Patents Assigned to Mitsui
  • Patent number: 6325571
    Abstract: A particulate object conveying apparatus for conveying particulate objects of indefinite shape, e.g., particulate polycrystalline silicon, one by one, comprises: a stagnating portion for stagnating particulate objects; a rotor having a plural number of grooves formed in and equidistantly arrayed on its outer circumference surface, when ascending, the grooves passing the stagnating portion; and object driving-out means for driving the particulate object out of each groove of the rotor.
    Type: Grant
    Filed: August 11, 2000
    Date of Patent: December 4, 2001
    Assignee: Mitsui High-Tec Inc.
    Inventors: Migaku Ishida, Akikazu Higuchi
  • Patent number: 6322904
    Abstract: A copper foil having improved resistance to abrasion damage during the manufacture of printed circuit boards has a uniform deposit of benzotriazole (BTA) or BTA derivative, optionally a mixture thereof, of at least about 5 mg/m2.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: November 27, 2001
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Makoto Dobashi, Hiroaki Kurihara, Toshiko Yokota, Hiroshi Hata, Naotomi Takahashi, Tatsuya Sudo
  • Patent number: 6323150
    Abstract: Disclosed is a process for preparing a solid titanium catalyst component, comprising the steps of (I) contacting a liquid magnesium compound with a liquid titanium compound to precipitate a solid in the contact liquid (&bgr;), and adding an electron donor (d-i) selected from the group consisting of a polycarboxylic ester and a polyether compound to the contact liquid (&bgr;) during the time from beginning to end of the solid precipitation, to form a solid product (&agr;); and (II) contacting the solid product (&agr;) obtained after completion of the solid precipitation with an electron donor (d-ii) selected from the group consisting of a polycarboxylic ester and a polyether compound, to prepare a solid titanium catalyst component. According to the process, a solid titanium catalyst component capable of polymerizing an olefin with high activity and capable of preparing an olefin polymer of high stereoregularity can be prepared.
    Type: Grant
    Filed: August 10, 1998
    Date of Patent: November 27, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Shinichi Kojoh, Tsuneo Yashiki, Kazumitsu Kawakita, Masao Nakano, Sadahiko Matsuura
  • Publication number: 20010042686
    Abstract: An object of the invention is to provide a method for continuously producing electrodeposited copper foil while thiourea-decomposed products remaining in copper electrolyte are removed through activated carbon treatment. Another object is to provide high-resistivity copper foil obtained through the method.
    Type: Application
    Filed: April 20, 2001
    Publication date: November 22, 2001
    Applicant: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Kazuko Taniguchi, Makoto Dobashi, Hisao Sakai, Yasuji Hara
  • Publication number: 20010042688
    Abstract: The present invention provides a filtration method of copper electrolyte that can remove minute electrolytic by-products and dirt and may improve filtration efficiency by improving a conventional filtration method, the so-called precoating method. In a filtration method of copper electrolyte for removing electrolytic by-products and dirt which affect copper electrolysis, by passing copper electrolyte through a filter element precoated with a filtering aid, in the present invention, a precoated layer of a filtering aid is formed on a filter element in advance. Activated carbon preliminary treatment solution containing powdery activated carbon is passed through the filter element formed with the precoated layer, and is also circulated until no powdery activated carbon leaks from an outlet of the filter element, thus forming a powdery activated carbon layer on the precoated layer. Subsequently, the copper electrolyte is passed through for filtration.
    Type: Application
    Filed: April 20, 2001
    Publication date: November 22, 2001
    Applicant: MITSUI MINING & SMELTING CO., LTD.
    Inventors: Kazuyoshi Nabekura, Yutaka Hirasawa, Naotomi Takahashi
  • Patent number: 6319620
    Abstract: This invention provides a composite foil comprising an organic release layer between a metal carrier layer and an ultra-thin copper foil, and a process for producing such composite foils comprising the steps of depositing the organic release layer on the metal carrier layer and then forming an ultra-thin copper foil layer on said organic release layer, preferably by electrodeposition. The organic release layer preferably is a heterocyclic compound selected from triazoles, thiazoles, imidazoles, or their derivatives, and provides a uniform bond strength which is adequate to prevent separation of the carrier and ultra-thin copper foil during handling and lamination, but which is significantly lower than the peel strength of a copper/substrate bond, so that the carrier can easily be removed after lamination of the composite foil to an insulating substrate. The invention also includes laminates made from such composite foils and printed wiring boards made from such laminates.
