Patents Assigned to Nippon Mektron, Limited
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Patent number: 5910552Abstract: A novel fluorine-containing copolymer elastomer having bromine groups as cross-linkable groups, which comprises about 45 to about 80% by mole of tetrafluoroethylene, about 50 to about 20% by mole of a perfluoro(vinylether) represented by the following general formula:CF.sub.2 .dbd.CFO(CF.sub.2).sub.2 (OCF.sub.2)nOCF.sub.3where n is an integer of 1 to 5, and about 0.2 to about 5% by mole of a bromine-containing unsaturated monomer compound, sum total being 100% by mole, gives vulcanization products having distinguished resistances to chemicals, low temperature and heat.Type: GrantFiled: March 14, 1997Date of Patent: June 8, 1999Assignee: Nippon Mektron, LimitedInventors: Satoru Saito, Haruyoshi Tatsu
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Patent number: 5902868Abstract: A novel fluorine-containing copolymer elastomer having bromine groups as cross-linkable groups, which comprises about 45 to about 80% by mole of tetrafluoroethylene, about 50 to about 20% by mole of a perfluoro(vinylether) represented by following general formula:CF.sub.2 .dbd.CFO(CF.sub.2).sub.2 (OCF.sub.2)nOCF.sub.3where n is an integer of 1 to 5, and about 0.2 to about 5% by mole of a bromine-containing unsaturated monomer compound, sum total being 100% by mole, gives vulcanization products having distinguished resistances to chemicals, low temperature and heat.Type: GrantFiled: October 22, 1997Date of Patent: May 11, 1999Assignee: Nippon Mektron, LimitedInventors: Satoru Saito, Haruyoshi Tatsu
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Patent number: 5898054Abstract: A peroxide-vulcanizable fluorine-containing elastomer containing iodines as cross-linking sites, capable of producing vulcanization products having a distinguished heat resistance is produced by polymerization reaction of a fluorinated olefin having 2 to 8 carbon atoms in the presence of a diiodide compound represented by the following general formula:I--R--where R is a divalent fluorohydrocarbon group, chlorofluorohydrocarbon group or hydrocarbon group, having 2 to 8 carbon atoms, respectively, and 2,2-difluoroiodoethylene.Type: GrantFiled: November 28, 1997Date of Patent: April 27, 1999Assignee: Nippon Mektron, LimitedInventors: Satoru Saito, Kuniyoshi Kawasaki, Haruyoshi Tatsu
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Patent number: 5891964Abstract: 2,2 bis(3-mercaptophenyl)hexafluoropropane ?bisthiophenol AF! is obtained in good yield by chlorosulfonating 2,2'-bisphenylhexafluoropropane and reducing the thus quantitatively obtained 2,2'-bis(3-chlorosulfonylphenyl)hexafluoropropane with zinc under acidic conditions and is effectively used as a cross-linking agent for a fluorine-containing elastomer having halogenophenyl groups as cross-linkable groups.Type: GrantFiled: July 3, 1996Date of Patent: April 6, 1999Assignee: Nippon Mektron, LimitedInventors: Takehiro Sonoi, Haruyoshi Tatsu, Satoru Saito, Sergei Rafailovich Sterlin, Victor Filippovich Cherstokov, Nina Ivanovna Delyagina
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Patent number: 5891974Abstract: A novel fluorine-containing copolymer elastomer having bromine groups as cross-linkable groups, which comprises about 45 to about 80% by mole of tetrafluoroethylene, about 50 to about 20% by mole of a perfluoro(vinylether) represented by the following general formula:CF.sub.2 .dbd.CFO(CF.sub.2).sub.2 (OCF.sub.2)nOCF.sub.3where n is an integer of 1 to 5, and about 0.2 to about 5% by mole of a bromine-containing unsaturated monomer compound, sum total being 100% by mole, gives vulcanization products having distinguished resistances to chemicals, low temperature and heat.Type: GrantFiled: October 22, 1997Date of Patent: April 6, 1999Assignee: Nippon Mektron, LimitedInventors: Satoru Saito, Haruyoshi Tatsu
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Patent number: 5876617Abstract: A copolymer, which comprises about 30 to about 70% by weight of perfluoroalkylethyl (meth)acrylate represented by the following general formula:CH.sub.2 .dbd.CRCOOCH.sub.2 CH.sub.2 Rfwhere R is a hydrogen atom or a methyl group, and Rf is a perfluoroalkyl group having 4 to 16 carbon atoms; about 25 to about 60% by weight of stearyl (meth)acrylate; about 1 to about 15% by weight of 2-chloroethyl vinyl ether; and (d) about 0.1 to about 5% by weight of N-methylol (meth)acrylamide, sum total being 100% by weight, is novel and can form a water- and oil-repellent agent having a good resistance to yellowing of textiles, etc. and capable of shorter curing and low temperature curing.Type: GrantFiled: June 6, 1997Date of Patent: March 2, 1999Assignee: Nippon Mektron, LimitedInventors: Masato Sato, Hanghua Pan, Koichi Takahashi, Tetsuya Mizuno
