Patents Assigned to Mitsui Toatsu Chemicals, Incorporated
  • Patent number: 5053539
    Abstract: A methylene-crosslinked polyarylamine is disclosed which contains a less amount of N-methylmethylenedianiline. A process for continuously preparing this kind of methylene-crosslinked polyarylamine is also revealed which comprises reacting aniline with formalin in the presence of hydrochloric acid under specific reaction conditions.
    Type: Grant
    Filed: January 17, 1991
    Date of Patent: October 1, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Naoyuki Yano, Tatsuya Nagayoshi, Takashi Nagou, Zunzi Tashima, Noritoshi Ishida, Hiroyuki Itoh, Katsuyuki Nagamatsu
  • Patent number: 5049606
    Abstract: A thermosetting resin composition formed of a polyaminobismaleimide resin, which is composed of a bismaleimide compound and a diamine compound, and a solid lubricant. The composition has low coefficient of friction and excellent wear resistance, and can be utilized for self-lubricating parts.
    Type: Grant
    Filed: February 27, 1990
    Date of Patent: September 17, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Norimasa Yamaya, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5043277
    Abstract: Escherichia coli carrying a hybrid plasmid having been constructed by inserting a desired foreign gene into an expression vector so as to permitting expression of said desired foreign gene therein was cultured at a temperature 40.degree. C. or over so that the expression of said desired foreign gene was suppressed. This E. coli (i.e., transformant) was cultured at 40.degree. C. or over in a first process to suppress the expression of the foreign gene and to support sufficient cell growth and thereafter below 40.degree. C. in a second process to release the suppression of the expression so as to permit effective production of the foreign gene product, which resulted in high concentration of the foreign gene product in the final culture.
    Type: Grant
    Filed: February 17, 1988
    Date of Patent: August 27, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Nobuhiro Fukuhara, Setsuo Yoshino, Kaoru Yamamoto, Satori Sone, Maki Suzuki, Yoshiyuki Nakajima
  • Patent number: 5041464
    Abstract: A process for preparing polymer emulsion particles having pores therein, an outside diameter D of 0.1 to 5.0[ , an inside diameter d of 0.05 to 4.0.mu. , and a ratio (d/D) of 0.1 to 0.9 in dry condition, comprising the steps of forming core-shell emulsion particles from specific monomers by two-emulsion polymerizations, and swelling the core of the particles with water by hydrolyzing the vinyl acetate part of polymer (A), thereby inducing the hydroxyl groups therein, e.g., using an acidic material or a basic material at 50.degree. to 100.degree. C. The particles when use as a pigment in coating compositions provide excellent converage rate, brightness, gloss and water resistance.
    Type: Grant
    Filed: December 26, 1989
    Date of Patent: August 20, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Futoshi Hoshino, Takeshi Yanagihara, Makoto Nakano
  • Patent number: 5034016
    Abstract: Dyed denim cotton yarns capable of meeting the market demand for color jeans can be provided by immersing denim cotton yarns in a dye bath containing a dye or dye composition comprising a specific indirubin derivative(s), a specific quinophthalone derivative(s) and/or an indigo dye, squeezing and air-oxidizing the dyed yarns, and repeating a series of these steps.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: July 23, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Hitoshi Koshida, Tetsuo Sakagawa, Takayuki Nakayama, Hiroshi Suwa, Masao Imai, Akio Karasawa
  • Patent number: 5034209
    Abstract: Chlorine is produced by reacting hydrogen chloride and oxygen in the presence of a chromium oxide catalyst in a reactor whose catalyst-contacting part is lined with one of lining materials represented by the following general formula(I):M.sub.a X.sub.b (I)wherein M means boron, aluminum, silicon, titanium, zirconium or chromium, X denotes oxygen, nitrogen or carbon, a is an integer of 1-2 and b stands for an integer of 1-3 or with a mixture of at least two of the lining materials. The above process and reactor are effective in maintaining the activity of the catalyst.
    Type: Grant
    Filed: April 13, 1990
    Date of Patent: July 23, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masanobu Ajioka, Shinji Takenaka, Hiroyuki Itoh, Masafumi Kataita, Yoshitsugu Kohno
  • Patent number: 5028581
    Abstract: Odorless or absolutely ordorless multi-valent metal-modified salicylic acid. The former copolymers are obtained by condensing salicylic acid with a benzyl aldehyde, reacting the resultant resin with a styrene derivative and reacting the resin thus-obtained with a multivalent metal salt. The latter copolymers are obtained by adding water dropwise to the resultant multi-valvent metal-modified resin at a temperature above the boiling point of water to remove completely volatile matters.
