Patents Assigned to Nalco Chemical Company
  • Patent number: 5866521
    Abstract: The invention is for an additive composition for metal-working fluids and a method for producing the additive composition. The additive composition comprises from about 0.01 to about 25.0 mole weight of iso-stearic acid to 2-amino-2-methyl-1-propanol whereby a salt of iso-stearic acid-2-amino-2-methyl-1-propanol is formed. The metal-working fluid composition comprises from about 0.01 to about 40 percent by weight of iso-stearic acid-2-amino-2-methyl-1-propanol salt and from about 99.99 to about 60 percent by weight of a synthetic or semi-synthetic metal-working fluid.
    Type: Grant
    Filed: September 5, 1995
    Date of Patent: February 2, 1999
    Assignee: Nalco Chemical Company
    Inventor: Robert L. Trivett
  • Patent number: 5866041
    Abstract: The present invention provides an antifoam emulsion with improved shelf-life and a method for making same. The improved shelf-life results from dispersing a fatty alcohol dispersion in an emulsion of another liquid. To this end, the antifoam emulsion of the present invention includes an internal phase of a fatty alcohol dispersion, an emulsifier, and an external phase including a water insoluble or partially miscible liquid.
    Type: Grant
    Filed: June 26, 1997
    Date of Patent: February 2, 1999
    Assignee: Nalco Chemical Company
    Inventors: James J. Svarz, Ryan A. Gabel
  • Patent number: 5858798
    Abstract: Primary amines, ammonia, or mixtures thereof can be detected using a reagent comprising from about 650 ppm to about 25 percent by weight of phthalic dicarboxyaldehyde; from about 74 to about 99.88 percent by weight of an alkali metal borate; and, from about 550 ppm to about 22 percent by weight of a nucleophile.
    Type: Grant
    Filed: July 12, 1996
    Date of Patent: January 12, 1999
    Assignee: Nalco Chemical Company
    Inventors: Martin R. Godfrey, Donald E. Govoni, Linda M. Link
  • Patent number: 5858244
    Abstract: A biodegradable scale inhibitor and dispersant is provided. The scale inhibitor includes a copolymer comprising at least one of N-oxygenatedhydrocarbonamide monomers and at least one of amino acid monomers. A method of reducing scale build-up on heating exchanger surfaces that come in contact with an industrial water is provided by adding a copolymer comprising at least one of N-oxygenatedhydrocarbonamide monomers and at least one of amino acid monomers to the water system such as cooling towers.
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: January 12, 1999
    Assignee: Nalco Chemical Company
    Inventors: Jiansheng Tang, Ronald V. Davis
  • Patent number: 5849220
    Abstract: A corrosion inhibiting composition for use in inhibiting corrosion of metallic surfaces, the composition comprising a first surfactant wherein the first surfactant includes at least one sorbitan fatty acid ester and a second surfactant wherein the second surfactant includes at least one polyoxyethylene derivative of a sorbitan fatty acid ester.
    Type: Grant
    Filed: January 26, 1998
    Date of Patent: December 15, 1998
    Assignee: Nalco Chemical Company
    Inventors: Carol B. Batton, Tzu-Yu Chen, Christopher C. Towery
  • Patent number: 5840158
    Abstract: A method for the manufacture of paper comprising the steps of:a) forming an aqueous cellulosic papermaking slurry;b) adding an effective coagulating amount of a coagulant and a flocculant to said cellulosic papermaking slurry, wherein said coagulant is prepared by blendingi) an effective coagulating amount of an aqueous conditioned colloidal silica sol with an average particle size within the range of from 1 to 150 nm and wherein the aqueous colloidal silica sol is conditioned by contacting said sol with a strong acid cation exchange resin, andii) an effective coagulating amount of a cationically-charged water-soluble polymeric coagulant;c) draining said cellulosic suspension to form a sheet; and,d) drying said sheet.The components of the invention are blended together so that addition is simultaneous. The colloidal silica is conditioned by passing over a cationic exchange resin prior to addition of cationic polymer.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: November 24, 1998
    Assignee: Nalco Chemical Company
    Inventors: Pek Lee Choo, Bruce A. Keiser, Michio Kobayashi, Maureen B. Nunn, David A. Picco, Kristine S. Salmen
  • Patent number: 5837100
    Abstract: An improved papermaking process comprising forming an aqueous coated broke papermaking slurry and adding a blend of a water-soluble dispersion polymer and a coagulant to the slurry to increase retention and/or drainage is disclosed. After addition of the polymers, the slurry is drained to form a sheet, and the sheet is dried.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: November 17, 1998
    Assignee: Nalco Chemical Company
    Inventors: Alessandra Gerli, David I. Weinstein
  • Patent number: 5837215
    Abstract: A method for flocculation of red mud in Bayer Process streams utilizing a fatty acid or fatty acid ester free latex polymer flocculant. Preferred fatty acid free emulsifiers useful for the preparation of such flocculants are obtained by reacting ethylene and/or propylene oxide with a reagent selected from the group consisting of ethylene diamine, ethanol and ethylene glycol.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: November 17, 1998
    Assignee: Nalco Chemical Company
    Inventors: James Morton Tippett, Graeme John Farquarson, Radhakrishnan Selvarajan, John T. Malito
  • Patent number: 5837776
    Abstract: Aqueous dispersions of water soluble nonionic and anionically charged vinyl and allyl addition polymers can be obtained by polymerizing in the presence of an anionically charged water soluble polymer stabilizer in a saturated salt solution. Methods for the preparation of these polymers, and their compositions are disclosed.
