Patents Assigned to Mitsui Toatsu Chemicals, Incorporated
  • Patent number: 4956169
    Abstract: Chlorine is produced by reacting hydrogen chloride and oxygen in the presence of a chromium oxide catalyst in a reactor whose catalyst-contacting part is lined with one of lining materials represented by the following general formula (I):M.sub.a X.sub.b (I)wherein M means boron, aluminum, silicon, titanium, zirconium or chromium, X denotes oxygen, nitrogen or carbon, a is an integer of 1-2 and b stands for an integer of 1-3 or with a mixture of at least two of the lining materials. The above process and reactor are effective in maintaining the activity of the catalyst.
    Type: Grant
    Filed: March 18, 1988
    Date of Patent: September 11, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masanobu Ajioka, Shinji Takenaka, Hiroyuki Itoh, Masafumi Kataita, Yoshitsugu Kohno
  • Patent number: 4954571
    Abstract: The invention provides a rubber dispersed copolymer resin having excellent heat resistance, impact strength and moldability and composed of (1) a dispersed phase formed of a rubbery polymer and copolymerized styrene-type, acrylonitrile-type and maleimide-type monomers, said rubbery polymer specificaly controlled occluding the copolymer of monomers, being grafted with the copolymer and/or forming a multicomponent gel together with copolymers, and (2) a continuous phase formed at least of a specifically controlled copolymer of the styrene-type, acrylonitrile-type and maleimide-type monomers. The resin is useful as a molding material for electric appliances, electronic equipment and cars.
    Type: Grant
    Filed: September 26, 1988
    Date of Patent: September 4, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Mune Iwamoto, Norifumi Ito, Sugazaki: Kazuo, Tetsuyuki Matsubara, Toshihiko Ando
  • Patent number: 4954410
    Abstract: A novel negative charge color toner composition for electrostatic charge development having good light resistance and copy sharpness which contains, as a dyestuff in a toner resin, a 1-amino-2-phenoxy- or 2-thiophenoxy-4-hydroxyanthraquinone whose phenoxy or thophenoxy group is substituted and/or a 1,4-diamino-2,3-phenoxyanthraquinone whose phenoxy group is substitited, which can be conventionally produced.
    Type: Grant
    Filed: February 24, 1989
    Date of Patent: September 4, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Keisuke Takuma, Tsukasa Ohyama, Isamu Ghoda, Tamio Mikoda, Hitoshi Koshida, Akitoshi Igata
  • Patent number: 4952717
    Abstract: Disclosed herein are phosphoric acid esters of myoinositol, which are represented by the following general formula (I): ##STR1## and their salts, as well as a preparation process thereof. The myoinositol derivatives can each be obtained by causing a phosphorylating agent to act on a myoinositol derivative substituted with catalytic reduction removable substituent groups at the positions other than those desired to be substituted by phosphoric acid residual groups and then catalytically reducing the thus-phosphorylated myoinositol.
    Type: Grant
    Filed: October 20, 1987
    Date of Patent: August 28, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Shoichiro Ozaki, Yutaka Watanabe, Akira Awaya, Yusaku Ishizuka
  • Patent number: 4952648
    Abstract: Disclosed herein are novel multivalent metal-modified salicyclic acid resins useful as color-developing agents for pressure-sensitive copying paper. They can each be produced by causing a salicyclic acid ester and a styrene derivative to undergo a Friedel-Crafts reaction in the presence of a strong acid catalyst, hydrolyzing the resulting salicylic acid ester resin, and then reacting the thus-obtained salicyclic acid resin with a multivalent metal salt.
    Type: Grant
    Filed: August 4, 1988
    Date of Patent: August 28, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Keizaburo Yamaguchi, Yoshimitsu Tanabe, Akihiro Yamaguchi
  • Patent number: 4948772
    Abstract: Substantially flat surfaced emulsion particles polymerized vinyl monomer, having a concavity in at least one of the flat surfaces, a diameter D of from 0.1 to 5.0 .mu.m, and a particle diameter thickness d ratio (d/D) of 1.2 to 5.0, prepared by the step of (1) aqueous emulsion polymerizing a first vinyl monomer or mixture of monomers (a) to form vinyl polymer seed particles; and (2) aqueous emulsion polymerizing a second vinyl monomer or mixture of monomers (b) in the presence of the vinyl polymer seed particles and a non-aqueous organic solvent having a surface tention to water at 20.degree. C. of 48 dyne/cm or more, in a weight ratio of monomer (a) to monomer (b) of 0.5/99.5 to 50/50; and are useful in high performance recording material, paint compositions and paper coating compositions.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: August 14, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Futoshi Hoshino, Makoto Nakano, Takeshi Yanagihara
  • Patent number: 4943594
    Abstract: Thermoplastic polyimide foams are provided which essentially consist of recurring units represented by the formula (I): ##STR1## wherein X is a bond, divalent hydrocarbon radical having from 1 to 10 carbon atoms etc. and R is an aliphatic radical having 2 or more carbon atoms, cycloaliphatic radical etc.The foams have an apparent density of from 0.02 to 0.2 g/cc, average cell diameter of 0.1 to 1 mm and a closed cell content of 50% or more.
