Patents Assigned to Mitsui
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Publication number: 20010033940Abstract: A poly-4-methyl-1-pentene resin laminate excellent in not only heat sealing properties and oxygen gas permeability but also blocking resistance is provided. The poly-4-methyl-1-pentene resin laminate comprises a layer made of a 4-methyl-1-pentene polymer (A), an intermediate layer made of an adhesive resin composition (B) and a layer made of a propylene polymer composition (C) comprising 60 to 90 parts by weight of a propylene polymer (c-1) and 10 to 40 parts by weight of a 1-butene polymer (c-2), the total amount of said components (c-1) and (c-2) being 100 parts by weight. This poly-4-methyl-1-pentene resin laminate can be used as a material of freshness-keeping packaging media and culture containers. Also provided is a poly-4-methyl-1-pentene resin laminate having excellent peel resistance and capable of being easily controlled in the oxygen gas permeability.Type: ApplicationFiled: May 31, 2001Publication date: October 25, 2001Applicant: Mitsui Chemicals, Inc.Inventors: Tatsuya Tanizaki, Takashi Nakahara, Mineo Kubo
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Patent number: 6306550Abstract: Dyes suitable for use in the fabrication of color filters are described which contain one or more photopolymerizable substituents preferably represented by the following formula: D—(A—Yn1)n2 (1) where D represents a chromphoric nucleus, A denotes a connecting group, Y means the photopolymerizable group, n1 is 1-10,000, and n2 stands for an integer of 1-10. Also described are photosensitive resist resin compositions containing the dyes as well as color filters fabricated by curing the photosensitive resist resin compositions.Type: GrantFiled: June 25, 1999Date of Patent: October 23, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Hisato Itoh, Akio Karasawa, Kenichi Sugimoto
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Patent number: 6303747Abstract: A transparent optical material containing at least one selenium atom, a plastic lens comprising the transparent optical material, and methods for preparing them. In addition, there are also disclosed novel selenium-containing compounds represented by the following formulae (1), (2) and (4) which are useful for the transparent optical material and the plastic lens: wherein symbols are as defined in the specification.Type: GrantFiled: May 12, 2000Date of Patent: October 16, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Koju Okazaki, Mamoru Tanaka, Shiro Honma, Hiroyuki Morijiri, Yoshinobu Kanemura, Masahiko Kusumoto
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Patent number: 6303815Abstract: A process for preparing phosphine oxides by reacting iminophosphoranes with phosphorus oxytrichloride by which highly purified phosphine oxides can be obtained industrially in a higher yield. Specifically, phosphine oxides are prepared in such a manner that iminophosphoranes are reacted with phosphorus oxytrichloride using an aprotic organic solvent with permittivity 2.2 or more at 20° C. as a solvent under special reaction conditions to give a liquid reaction product containing phosphine oxides and aminophosphonium chlorides which are yielded as a by-product at the same time as the phosphine oxides, and the above described chlorides are removed from the above described liquid reaction product by a solid-liquid separation process, and the solution having been subjected to the solid-liquid separation process is washed with water.Type: GrantFiled: April 13, 2000Date of Patent: October 16, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Tadahito Nobori, Isao Hara, Katsuhiko Funaki, Takaomi Hayashi, Atsushi Shibahara, Shinji Kiyono, Kazumi Mizutani, Usaji Takaki
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Patent number: 6303727Abstract: A novel and useful linear triene compound represented by the following formula (1) is co-polymerized with an &agr;-olefin to obtain an ethylenically unsaturated copolymer which is superior in weather-ability, heat resitance and fastness to ozone, together with superior scorch stability and vulcanizability at high velocity in which R1, R2, R3, R4, R5 and R6 stand each, independently of each other, for hydrogen atom or an alkyl having 1-3 carbon atoms, R7 represents an alkyl having 1-3 carbon atoms and n is an integer of 0-5, with the proviso that each of R4s or of R5s may be identical with or different from each other, respectively, when n is 2 or greater.Type: GrantFiled: May 26, 1999Date of Patent: October 16, 2001Assignee: Mitsui Chemicals Inc.Inventors: Ken Maeda, Masaaki Yasuda, Terunori Fujita, Keiji Okada, Makoto Kamimura, Kazuyuki Takimoto, Hidetatsu Murakami, Masaaki Kawasaki, Keiji Watanabe