    Type: Grant
    Filed: January 10, 1997
    Date of Patent: November 17, 1998
    Assignee: Nalco Chemical Company
    Inventors: Radhakrishnan Selvarajan, John R. Hurlock
  • Patent number: 5833937
    Abstract: An improved method for extracting a precious metal from mineral fines by heap leaching with dilute sulfuric acid which comprises agglomerating the mineral fines prior to formation into a heap with an agglomerating agent composition comprising sequential addition of a first polymer selected from the group consisting of anionic and nonionic water-soluble polymers and then a second cationic water-soluble polymer to the fines. Preferred first polymers are poly(acrylamide) and 70/30 mole percent poly(acrylamide/sodium acrylate), and preferred second polymers are poly(diallyldimethylammonium chloride), 90/10 mole percent poly(acrylamide/diallyldimethylammonium chloride) and 99/1 mole percent poly(diallyldimethylammonium chloride/vinyltrimethoxysilane).
    Type: Grant
    Filed: October 17, 1997
    Date of Patent: November 10, 1998
    Assignee: Nalco Chemical Company
    Inventor: E. Michael Kerr
  • Patent number: 5808103
    Abstract: Disclosed are the Rhodamine B esters of hydroxy C.sub.2 -C.sub.6 lower alkyl acrylates. Specifically, the hydroxy lower alkyl radical is a linear hydroxy lower alkyl radical having the hydroxy group attached to the terminal carbon atom. Also shown are copolymers of diallyldimetyl ammonium chloride which contains from 0.01-2 mole percent of these Rhodamine B esters and their use in treating industrial waters.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: September 15, 1998
    Assignee: Nalco Chemical Company
    Inventors: William J. Ward, Jeffrey R. Cramm, Peter E. Reed, Brian S. Johnson
  • Patent number: 5800714
    Abstract: Water recovered from the polymerization of vinyl monomers can be treated to remove or deactivate chain transfer agents present in the water allowing resuse in polymerization processes. The water recovered from a vinyl polymerization reaction is contacted with a cation exchange resin in the hydrogen form prior to recycle, or may be acidified and then contacted with an anion exchange resin in the hydroxide form.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: September 1, 1998
    Assignee: Nalco Chemical Company
    Inventors: Thomas M. Miller, Bhasker B. Dave, W. Hugh Goodman
  • Patent number: 5798046
    Abstract: The present invention provides a method for removing secondary fiber contaminants from paper mill process waters comprising adding a polyvinyl chloride, a cationic polymeric coagulant and a polymeric flocculant to paper mill process waters containing secondary fiber contaminants in an amount sufficient to agglomerate the secondary fiber contaminants to larger particles sizes, and removing the secondary fiber contaminants from the process water by a dissolved air flotation clarification technique. The addition of particulate polyvinyl chloride in combination with a polymeric coagulant and flocculant prior to the DAF clarification process causes the contaminants to become preferentially coated with the polyvinyl chloride particles. This coating is what causes the subsequent removal of the secondary fiber contaminants in the DAF clarification process to be more effective.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: August 25, 1998
    Assignee: Nalco Chemical Company
    Inventors: Carol S. Greer, Ann M. Capozzi, Linda S. Wilkins
  • Patent number: 5798023
    Abstract: A method for minimizing pitch, ink, and stickies particle deposits in the paper making process by causing the retention of such particles onto fiber, comprising the steps of adding an effective pitch, ink, and stickies controlling amount of talc to a suspension of fiber in contact with the paper machine and associated parts and adding an effective pitch, ink, and stickies controlling amount of bentonite to the suspension, thereby increasing retention of pitch, ink, and stickies onto the fiber and minimizing the deposition of pitch, ink, and stickies particles on the paper machine and associated parts.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: August 25, 1998
    Assignee: Nalco Chemical Company
    Inventors: Przemyslaw Pruszynski, John R. Armstrong
  • Patent number: 5796478
    Abstract: A method and apparatus for detecting, measuring and monitoring films formed on exposed surfaces of a fluid system caused by microorganisms present in the fluid system. Pursuant to the present invention, a fluorometer is utilized to irradiate an exposed surface with light of the appropriate magnitude and intensity which results in an excitation of the NAD(P)H and ATP and other fluorescent molecules contained within microorganisms and subsequent fluorescent emission from the microorganisms. As a result, films caused by the presence of microorganisms in the fluid system can be detected and monitored.