    Type: Grant
    Filed: December 19, 1989
    Date of Patent: July 24, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Hiroshi Ezawa, Toshiyuki Nakakura, Takayuki Watanabe, Hiroaki Tsushima
  • Patent number: 4939306
    Abstract: A novel compound, 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol, and a novel preparation process of 4,4'-biphenol by using the novel compound as the raw material.4-(4-Hydroxyphenyl)-3-cyclohexene-1-ol can be obtained by conducting a thermal decomposition reaction of 4,4-bis(4-hydroxyphenyl)cyclohexanol. 4,4'-Biphenol can be industrially manufactured by conducting a dehydrogenation reaction of 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol.
    Type: Grant
    Filed: April 14, 1989
    Date of Patent: July 3, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tohru Miura, Teruyuki Nagata, Koju Okazaki, Masayuki Furuya, Emiko Nishida
  • Patent number: 4937393
    Abstract: In the manufacturing method of ethylene glycol and/or propylene glycol, these glycols can be prepared with a highly selectivity and at a high yield by applying the catalyst comprising a carboxylic acid and a carboxylic acid salt or a metal salt of formic acid alone.
    Type: Grant
    Filed: May 17, 1988
    Date of Patent: June 26, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Takayoshi Masuda, Katuyoshi Asano, Naomi Hori, Shinji Ando
  • Patent number: 4937353
    Abstract: Disclosed herein is to react an aniline and an ethylene glycol at a superatmospheric pressure in preparing an indole by subjecting the aniline and ethylene glycol to a gas-phase catalytic reaction in the presence of a catalyst, thereby improving the selectivity of the reaction and the service life of the catalyst.
    Type: Grant
    Filed: November 3, 1988
    Date of Patent: June 26, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Akihide Kudoh, Tadatoshi Honda, Makoto Kotani, Kazuhiro Terada, Takeshi Tsuda, Shinji Kiyono
  • Patent number: 4937339
    Abstract: In a process for preparing isocyanurate ring-containing materials useful in the production of lacquers and foams which comprises trimerizing an organic isocyanate compound in the presence of a catalyst, the use of potassium fluoride as the catalyst makes it possible to yield the desired product rapidly without formation of by-products. More preferably, the reaction efficiency can further be enhanced by using a polyethylene oxide compound, a quaternary ammonium salt and/or a phosphonium compound in combination with potassium fluoride.
    Type: Grant
    Filed: December 16, 1988
    Date of Patent: June 26, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tetsunosuke Shiomura, Yoshiho Sonobe, Akihiro Yamaguchi, Ryuzi Haseyama
  • Patent number: 4933158
    Abstract: There is here disclosed a method for removing nitrous oxide (N.sub.2 O), carbon dioxide (CO.sub.2) and dinitrogen difluoride (N.sub.2 F.sub.2) from a nitrogen trifluoride gas. The present invention is directed to a method for purifying a nitrogen trifluoride gas which comprises the steps of thermally treating, at a temperature of 250.degree. to 700.degree. C., a zeolite selected from the group consisting of analcime, clinoptilolite, mordenite, ferrierite, phillipsite, chabazite, erionite and laumotite; forming a packed bed of the treated zeolite; and passing the nitrogen trifluoride gas containing the gaseous impurities at a temperature of -125.degree. to 50.degree. C. through the filler layer.
    Type: Grant
    Filed: October 24, 1989
    Date of Patent: June 12, 1990
    Assignees: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Makoto Aritsuka, Naruyuki Iwanaga
  • Patent number: 4931531
    Abstract: This invention relates to a novel polyimide which is high-temperature resistant and capable of being molded in a fused state. This invention also relates to a high-temperature adhesive using the polyimide.The polyimide consists essentially of recurring units of the formula: ##STR1## where R is a tetra-valent radical selected from the group consisting of an aliphatic radical having 2 or more carbon atoms, alicyclic radical, monoaromatic radical, condensed polyaromatic radical, and non-condensed polyaromatic radical wherein aromatic radicals are linked to one another directly or via a bridge member.The polyimide can be prepared by reacting bis[4-(4-aminophenoxy)phenoxy)phenyl] sulfone with a tetracarboxylic dianhydride in an organic solvent and imidizing the resultant polyamic acid.
    Type: Grant
    Filed: June 24, 1988
    Date of Patent: June 5, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Shoji Tamai, Masahiro Ohta, Saburo Kawashima, Katsuaki Iiyama, Hideaki Oikawa, Akihiro Yamaguchi
  • Patent number: 4928438
    Abstract: This invention provides a wafer processing film comprising a base film having a Shore D hardness of 40 or less and an adhesive layer disposed on one surface of the base film. In grinding the surfaces of wafers such as silicon and similar wafers, breakage can be prevented by affixing the wafers to the adhesive layer of the processing film and then grinding them.
