Patents Assigned to Nippon Mektron, Limited
  • Patent number: 5478902
    Abstract: A fluorine-containing-copolymer composition comprises a novel terpolymer of tetrafluoroethylene-perfluoro (methylvinylether)-1,1,3,3,3-pentafluoropropene and dialkali metal salt of bisphenol compound gives a vulcanization product having a low compression set.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: December 26, 1995
    Assignee: Nippon Mektron, Limited
    Inventors: Yuichi Yamamoto, Haruyoshi Tatsu
  • Patent number: 5461129
    Abstract: Tetrafluoroethylene-perfluorovinylether copolymer having a specific melt viscosity of 30.times.10.sup.4 to 200.times.10.sup.4 poises at 372.degree. C., which comprises 99% to 90% by weight of tetrafluoroethylene and 1% to 10% by weight of perfluoro(ethyl vinyl ether) can produce a film or sheet having good resistance to flex fatigue by molding.
    Type: Grant
    Filed: July 25, 1994
    Date of Patent: October 24, 1995
    Assignee: Nippon Mektron, Limited
    Inventors: Satoshi Kurihara, Hiroaki Murata, Haruyoshi Tatsu
  • Patent number: 5451640
    Abstract: A vulcanizable, fluorine-containing elastomer composition, which comprises a fluorine-containing elastomer copolymerized with chlorotrifluoroethylene, (A) a salicylaldo-imino copper complex having the following chemical formula as a cross-linking agent: ##STR1## (B) at least one of a divalent metal oxide and hydroxide as an acid receptor, and (C) a polyfunctional unsaturated compound as a cross-linking agent have a high vulcanization rate and good physical properties in the normal state of vulcanization product.
    Type: Grant
    Filed: June 7, 1994
    Date of Patent: September 19, 1995
    Assignee: Nippon Mektron, Limited
    Inventor: Eiichi Yamashita
  • Patent number: 5446081
    Abstract: A composition for low hardness, fluorine-containing rubber comprising solid fluorine-containing rubber, liquid fluorine-containing rubber, an aliphatic amine having an alkyl group having at least 8 carbon atoms and a perfluoropolyether has a good mold releasability at the vulcanization molding and can produce a vulcanized product having a JIS A hardness, according to JIS K-6301, of not more than 50 and less adhesiveness to a metal.
    Type: Grant
    Filed: September 2, 1993
    Date of Patent: August 29, 1995
    Assignee: Nippon Mektron, Limited
    Inventor: Takehiro Sonoi
  • Patent number: 5334667
    Abstract: By using salicylaldoimino copper complex having the following formula as a cross-linking agent for a fluorine-containing elastomer containing at least one of iodine and bromine in the molecule, a vulcanization product with an improved heat resistance can be obtained and generation of harmful substances such as methyl iodine, methyl bromine, etc.
    Type: Grant
    Filed: December 27, 1993
    Date of Patent: August 2, 1994
    Assignee: Nippon Mektron, Limited
    Inventors: Yuichi Yamamoto, Haruyoshi Tatsu
  • Patent number: 5252678
    Abstract: An acrylic elastomer capable of giving a vulcanization product having a distinguished tensile strength and a good stretching even by cross-linking with an organic peroxide can be obtained by using an organic peroxide having a non-conjugated double bond as a polymerization initiator in polymerization of at least one of (a) alkyl acrylates having an alkyl group of 1 to 8 carbon atoms and (b) alkoxyalkyl acrylates having an alkoxylalkyl group of 2 to 8 carbon atoms.
    Type: Grant
    Filed: October 27, 1992
    Date of Patent: October 12, 1993
    Assignee: Nippon Mektron Limited
    Inventors: Yuichi Yamamoto, Kazuma Yokoi, Haruyoshi Tatsu
  • Patent number: 5241010
    Abstract: A vulcanizable acrylic rubber composition comprising an acrylic rubber containing an active halogen group and a carboxyl group, trithiocyanuric acid, and a metal salt of dithiocarbamic acid alone or together with thiuram sulfide gives a vulcanized product having very good compression set and tensile strength even if the secondary vulcanization is omitted.
    Type: Grant
    Filed: April 23, 1991
    Date of Patent: August 31, 1993
    Assignee: Nippon Mektron Limited
    Inventor: Kazuma Yokoi
  • Patent number: 5239055
    Abstract: Pure perfluoro(propylvinylether) is obtained by extractive distillation of crude perfluoro(propylvinylether) containing a hydrogen fluoride adduct of perfluoro(propylvinylether), which is obtained by gas phase or liquid phase thermal decomposition of perfluoro(2-propoxypropionyl)fluoride, in the presence of a ketone having a boiling point of 100.degree. C. of higher.