    Type: Grant
    Filed: March 16, 1998
    Date of Patent: November 20, 2001
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Takashi Kataoka, Yutaka Hirasawa, Takuya Yamamoto, Kenichiro Iwakiri
  • Patent number: 6320014
    Abstract: Disclosed are polyester pellets made of a polyester which comprises dicarboxylic acid constituent units derived from dicarboxylic acids containing terephthalic acid and isophthalic acid and diol constituent units derived from diols containing ethylene glycol and 1,3-bis(2-hydroxyethoxy)benzene, and which has the properties: constituent units derived from terephthalic acid are 15 to 99.5% by mol and constituent units derived from isophthalic acid are 0.5 to 85% by mol, both based on the total amount of dicarboxylic acid isophthalic acid constituent units (i); constituent units derived from ethylene glycol are 25 to 99.5% by mol and constituent units derived from 1,3-bis(2-hydroxyethoxy)benzene are 0.5 to 75% by mol, both based on the total amount of the diol constituent units (ii); the intrinsic viscosity is in the range of 0.5 to 1.5 dl/g; and the melting point (Tm (°C.)), as measured by a differential scanning calorimeter, satisfies the formula [1/527−0.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: November 20, 2001
    Assignee: Mitsui Chemicals INC
    Inventors: Koji Takahashi, Koji Nakamachi, Hiroji Niimi, Shoji Hiraoka, Masayuki Sakai, Hitoshi Tsuboi
  • Patent number: 6320020
    Abstract: A sulfur-containing (thio)ether (co)polymer comprising repetitive structural units represented by general formulas 1 and 2, and an optical element using the (co)polymer: where A and B are bivalent organic group; R1 and R2 are hydrogen or alkyl; X1 to X4 are oxygen or sulfur; Y1 and Y2 are halogen, hydroxy, —OR3 or —SR4, in which R3 is sulfur-containing alkyl, aryl, heterocycle or acyl optionally having a substituent other than SH; and R4 is alkyl, aryl, heterocycle or acyl; provided that —OR3 and/or —SR4 constitute 10 to 100% of the total of Y1+Y2. The (co)polymer exhibits good optical, mechanical and thermal properties and a higher refractive index, and may be prepared in a good productivity. The sulfur-containing (thio)ether (co)polymer is useful for manufacturing a variety of optical elements.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: November 20, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Keisuke Takuma, Kenichi Sugimoto, Atsuo Otsuji, Rihoko Suzuki, Kenichi Fujii, Masao Imai
  • Patent number: 6320078
    Abstract: In the case that a selectively monoacylated phenylenediamine derivative which is useful as any of medicines, agricultural chemicals, animal drugs and the intermediates of chemicals is prepared by reacting a benzoic acid derivative with a phenylenediamine derivative, the benzoic acid derivative is converted into a benzoyl imidazole derivative and this benzoyl imidazole derivative is then reaction with the phenylenediamine derivative, whereby the improvement of a preparation efficiency and the high selectivity of the monoacylation can be achieved, the steps of protection and deprotection being omitted.
    Type: Grant
    Filed: July 23, 1999
    Date of Patent: November 20, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tsuneji Suzuki, Tomoyuki Ando, Katsutoshi Tsuchiya, Hiroki Ishibashi
  • Patent number: 6319961
    Abstract: The present invention provides an ethylene resin foamed product containing uniform cells and having excellent appearance, toughness and flexibility. The ethylene resin foamed product comprises an ethylene/&agr;-olefin copolymer having the following properties: the density is in the range of 0.880 to 0.940 g/cm3; the melt flow rate (MFR) at 190° C. under a load of 2.16 kg is in the range of 0.1 to 20 g/10 min; the decane-soluble component fraction (W) at room temperature and the density (d) satisfy the relation W<80×exp(−100(d−0.88))+0.1 in case of MFR≦10 g/10 min and the relation W<80×(MFR-9)0.26×exp(−100(d−0.88))+0.1 in case of MFR>10 g/10 min; and the temperature (TM) at the maximum peak position in the endothermic curve as measured by a differential scanning calorimeter and the density (d) satisfy the relation Tm<400×d−250.
