Patents Assigned to Mitsui Petrochemical Industries
  • Patent number: 5753769
    Abstract: A process for preparing a propylene polymer composition having excellent rigidity, heat resistance and impact resistance comprising conducting multistage polymerization including a step (a) for preparing a propylene (co)polymer (A), a step (b) for preparing a propylene-olefin copolymer (B) and a step (c) for preparing an ethylene-olefin copolymer (C) in the presence of (I) a transition metal compound and (II) a compound activating the transition metal compound (I), in which the steps (a), (b) and (c) are carried out in any order, each of the second and subsequent stage polymerizations is carried out in the presence of a polymer or polymers obtained by the preceding stage or stages, respectively, and the resulting propylene polymer composition contains the propylene (co)polymer (A) in an amount of 20 to 90% by weight, the propylene-olefin copolymer (B) in an amount of 5 to 75% by weight and the ethylene-olefin copolymer (C) in an amount of 5 to 75% by weight, and has MFR, as measured at 230.degree. C.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 19, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Takashi Ueda, Mikio Hashimoto, Masaaki Kawasaki, Daisuke Fukuoka, Junichi Imuta
  • Patent number: 5738249
    Abstract: A rotor 22 accommodated in a casing 26 has a circumferential surface sliding on the internal surface of the casing 26 in airtight condition. The casing 26 is provided with a powder feed part 27 positioned above the rotor and is provided with a powder drop part 30 positioned under the rotor. At least one quantity-measuring recessed part is formed in the slide surface of the rotor. In accordance with the rotation of the rotor, the quantity-measuring recessed part comes to communicate with the powder feed part, so that powder is fed from the powder feed part into the quantity-measuring recessed part. When the rotation is advanced, the quantity-measuring recessed part comes to communicate with the powder drop part, so that the powder drops from the quantity-measuring recessed part through the powder drop part into a high-pressure part 19 arranged thereunder.
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: April 14, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yoshiaki Kikuchi, Tomohiro Arase, Shotaro Matsuda, Ryoichi Yamamoto
  • Patent number: 5739366
    Abstract: The novel transition metal compound of the invention is represented by the following formula (I): ##STR1## wherein M is a transition metal; R.sup.1 and R.sup.2 are each a hydrogen atom, a hydrocarbon group or the like; R.sup.3 is an alkyl group of 2 to 20 carbon atoms; R.sup.4 is an alkyl group of 2 to 20 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like. The transition metal compound is useful for an olefin polymerization catalyst with which a propylene (co)polymer having specific structure is prepared.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 14, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Junichi Imuta, Junji Saito, Takashi Ueda, Yoshihisa Kiso, Akira Mizuno, Masaaki Kawasaki
  • Patent number: 5735470
    Abstract: An irrigation hose provides a long life expectancy. The irrigation hose is characterized in that a plurality of flow passages are defined by partitions dividing the inside of the hose which is made of thermoplastic resin; and that each flow passage is provided with irrigation holes formed in a member of the tube portion which is in contact with outside air, that is the outer wall thereof. The irrigation hose can provide different irrigation methods appropriate to the crops or growth stages with just one hose, without exchanging or laying multiple hoses with different irrigation methods. A film 16 is inserted between a film 12 which is made of long thermoplastic resin film with irrigation holes formed throughout at regular pitch and another film 12 which is also made of a long thermoplastic resin film with irrigation holes on both sides.
    Type: Grant
    Filed: July 17, 1997
    Date of Patent: April 7, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Tatsuya Ohe, Toshihisa Hori
  • Patent number: 5733983
    Abstract: A heat-resistant rubber composition of the invention is a vulcanizable composition comprising a specific ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) and an organic peroxide (B). This heat-resistant composition has high crosslinking efficiency given by the organic peroxide and high modulus, and can provide a vulcanized rubber molded product of excellent resistance to environmental deterioration such as thermal aging resistance. The other heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an .alpha.-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B).
    Type: Grant
    Filed: December 10, 1996
    Date of Patent: March 31, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Takashi Hakuta, Tetsuo Tojo, Masaaki Kawasaki, Mikio Hosoya
  • Patent number: 5731393
    Abstract: An ethylene polymer having small values of Mw/Mn and Mz/Mw, a small proportion of long-chain branches and a high swell ratio and a process for preparing the polymer are disclosed. A solid titanium catalyst component obtained by initially contacting a solid titanium composite containing titanium, magnesium, halogen and a compound having at least two ether linkages present through plural atoms with an organometallic compound and then contacting the resulting product with oxygen is further disclosed. An ethylene polymerization catalyst comprising the above catalyst component and an organometallic compound catalyst component is furthermore disclosed. The ethylene polymer is excellent in moldability, and from this polymer, a molded article which is excellent in rigidity and impact resistance and free from poor appearance can be obtained. By the use of the ethylene polymerization catalyst, an ethylene polymer having excellent properties as mentioned above can be obtained.