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Patent number: 5874506Abstract: A fluorine-containing elastomer comprising vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene having a high fluorine content (e.g. at least 68% by weight) can be vulcanized with a polyol-based cross-linking agent by further copolymerizing 2H-pentafluoropropylene into the elastomer, whereby the resulting vulcanization products having improved characteristics such as rheological properties, normal state physical properties and compression set can be obtained. Vulcanization products obtained by vulcanization with a polyol-based cross-linking agent and a quaternary onium salt compound have a good permeation resistance to fuel oil as a result of a permeation test with a mixed solvent of gasoline/methanol in a volume ratio of 85/15.Type: GrantFiled: April 4, 1997Date of Patent: February 23, 1999Assignee: Nippon Mektron, LimitedInventors: Haruyoshi Tatsu, Akihiro Naraki, Yuichi Yamamoto
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Patent number: 5859181Abstract: A solvent-soluble siloxane polyimide comprising a copolymer obtained by reaction of a diamine compound mixture comprising a diaminopolysiloxane and an alicyclic diamine with an aromatic tetracarboxylic acid anhydride, followed by polyimidization reaction of the resulting polyamic acid forms a heat-resistant adhesive by adding an epoxy resin, a diamine-based curing agent and an organic solvent thereto, The formed adhesives show a distinguished heat-resistant adhesiveness when the resulting siloxane polyimide soluble in ordinary organic solvents is used as a main component of the adhesive for bonding between a base material and a copper foil of a flexible printed substrate. By further addition of a fluorinated resin to the heat-resistant adhesive, the adhesiveness can be more improved.Type: GrantFiled: December 17, 1997Date of Patent: January 12, 1999Assignee: Nippon Mektron, LimitedInventors: Dong Zhao, Hiroshi Sakuyama, Tomoko Katono, Lin-chiu Chiang, Jeng-Tain Lin
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Patent number: 5859144Abstract: A rubber compound comprising a fluorine rubber component and an acrylic rubber component is produced by adding an acrylic monomer to an aqueous emulsion of fluorine-containing elastomer obtained by emulsion polymerization, using a fluorine-containing surfactant, followed by radical polymerization reaction. The obtained rubber compound can satify both of vulcanization moldability and heat aging resistance, and is at a lower cost than the expensive fluorine rubber.Type: GrantFiled: September 12, 1996Date of Patent: January 12, 1999Assignee: Nippon Mektron, LimitedInventors: Kuniyoshi Saito, Iwao Moriyama, Jun Okabe
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Patent number: 5849932Abstract: A novel bismaleimide compound having the following formula: ##STR1## is synthesized from 1,3-bis(aminomethyl)cyclohexane and maleic anhydride, and is readily soluble in a variety of ordinary low boiling point organic solvents.Type: GrantFiled: February 26, 1997Date of Patent: December 15, 1998Assignee: Nippon Mektron, LimitedInventor: Lin-chiu Chiang
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Patent number: 5831127Abstract: A novel bisaminothiophenol compound represented by the following general formula: ##STR1## where Rf is a perfluoroalkylidene group having 1 to 10 carbon atoms, is used as a cross-linking agent for fluorine-containing elastomers having CN groups as cross-linkable groups.Type: GrantFiled: October 23, 1995Date of Patent: November 3, 1998Assignee: Nippon Mektron LimitedInventors: Satoru Saito, Haruyoshi Tatsu, Lev Solomonovich German, deceased, Valerii Romanovich Polishchuk, deceased
