Patents Assigned to Mitsui Toatsu Chemicals, Inc.
  • Patent number: 5473010
    Abstract: The present invention relates to a polyimide based resin composition comprises 1 to 50 parts by weight of polyetherimide for 100 parts by weight a resin composition comprising 50 to 99 parts by weight of polyarylether ketone and 50 to 1 parts by weight of polyimide having specific structural units.The polyimide based resin compositions have excellent fatigue characteristics and creep resistance and are expected widely to apply in field of machine and automobile parts which is required permanence for mechanical strength.
    Type: Grant
    Filed: August 30, 1994
    Date of Patent: December 5, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Atsushi Morita, Tomohito Koba, Toshiaki Takahashi, Katsunori Shimamura, Toshiyuki Kataoka, Hiroyuki Furukawa, Hiroaki Tomimoto
  • Patent number: 5470918
    Abstract: The present invention provides a water-resistant surface coating formulation comprising a reaction product obtained by subjecting an acrylamide polymer to a crosslinking reaction with 0.1 to 20 parts by mole, per 100 parts by mole of amido groups in the acrylamide polymer, of a glyoxalmonoureine; a method for improving the water resistance of paper by using the formulation; and coated paper so obtained. As a result of improved water resistance of the coating formulation, this invention makes it possible to conduct coating work stably.
    Type: Grant
    Filed: May 24, 1994
    Date of Patent: November 28, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Haruki Tsutumi, Yoshiaki Ikemoto, Mitsuhiro Maehama, Toshiki Oyanagi, Tsugio Matsubara
  • Patent number: 5470943
    Abstract: This invention relates to a novel fluorine-containing polyimide or polyimide copolymer being colorless and having transparency and very low dielectric characteristics, and has a novel aromatic diamino compound used for the polyimide, a preparation process thereof, a polyimide-based resin composition comprising the polyimide or polyimide copolymer and a fibrous reinforcement, a process for preparing the resin composition, an injection molded article of the resin composition.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: November 28, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoshihiro Sakata, Wataru Yamashita, Yuichi Okawa, Shoji Tamai, Tsutomu Ishida, Mitsunori Matsuo, Keizaburo Yamaguchi, Akihiro Yamaguchi
  • Patent number: 5468840
    Abstract: An alkali metal compound such as metallic cesium, cesium hydroxide, cesium hydroxide monohydrate, metallic rubidium, rubidium hydroxide or rubidium hydroxide monohydrate is used as a catalyst, crude polyoxyalkylene polyol containing the catalyst is neutralized with a mineral acid or an organic acid, an aqueous solution layer containing an alkali metal salt is brought into contact with an anion exchange resin to adsorb mineral acid anion or organic acid anion, the alkali metal compound catalyst is recovered. alkylene oxide undergoes ring-opening addition polymerization on an active hydrogen compound in the presence of the recovered alkali metal compound catalyst to prepare polyoxyalkylene polyol, the catalyst is thereafter separated, recovered and reused, and such recycle of the alkali metal compound catalyst provides an economical process.
    Type: Grant
    Filed: August 29, 1994
    Date of Patent: November 21, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tomoki Tsutsui, Tsukuru Izukawa, Kazuhiko Ohkubo, Yoshitsugu Sakaki
  • Patent number: 5457154
    Abstract: A moldable polyimide resin composition which has melt-flowability and excellent processability in addition to essential heat-resistant of polyimide and comprises an aromatic bisimide compound and polyimide resin. A further aspect relates to a carbon fiber reinforced polyimide resin composition which has excellent mechanical strengths and comprises a carbon fiber coated with aromatic bisimide compound on the surface and the polyimide resin. A still further aspect relates to a novel bisimide compound which is very useful as the aromatic bisimide compound in the composition.
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: October 10, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masahiro Ohta, Akio Matsuyama, Eiji Senoue, Fumiaki Kuwano, Osamu Yasui, Yasunori Yoshida, Akinori Ryu, Tadashi Kobayashi
  • Patent number: 5455201
    Abstract: A holding container which is made of a polyether ether ketone resin and is suitable for use in holding one or more substrates upon fabrication of the corresponding number of thin-film semiconductor substrates useful in driving a planar display, for example, a liquid crystal display.