    Type: Grant
    Filed: April 9, 1997
    Date of Patent: March 24, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Shin-ichi Kojoh, Mamoru Kioka
  • Patent number: 5728509
    Abstract: At least one convex (or concave) arcuate face is formed by photolithography on a photoresist film formed on a surface of an optical device made of an optical material. The surface of the optical device and the photoresist film are etched to form, on the surface of the optical device, at least one convex (or concave) arcuate face similar to the convex (or concave) arcuate face formed on the photoresist film. After the surface of the optical material is mirror face polished, a photoresist film is formed on the polished surface, and the polished surface and the photoresist film are etched uniformly. An optical device obtained in this manner is used for a laser oscillator, a monolithic laser system, a nonlinear optical device, a microlens, a ring laser and so forth. Further, a plurality of reflecting portions are provided on a pair of opposing surfaces of a light transmitting optical material. At least one of the opposing surfaces is formed on the convex arcuate face.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: March 17, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Akira Eda, Kiyofumi Muro
  • Patent number: 5728744
    Abstract: Disclouse is an olefin thermoplastic elastomer foamed product obtained by heating a foamable composition comprising a partially crosslinked thermoplastic elastomer composition (A), a specific olefin plastic (B) and a foaming agent (C) in specific proportions. The partially crosslinked thermoplastic elastomer (A) is obtained by dynamically heat-treating a mixture in the presence of organic peroxide, said mixture comprising specific proportions of a peroxide-crosslinkable copolymer rubber (a), which is a specific ethylene/.alpha.-olefin/nonconjugated diene copolymer rubber, and a peroxide-decomposable olefin plastic (b), which is a (co)polymer containing 50 to 100% by mol of an .alpha.-olefin of 3 to 20 carbon atoms and has a specific MFR. The olefin plastic (B) is a (co)polymer containing 50 to 100% by mol of an .alpha.-olefin of 2 to 20 carbon atoms and has a specific MFR. Also disclosed is a process for preparing the olefin thermoplastic elastomer foamed product.
    Type: Grant
    Filed: November 21, 1996
    Date of Patent: March 17, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Keiji Okada, Masato Karaiwa, Akira Uchiyama
  • Patent number: 5726262
    Abstract: A solid titanium catalyst component ?Ia! containing magnesium, halogen, titanium and a compound having at least two ether linkags with a plurality of intermediately existing bonding atoms; a catalyst and a prepolymerized olefin-containing catalyst prepared by using the solid titanium catalyst component ?Ia!; a method for preparing a polyolefin wherein said catalyst or prepolymerized olefin containing catayst is used. A catalyst and a prepolymerized olefin containing catalyst prepared by using a solid titanium catalyst component ?Ib! containing magnesium, halogen, titanium and a specific electron donor (a1), and a compound having at least two ether linkags with a plurality of intermediately existing bonding atoms; a method for preparing a polyolefin wherein said catalyst or prepolymerized olefin containing catayst is used.
    Type: Grant
    Filed: December 24, 1996
    Date of Patent: March 10, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Mamoru Kioka, Tetsunori Shinozaki
  • Patent number: 5725798
    Abstract: There is provided a carboxylic acid compound represented by the following formulae (I) to (IV): ##STR1## a liquid crystal material consisting of the carboxylic acid ester compound, a liquid crystal composition comprising the carboxylic acid ester compound, and a liquid crystal element using the carboxylic acid ester compound. There can be obtained advantages such as low operating temperature, high speed switching, very small electric power consumption, and high-stable contrast.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: March 10, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yuuichirou Tatsuki, Shinichi Nishiyama, Junichi Kawabata, Tooru Yamanaka, Chiho Tanaka
  • Patent number: 5725715
    Abstract: A squeezable tubular container (a) which is formed from a composition containing a polyethylene having a density of 0.900 to 0.975 g/cm.sup.3 and an ethylene/.alpha.-olefin copolymer having a density smaller than 0.900 g/cm.sup.3, (b) has a crosslinking caused under irradiation with electron beam, and (c) is sterilizable at a high temperature or is heat-sealable or ultrasonically sealable; and a process for the production thereof.
