Patents Assigned to Mitsui Toatsu Chemicals, Inc.
  • Patent number: 5559247
    Abstract: A carboxylate is herein disclosed which is represented by the formula (1) or (2) ##STR1## wherein a ring X is an aromatic residue which may have a substituent; the other substitutents are as defined herein. A heat-sensitive recording material comprising this carboxylate is excellent in the stability of the color image and can provide an optically character-readable sharp color image.
    Type: Grant
    Filed: April 14, 1995
    Date of Patent: September 24, 1996
    Assignees: Mitsui Toatsu Chemicals, Inc., Yamamoto Chemicals, Inc.
    Inventors: Mansuke Matsumoto, Nobuaki Sasaki, Bunji Sawano, Kiyoharu Hasegawa, Kazuyoshi Kikkawa
  • Patent number: 5558883
    Abstract: A molding equipment for making composite molded article having:(a) a fixed side mold having a convex portion integral with a gate; the convex portion being formed according to the shape of the molded article; the gate being used for injecting melted resin into a resin molding space;(b) a movable side mold capable of being moved close to and away from the fixed side mold; the movable side mold having a concave portion; the concave portion being joined with the convex portion of the fixed side mold (1) to form the resin molding space when the molding equipment is clamped;(c) a set of slide cores being mounted between the fixed side mold (1) and the movable side mold; the slide cores being movable toward and away from the fixed side mold; and(d) a skin material setting frame being mounted between the fixed side mold and the slide cores; the skin material setting frame being capable of setting a skin material.
    Type: Grant
    Filed: December 28, 1994
    Date of Patent: September 24, 1996
    Assignees: Mitsui Toatsu Chemicals, Inc., Moriroku Kabushiki Kaisha
    Inventors: Tsunetoshi Shinada, Katsuo Wada, Masaki Misumi, Satoru Kurono
  • Patent number: 5556711
    Abstract: A multilayer composite consisting of aluminum and a resin composition primarily comprising a lactic acid base polymer, is disclosed. The composite material is excellent in mechanical and gas barrier properties and has characteristic of totally decomposing under alkaline conditions.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: September 17, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masanobu Ajioka, Katashi Enomoto, Akihiro Yamaguchi, Kazuhiko Suzuki
  • Patent number: 5554765
    Abstract: A moldable polyimide resin composition which has melt-flowability and excellent processability in addition to essential heat-resistant of polyimide and comprises an aromatic bisimide compound and polyimide resin. A further aspect relates to a carbon fiber reinforced polyimide resin composition which has excellent mechanical strengths and comprises a carbon fiber coated with aromatic bisimide compound on the surface and the polyimide resin. A still further aspect relates to a novel bisimide compound which is very useful as the aromatic bisimide compound in the composition.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 10, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masahiro Ohta, Akio Matsuyama, Eiji Senoue, Fumiaki Kuwano, Osamu Yasui, Yasunori Yoshida, Akinori Ryu, Tadashi Kobayashi
  • Patent number: 5552494
    Abstract: A molding of an ABS-based resin is described. Rubber particles located at a depth of 0.5-1.5 .mu.m from a surface of the molding morphologically comprise at least the following two types of particles:(1) A particles having an a/b ratio not greater than 1.5, wherein a and b represent a major axis and a minor axis, respectively, and(2) B particles having an a/b ratio not smaller than 5, wherein a and b have the same meanings as defined abovewhen a section extending at the depth in parallel with the surface of the molding is observed in an electron micrograph taken by the ultrathin sectioning technique. Assuming that the total area of the rubber particles as observed in the electron micrograph is 100%, the total area of the A particles accounts for at least 10% and that of the B particles is in a range of 0.01-90%.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: September 3, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Mune Iwamoto, Akihiko Nakajima, Masato Takaku, Hisao Morita, Toshihiko Ando, Tomofumi Shirafuji, Mutsuko Uchida
  • Patent number: 5552509
    Abstract: A phenolic resin composition herein disclosed comprises, as essential components, (i) at least one phenol resin A selected from the group consisting of residues formed through purification of bisphenol A, residues obtained by cleaving the bisphenol A-purification residue, condensates of the bisphenol A-purification residue obtained by reacting the bisphenol A-purification residue with formaldehyde and condensates of the cleavage residue obtained by reacting the cleavage residue with formaldehyde, and (ii) at least one phenolic resin B selected from the group consisting of high-boiling fraction obtained through production of bisphenol F and condensates of the high-boiling fraction obtained by reacting the high-boiling fraction with formaldehyde.