    Type: Grant
    Filed: November 12, 1993
    Date of Patent: October 3, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoshihisa Gotoh, Motoo Kawamata, Toshiaki Takahashi
  • Patent number: 5451695
    Abstract: A polymerizable monomer has the formula, ##STR1## where R.sub.5 and R.sub.6 are similar or dissimilar and are selected from group consisting of hydrogen and methyl, k is an integer of 2-10, and the isopropenyl substituent on the aromatic ring is in the p-position or m-position.The polymerizable monomer can be used to prepare a high hardness transparent resin which in turn can be used to prepare a laminated transparent plastic material.
    Type: Grant
    Filed: January 5, 1995
    Date of Patent: September 19, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Noboru Kawasaki, Katsuyoshi Sasagawa, Toshiyuki Suzuki, Kenichi Fujii
  • Patent number: 5449829
    Abstract: A diphenylamine with both the phenyl groups being substituted is prepared by reacting a phenol with ammonia in the presence of a hydrogen transfer catalyst and a cyclohexanone; or by converting a portion of the phenol to the cyclohexanone in the presence of a hydrogen transfer catalyst and under hydrogen pressure and then reacting the remaining portion of the phenol with ammonia in the presence of the cyclohexanone so converted and the hydrogen transfer catalyst. The diphenylamine can be obtained very efficiently.
    Type: Grant
    Filed: June 15, 1994
    Date of Patent: September 12, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Chiyuki Kusuda, Masaru Wada, Teruyuki Nagata
  • Patent number: 5448037
    Abstract: A transparent panel heater which can be used for heating a window portion of liquid crystal displays, refrigerated showcases, freezer showcases, defrosters of windshields, and the like. The panel heater has a transparent substrate, a transparent conductive film formed on the substrate, a substantially light-transmittable metallic thin layer formed on the conductive film and a pair of electrodes for electrifying the conductive film. The metallic thin layer is preferably deposited by a dry process such as a sputtering process, an ion plating method, various CVD methods, and the like. The electrodes are preferably formed on the metallic thin layer by a wet plating method.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: September 5, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Mitsuo Takase, Nobuhiro Fukuda, Toshihiro Dodo, Shin Fukuda
  • Patent number: 5447901
    Abstract: A color-developing composition comprises a multi-valent-metal-modified salicylic acid resin (Resin A) and a polycondensation resin (resin B) at a weight ratio of 90-30 to 10-70. Resin A is composed of 5-35 mole % of a structural unit (I) and 65-95 mole % of at least one structural unit (II) or 65-95 mole % of a coupled structural unit of at least one unit (II) and at least one unit (III) and has a weight-average molecular weight of 350-5,000. Resin B is composed of the unit (II) and/or the unit (III) and has a weight-average molecular weight of 350-5,000. ##STR1## wherein Z represents M/m, M being a metal ion of m valence and m being an integer; R.sub.1 and R.sub.2 represent H or a C.sub.1-12 alkyl, aralkyl, aryl or cycloalkyl group; R.sub.3 and R.sub.6 represent H or a C.sub.1-4 alkyl group; and R.sub.4 and R.sub.5 represent H or CH.sub.3.
    Type: Grant
    Filed: August 26, 1994
    Date of Patent: September 5, 1995
    Assignee: Mitsui Toatsu Chemical, Inc.
    Inventors: Keizaburo Yamaguchi, Yoshimitsu Tanabe, Kiyoharu Hasegawa, Akihiro Yamaguchi
  • Patent number: 5447962
    Abstract: Foams comprising innumerable cells dispersed in thermoplastic polymer compositions substantially consisting of polylactic acid or a copolymer of lactic acid and hydroxycarboxylic acid and having degradable characteristics in the natural environment.The foams can be used for containers such as food trays and throw away cups comprising molded sheet foam of a thermoplastic and degradable polymer or heat insulating materials and cushioning materials comprising bulk foam.
