Patents Assigned to Mitsui
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Patent number: 5962607Abstract: A method for vapor phase polymerization comprises blowing a gaseous monomer from a bottom of a fluidized bed reactor through a distributor plate into the reactor by means of a blower while feeding a solid catalyst into the reactor to thereby form a fluidized bed in the reactor and conducting a vapor phase polymerization to produce a polymer or copolymer, wherein the blower has a slide or rotational slide part between its discharge side as a high pressure side and its suction side as a low pressure side in a blower body casing, said slide or rotational slide part being provided with a noncontacted gas leakproof seal part at a clearance ranging from 0.7 to 2.5 mm.Type: GrantFiled: May 14, 1997Date of Patent: October 5, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Ryoichi Yamamoto, Toshihiro Okano, Mitsunori Ichimura, Yoshiaki Kikuchi
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Patent number: 5962615Abstract: An ethylene polymer having small values of Mw/Mn and Mz/Mw, a small proportion of long-chain branches, a high melt tension and a high swell ratio produced by using a solid titanium catalyst component obtained by initially bring a solid titanium composition which is obtained by the contact of a solid magnesium aluminum composite containing magnesium, halogen, aluminum, and an alkoxy group of 6 or more carbon atoms and/or alcohol of 6 of more carbon atom with a tetravalent titanium compound into contact with an organometallic compound, and then bringing the resulting product into contact with oxygen. The ethylene polymer is excellent in moldability, and the molded article obtained therefrom is excellent in rigidity and impact resistance and free from poor appearance.Type: GrantFiled: February 2, 1996Date of Patent: October 5, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Shin-ichi Kojoh, Mamoru Kioka
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Patent number: 5959150Abstract: A process for preparing methylamines is disclosed herein which comprises the step of reacting methanol with ammonia in the presence of a mordenite in which the ratio of the length of mordenite crystals in a c axis direction to that of the mordenite crystals in an a axis direction or a b axis direction, c/a or c/b is 2 or more, whereby the synthetic activity of the methylamines can be maintained at a high level, and the production ratio of trimethylamine can be inhibited to a low level of about several percent to predominantly produce dimethylamine and monomethylamine.Type: GrantFiled: April 21, 1995Date of Patent: September 28, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Tadamitsu Kiyoura, Shigeki Nakahara
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Patent number: 5958209Abstract: A high tensile strength copper foil having a matte side roughness Rz of 2.5 .mu.m or less and a tensile strength of 40,000 Kgf/mm.sup.2 after heating one hour at 180.degree. C. is produced by a process in which copper is electrodeposited from a solution containing predetermined small amounts of a polyether glycol and tin and iron ions. The chloride ion content is maintained below 0.1 wt. ppm. The copper foil is characterized by having copper crystals with atomic cells having a predominantly (111) orientation.Type: GrantFiled: May 13, 1997Date of Patent: September 28, 1999Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Hisao Sakai, Toshiko Yokota, Tsutomu Asai, Susumu Takahashi, Mitsuo Suzuki, Makoto Dobashi, Yasuji Hara
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Patent number: 5959142Abstract: A process for producing refined methacrylic acid comprising the steps of oxidizing methacrolein and the like catalytically in a vapor phase to form a methacrylic acid-containing gas, cooling and condensing the gas to an aqueous methacrylic acid solution, adding to the solution an organic solvent that forms two liquid phases with water to carry out an extraction operation and thereby to obtain an extract, bringing the extract into contact with water to mix them together, separating the mixture into an organic phase and a water phase, and distilling the organic phase. According to this process, highly refined methacrylic acid containing little dibasic acids such as maleic acid and citraconic acid can be obtained economically and without increasing wastes that are unrecoverable to the process.Type: GrantFiled: October 31, 1995Date of Patent: September 28, 1999Assignees: Mitsui Chemicals, Inc., Kuraray Co., Ltd.Inventors: Kazuo Wakimura, Tadaharu Hase, Yoshihiro Sezaki, Koji Fujita, Takeshi Isobe, Shin-ichi Tadokoro, Rensuke Ikarashi