    Type: Grant
    Filed: August 31, 1993
    Date of Patent: September 3, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tomoko Takashima, Shigeru Iimuro, Takashi Kitamura
  • Patent number: 5548073
    Abstract: Novel azo compounds having the specific structural formula (1) or (3) set out below, water-soluble dyes containing the compounds, and polarizing films containing the water-soluble dyes: ##STR1## wherein R.sub.1 represents a hydrogen or halogen atom or a hydroxyl, C.sub.1-2 alkyl, C.sub.1-2 alkoxyl, C.sub.1-2 acylamino, cyano, carboxyl or sulfonic acid group; R.sub.3 and R.sub.8 individually represent a hydrogen atom or a hydroxyl, C.sub.1-2 alkyl or C.sub.1-2 alkoxyl group; R.sub.2 and R.sub.4 individually represent a hydrogen atom or a hydroxyl, C.sub.1-2 alkyl, C.sub.1-2 alkoxyl or C.sub.1-2 acylamino group; R.sub.5 represents a hydrogen atom or a carboxyl or C.sub.1-2 alkoxyl group; R.sub.6 represents a hydrogen atom, a hydroxyl, amino, methylamino, .beta.-hydroxyethylamino or C.sub.1-2 acylamino group, or a phenylamino or benzoylamino group which the phenyl nucleus may be substituted by one or more nitro, amino, hydroxyl, C.sub.1-2 alkyl, carboxyl and/or sulfonic acid groups and/or chlorine atoms; R.sub.
    Type: Grant
    Filed: March 15, 1995
    Date of Patent: August 20, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tsutami Misawa, Akira Ogiso, Rihoko Imai, Hisato Itoh
  • Patent number: 5548007
    Abstract: A radiation-resistant polypropylene resin composition is disclosed which comprises a polypropylene having a substantially syndiotactic structure, and if desired, a phosphorus-containing anti-oxidant, an amine-containing anti-oxidant and/or a nucleating agent. Molded articles obtained from this resin composition can be utilized as containers for foods and medicines, and their physical properties scarcely deteriorate during sterilization by radiation.
    Type: Grant
    Filed: March 7, 1995
    Date of Patent: August 20, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tadashi Asanuma, Shigeru Kimura, Nobutaka Uchikawa, Tetsunosuke Shiomura
  • Patent number: 5548008
    Abstract: A radiation-resistant polypropylene resin composition is disclosed which comprises a polypropylene having a substantially syndiotactic structure, and if desired, a phosphorus-containing anti-oxidant, an amine-containing anti-oxidant and/or a nucleating agent. Molded articles obtained from this resin composition can be utilized as containers for foods and medicines, and their physical properties scarcely deteriorate during sterilization by radiation.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: August 20, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tadashi Asanuma, Shigeru Kimura, Nobutaka Uchikawa, Tetsunosuke Shiomura
  • Patent number: 5545751
    Abstract: A process for the preparation of 4-methoxy-2,2',6-trimethyldiphenylamine, which comprises heating and reacting 2,6-dimethylcyclohexanone and 2-methyl-4-methoxyaniline in the presence of a dehydrogenation catalyst while removing the resultant hydrogen and water from the reaction system.
    Type: Grant
    Filed: December 14, 1994
    Date of Patent: August 13, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Chiyuki Kusuda, Masayuki Furuya, Masaru Wada, Yoshihiro Irizato, Hiroshi Naruse, Teruyuki Nagata
  • Patent number: 5545752
    Abstract: A processes for the preparation of diphenylamine or a nucleus-substituted derivative thereof, which comprise, upon feeding into a reaction system a phenol compound and reacting in the reaction system a cyclohexanone compound with an aniline compound in the presence of a hydrogen transfer catalyst and a catalytic amount of the cyclohexanone compound corresponding to the phenol compound while using the phenol compound as a hydrogen acceptor and forming the cyclohexanone compound in the reaction system, (1) conducting reaction while adding dropwise the aniline compound and (2) employing a hydroxide, carbonate or bicarbonate of an alkali metal and/or alkaline earth metal when the hydrogen transfer catalyst is one of noble metals of Group VIII of the periodic table, respectively.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: August 13, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Teruyuki Nagata, Chiyuki Kusuda, Masaru Wada
  • Patent number: 5545702
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: August 13, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi, Kazunori Kamada, Shigeru Nakahata, Katsumi Sakamoto, Tatsunobu Nakashima, Akito Watanabe, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono, Kazuo Sugazaki
  • Patent number: 5538985
    Abstract: Antipsychotics and ischemic cerebral disease therapeutics comprising as an effective ingredient a compound represented by the following formula (1) or (2): ##STR1## or a salt thereof. These drugs do not induce extrapyramidal side effects.