    Type: Grant
    Filed: March 29, 1991
    Date of Patent: August 24, 1993
    Assignee: Nippon Mektron Limited
    Inventors: Masatoshi Abe, Masashi Fukazawa, Seiichi Nakamura
  • Patent number: 5219904
    Abstract: A cross-linkable, fluorine-containing elastomer composition comprising a fluorine-containing elastomer containing at least one of iodine and bromine in the molecule, an organic peroxide having a peroxy group --O--O--C(CH.sub.3).sub.2 R, where R is a lower alkyl group, in the molecule and an activation energy of not more than 34.0 Kcal/mole and another organic peroxide having the same peroxy group as defined above in the molecule and an activation energy of less than 34.0 Kcal/mole as cross-linking agents for the elastomer has less generation of CH.sub.3 I or CH.sub.3 Br at the decomposition of the organic peroxides without any substantial decrease in the compression set of the vulcanization products.
    Type: Grant
    Filed: May 19, 1992
    Date of Patent: June 15, 1993
    Assignee: Nippon Mektron Limited
    Inventor: Masatoshi Abe
  • Patent number: 5202244
    Abstract: Aphidicolin is produced with a high productivity by culturing microorganisms belonging to the genus Verticillium, for example, Verticillium sp FERM BP-3430, in a culture medium, thereby forming and accumulating aphidicolin therein and recovering the aphidicolin therefrom.
    Type: Grant
    Filed: July 18, 1991
    Date of Patent: April 13, 1993
    Assignee: Nippon Mektron Limited
    Inventors: Tokiyuki Hiramitsu, Atsushi Mouri, Nobuyoshi Niizuma
  • Patent number: 5202401
    Abstract: Acrylic elastomer obtained by copolymerization of an epoxy group-containing vinyl monomer and an .alpha., .beta.-unsaturated carboxylic acid aryl ester can produce vulcanization products having good compression set and heat resistance when vulcanized together which (1) a cyanuric acid and (2) a quaternary ammonium salt or phosphonium salt as cross-linking agents without secondary vulcanization.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: April 13, 1993
    Assignee: Nippon Mektron Limited
    Inventor: Kazuma Yokoi
  • Patent number: 5200472
    Abstract: A vulcanizable acrylic elastomer composition, which comprises copolymers of at least one of (a) an alkyl acrylate having an alkyl group having 1 to 8 carbon atoms and (b) an alkoxyalkyl acrylate having an alkoxyalkyl group having 2 to 8 carbon atoms, (c) an epoxy group-containing vinyl monomer and (d) .alpha.,.beta.-unsaturated carboxylic acid aryl ester, and (1) a disphenyl phthalate and (2) a quaternary ammonium salt or a phosphonium salt, and (3) at least one of a urea and a guanidine as cross-linking agents.
    Type: Grant
    Filed: May 10, 1991
    Date of Patent: April 6, 1993
    Assignee: Nippon Mektron, Limited
    Inventor: Akihiro Naraki
  • Patent number: 5194540
    Abstract: An acrylic elastomer capable of giving a vulcanization product having a distinguished tensile strength and a good stretching even by cross-linking with an organic peroxide can be obtained by using an organic peroxide having a non-conjugated double bond as a polymerization initiator in polymerization of at least one of (a) alkyl acrylates having an alkyl group of 1 to 8 carbon atoms and (b) alkoxyalkyl acrylates having an alkoxyalkyl grouop of 2 to 8 carbon atoms.
    Type: Grant
    Filed: July 11, 1992
    Date of Patent: March 16, 1993
    Assignee: Nippon Mektron Limited
    Inventors: Yuichi Yamamoto, Kazuma Yokoi, Haruyoshi Tatsu
  • Patent number: 5159026
    Abstract: A cross-linkable fluorine-containing elastomer composition comprising a fluorine-containing elastomer containing at least one of iodine and bromine in the molecule, an organic peroxide having a peroxy group --O--O--C(CH.sub.3).sub.2 R, where R is a lower alkyl group, in the molecule and an activation energy of not more than 34.0 Kcal/mole and another organic peroxide having the same peroxy group as defined above in the molecule and an activation energy of less than 34.0 Kcal/mole as cross-linking agents for the elastomer has less generation of CH.sub.3 I or CH.sub.3 Br at the decomposition of the organic peroxides without any substantial decrease in the compression set of the volcanization products.