    Type: Grant
    Filed: September 19, 2000
    Date of Patent: November 20, 2001
    Assignee: Mitsui Chemicals INC
    Inventor: Mamoru Takahashi
  • Patent number: 6319986
    Abstract: A semiaromatic polyamide resin composition comprising: (A) a polyamide copolymer in which a main constituent component unit is a polyamide formed of a recurring unit of a dicarboxylic acid component unit and a diamine component unit, at least not less than 45 mol % of said dicarboxylic acid component unit being a terephthalic acid component unit, and said diamine component unit comprising a straight-chain alkylenediamine component unit and/or an alkylenediamine component unit having a side-chain alkyl group; (B) an aliphatic polyamide containing, a unit derived from a lactam having 12 carbon atoms, a unit derived from an aminocarboxylic acid having 12 carbon atoms or a unit derived from a dodecanoic diacid and a diamine; and (C) a graft-modified product of a graft-modified ethylene/&agr;-olefin copolymer, a graft-modified product of an aromatic vinyl compound/conjugated diene copolymer, or a graft-modified product of a hydrogenated product of the aromatic vinyl compound/conjugated diene copolymer.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: November 20, 2001
    Assignee: Mitsui Chemicals
    Inventors: Yoshikatsu Amimoto, Yoshimasa Ogo, Masayuki Sakka
  • Patent number: 6316677
    Abstract: A process for the production of a bisphenol compound comprising: a step for reacting a phenolic compound (a) with at least one compound (b) selected from the group consisting of dialkenylbenzene compounds, bis(hydroxyalkyl)benzene compounds and (hydroxyalkyl)-alkenylbenzene compounds or at least one compound (c) selected from the group consisting of monoalkenylphenolic compounds and mono(hydroxyalkyl)phenolic compounds in the presence of an acidic catalyst to obtain a reaction mixture containing said bisphenol compound, a step for neutralizing the reaction mixture with an anion exchange resin, a step for removing a remaining phenolic compound from the reaction mixture to concentrate the neutralized reaction mixture, and a step for isolating the bisphenol compound from the resulting concentrated mixture. This process enables to produce a bisphenol compound, which is useful for preparing raw materials of thermoplastic polymers, surface-active agents and stabilizers.
    Type: Grant
    Filed: March 16, 1999
    Date of Patent: November 13, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masahiro Enna, Naoshi Nagai, Toshiyuki Isaka
  • Patent number: 6315918
    Abstract: Non-aqueous electrolytic solutions for capacitors which release a little gas, have excellent potential window of electrochemical stability and enable capacitors to show excellent charging/discharging cycle properties and safety performance, and capacitors containing such non-aqueous electrolytic solutions. The non-aqueous electrolytic solution for capacitors comprises an electrolytic solution containing at least one cyclic carbonic ester selected from specified compounds and an electrolyte.
    Type: Grant
    Filed: September 11, 1998
    Date of Patent: November 13, 2001
    Assignees: Mitsui Chemicals Inc., Matsushita Electric Industrial Co., Ltd.
    Inventors: Satoko Mita, Tsuneaki Koike, Takeshi Ishitoku, Tatsuyoshi Ishida, Yoshinori Takamuku, Hideki Shimamoto
  • Patent number: 6313243
    Abstract: The present invention is intended to provide an olefin polymerization catalyst exhibiting excellent olefin polymerization activity and capable of producing polyolefins of excellent properties and to provide a process for olefin polymerization using this catalyst.
    Type: Grant
    Filed: February 15, 2000
    Date of Patent: November 6, 2001
    Assignee: Mitsui Chemicals INC
    Inventors: Yasushi Tohi, Shigekazu Matsui, Terunori Fujita
  • Patent number: 6312622
    Abstract: Composite nickel fine powder comprises metal nickel fine particles, at least one member attached to the surface of the fine particles and selected from the group consisting of oxides and double oxides containing at least one metal element selected from the group consisting of the Groups 2 to 14 of the Periodic Table and whose atomic number falls within the range of from 12 to 82, and a saturated or unsaturated fatty acid supported on the surface of the nickel fine particles provided thereon with the oxide and/or double oxide attached thereto. The composite nickel fine powder is excellent in resistance to heat shrinkage, has a high tap density, and has characteristic properties suitable for use as a material for making a conductive paste.