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Patent number: 6303666Abstract: A process is provided for the production of expanded olefinic thermoplastic elastomer product having good external appearance, flexibility and heat resistance. This process features using, as raw materials, a particular olefinic thermoplastic elastomer and carbon dioxide as a blowing agent.Type: GrantFiled: July 23, 1999Date of Patent: October 16, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Kaoru Yorita, Eiichi Sugihara, Masahiro Takedachi, Haruo Inoue, Shigeo Nishikawa, Yoko Shimada, Michio Eriguchi, Takanori Sueda, Akira Uchiyama, Yuichi Ito
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Patent number: 6303349Abstract: Optically active chroman-3-acetic acids and optically active chroman-3-acetic acid esters can be obtained by treating a mixture of (3R)- and (3S)-chroman-3-acetic esters of formula (I) [wherein R1 is a straight or branched alkyl group having 1-5 carbon atoms and R2 is a hydrogen atom or substituted or unsubstituted amino group] is treated with an esterase which has an optically selective hydrolyzing activity or microorganisms which carry said hydrolase, or a preparation therefrom. A novel esterase derived from bacteria of genus Pseudonocardia can also be used as said esterase.Type: GrantFiled: March 13, 2000Date of Patent: October 16, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Toshihiro Oikawa, Nobuhiro Fukuhara, Yasuko Matsuba
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Patent number: 6303713Abstract: A graft modified ethylene/&agr;-olefin copolymer obtained by graft polymerizing an ethylene/&agr;-olefin of 3 to 20 carbon atoms copolymerizing with a polar monomer in the presence of a catalyst for olefin polymerization comprising an organoaluminum oxy-compound (a) and at least two kinds of transition metal compounds (b). This ethylene/&agr;-olefin copolymer has high melt tension and high flowability. An ethylene copolymer composition comprising the above-mentioned graft modified ethylene/&agr;-olefin copolymer and polyolefin. The graft modified ethylene/&agr;-olefin copolymer of the invention is excellent in heat stability and moldability. From this copolymer, a film having a high transparency and good adhesion to highly polar materials can be produced. The ethylene copolymer composition of the invention is excellent in heat stability and moldability. From this composition, a film having high transparency and good adhesion to highly polar materials can be produced.Type: GrantFiled: August 20, 1999Date of Patent: October 16, 2001Assignee: Mitsui Chemicals INCInventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Mamoru Takahashi, Akira Todo, Seiji Ohta, Hajime Inagaki
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Patent number: 6300416Abstract: A rubber composition useful as a tire side wall or tire tread is formed from an unsaturated olefin copolymer (A) or (A′) and diene rubber (B). Copolymers (A) and (A′) are each obtained from (i) ethylene, (ii) aromatic vinyl compound, (iii) non-conjugated polyene, and, optionally (iv) alpha-olefin having at least 3 carbon atoms. When used in forming a tire side wall, copolymer (A) has a molar ratio of (i)/(iv) from 100/0 to 40/60; molar ratio of [((i)+(iv))/(ii)] from 98/2 to 60/40; an intrinsic viscosity, measured in decalin, at 135° C., from 1.0 to 6.0 dl/g; and iodine value from 10 to 50. For use in tire tread, copolymer (A′), has a molar ratio (i)/(iv) from 100/0 to 40/60; molar ratio [((i)+(iv)):(ii)] from 99/1 to 85/15. The weight ratio (A′)/(B) is from 1/99 to 50/50. The compositions for tire side wall are characterized by excellent strength properties and bending fatigue resistance and low fuel consumption.Type: GrantFiled: September 17, 1998Date of Patent: October 9, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Keiji Okada, Kenichi Morizono, Kazuyuki Takimoto, Tetsuhiro Matsumoto, Masaaki Kawasaki, Tetsuo Tojo
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Patent number: 6300368Abstract: Preparation of antiarrhythmic agents containing novel anilide derivatives represented by the following formula as active ingredient provides a new type of antiarrhythmic agent of highly safe and effective, without effects on cardiac function.Type: GrantFiled: June 28, 1999Date of Patent: October 9, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Hiroyuki Yamashita, Kazuhiko Togashi, Akiyoshi Kai, Junichi Mohri, Haruki Mori, Kohichi Kawai, Akihiro Oyabe, Takashi Sato