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Patent number: 5957828Abstract: A silver sol comprises silver particles having a particle size ranging from 1 to 100 nm and a silver solid content ranging from 1 to 80% by weight. The silver sol can be prepared by a method comprising the steps of reacting a solution of a silver compound with a reducing agent at a temperature ranging from 5 to 50.degree. C. and a stirring speed falling within the range of from 1,000 to 10,000 rpm to form silver fine particles; recovering the resulting silver fine particles using a centrifugal separator; and then dispersing the silver fine particles in a medium to give a silver sol having a silver solid content ranging from 1 to 80% by weight. The silver sol or a coating material obtained by diluting the sol to a desired silver solid content and, if desired, adding a binder permits the formation of a transparent conductive film on, for instance, a cathode-ray tube while reducing the production cost.Type: GrantFiled: May 7, 1998Date of Patent: September 28, 1999Assignee: Mitsui Mining and Smelting Co., Ltd.Inventor: Takao Hayashi
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Patent number: 5958333Abstract: The present invention provides a soldering alloy which does not include harmful Pb or Cd and which has an excellent tensile strength, elongation value, and melting point property. The soldering alloy according to the present invention can thus solve the conventional environmental problems, set the soldering temperature at a low level to thereby restrict the thermal damage to a soldered portion, and prevent breaking of the soldering alloy due to a heat cycle, with an excellent tensile strength and elongation value. A tin-silver-based soldering alloy according to the present invention consist essentially of 3 to 4% by weight of Ag, 2 to 6% by weight of Bi, 2 to 6% by weight of In, and the balance being Sn.Type: GrantFiled: August 15, 1997Date of Patent: September 28, 1999Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Junichi Matsunaga, Ryuji Ninomiya
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Patent number: 5959046Abstract: A process for producing a propylene polymer having an intrinsic viscosity (.eta.), as measured in decahydronaphthalene at 135.degree. C., of 1 to 12 dl/g comprises polymerizing propylene optionally with other olefins in the presence of an olefin polymerization catalyst comprising a transition metal compound represented by the formula ##STR1## wherein R.sup.1 and R.sup.2 are each a hydrogen atom or a hydrocarbon group of 1 to 3 carbon atoms,X.sup.1 and X.sup.2 are each a halogen atom, andY is a divalent silicon-containing group.Type: GrantFiled: April 21, 1997Date of Patent: September 28, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Junichi Imuta, Junji Saito, Takashi Ueda, Yoshihisa Kiso, Akira Mizuno, Masaaki Kawasaki
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Patent number: 5959256Abstract: A multilayer printed wiring board wherein circuits are provided respectively on both the faces of a substrate and subsequent circuits are provided in order and via insulating layers respectively on the outsides of the preceding circuits, characterized in that the insulating layers comprise an epoxy resin, polyvinyl acetal resin, melamine or urethane resin and rubber-modified epoxy resin in a specific mixing ratio.Type: GrantFiled: July 10, 1997Date of Patent: September 28, 1999Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Muneo Saida, Muneharu Ohara, Teturoh Satoh
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Patent number: 5955639Abstract: A copolymer of ethylene and an alpha-olefin having an ethylene content of from 30 to 90 mole %, a number average molecular weight of from 300 to 30,000 and a molecular weight distribution defined by a Q value (the ratio of the weight average molecular weight to the number average molecular weight) of not more than 3 and a Z value (the ratio of the maximum value of the molecular weight to the minimum value of the molecular weight when the molecular weight is measured by gel permeation chromatography) of from 15 to 200. The said copolymer can be produced by a process comprising copolymerizing ethylene with an alpha-olefin in the liquid phase in the presence of a polymerization catalyst composed of a combination of a soluble vanadium compound and an organoaluminum compound in the co-presence of hydrogen, characterized in that(a) the copolymerization is carried out in a continuous manner,(b) the concentration of the vanadium compound in the polymerization system is maintained at 0.Type: GrantFiled: July 29, 1993Date of Patent: September 21, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Hidekuni Oda, Tatuo Kinoshita, Akiyoshi Shimizu