    Type: Grant
    Filed: October 31, 2000
    Date of Patent: November 6, 2001
    Assignee: Mitsui Mining and Smelting Co., Ltd.
    Inventors: Yoshiharu Toshima, Takayuki Araki, Yasuhide Yamaguchi
  • Patent number: 6313226
    Abstract: An olefinic resin composition having the specific range of density, melt flow rate (MFR), viscoelastic properties and melt tension is obtained. The composition comprises (A) a polyethylene, (B) an ethylene/&agr;-olefin copolymer having the MFR of 0.1 to 10, and (C) an ethylene/&agr;-olefin copolymer or a propylene/&agr;-olefin copolymer having the MFR of 20 to 200. When the composition is processed by calendering, its feed to the rolls and take-up from the rolls are satisfactory, and high-speed formation of sheets having high accuracy in thickness is possible. The compounding of a fire retardant and a foaming agent to the composition enables fire-retardant foamed sheets being bulky and giving a good feel to be obtained. The lamination of these sheets onto the paper substrate is suitable for wall paper.
    Type: Grant
    Filed: February 23, 2000
    Date of Patent: November 6, 2001
    Assignee: Mitsui Chemicals Inc.
    Inventors: Naoto Yasaka, Takanori Sueda
  • Patent number: 6313194
    Abstract: A method for degrading a polymer by bringing same into contact with a solid phase composed of a carrier, a microorganism and an aqueous solution. The aqueous solution contains nutrients required for the growth of the microorganism and water. The carrier has a maximum water retention of at least 40 wt. % but at most 4,000 wt. %, the aqueous solution is retained in the carrier in an amount of at least 10% but at most 100% of the maximum water retention of the carrier, and the solid phase has a percentage of interstices of 25% or greater but smaller than 100%.
    Type: Grant
    Filed: October 4, 1996
    Date of Patent: November 6, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tadashi Yagi, Kazuto Ishihara, Takeshi Irimajiri
  • Publication number: 20010036420
    Abstract: A tin-silver-based soldering alloy, comprises 3.0 to 4.0% by weight of Ag, 6.05 to 10.0% by weight of In, 2.0 to 5.95% by weight of Bi, and the balance being Sn, wherein In+Bi≦12.0% by weight.
    Type: Application
    Filed: June 5, 2001
    Publication date: November 1, 2001
    Applicant: MITSUI MINING & SMELTING COMPANY, LTD.
    Inventors: Junichi Matsunaga, Yuunosuke Nakahara, Ryuji Ninomiya
  • Patent number: 6309997
    Abstract: The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal compound useful for the catalyst, and an &agr;-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc.
    Type: Grant
    Filed: April 24, 1998
    Date of Patent: October 30, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Terunori Fujita, Yasushi Tohi, Makoto Mitani, Shigekazu Matsui, Junji Saito, Masatoshi Nitabaru, Kiyoaki Sugi, Haruyuki Makio, Toshiyuki Tsutsui
  • Patent number: 6310147
    Abstract: An epoxy-resin composition comprising (A) an at least bifunctional epoxy compound and/or an at least bifunctional epoxy resin, (B) an at least bifunctional ester-containing compound and/or an at least bifunctional ester-containing resin as a curing agent, 10 to 100% of whose hydroxy groups are esterified with aliphatic or aromatic acyl groups, and (C) an accelerating agent, the accelerating agent essentially containing a phosphine oxide represented by general formula (1): where R1 to R6 all of which may be the same or not are hydrogen, straight, branched or cyclic alkyl having 1 to 10 carbons or aryl or aralkyl having 6 to 10 carbons.
    Type: Grant
    Filed: May 17, 1999
    Date of Patent: October 30, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tatsuhiro Urakami, Kenichi Sugimoto, Takuo Tajima, Koutaro Suzuki, Keisuke Takuma, Tadahito Nobori, Usaji Takaki