    Type: Grant
    Filed: July 2, 1996
    Date of Patent: March 10, 1998
    Assignees: Mitsui Petrochemical Industries, Ltd,, Yoshino Kogyosho Co., Ltd., Japan Atomic Energy Research Institute
    Inventors: Keizo Makuuchi, Fumio Yoshii, Yasuo Futami, Masanobu Ishiyama, Gen Miyamoto, Hideo Kushida, Sei Nakajima, Takahiro Kurihara, Ryoji Sugawara, Hideshi Kawachi, Mikio Nakagawa
  • Patent number: 5723640
    Abstract: The novel transition metal compound of the invention is represented by the following formula (I): ##STR1## wherein M is a transition metal; R.sup.1 is a hydrocarbon group of 2 to 6 carbon atoms, R.sup.2 is an aryl group of 6 to 16 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like. An olefin polymerization catalyst component of the present invention comprises the aforementioned transition metal compound.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: March 3, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Daisuke Fukuoka, Takashi Tashiro, Koji Kawaai, Junji Saito, Takashi Ueda, Yoshihisa Kiso, Junichi Imuta, Terunori Fujita, Masatoshi Nitabaru, Masayasu Yoshida
  • Patent number: 5724115
    Abstract: Disclosed is a liquid crystal device comprising a liquid crystal cell filled with a liquid crystal material capable of exhibiting a smectic phase, said cell including upper and lower substrates each having in order an electrode and an orientation film in contact with the liquid crystal material, a cross angle .THETA. formed by the orientation treatment directions of the orientation films is 180.degree.-.delta. or 360.degree.-.delta. (0.degree.<.delta..ltoreq.90.degree.). Also disclosed is a process for preparing the above-mentioned liquid crystal device comprising treating the orientation films and preparing the liquid crystal cell so as to have the orientation treatment directions of the orientation films form the cross angle .THETA. within the above range in the cell.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: March 3, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yukari Sakai, Mitsuko Nagai, Hideo Hama
  • Patent number: 5719653
    Abstract: Striped electrodes are formed on upper and lower substrates respectively, and a plurality of partition members are formed in a striped fashion so that a plurality of parallel sealed linear interstices R, each having a rectangular section, are formed between the substrates. A upper-side rubbing direction crosses a lower-side rubbing direction at a predetermined angle, and the direction of extension of each of the partition members is caused to fall within the above cross angle. An antiferroelectric liquid crystal is sealed in the linear interstices, and the liquid crystal panel is cooled while proceeding from one end of the linear interstices to the other end thereof. The layer normal direction of liquid crystal molecular layer becoming irregular between the upper and lower substrates is prevented by the employment of the cross rubbing method to thereby avoid the occurrence of defects in the liquid crystal.
    Type: Grant
    Filed: January 24, 1996
    Date of Patent: February 17, 1998
    Assignees: Toppan Printing Co., Ltd., Mitsui Petrochemical Industries, Ltd.
    Inventors: Takao Minato, Katsuhiro Suzuki, Hideo Hama, Yukari Sakai
  • Patent number: 5718982
    Abstract: A multilayer laminate film comprising (A) a first layer comprising a propylene polymer and oriented in at least one direction, (B) a second layer comprising a propylene copolymer having a melting point lower than the melting point of the propylene polymer of the first layer, (C) a third layer comprising a polymer composition comprising a graft modified olefin polymer in which an unsaturated carboxylic acid or a derivative thereof is grafted, and (D) a fourth layer comprising an ethylene vinyl alcohol copolymer, these four layers being laminated in the above order. The above multilayer laminate exhibits excellent interlaminar adhesion and has excellent heat resistance.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: February 17, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hideshi Kawachi, Haruhiko Tanaka
  • Patent number: 5714220
    Abstract: The container according to the invention is composed of a saturated polyester resin composition comprising a saturated polyester ?A! in an amount of 50 to 95 parts by weight, a metallic salt of an ethylene/unsaturated carboxylic acid copolymer ?B! in an amount of 0.5 to 20 parts by weight, a modified ethylene/.alpha.-olefin copolymer rubber ?C! in an amount of 0.5 to 30 parts by weight, a benzotriazole type weathering stabilizer ?D! in an amount of 0.01 to 2.0 parts by weight and a hindered amine type weathering stabilizer ?E! in an amount of 0 to 2.0 parts by weight, and if necessary, a carbodiimide compound ?F! in an amount of 0.01 to 5.0 parts by weight, the amounts of said components ?D!, ?E! and ?F! being each based on 100 parts by weight of the total amounts of the components ?A!, ?B! and ?C!. The container of the invention is excellent in not only low-temperature impact strength but also rigidity, weld strength, weathering resistance and fade resistance.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: February 3, 1998