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Patent number: 5955209Abstract: The thin-film electroluminescent device of the present invention comprises a thin film of a polyoxadiazole derivative represented by the formula: ##STR1## wherein each of X.sub.0 and Y.sub.0 independently represents a divalent organic group which may comprise a silicon atom, and n is an integer of 2 or greater,formed as an electroluminescent layer or a charge injecting/transporting layer between electrodes, at least one thereof being transparent. This thin-film electroluminescent device is excellent not only in electroluminescence and capability of charge injection/transport to thereby ensure high light emission efficiency but also in durability such as heat resistance.Type: GrantFiled: May 6, 1996Date of Patent: September 21, 1999Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Hideyuki Murata, Takahiro Fujiyama, Shogo Saito, Tetsuo Tsutsui, Tooru Yamanaka
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Patent number: 5953857Abstract: A method for controlling plant growth by exposing plants to light passing through a covering material comprising a base material containing a colorant. The type and content of the colorant are chosen to provide a photosynthetically effective photon flux (PPF) transmittance of 50% or greater when light is passed through the covering material, and an A value suitable for the purpose of promoting or retarding the growth of plants irradiated with light transmitted by the covering material, the A value being defined by the following equation:A=R/Frwhere R is the photon flux of red light in the wavelength range of 600 to 700 nm and Fr is the photon flux of far red light in the wavelength range of 700 to 800 nm.Type: GrantFiled: July 3, 1997Date of Patent: September 21, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Ichiro Aiga, Katsusuke Murakami, Shuhei Ikado, Ryu Nakamura, Ryu Oi, Kazuhiro Seino, Keisuke Takuma
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Patent number: 5955206Abstract: A composition for polysulfide-based resin comprising a polythiol having 4 or more functional groups and a compound having a reactive unsaturated bond(s) and/or b epoxy group(s) and/or c iso(thio)cyanato group(s) in one molecule (however, a+b+c.gtoreq.2, and a and b are not simultaneously 0). A polysulfide-based resin obtained by curing the composition, an optical material comprising the resin, a lens consisting of the optical material and a method for producing the polysulfide-based resin are also set forth.Type: GrantFiled: April 30, 1996Date of Patent: September 21, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Koju Okazaki, Chitoshi Shimakawa, Mamoru Tanaka, Yoshinobu Kanemura, Teruyuki Nagata, Yoshihiro Irizato, Shinichi Umeda
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Patent number: 5952477Abstract: The present invention is concerned with a novel azo compound represented by formula (1), (2) or (3), a water-soluble dye comprising this azo compound, and a polarizing film containing this azo compound. The obtained polarizing film has high hydrothermoresistance and a high polarization degree and is excellent in optical characteristics: ##STR1## wherein each of the groups is defined.Type: GrantFiled: October 15, 1997Date of Patent: September 14, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Tsutami Misawa, Akira Ogiso, Rihoko Imai, Hisato Itoh
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Patent number: 5952426Abstract: A method for preparing molded articles of a crosslinked polyolefin is here disclosed which comprises the steps of mixing polyolefin granules comprising polyolefin granules containing a hydrosilylation catalyst, polyolefin granules containing the copolymer of an alkenylsilane and an olefin, and if necessary, polyolefin granules containing neither the hydrosilylation catalyst nor the copolymer of the alkenylsilane and the olefin, and then heating, melting and molding the mixture in a molding machine.According to the present invention, the molded articles of the crosslinked polyolefin containing no residual crosslinking agent and having improved heat resistance and mechanical strength can be obtained by the easy method which comprises mixing the above-mentioned respective granules, and then heating, melting and molding the mixture.Type: GrantFiled: June 11, 1993Date of Patent: September 14, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Tadashi Asanuma, Kazuhiko Yamamoto, Kaoru Kawanishi