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Patent number: 5824749Abstract: A fluorine-containing elastomer composition, which comprises a terpolymer of tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) or perfluoro (lower alkoxy-lower alkyl vinyl ether) and cross-linkable cyano group-containing (perfluorovinylether), and a bis(aminothiophenol) compound represented by the following general formula as a cross-linking agent: ##STR1## wherein A is an alkylidene group having 1 to 6 carbon atoms, a perfluoroalkylidene group having 1 to 10 carbon atoms, a SO.sub.2 group, an O atom, a CO group or a carbon-carbon bond capable of directly bonding two benzene rings and one of X and Y is an amino group, while the other is a mercapto group, can produce cross-linked fluororubber moldings having an improved compression set.Type: GrantFiled: October 18, 1996Date of Patent: October 20, 1998Assignee: Nippon Mektron, LimitedInventors: Takehiro Sonoi, Haruyoshi Tatsu, Lev Solomonovich, deceased, Valerii Romanovich Polishchuk, deceased, Satoru Saito
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Patent number: 5808132Abstract: Heptafluoroisobutenyl methyl ether having the following formula: ##STR1## is oxidized with ozone to produce perfluoro(2-methyl-1,2-epoxy-propyl) methyl ether. The resulting intermediate compound is allowed to react with an aromatic compound ArH to produce .alpha.,.alpha.-bis(trifluoromethyl)arylacetic acid methyl ester having the following formula: ##STR2## By hydrolysis, decarboxylation and further hydrolysis of the ester compound, .alpha.,.alpha.-bis(trifluoromethyl)arylacetic acid for use as raw materials for medicines, agricultural chemicals, liquid crystals, etc. or reagents for determining an optical purity can be obtained.Type: GrantFiled: March 12, 1996Date of Patent: September 15, 1998Assignee: Nippon Mektron, LimitedInventors: Takehiro Sonoi, Toshimasa Sagawa, Futoshi Masaki, Toshio Kubota
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Patent number: 5789532Abstract: Perfluoroalkyleneethertriazine oligomer obtained by reacting a dinitrile compound NC--RF.sup.0 --CN where Rf.sup. is --(CFXOCF.sub.2)a(CF.sub.2)b(CF.sub.2 OCFX)c--, where X is a fluorine atom or a CF.sub.3 group, a is an integer of 1 to 5, b is an integer of 1 to 2 and c is an integer of 1 to 5, or Rf.sup.0 is --CF.sub.2 O(CF.sub.2 O)dCF.sub.2 --, where d is an integer of 1 to 8, with ammonia, further reacting the resulting diamizine compound with a dinitrile compound NC--Rf.sup.1 --CN, Rf.sup.1 has the same meaning as that for Rf.sup.0 or Rf.sup.1 is a perfluoroalkylene group having 4 to 8 carbon atoms thereby obtaining a perfluoroalkyleneetherpolyimidoylamizine oligomer, then reacting the resulting oligomer with a perfluoronitrile compound Rf.sup.2 CN, Rf.sup.2 is CF.sub.3 (OCF.sub.2)e-- where e is an integer of 3 to 10 thereby treating the terminal groups thereof, and then subjecting the resulting terminal-treated oligomer to a ring-closing reaction with a perfluoroacylating agent RF.sup.3 COY, Rf.sup.Type: GrantFiled: December 26, 1996Date of Patent: August 4, 1998Assignees: Nippon Mektron, Limited, S.V. LebedevInventors: Riichi Iwa, Haruyoshi Tatsu, Sokolov Sergey Vasilyevich, Kollar Alexander Nikolaevich
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Patent number: 5783659Abstract: Perfluoroalkyleneethertriazine oligomer obtained by reacting a dinitrile compound NC--Rf.sup.0 --CN, where Ff.sup.0 is --(CFXOCF.sub.2)a(CF.sub.2)b(CF.sub.2 OCFX)c--, where X is a fluorine atom or a CF.sub.3 group, a is an integer of 1 to 5, b is an integer of 1 to 2 and c is an integer of 1 to 5, or Rf.sup.0 is --CF.sub.2 O(CF.sub.2 O)dCF.sub.2 --, where d is an integer of 1 to 8, with ammonia, further reacting the resulting diamizine compound with a dinitrile compound NC--RF.sup.1 --CN, RF.sup.1 has the same meaning as that for Rf.sup.0 or Rf.sup.1 is a perfluoroalkylene group having 4 to 8 carbon atoms thereby obtaining a perfluoroalkyleneetherpolyimidoyamizine oligomer, then reacting the resulting oligomer with a perfluoronitrile compound Rf.sup.2 CN, Rf.sup.2 is CF.sub.3 (OCF.sub.2).sub.e -- where e is an integer of 3 to 10 thereby treating the terminal groups thereof, and then subjecting the resulting terminal-treated oligomer to a ring-closing reaction with a perfluoroacylating agent RF.sup.3 COY, Rf.Type: GrantFiled: December 26, 1996Date of Patent: July 21, 1998Assignees: Nippon Mektron, Limited, S.V. LebedevInventors: Riichi Iwa, Haruyoshi Tatsu, Sokolov Sergey Vasilyevich, Kollar Alexander Nikolaevich