    Type: Grant
    Filed: January 27, 1994
    Date of Patent: September 5, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masanobu Ajioka, Katashi Enomoto, Akihiro Yamaguchi, Kazuhiko Suzuki, Takayuki Watanabe, Yasuhiro Kitahara
  • Patent number: 5446142
    Abstract: The present invention provides a light-absorbing compound represented by the formula (I):Dye-(OR.sup.1)(OR.sup.2)(OR.sup.3) . . . (OR.sup.n) (I)wherein Dye is a light-absorbing compound residue having at least one aromatic ring; OR.sup.1 to OR.sup.n are substituents on the aromatic ring, and are independently (a) substituted or unsubstituted saturated hydrocarbonoxy groups having 1 to 20 carbon atoms, or (b) substituted or unsubstituted unsaturated hydrocarbonoxy groups having 2 to 20 carbon atoms, and at least one of OR.sup.1 to OR.sup.n is an unsaturated hydrocarbonoxy group; and n is a value of from 1 to 10. The present invention also provides an optical recording medium containing the above-mentioned light-absorbing compound in a recording layer.
    Type: Grant
    Filed: June 11, 1993
    Date of Patent: August 29, 1995
    Assignees: Mitsui Toatsu Chemicals, Inc., Yamamoto Chemicals, Inc.
    Inventors: Hisato Itoh, Takahisa Oguchi, Kenichi Sugimoto, Ryu Oi, Hideki Umehara, Shin Aihara
  • Patent number: 5446135
    Abstract: Dyes having the specific structural formula (1) set out below, their copper salt dyes, water-soluble azo dyes containing the dyes or the copper salt dyes, and polarizing films containing the water-soluble azo dyes: ##STR1## wherein A means a benzene or naphthalene ring having a sulfone group or a base thereof, Y and Z individually denote a group of the following formula (a); ##STR2## wherein R.sup.2 is a hydrogen atom, a methyl group, a methoxyl group or an ethoxyl group and R.sup.3 is a methyl, methoxyl or ethoxyl group,R.sup.1 represents an amino, C.sub.1-4 alkylamino, C.sub.2-4 alkylcarboxyamino, benzoylamino or phenylamino group bonded to the 6 or 7 position of the naphthalene ring, and X denotes a hydrogen, sodium, potassium or lithium atom, with the proviso that Y and Z are different but, when both R.sup.2 s are hydrogen atoms and both R.sup.3 s are methoxyl groups, Y and Z may be the same.
    Type: Grant
    Filed: March 14, 1994
    Date of Patent: August 29, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tsutami Misawa, Akira Ogiso, Rihoko Imai, Hisato Itoh
  • Patent number: 5444107
    Abstract: A degradable polymer composition essentially consisting of a mixture of a thermoplastic polymer composition primarily comprising polylactic acid or lactic acid-hydroxycarboxylic acid copolymer and one or more substance selected from starch and modified starch, and is a degradable polymer which does not cause problems such as environmental pollution and can be used for films, filaments and packaging materials, food packaging materials in particular.
    Type: Grant
    Filed: July 23, 1992
    Date of Patent: August 22, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masanobu Ajioka, Katashi Enomoto, Akihiro Yamaguchi, Hosei Shinoda
  • Patent number: 5443973
    Abstract: A culture liquid of microorganisms having an ability of producing .alpha.-hydroxyisobutylamide from acetone cyanhydrin or the cultivated cells of the microorganisms or the processed cells of them is/are reacted to acetone cyanhydrin in an aqueous medium to produce .alpha.-hydroxyisobutylamide. The amide is reacted with water and/or an aliphatic alcohol in the presence of a solid acid catalyst at a temperature of 150.degree. C. or higher in a gaseous phase or a gaseous-liquid mixed phase to produce an .alpha.,.beta.-unsaturated carboxylate or an aliphatic alcohol or an .alpha.,.beta.-unsaturated carboxylic acid.