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Patent number: 5952457Abstract: A catalyst for the polymerization of an alkylene oxide compound is disclosed. This catalyst is composed of a phosphazene compound or a phosphazenium salt which is derived from the phosphazene compound and an active hydrogen compound. A poly(alkylene oxide) can be efficiently produced by polymerizing the alkylene oxide compound in the presence of the catalyst and, when the catalyst is composed of the phosphazene compound, the active hydrogen compound. The poly(alkylene oxide) contains no metal component and compared with those produced using conventional amine-base catalysts, has also been improved significantly in odor.Type: GrantFiled: September 4, 1996Date of Patent: September 14, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Masahiro Kouno, Tadahito Nobori, Kazumi Mizutani, Usaji Takaki
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Patent number: 5951724Abstract: A fine particulate polishing agent comprises fine particles of a solid solution composed of single-crystal ceric oxide and silicon dioxide and fine particles of silicon dioxide. A slurry polishing agent comprising the fine particulate polishing agent can be prepared by a method which comprises the steps of mixing, with stirring, single-crystal ceric oxide fine particles, silica sol and a liquid; drying the mixture; subjecting the dried particulate material to a thermal treatment at a high temperature and then cooling the solid solution powder formed by the thermal treatment and composed of single crystal ceric oxide and silicon dioxide; again mixing the powder with silica sol and a liquid; and then subjecting the mixture to deagglomeration using a wet pulverizing mill to give a slurry.Type: GrantFiled: February 26, 1998Date of Patent: September 14, 1999Assignee: Mitsui Mining and Smelting Co., Ltd.Inventors: Kenzo Hanawa, Naoyoshi Mochizuki, Naruo Ueda, Kazuhiko Kato
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Patent number: 5952450Abstract: A crosslinked polycarbonate is obtained by polycondensation of diol (A), trivalent or more polyhydric alcohol (B) whose arbitrary two hydroxy groups are not in the positional relationship of 1,2-disubstitution or 1,3-disubstitution, and carbonyl component (C) such as carbonic acid diesters. In the polycondensation step, no side reaction does not occur.This crosslinked polycarbonate is used as a modifier for polylactic acids. The brittleness of the polylactic acid is improved while maintaining mechanical strength, thermostability, and transparency.Type: GrantFiled: July 31, 1998Date of Patent: September 14, 1999Assignees: Shimadzu Corporation, Mitsui Chemicals, Inc.Inventors: Jiro Ishihara, Hiroki Kuyama, Eiichi Ozeki, Takeshi Ishitoku, Masahide Tanaka, Naoya Sakamoto
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Patent number: 5948519Abstract: A porous biaxially oriented film comprising a copolymer of an ethylene having an intrinsic viscosity ?.eta.! of from 3.5 to 10.0 dl/g and an .alpha.-olefin having 4 to 8 carbon atoms, the content of the .alpha.-olefin being in a number of from 1.0 to 7.5 per 1000 carbon atoms and the film retaining the structure which is based upon the microfibrils when it is heat-treated at 160.degree. C. under a constrained state and is then observed at room temperature, and a separator made of this film for batteries. The porous biaxially oriented film exhibits excellent gas permeating property over a practicable temperature range, exhibits excellent mechanical strength and, particularly, tensile strength, and loses gas permeating property when a maximum practicable temperature is exceeded. The film can be favorably used as a separator for batteries.Type: GrantFiled: October 28, 1996Date of Patent: September 7, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Kazuo Yagi, Akinao Hashimoto, Hitoshi Mantoku
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Patent number: 5947536Abstract: The invention is directed to a latch device for a tailgate of a vehicle having a motorized unit rotatably located on the tailgate along with a manually operated handle. The motorized unit selectively and through mechanical connections rotates either the main open lever to the latch and unlatch the tailgate or the sub open lever to latch or unlatch the window hatch in the tailgate.Type: GrantFiled: October 24, 1997Date of Patent: September 7, 1999Assignee: Mitsui Kinzoku Kogyo Kabushiki KaishaInventors: Tetsuro Mizuki, Yuji Yoda