    Type: Grant
    Filed: July 10, 1990
    Date of Patent: October 27, 1992
    Assignee: Nippon Mektron, Limited
    Inventor: Abe Masatoshi
  • Patent number: 5151492
    Abstract: A fluorine-containing elastomer capable of giving a primary vulcanization product with a good permanent set through peroxide vulcanization is produced by homopolymerization or copolymerization of a fluorine-containing olefin having 2 to 8 carbon atoms in the presence of an iodine and bromine-containing compound represented by the general formula RBrnIm, wherein R represents a fluorohydrocarbon group, a chlorofluorohydrocarbon group, a chlorohydrocarbon group or a hydrocarbon group, and n and m are integers of 1 and 2, and a small amount of perfluoro(unsaturated compound) which is iodotrifluoroethylene, perfluoro(bromoalkylvinylether) or perfluoro(iodoalkylvinylether).
    Type: Grant
    Filed: January 22, 1992
    Date of Patent: September 29, 1992
    Assignee: Nippon Mektron, Limited
    Inventors: Masatoshi Abe, Haruyoshi Tatsu
  • Patent number: 5049622
    Abstract: CF.sub.2 .dbd.CF.sub.2 and CF.sub.3 OCF.dbd.CF.sub.2 are subjected to copolymerization reaction in the presence of an organic compound containing at least one of iodine and bromine, and then CF.sub.2 .dbd.CF.sub.2 and CH.sub.2 .dbd.CF.sub.2 are supplied to the reaction system to continue the polymerization reaction.The thus obtained fluorine-containing block copolymer is of a low vinylidene fluoride content type and has a good solvent resistance.
    Type: Grant
    Filed: September 18, 1990
    Date of Patent: September 17, 1991
    Assignee: Nippon Mektron Limited
    Inventor: Masatoshi Abe
  • Patent number: 4981918
    Abstract: A crosslinkable, fluorine-containing elastomer composition containing an organic peroxide having a peroxy group --O--O--C (CH.sub.3).sub.2 R, where R is a lower alkyl group, in the molecule and an activation energy of not more than 34.0 Kcal/mole as a crosslinking agent for a fluorine-containing elastomer containing at least one of iodine and bromine. The organic peroxide reduces an amount of CH.sub.3 I or CH.sub.3 Br to be generated at its decomposition.
    Type: Grant
    Filed: July 10, 1989
    Date of Patent: January 1, 1991
    Assignee: Nippon Mektron Limited
    Inventors: Shin Okamoto, Masatoshi Abe
  • Patent number: 4960947
    Abstract: Hexafluoroacetone or its hydrate is produced in a higher yield than that of the conventional process (1) by oxidizing a heptafluoroisobutenyl ether with ozone or (2) by thermally decomposing an octafluoroisobutyl ether or a heptafluoroisobutenyl ether in the presence of oxygen and an activated carbon catalyst.
    Type: Grant
    Filed: June 28, 1989
    Date of Patent: October 2, 1990
    Assignee: Nippon Mektron Limited
    Inventors: Takehiro Sonoi, Toshimasa Sagawa, Okimasa Yamada, Tetsuya Mizuno
  • Patent number: 4943622
    Abstract: A fluorine-containing elastomer capable of giving a vulcanized product with a good permanent set through peroxide vulcanization is produced by homopolymerization or copolymerization of a fluorine-containing olefin having 2 to 8 carbon atoms in the pressence of an iodine and bromine-containing compound represented by the general formula RBrn Im, where R represents a fluorohydrocarbon group, a chorofluorohydrocarbon group, a chlorohydrocarbon group or a hydrocarbon group, and n and m are integers of 1 and 2, and a small amount of 1,1-difluoro-2-bromoethylene.
    Type: Grant
    Filed: May 17, 1988
    Date of Patent: July 24, 1990
    Assignee: Nippon Mektron, Limited
    Inventors: Akihiro Naraki, Masatoshi Abe, Shin Okamoto, Jun Okabe
  • Patent number: 4920170
    Abstract: A fluorine-containing elastic copolymer with distinguished low temperature characteristics, comprising (a) about 30 to about 80% by mole of tetrafluoroethylene, (b) about 5 to about 60% by mole of perfluoro(lower alkyl vinyl ether) and (c) a perfluoroether compound represented by following general formula:CF.sub.2 .dbd.CFOCF.sub.2 CFXORfwherein X: F or --CF.sub.3 and Rf: --CnF.sub.2n+1, is obtained by copolymerizing the (a) component, the (b) component and the (c) component in the presence of a radical polymerization initiator.
    Type: Grant
    Filed: June 28, 1988
    Date of Patent: April 24, 1990
    Assignee: Nippon Mektron Limited
    Inventors: Masatoshi Abe, Shin Okamoto, Akihiro Naraki