    Type: Grant
    Filed: January 24, 1995
    Date of Patent: July 23, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hajime Iizuka, Takahisa Oguchi, Yoji Aoki, Norio Ohto, Kazutoshi Horikomi, Takaichi Miwa, Takeshi Kamioka, Shoji Kawashima
  • Patent number: 5536795
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: July 16, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi
  • Patent number: 5536878
    Abstract: Disclosed are (1) a method for preparing an aromatic secondary amino compound which comprises reacting an N-cyclohexylideneamino compound in the presence of a hydrogen moving catalyst and a hydrogen acceptor by the use of a sulfur-free polar solvent and/or a cocatalyst, and (2) a method for preparing an aromatic secondary amino compound which comprises reacting cyclohexanone or a nucleus-substituted cyclohexanone, an amine and a nitro compound corresponding to the amine in a sulfur-free polar solvent in the presence of a hydrogen moving catalyst, a cocatalyst being added or not added. In a further aspect, a method is provided for the preparation of aminodiphenylamine by reacting phenylenediamine and cyclohexanone in the presence of a hydrogen transfer catalyst in a sulfur-free polar solvent while using nitroaniline as a hydrogen acceptor.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: July 16, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Teruyuki Nagata, Chiyuki Kusuda, Masaru Wada, Kenichi Satou, Masae Uchida
  • Patent number: 5534595
    Abstract: Disclosed is a syndiotactic propylene copolymer containing 0.01 to 40 mol % of olefin units containing --OH group in the side chain. Of absorption peaks attributed to the methyl groups of the propylene units on an absorption spectrum by .sup.13 C-NMR of the copolymer, the intensity of an absorption peak observed at about 20.2 ppm is 0.3 or more of the intensity of absorption peaks of all the methyl groups attributed to the propylene units. The copolymer is produced by copolymerizing propylene and an alkenylsilane or alkenylborane compound in the presence of a catalyst system comprising an asymmetric ligands-having transition metal compound and an aluminoxane, followed by heat-treating the resulting propylene-alkenylsilane copolymer in the presence of a trialkylamine oxide and KF.HF or oxidizing and decomposing the resulting propylene-alkenylborane compound copolymer. Also disclosed is a resin composition comprising the copolymer and other polyolefin(s).
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 9, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tadashi Asanuma, Hiroshi Matsuzawa, Tateyo Sasaki, Kaoru Kawanishi
  • Patent number: 5534655
    Abstract: A process for preparing acrylamide is disclosed herein which comprises subjecting acrylonitrile to a hydration reaction in the presence of a copper-based catalyst, said process comprising the step of allowing a compound having an active methylene group and an acidic group in one molecule or a salt of the compound, for example, malonic acid, cyanoacetic acid or its salt to be present in a reaction system. According to the hydration reaction, it is possible to inhibit the secondary formation of impurities which cannot be heretofore removed, without any deterioration of a catalyst activity, and acrylamide can be obtained which is useful as a material for the manufacture of a high-molecular weight flocculant having a sufficiently large molecular weight and a good water solubility.
    Type: Grant
    Filed: February 23, 1995
    Date of Patent: July 9, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoshihiko Kambara, Yoshikazu Uehara, Takeya Abe, Koichi Asao
  • Patent number: 5532054
    Abstract: A molding material shaped like a plate and comprising a composite of continuous fibers and thermoplastic resin wherein each of the filaments which form the continuous fiber is coated around the surface thereof with the thermoplastic resin. Although the molding material has a high density of reinforcing fibers therein, it provides excellent distribution of fibers in the molding process; few of its fibers are broken, and its mechanical strength is considerably enhanced when its specific surface is made larger than a certain value. This molding material can be used for injection, extrusion and compression moldings.
    Type: Grant
    Filed: September 16, 1994
    Date of Patent: July 2, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tomohita Koba, Toshiyuki Nakakura, Hideo Sakai, Misao Masuda, Satoru Kishi, Chiaki Maruko
  • Patent number: 5532349
    Abstract: A process for producing 1-(2'-deoxy-B-D-erythropentofuranosyl)-5-trifluoromethyluracil derivatives having the formula as shown below: ##STR1## wherein X.sup.1 and X.sup.2 are independently hydrogen or halogen, comprising:(a) reacting 5-trifluoromethyl-5,6-dihydrouracil with alkylsulfoxide in the presence of a halogen and and acid to obtain 5-trifluoromethyluracil;(b) reacting the obtained 5-trifluoromethyluracil with a silylating agent to obtain 5-trifluoromethyl-2,4 -bis(trimethylsilyloxy)uracil; and(c) reacting the obtained 5-trifluoromethyl-2,4-bis(trimethylsilyloxy)uracil with a protected 2-deoxyalpha-D-erthro-pentofuranosyl)halide derivative in chloroform solvent in the presence of fluoride ion and in the presence of a copper compound as a catalyst.The resulting, deblocked nucleosides are useful as antiviral and antitumor agents.
    Type: Grant
    Filed: July 15, 1994
    Date of Patent: July 2, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Nobuya Kawauchi, Nobuyuki Fukazawa, Hiroki Ishibashi, Kengo Otsuka
  • Patent number: 5532365
    Abstract: The present invention relates to novel (tetrahydro-3-furanyl)methylamino derivatives of the following formula (1): ##STR1## wherein the variables are defined in the specification, which are useful as insecticides.
    Type: Grant
    Filed: April 5, 1995
    Date of Patent: July 2, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kenji Kodaka, Katsutoshi Kinoshita, Takeo Wakita, Shirou Shiraishi, Kazutomi Ohnuma, Eiichi Yamada, Naoko Yasui, Michihiko Nakaya, Hirozumi Matsuno, Nobuyuki Kawahara, Koichi Ebihara