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Patent number: 6300464Abstract: An optical resin prepared by curing a polymerizable composition comprising a (thio)epoxy compound having at least one intramolecular disulfide bond exhibits a considerably high refractive index while maintaining good optical properties and a high Abbe number. In addition, the above polymerizable composition to which is added primary and/or secondary amines as an yellowing inhibitor in a proportion of 0.001 to 0.5 of the total molar number of NH2 and NH groups in the amines to the total molar number of thioepoxy and epoxy groups in the (thio)epoxy compound having at least one intramolecular disulfide bond, can provide a transparent resin in which yellowing and reduction in heat resistance associated therewith are adequately prevented while maintaining a high refractive index.Type: GrantFiled: December 26, 2000Date of Patent: October 9, 2001Assignee: Mitsui Chemical, Inc.Inventors: Hiroyuki Morijiri, Seiichi Kobayashi, Koju Okazaki, Chitoshi Shimakawa, Akinori Ryu, Yoshinobu Kanemura
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Patent number: 6297332Abstract: An epoxy-resin composition comprising (A) an at least bifunctional epoxy compound and/or an at least bifunctional epoxy resin, (B) a curing agent, and (C) an accelerating agent, the accelerating agent essentially containing a phosphine oxide represented by general formula (1); where R1 to R6 all of which may be the same or not are hydrogen, straight, branched or cyclic alkyl having 1 to 10 carbons or aryl or aralkyl having 6 to 10 carbons.Type: GrantFiled: April 22, 1999Date of Patent: October 2, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Tatsuhiro Urakami, Kenichi Sugimoto, Keisuke Takuma, Tadahito Nobori, Usaji Takaki
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Patent number: 6296783Abstract: A polymeric gel electrolyte comprising: (a) an acrylic ester polymer matrix containing structural units derived from at least one acrylic ester selected from among acrylic esters represented by the general formulae: (wherein, in the formula (I), R1, R2 and R2′ are identical with or different from each other and represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R3 represents an alkyl group having 1 to 4 carbon atoms, and n is an integer of 1 to 100; and, in the formula (II), R4 to R9 are identical with or different from each other and represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and p, q and r are identical with or different from each other and are an integer of 1 to 100); (b) a nonaqueous solvent of a carbonic ester; and (c) a salt of a metal of Group Ia of the periodic table.Type: GrantFiled: July 29, 1998Date of Patent: October 2, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Masaharu Shindo, Takako Sasano
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Patent number: 6297333Abstract: The olefin polymerization catalyst of the invention is formed from a Group IVB transition metal compound represented by the following formula (I) and an organoaluminum oxy-compound or a compound which reacts with the transition metal compound to form an ion pair.Type: GrantFiled: May 20, 1999Date of Patent: October 2, 2001Assignee: Mitsui Chemicals IncInventors: Junichi Imuta, Masayasu Yoshida, Yasushi Tohi
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Publication number: 20010024752Abstract: Manganese dioxide for lithium primary batteries which is obtained by soda neutralization and heat treatment of electrolytic manganese dioxide and has a sodium content of 0.05 to 0.2% by weight and a process for producing the same.Type: ApplicationFiled: January 3, 2001Publication date: September 27, 2001Applicant: Mitsui Mining & Smelting Company, Ltd.,Inventors: Hiroshi Sumida, Kiyoteru Enomoto, Masaki Sato
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Patent number: 6294268Abstract: The present invention relates to a multi-layer laminate comprising at least two layers of an oriented ultra-high molecular polyolefin layer and a thermoplastic resin layer. The multi-layer laminate exhibits excellent abrasion resistance, tensile strength, shock resistance, heat-sealing property, uniformity in the film thickness, and can be efficiently produced. The invention is further concerned with a process and an apparatus for producing the multi-layer laminate.Type: GrantFiled: November 30, 1998Date of Patent: September 25, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Kyoji Muraoka, Iwatoshi Suzuki, Toshimasa Takata