    Type: Grant
    Filed: August 19, 1992
    Date of Patent: August 22, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kenichi Soshiwata, Masao Shimada, Akira Hatamori
  • Patent number: 5443957
    Abstract: A monoclonal antibody which reacts with glycolipid asialo GM1 but not with any of glycolipids GM1 and GM2 can be produced by hybridoma cells obtained by fusing antibody-producing cells of a mammal immunized with the glycolipid asialo GM1 with myeloma cells.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: August 22, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shizio Shimada, Tadashi Sudo, Daiji Iwata
  • Patent number: 5444143
    Abstract: A preparation process of polyhydroxycarboxylic acid having an inherent viscosity of 0.3 dl/g or more by dehydrating polycondensation of lactic acid containing hydroxycarboxylic acid in an organic solvent in the presence or absence of a catalyst, comprising using a hydroxycarboxylic acid raw material which comprises one or more impurities selected from the group consisting of methanol, ethanol, acetic acid, pyruvic acid, fumaric acid, methyl lactate, ethyl lactate and butyl lactate in a total amount of 0.3% by mole or less for the amount of said hydroxycarboxylic acid raw material.
    Type: Grant
    Filed: December 21, 1993
    Date of Patent: August 22, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masahiro Ohta, Shoji Obuchi, Yasunori Yoshida
  • Patent number: 5440008
    Abstract: A process for preparing polyhydroxycarboxylic acid by conducting dehydration polycondensation of hydroxycarboxylic acids in the presence or absence of a catalyst and in the presence or absence of an organic solvent, comprising using a vertical high viscosity reactor during all or a portion of the dehydration polycondensation steps and conducting hot polycondensation while separating and removing low boiling components. The process can provide high molecular weight polyhydroxycarboxylic acid with ease and cheaply in industry.
    Type: Grant
    Filed: May 19, 1994
    Date of Patent: August 8, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Fumiaki Ichikawa, Mineo Kobayashi, Masahiro Ohta, Yasunori Yoshida, Shoji Obuchi, Hiroyuki Itoh
  • Patent number: 5440358
    Abstract: The present invention relates to a high surface hardness transparent resin having excellent scratch resistance, heat resistance and chemical resistance, a glazing material, a protective cover for display devices, an optical lens and a hard coat material comprising the aforesaid resin, and a novel polymerizable monomer which is useful as a raw material of the above-mentioned resin.The monomer is represented by the formula (I) ##STR1## (wherein R is an aliphatic residue having or non having an halogen atom, an oxygen atom, an alicyclic ring, a heterocyclic ring or an aromatic ring, an alicyclic residue, or a heterocyclic residue, n is an integer of 1 to 4, when n=1, X is oxygen or sulfur, when n.gtoreq.
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: August 8, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Toshiyuki Suzuki, Katsuyoshi Sasagawa, Masao Imai, Yoshinobu Kanemura
  • Patent number: 5439994
    Abstract: A novel transition metal compound represented by the formula ##STR1## (wherein each of A.sup.1, A.sup.2, A.sup.3 and A.sup.4 is a cyclopentadienyl group, an indenyl group, a fluorenyl group or their derivative; A.sup.5 is a hydrocarbondiylidene group having 4 to 30 carbon atoms; a pair of A.sup.1 and A.sup.2 as well as a pair of A.sup.3 and A.sup.4 is respectively bonded to the identical carbon atom in A.sup.5 to form a crosslinking structure; each of R.sup.1 and R.sup.2 is a halogen atom, a hydrogen atom, an alkyl group or a silicon-containing alkyl group having 1 to 10 carbon atoms, an aryl group, an alkylaryl group, an arylalkyl group or a halogenated aryl group having 6 to 20 carbon atoms; R.sup.1 and R.sup.2 may be identical or different; each of M.sup.1 and M.sup.2 is titanium, zirconium or hafnium; and M.sup.1 and M.sup.2 may be mutually identical or different), and a method for polymerizing an olefin in the presence of this compound and a co-catalyst.
    Type: Grant
    Filed: July 20, 1994
    Date of Patent: August 8, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Norihide Inoue, Tetsunosuke Shiomura, Masahiro Kouno, Yoshiho Sonobe, Kazumi Mizutani