    Type: Grant
    Filed: August 14, 1989
    Date of Patent: July 2, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Keizaburo Yamaguchi, Yoshimitsu Tanabe, Akihiro Yamaguchi
  • Patent number: 5028641
    Abstract: A thermosetting resin composition formed of a polyaminobismaleimide resin, which is composed of a bismaleimide compound and a diamine compound, and a powdery inorganic filler. The composition has excellent heat resistance as well as superb mechanical properties at high temperature not to mention room temperature, and is expected to find wide-spread commercial utility in electric and electronic components such as sealing materials, sockets and connectors and other applications.
    Type: Grant
    Filed: August 2, 1989
    Date of Patent: July 2, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Norimasa Yamaya, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5024926
    Abstract: Near-infrared absorbers which contain phthalocyanine derivatives in which the four benzene rings contained in the molecule independently have 1 to 4 substituents are light and thermal resistant and possess high molar extinction coefficients. Such near-infrared absorbers are useful in optical recording media, near-infrared absorption filters, and liquid crystal display devices.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: June 18, 1991
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Katashi Enomoto, Takahisa Oguchi, Tsutomu Nishizawa
  • Patent number: 5023343
    Abstract: There are here provided a novel tetraphenylthiophene derivative represented by the general formula ##STR1## wherein AM is a tertiary amino group, each of l, m and n is the integer 0 or 1 and l.gtoreq.m.gtoreq.n are useful as the charge-transporting material in an electrophotographic photoreceptor having an electrically conductive base and a photosensitive layer thereon containing a charge-transporting material and a charge-generating material, which preferably is an azo compound.
    Type: Grant
    Filed: July 16, 1990
    Date of Patent: June 11, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Eishi Tanaka, Tsutomu Nishizawa, Yasuyuki Yamada, Hisato Itoh, Akihiro Yamaguchi, Masakatsu Nakatsuka
  • Patent number: 5023366
    Abstract: Disclosed herein are salicylic acid copolymers having a weight average molecular weight of 500-10,000 and obtained (a) by condensing salicylic acid (i) with a benzyl alcohol (ii) and/or benzyl ether (iii) or a benzyl halide (iv) in the presence of an acid catalyst or (b) by reacting a co-condensation resin of (i) and (ii) and/or (iii) with (iv) or (c) by reacting a co-condensation resin of (i) and (ii) and/or (iii) or (iv) with a styrene derivative in the presence of an acid catalyst; multivalent metal salts of the salicylic acid copolymers; color-developing agents comprising the multivalent metal salts; and color-developing sheets suited for pressure-sensitive copying paper and comprising the color-developing agents. Their production processes are also disclosed.
    Type: Grant
    Filed: October 23, 1987
    Date of Patent: June 11, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Keizaburo Yamaguchi, Yoshimitsu Tanabe, Makoto Asano, Akihiro Yamaguchi
  • Patent number: 5015766
    Abstract: A molten Raney copper alloy containing copper and a metal selected from Al, Si and Zn as major components and, if necessary, specific metals as minor components is solidified at a cooling rate of not less than 1.times.10.sup.2 K/sec by a rotary water atomizing process, water or gas atomizing process, single roll process or similar process. The Raney copper alloy thus obtained is leached to obtain a Raney copper catalyst. The resultant catalyst exhibits activity several times higher than that of conventional Raney copper catalysts in the reaction of acrylonitrile with water to give acrylamide.
    Type: Grant
    Filed: December 15, 1988
    Date of Patent: May 14, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yoshihiko Kambara, Itsuo Oonaka, Koichi Asao, Kyoko Fukushima
  • Patent number: 5013848
    Abstract: A novel aromatic bismaleimide of the formula (I): ##STR1## wherein X is ##STR2## where R.sub.1 R.sub.2, R.sub.3 and R.sub.4 are a hydrogen atom or a methyl group. The bismaleimide is prepared by reacting an aromatic diamine having the formula (II): ##STR3## wherein X is the same as in the formula (I), with maleic anhydride and then conducting the ring-closing reaction of the resultant aromatic bismaleamic acid.
    Type: Grant
    Filed: July 22, 1987
    Date of Patent: May 7, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yukihiro Yoshikawa, Midori Yamazaki, Keizaburo Yamaguchi, Kenichi Sugimoto, Yoshimitsu Tanabe, Akihiro Yamaguchi
  • Patent number: 5011953
    Abstract: Disclosed herein is a method for preparing epichlorohydrins by reacting allyl chlorides with an alkyl hydroperoxide in the presence of a modified catalyst formed by substituting specific substituents for 1 to 50% of the silanol groups of a catalyst having titanium atoms bound to a silicon dioxide carrier via oxygen atoms and having on the same carrier 1 to 6 silanol groups per square nanometer thereof.