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Patent number: 6291718Abstract: A process for preparing hydroperoxides which comprises oxidizing hydrocarbon by a gas containing oxygen in the presence of a specific compound and converting them selectively to corresponding hydroperoxides. The specific compound is the compound that can capture radicals. The preferable example may be a compound selected from radicals of oxygen, nitrogen, phosphorus, sulfur, carbon or silicon or a compound that forms radicals of these in the reaction system. The present invention can be applied to oxidation of hydrocarbons including arylalkylhydrocarbons such as cumene, m-diisopropylbenzene, p-diisopropylbenzene, 1,3,5-triisopropylbenzene, isopropylnaphthalene, diisopropylnaphthalene, isopropylbiphenyl, diisopropylbiphenyl, etc.Type: GrantFiled: March 2, 1999Date of Patent: September 18, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Shigekazu Matsui, Hiroshi Kuroda, Nobuya Hirokane, Haruyuki Makio, Toshihiro Takai, Koji Kato, Terunori Fujita, Makoto Kamimura
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Patent number: 6290896Abstract: A formed product which has a thickness of 0.1˜2 mm and a haze of 5%/2 mm or less and is degraded with ease in the natural environment is obtained by holding a transparent L-lactic acid base polymer sheet having an L-lactic acid proportion of 75% or more and a thickness of 0.2˜2 mm under conditions where: (1) a holding temperature is in the range of 55˜90° C., (2) a holding time m1 (min) satisfies the formula: log10m1<−0.083 T1+7.66, forming said sheet by adhering to the internal surface of a mold through vacuum suction, compressed air pressure or vacuum/air pressure under a condition where: (3) a mold temperature T2 is set in the range of from the glass transition temperature Tg of the L-lactic acid base polymer to the holding temperature T1, and taking out the formed product from the mold after reducing an internal temperature of the mold to less than Tg.Type: GrantFiled: May 18, 1995Date of Patent: September 18, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Kazuhiko Suzuki, Takayuki Watanabe, Yasuhiro Kitahara, Masanobu Ajioka
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Patent number: 6291600Abstract: In a novel method of homo- or copolymerization of vinyl chloride, a specified coating agent is applied on the surfaces of the portions which will become into contact with the vinyl chloride monomer during the polymerization process. The coating agent is in a form of an aqueous solution of a modified condensation product of phenol and aldehyde, the pH of the solution being adjusted in a range that the product is dissolved at an ambient temperature upon coating of the solution and separates out of the solution upon being heated on the surfaces. The wall surface of the polymerization tank and the like is then coated with a thin film of the coating agent having a uniform thickness and being strongly adhered to the wall surface, thereby providing an excellent effect of preventing adhesion of the product polymer to the wall surface.Type: GrantFiled: April 9, 1993Date of Patent: September 18, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Seiichi Masuko, Ichisaburo Nakamura, Yoshimatsu Naka, Keiichi Fukuda, Akira Yamamoto, Yasuyuki Hatakeyama, Akihiro Yamaguchi, Keizaburo Yamaguchi
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Patent number: 6291081Abstract: A process for producing an electrodeposited copper foil with its surface prepared, comprising the steps of: subjecting an electrodeposited copper foil having a shiny side and a matte side whose average surface roughness (Rz) is in the range of 2.5 to 10 &mgr;m to the first mechanical polishing so that the average surface roughness (Rz) of the matte side becomes 1.5 to 6 &mgr;m; and subjecting the matte side having undergone the first mechanical polishing to at least one further mechanical polishing so that the average surface roughness (Rz) of the matte side becomes 1.0 to 3.0 &mgr;m. The protrudent parts of the matte side are selectively polished by the first mechanical polishing, and the surface having undergone the first mechanical polishing is further subjected to the second and any ensuing mechanical polishings under milder conditions. Thus, a highly planar polished face with excellent surface properties can be obtained.Type: GrantFiled: August 31, 2000Date of Patent: September 18, 2001Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Hitoshi Kurabe, Mitsuhito Shibata, Masakazu Mitsuhashi