon atoms and a specific cyclic olefin, a ring-opening polymer of said specific cyclic olefin and a hydroganted, ring-opening polymer thereof and ?B! a core-shell elastomer containing 40 to 85 parts of weight of a core component which comprises a styrene-butadiene copolymer and 15 to 60 parts by weight of a shell component which comprises a copolymer of an acrylate or methacrylate having a specific cyclic structure, a monovinyl aromatic monomer, other monovinyl monomer and a plyfunctional monomer. This polymer composition is excellent in transparency and impact resistance.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: June 23, 1998
    Assignees: Mitsui Petrochemical Industries, Ltd., Hoechst Aktiengesellschaft
    Inventors: Toshihiro Sagane, Masayuki Okabe, Masahiro Kishine
  • Patent number: 5767331
    Abstract: A copolymer of ethylene and an alpha-olefin having an ethylene content of from 30 to 90 mole %, a number average molecular weight of from 300 to 30,000 and a molecular weight distribution defined by a Q value (the ratio of the weight average molecular weight to the number average molecular weight) of not more than 3 and a Z value (the ratio of the maximum value of the molecular weight to the minimum value of the molecular weight when the molecular weight is measured by gel permeation chromatography) of from 15 to 200. The said copolymer can be produced by a process comprising copolymerizing ethylene with an alpha-olefin in the liquid phase in the presence of a polymerization catalyst composed of a combination of a soluble vanadium compound and an organoaluminum compound in the co-presence of hydrogen, characterized in that(a) the copolymerization is carried out in a continuous manner,(b) the concentration of the vanadium compound in the polymerization system is maintained at 0.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: June 16, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hidekuni Oda, Tatuo Kinoshita, Akiyoshi Shimizu
  • Patent number: 5767033
    Abstract: The novel transition metal compound of the invention is represented by the following formula: ##STR1## wherein R.sup.1 and R.sup.2 are each a hydrogen atom or a hydrocarbon group of 1 to 3 carbon atoms;X.sup.1 and X.sup.2 are each a halogen atom; andY is a divalent silicon-containing group selected from the group consisting of dimethylsilylene, diphenylsilylene and methylphenylsilylene. The transition metal compound is useful for an olefin polymerization catalyst with which a propylene (co)polymer having specific structure is prepared.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: June 16, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Junichi Imuta, Junji Saito, Takashi Ueda, Yoshihisa Kiso, Akira Mizuno, Masaaki Kawasaki
  • Patent number: 5764668
    Abstract: To overcome the dilemma on device design in control of waveguide mode experienced in the conventional weak wave-guide-laser and SCH structure laser, realize higher output and lower dispersion of radiation beam, and improve the waveguide mode, on both sides of an active layer, carrier blocking layers for reducing the waveguide function of the active layer are provided, and waveguide layers are provided on both outer sides of the carrier blocking layers, and cladding layers are provided on both outer sides of the waveguide layers, the active layer is lamination of side barrier layers and a quantum well layer sandwiched therebetween, or side barrier layers, and a quantum well layer and a barrier layer sandwiched therebetween, the composition of the quantum well layer is Ga.sub.y In.sub.1-y As (0.6<y<1.0), and the carrier blocking layers are made of a material having a wider band gap and a lower refractive index than the material of the waveguide layers.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: June 9, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Shoji Ishizaka, Kiyofumi Muro, Tsuyoshi Fujimoto, Yoshikazu Yamada
  • Patent number: 5763517
    Abstract: The thermoplastic resin composition of the present invention comprises (A) polyamide having a melting point of not lower than 280.degree. C., particularly preferably (A-1) specific polyamide having a melting point of higher than 300.degree. C., (B) a specific modified polymer, (C) a hindered phenol type antioxidant having a molecular weight of not less than 500 and a TGA 10% weight loss temperature of not lower than 300.degree. C., and (D) a sulfur type antioxidant having a molecular weight of not less than 600 and a TGA 10% weight loss temperature of not lower than 280.degree. C. The molded product of the present invention is made of the above-mentioned thermoplastic resin composition. The thermoplastic resin composition of the invention is excellent in heat stability.