    Type: Grant
    Filed: November 8, 1989
    Date of Patent: April 30, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Takehisa Nakanishi, Eiji Koga, Isao Fukada
  • Patent number: 5008267
    Abstract: A pyrimidinedione derivative compound has a basic backbone in which a phenyl group part and a pyrimidinedione part are linked by a structure comprising an alkyl chain containing at least two nitrogen atoms. The pyrimidinedione derivative is useful for a medical treatment of cardiac arrhythmias.
    Type: Grant
    Filed: October 24, 1989
    Date of Patent: April 16, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tsutomu Katakami, Tatsuro Yokoyama, Michihiko Miyamoto, Haruki Mori, Nobuya Kawauchi, Tadahito Nobori, Kunio Sannohe, Joji Kamiya, Masaaki Ishii, Kanji Yoshihara
  • Patent number: 5002925
    Abstract: Disclosed are a novel compound represented by the formula ##STR1## a composition for sublimation transfer record containing the above-mentioned compound, and a composition for color toner containing the above-mentioned compound.
    Type: Grant
    Filed: April 14, 1989
    Date of Patent: March 26, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Keisuke Takuma, Tsukasa Ohyama, Akitoshi Igata, Tamio Mikoda, Isamu Ghoda, Hitoshi Koshida
  • Patent number: 5000006
    Abstract: A gaseous mixture containing chlorine, carbon dioxide and non-condensable gas is compressed and cooled to separate it into a residual gas formed principally of a major portion of the non-condensable gas and a condensate formed primarily of chlorine. The condensate is fed to a stripping column to desorb carbon dioxide and a minor portion of the non-condensable gas dissolved in the condensate. The stripped gas formed primarily of chlorine and carbon dioxide may be treated further. Namely, the stripped gas is mixed with the residual gas. At least a portion of the mixed gas is fed into an absorption column, whereby a major portion of remaining chlorine is absorbed to lower the chlorine content. Removal of chlorine from such a gaseous mixture or an off-gas from the above process can be achieved by washing it with an aqueous solution or suspension containing an alkali metal sulfite and/or an alkaline earth metal sulfite while controlling the pH of the solution or suspension within a range of 1.9-6.3.
    Type: Grant
    Filed: February 16, 1989
    Date of Patent: March 19, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Hiroyuki Itoh, Yoshitsugu Kono, Isao Kikuchi, Shinji Takenaka, Masanobu Ajioka, Mitsuo Kudoh
  • Patent number: 5001031
    Abstract: An electrophotographic toner composition is provided. It contains a vinyl polymer having a number average molecular weight of 1,000-10,000, a weight average molecular weight/number average molecular weight ratio of 41-200, a glass transition temperature of 50.degree.-70.degree. C., and specific shear rates at 110.degree. C. and 190.degree. C. respectively. The toner composition affords vivid copy marks even when used in a small amount, and exhibits good fixing property even at low temperatures.
    Type: Grant
    Filed: September 14, 1988
    Date of Patent: March 19, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Takashi Yamamoto, Masaaki Shin
  • Patent number: 4997874
    Abstract: An aqueous suspension of a multivalent-metal-modified salicylic acid resin, which is suitable for use in the production of color-developing sheets for pressure-sensitive recording paper sheets, contains a specific multivalent-metal-modified salicylic acid resin at the first-mentioned resin. Fine particles of the specific multivalent-metal-modified salicylic acid is dispersed in an aqueous solution of a dispersant composed of at least one compound selected from the group consisting of:(a) water-soluble anionic high-molecular compounds composed of polyvinyl alcohol derivatives containing sulfonic acid groups in their molecules, and salts thereof,(b) acrylamide-modified polyvinyl alcohols, and(c) water-soluble anionic high-molecular compounds composed of polymers or copolymers comprising particular styrenesulfonic acid derivatives as their essential components.The aqueous dispersion is prepared by finely grinding the specific multivalent-metal-modified salicylic acid in the aqueous solution of the dispersant.
    Type: Grant
    Filed: March 17, 1988
    Date of Patent: March 5, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Makoto Asano, Kiyoharu Hasegawa, Masatoshi Takagi, Akihiro Yamaguchi, Keizaburo Yamaguchi, Yoshimitsu Tanabe, Hiroyuki Akahori
  • Patent number: 4994586
    Abstract: A novel method for preparing an epoxy compound is disclosed which comprises the step of reacting an olefin compound having 4 to 16 carbon atoms with an organic hydroperoxide in an inactive solvent in the presence of a molybdenum compound and at least one metal halide selected from the group consisting of halides of alkali metals and alkaline earth metals, in order to form the corresponding epoxy compound. Typical examples of the aforesaid metal halide include sodium chloride, potassium iodide, sodium bromide and barium chloride. According to the present invention, the epoxy compound having 4 to 16 carbon atoms can be prepared in an extremely high yield.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: February 19, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Nobumasa Arashiba, Takashi Shimizu, Masaru Takeshita, Akira Otsu