    Type: Grant
    Filed: July 25, 1997
    Date of Patent: August 18, 1998
    Assignee: Nalco Chemical Company
    Inventor: Robert L. Wetegrove
  • Patent number: 5795487
    Abstract: The invention is a method for preparing a stabilized aqueous alkali or alkaline earth metal hypobromite solution. The method comprises the steps of:a. Mixing an aqueous solution of alkali or alkaline earth metal hypochlorite having from about 5 percent to about 70 percent available halogen as chlorine with a water soluble bromide ion source;b. Allowing the bromide ion source and the alkali or alkaline earth metal hypochlorite to react to form a 0.5 to 70 percent by weight aqueous solution of unstabilized alkali or alkaline earth metal hypobromite;c. Adding to the unstabilized solution of alkali or alkaline earth metal hypobromite an aqueous solution of an alkali metal sulfamate in a quantity to provide a molar ratio of alkali metal sulfamate to alkali or alkaline earth metal hypobromite is from about 0.5 to about 7; and,d. Recovering a stabilized aqueous alkali or alkaline earth metal hypobromite solution.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: August 18, 1998
    Assignee: Nalco Chemical Company
    Inventors: Anthony W. Dallmier, William F. McCoy
  • Patent number: 5788866
    Abstract: The invention is a water-soluble N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine containing copolymer, wherein said copolymer is formed from the polymerization of an N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine of the formula: ##STR1## wherein R is selected from the group consisting of alkyl and aryl groups, and R.sub.1 is selected from the group consisting of alkyl groups, aryl groups, and alkylaryl groups, and an anionic monomer.The invention is also a method of inhibiting the precipitation and deposition of scale on metal surfaces in contact with industrial cooling waters comprising the addition of an effective, scale-inhibiting amount of a water-soluble N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine containing copolymer, wherein said copolymer is formed from the polymerization of a betaine of the formula: ##STR2## wherein R is selected from the group consisting of alkyl and aryl groups, and R.sub.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: August 4, 1998
    Assignee: Nalco Chemical Company
    Inventors: Dodd W. Fong, Charles F. Marth, Ronald V. Davis
  • Patent number: 5788857
    Abstract: This invention relates to the use of iminoalkylenephosphonic acids to prevent corrosion, including both localized corrosion and general corrosion on iron based metal surfaces in contact with a corrosive system water in an aqueous system. The invention also relates to the use of the iminoalkylenephosphonic acids to control formation, deposition and adherence of scale at the surfaces of metals in contact with a scale-forming system water in an aqueous system.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: August 4, 1998
    Assignee: Nalco Chemical Company
    Inventors: Bo Yang, Jiansheng Tang
  • Patent number: 5785867
    Abstract: The present invention provides a composition and method of administering same for inhibiting the growth of microorganisms. The composition of the present invention includes sufficient amounts of a peracetic acid or peracetic acid/peracid blend and a non-oxidizing biocide. The method of the present invention includes the step of adding sufficient amounts of the peracetic acid or peracetic acid/peracid blend and the non-oxidizing biocide to industrial process waters.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: July 28, 1998
    Assignee: Nalco Chemical Company
    Inventors: Judy G. LaZonby, Robert E. McCarthy, Nancy L. Casselman
  • Patent number: 5783728
    Abstract: An improved method is disclosed for the preparation of novel alkali metal diphosphinate salts by the reaction of an acetylenic compound with an alkali metal hypophosphite in the presence of a free radical source, the use of these novel compounds in further reactions to prepare diphosphonate compounds and diphosphinate containing adducts, oligomers and polymers and utilization of these compounds, polymers and oligomers to control calcium carbonate scale and mild steel corrosion in cooling water.
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: July 21, 1998
    Assignee: Nalco Chemical Company
    Inventors: James F. Kneller, Donald A. Johnson, Vytas Narutis, Binaifer S. Khambatta