    Type: Grant
    Filed: May 26, 1988
    Date of Patent: May 29, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Osamu Narimatsu, Michiyasu Ito, Kazuyoshi Komatsu, Yasuhiro Shibata
  • Patent number: 4923951
    Abstract: An aromatic polyamide is produced by subjecting an aromatic diisocyanate and an aromatic dicarboxylic acid to polycondensation in the presence of an alkali metal compound and/or an alkaline earth metal compound as a catalyst in an aprotonic polar solvent. The aromatic polyamide can be rendered suitable for use in the production of high-tenacity fibers by charging in advance the solvent, aromatic dicarboxylic acid and catalyst in a mixing system, reducing the water content in the mixing system to at least 50 ppm and then introducing the aromatic diisocyanate to conduct the polycondensation.
    Type: Grant
    Filed: February 7, 1989
    Date of Patent: May 8, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tadashi Kobayashi, Shouji Obuchi, Hiroaki Matsuno, Mitsuo Wada, Hiroshi Takayanagi
  • Patent number: 4921933
    Abstract: Aromatic polyamide having good high-temperature resistance and processing ability is obtained by specifying the ratio of storage modulus at the glass transition temperature (Tg).degree.C. to that of (Tg+100).degree.C.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: May 1, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masanori Osawa, Kohei Shizuka, Masahiro Kouno, Akio Matsuyama, Hirotoshi Katsuoka, Kazumi Mizutani
  • Patent number: 4921905
    Abstract: A block copolymer of propylene can be obtained with its quality controlled uniform by conducting at first continuous polymerization of propylene in a polymerization system, receiving a polymer slurry, which has been discharged continuously from the polymerization system, in a batchwise polymerization tank, feeding ethylene to the tank to conduct batchwise polymerization of ethylene and propylene. Upon discharge of a copolymer slurry formed by the preceding batchwise polymerization, at least a predetermined amount of unreacted ethylene is left over in the tank. Into the tank with the unreacted ethylene still left over therein, there are simultaneously charged the polymer slurry from the polymerization system and a deactivator. During this charging, ethylene is not supplied.
    Type: Grant
    Filed: June 1, 1988
    Date of Patent: May 1, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Ichiro Fujio, Kaneo Ito, Tadashi Asanuma
  • Patent number: 4922005
    Abstract: Hexamethylene diisocyanate (HDI) is prepared by introducing a hexamethylenediamine (HDA) solution and an equivalent amount or more of hydrogen chloride gas simultaneously into a turbulent zone in the vicinity of an agitating blade in an inert organic solvent held under agitation within a tank-shaped reactor and allowing them to undergo a successive salt-forming reaction so as to obtain a high-concentration slurry of hexamethylenediamine hydrochloride (HDA.multidot.HCl) and then reacting the slurry with phosgene. The phosgenation is effected by charging an HDA.multidot.HCl slurry of a high concentration, such as that obtained by the above process, into a tank-shaped reactor held under a pressure above the atmosphere pressure but below 5 kg/cm.sup.2 G and controlling the amount of phosgene, which is to be blown into the reactor, at a level 1-18 molar times per hour the total amount of HDA.multidot.HCl and HDI in the reaction mixture.
    Type: Grant
    Filed: November 13, 1985
    Date of Patent: May 1, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masanobu Ajioka, Makoto Aiga, Masafumi Kataita, Akihiro Tamaki
  • Patent number: 4918216
    Abstract: .alpha.-L-aspartyl-L-phenylalanine methyl ester or the hydrohalide thereof is prepared by esterifying .alpha.-L-aspartyl-L-phenylalanine or .alpha.-L-aspartyl-L-phenylalanine which has been formed in situ by treating an N-protected-.alpha.-L-aspartyl-L-phenylalanine in an aqueous solution of sulfuric acid or a methanol-containing aqueous solution of sulfuric acid in the presence of an alkali metal halide or alkaline earth metal halide in a medium composed of sulfuric acid, water and methanol, thereby to allow the resulting .alpha.-L-aspartyl-L-phenyl-alanine methyl ester to precipitate as its corresponding hydrohalide, and then isolating the hydrohalide; and when the preparation of the methyl ester is desired, neutralizing the hydrohalide.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: April 17, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Ryuichi Mita, Toshio Katoh, Chojiro Higuchi, Takeshi Oura, Akihiro Yamaguchi
  • Patent number: 4906277
    Abstract: Novel 3-substituted phenyl-2-isoxazoline-5-carboxylic acids or esters thereof. These compounds have excellent properties as plant growth regulators.
    Type: Grant
    Filed: February 24, 1989
    Date of Patent: March 6, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Kengo Oda, Tsutomu Ishii, Yukiharu Fukushi, Yuji Enomoto, Makoto Nishida, Yoshikata Hojo