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Patent number: 5770633Abstract: Filler-containing, cross-linked, vulcanized fluorine rubber waste is regenerated by treatment with at least one of CH.sub.3 SO.sub.3 H, ClSO.sub.3 H, CF.sub.3 SO.sub.3 H and fuming sulfuric acid, followed by dissoluting into a solvent and separating solvent-insoluble filler therefrom, whereby revulcanizable fluorine rubber is recovered from the fluorine rubber waste, almost irrespective of types of cross-linking systems used for formation of cross-linked, vulcanized fluorine rubber.Type: GrantFiled: July 17, 1996Date of Patent: June 23, 1998Assignee: Nippon Mektron, LimitedInventors: Akihiro Naraki, Fumiyo Mizuide, Haruyoshi Tatsu
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Patent number: 5767204Abstract: A fluorine-containing elastomer composition, which comprises a terpolymer of tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) and a perfluoro unsaturated nitrile compound represented by the following general formula:CF.sub.2 .dbd.CFO(CF.sub.2)nOCF(CF.sub.3)CN,wherein n is an integer of 2 to 5, and a bis(aminophenyl) compound represented by the following general formula as a cross-linking agent: ##STR1## wherein A is an alkylidene group having 1 to 6 carbon atoms or a perfluoroalkylidene group having 1 to 10 carbon atoms and X and Y are a hydroxyl group or an amino group, can produce vulcanized products having good vulcanization physical properties and a.good compression set.Type: GrantFiled: October 16, 1995Date of Patent: June 16, 1998Assignees: Nippon Mektron Limited, The Central Synthetic Rubbers Research InstituteInventors: Riichi Iwa, Haruyoshi Tatsu, Volkova Margarita Alexeevna, Rondarev Dmitrii Stefanovich, Sokolov Sergey Vasilyevich, Greenblat Mark Peysakhovich, Senyushov Lev Nikolaevich
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Patent number: 5763699Abstract: 2,2-diphenylhexafluoropropanes are prepared by condensation reaction of benzene or benzenes substituted with a halogen atom or atoms, a lower alkyl group or groups or a hydroxyl group or groups with hexafluoroacetone in the presence of trifluoromethane sulfonic acid. Among the 2,2-diphenylhexafluoropropanes, 2,2-diphenylhexafluoropropane and 2,2-bis(p-chlorophenyl)hexafluoropropane are novel compounds.Type: GrantFiled: November 27, 1996Date of Patent: June 9, 1998Assignee: Nippon Mektron, LimitedInventors: Lev Solomonovich German, deceased, Valerii Romanovich Polishchuk, deceased, Riichi Iwa, Haruyoshi Tatsu
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Patent number: 5756814Abstract: (1) CF.sub.2 .dbd.CFO(CF.sub.2).sub.n COOR is allowed to react with chlorine or bromine to obtain CF.sub.2 XCFXO(CF.sub.2).sub.n COOR', (2) which is allowed to react with a Grignard reagent MgBrC.sub.6 H.sub.3 (CH.sub.3).sub.2 to convert the terminal group to --COC.sub.6 H.sub.3 (CH.sub.3).sub.2, (3) followed by reaction with diethylaminosulfur trifluoride to convert --COC.sub.6 H.sub.3 (CH.sub.3).sub.2 to --CF.sub.2 C.sub.6 H.sub.3 (CH.sub.3).sub.2, (4) followed further by oxidation of the resulting methyl group and by esterification to convert the methyl group to --CF.sub.2 C.sub.6 H.sub.3 (COOR).sub.2 and (5) followed by dechlorination or debromination to obtain CF.sub.2 .dbd.CFO(CF.sub.2).sub.n CF.sub.2 C.sub.6 H.sub.3 (COOR).sub.2. The resulting bifunctional vinyl ether compound having an aromatic ring is a novel compound and can be used as a copolymer component for fluorine-containing elastomers.Type: GrantFiled: June 23, 1997Date of Patent: May 26, 1998Assignee: Nippon Mektron, LimitedInventors: Leng-Tain Lin, Kenji Iimura, Takehiro Sonoi
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Patent number: 5744562Abstract: A copolymer comprising an alkyl acrylate and an. unsaturated ester compound represented by the following general formula:(1) CH.sub.2 .dbd.CRCOO(CH.sub.2)nPhOR',(2) CH.sub.2 .dbd.CRCOO(CH.sub.2)nOCO(CH.sub.2)mPhOR',(3) CH.sub.2 .dbd.CHOCO(CH.sub.2)nOCO(CH.sub.2)mPhOR',(4) CH.sub.2 .dbd.CHO(CH.sub.2)nOCO(CH.sub.2)mPhOR' or(5) CH.sub.2 .dbd.CHPh(CH.sub.2)nOCO(CH.sub.2)mPhOR'where R is a hydrogen atom or a methyl group; R' is a hydrogen atom, an acyl group or a trialkylsilyl group; and Ph is a phenylene group, forms a blend rubber having a good heat resistance and a good amine resistance with a fluorine-containing elastomer.Type: GrantFiled: July 24, 1996Date of Patent: April 28, 1998Assignee: Nippon Mektron, LimitedInventors: Kuniyoshi Saito, Iwao Moriyama, Jun Okabe