    Type: Grant
    Filed: September 26, 1996
    Date of Patent: June 9, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Sanehiro Yamamoto, Kazuto Sugiyama, Akinori Toyota, Yoshikatsu Amimoto, Fumitoshi Ikejiri
  • Patent number: 5763649
    Abstract: A process for producing aromatic carboxylic acids by subjecting an aromatic compound having one or more substituent alkyl groups and/or partially oxidized substituent alkyl groups to a liquid phase oxidation with a molecular oxygen-containing gas in a reaction solvent containing a lower aliphatic carboxylic acid in the presence of a catalyst composed of a heavy metal compound and a bromine compound, under a condition of a weight proportion of said reaction solvent to said aromatic compound within the range from 6.5 to 70 parts by weight per one part by weight of said aromatic compound, a reaction time within the range from 45 to 4.5 minutes and a product of the numerical value of said weight proportion of the reaction solvent to the aromatic compound multiplied by the numerical value of said reaction time expressed in munute within the range from 270 to 330.
    Type: Grant
    Filed: July 8, 1997
    Date of Patent: June 9, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventor: Hiroshi Fukuhara
  • Patent number: 5756575
    Abstract: The ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber composition of the present invention comprises in specified proportions a crystalline polyolefin resin (A) and an ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) composed of ethylene, an .alpha.-olefin having 3 to 20 carbon atoms and a specific branched chain polyene compound. The molar ratio of ethylene units to .alpha.-olefin units, iodine value and intrinsic viscosity ?.eta.! of the ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) are within respective specified ranges. This rubber composition is excellent in low temperature properties. When the above olefinic thermoplastic elastomer composition is partially or entirely crosslinked, a molding can be provided which is superior to the conventional vulcanized rubbers in low temperature properties, tensile strength, elongation at break and rubber properties.
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: May 26, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Masaaki Kawasaki, Hidenari Nakahama, Tetsuo Tojo, Toshiyuki Tsutsui, Kyoko Kobayashi, Toshihiro Sagane
  • Patent number: 5756790
    Abstract: The invention provides a method for preparing an optically active alcohol comprising the step of reacting a ketone compound with a hydride reagent in the presence of an optically active metal compound. The resulting optically active alcohols are useful as intermediates for the synthesis of physiologically active compounds such as drugs and pesticides, functional materials such as liquid crystals, and raw materials for synthesis in fine chemistry. A novel optically active cobalt (II) complex useful as a catalyst is also provided.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 26, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Teruaki Mukaiyama, Kiyotaka Yorozu, Takushi Nagata, Toru Yamada, Kiyoaki Sugi
  • Patent number: 5755940
    Abstract: The lithium ionic conducting glass thin film of the present invention comprises a glass containing 20 to 80 mol % of an Li.sub.2 O component. This glass thin film has a dense structure which shuts off gas and can be used as a solid electrolyte in a carbon dioxide sensor.The thin carbon dioxide sensor of the present invention comprises the above lithium ionic conducting glass thin film as a solid electrolyte. This sensor enables complete elimination of noise attributed to gas permeation by virtue of the lithium ionic conducting glass thin film having a dense structure with the result that the accuracy of carbon dioxide concentration measurement can be enhanced. Further, the lithium ionic conducting glass is formed into a thin film, so that the sensor has a low internal resistance, acts at low operating temperatures and exhibits a high response speed.
    Type: Grant
    Filed: February 12, 1996
    Date of Patent: May 26, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventor: Kiyotaka Shindo
  • Patent number: 5756193
    Abstract: Disclosed is a polyethylene resin composition for heavy-duty packaging bag, which has a specific MFR, a specific density and a specific melt tension and which comprises (I) a linear low-density polyethylene resin prepared from ethylene and an .alpha.-olefin of 4 or more carbon atoms and having a specific MFR, a specific molecular weight distribution and a density of 0.900 to 0.918 g/cm.sup.3, (II) a linear medium or high-density polyethylene resin having a density of 0.935 to 0.970 g/cm.sup.3 and (III) a high-pressure low-density polyethylene resin having a density of 0.915 to 0.924 g/cm.sup.3, in a specific ratio of components. Also disclosed is a polyethylene resin film prepared from said composition. The composition is able to provide a film which is excellent in low-temperature properties such as low-temperature drop-bag strength and can be advantageously used for a heavy-duty packaging bag even in a cold district of below-freezing temperature.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: May 26, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Akihiko Yamamoto, Naoshi Hamada, Toshihiro Nishimura, Kouji Kitahara