    Assignees: Mitsui Petrochemical Industries, Ltd., Kirin Beer Kabushiki Kaisha
    Inventors: Tsuyoshi Kage, Koji Takahashi, Hideki Sakai, Takashi Hiraoka
  • Patent number: 5714273
    Abstract: A resin-coated steel sheet for drawn-and-ironed cans and a method of producing the resin-coated steel sheet. The resin-coated steel sheet has a steel sheet with a tin-coat on each side and a resin layer of a first crystalline thermoplastic polyester resin on one of the tin-coats and a second non-crystalline thermoplastic polyester resin on the first crystalline thermoplastic polyester resin. The first crystalline thermoplastic polyester resin has an alloying ratio of: 50.ltoreq.alloying ratio <100. The second non-crystalline thermoplastic polyester resin has an alloying ratio of 0<alloying ratio <50. The method includes thermal fusion of a mixture of 95-5 percent by weight of a crystalline polyester resin and 5-95 percent of a non-crystalline polyester resin to produce the first crystalline thermoplastic polyester resin and the second non-crystalline thermoplastic polyester resin.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: February 3, 1998
    Assignees: Nippon Steel Corporation, Mitsui Petrochemical Industries, Inc.
    Inventors: Ryousuke Wake, Ryoichi Yoshihara, Hiroji Niimi, Takashi Hiraoka
  • Patent number: 5714426
    Abstract: In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from .alpha.-olefin of 3.about.20 carbon atoms, said ethylene copolymers having?A! a density of 0.85.about.0.92 g/cm.sup.3,?B! an intrinsic viscosity ?.eta.! as measured in decalin at 135.degree. C. of 0.1.about.10 dl/g,?C! a ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) as measured by GPC of 1.2.about.4, and?D! a ratio (MFR.sub.10 /MFR.sub.2) of MFR.sub.10 under a load of 10 kg to MFR.sub.2 under a load of 2.16 kg at 190.degree. C. of 8.about.50, and being narrow in molecular weight distribution and excellent in flowability.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: February 3, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Akinori Toyota
  • Patent number: 5710223
    Abstract: A process for polymerizing propylene utilizes a metallocene catalyst component of the formula (I) ##STR1## wherein M is a transition metal, R.sup.1 is a C.sub.2-6 hydrocarbon, R.sup.2 is a C.sub.6-16 aryl group, X.sup.1 and X.sup.2 are each a halogen atom and Y is a divalent hydrocarbon or a divalent silicon-containing group. Propylene polymers produced thereby have such properties that the triad tacticity of propylene units is high, the proportion of inversely inserted units based on the 2,1-insertion of propylene monomer is in a specific range and the intrinsic viscosity (.eta.), as measured in decahydronaphthalene at 135.degree. C., is in a specific range.
    Type: Grant
    Filed: September 25, 1996
    Date of Patent: January 20, 1998
    Assignee: Mitsui Petrochemical Industries Ltd.
    Inventors: Daisuke Fukuoka, Takashi Tashiro, Koji Kawaai, Junji Saito, Takashi Ueda, Yoshihisa Kiso, Junichi Imuta, Terunori Fujita, Masatoshi Nitabaru, Masayasu Yoshida
  • Patent number: 5710218
    Abstract: The invention provides ethylene-propylene-diene rubbers capable of imparting excellent heat resistance, weather resistance and dynamic fatigue resistance to vulcanized rubbers made therefrom. The ethylene-propylene-diene rubbers have sulfur dispersed therein at a temperature of 90.degree. to 160.degree. C. prior to the addition of vulcanization accelerators or other rubber additives. The ethylene-propylene-diene rubbers contain (A) 90 to 40% by weight of a high-molecular weight ethylene-propylene-diene copolymer rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 3.0 to 5.0 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, (B) 10 to 60% by weight of a low-molecular-weight ethylene-propylene-diene copolymer rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 0.15 to 0.8 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, and (C) sulfur in an amount of 0.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: January 20, 1998
    Assignee: Mitsui Petrochemical Industries
    Inventors: Hidenari Nakahama, Takashi Mishima