Patents Assigned to Nippon Zeon Co. Ltd.
  • Patent number: 5686156
    Abstract: A press-through package obtained by placing objects to be packed, in the accommodating pockets formed by vacuum forming or the like of a sheet made of a thermoplastic norbornene type resin, particularly preferably a hydrogenated product of ring-opening polymerization product of a dicyclopentadiene type monomer, and then closing the openings of pockets of the sheet with another sheet such as metal foil to pack the objects to be packed, which package makes the packed objects clearly visible in the pocket portions, prevents the deterioration of the packed objects by moisture bacause of its excellent water vapor barrier properties, and is good in production efficiency.
    Type: Grant
    Filed: June 26, 1995
    Date of Patent: November 11, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Toshiyasu Matsui, Tsutomu Hani, Teiji Kohara, Tadao Natsuume
  • Patent number: 5686509
    Abstract: An adhesion-reinforcing composition for an epoxy resin adhesive which comprises a copolymer resin particle having been ion-crosslinked with a univalent or divalent metal cation, which particle is comprised of (i) a core ingredient composed of a polymer comprising diene monomer units and optional crosslinking monomer units and having a glass transition temperature not higher than -30.degree. C. and (ii) a shell ingredient composed of a copolymer having a glass transition temperature of at least 70.degree. C. and comprising acrylate or methacrylate monomer units and 0.01-20 wt. parts, per 100 wt. parts of the shell ingredient, of units of a radically polymerizable unsaturated carboxylic acid monomer having a carboxyl group and 3-8 carbon atoms; the core/shell weight ratio being 5/1-1/4. A composition comprising 100 wt. parts of an epoxy resin, 15-60 wt.
    Type: Grant
    Filed: November 22, 1995
    Date of Patent: November 11, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Akira Nakayama, Toshio Nagase, Tadashi Ashida, Masahiko Ohnishi
  • Patent number: 5683347
    Abstract: A balloon catheter used for intra-aortic balloon pumping (IABP). In the balloon catheter, an outer diameter of a catheter tube is not made constant in the axial direction. Rather, the outer diameter of the catheter tube from a hemostatic valve to a bifurcation, the portion which is positioned outside the patient's blood vessel, is made 3 to 30 percent larger than the outer diameter of the catheter tube from the balloon portion to the hemostatic valve, which is positioned inside the patient's blood vessel. The bifurcation has a first passage and a second passage. The first passage is communicating with a shuttle gas port and is disposed straight along the direction of the axial center of the catheter tube.
    Type: Grant
    Filed: July 28, 1995
    Date of Patent: November 4, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Shinichi Miyata, Takashi Kawabata, Tetsuo Toyokawa, Kouichi Sakai
  • Patent number: 5683819
    Abstract: A composite comprised of a nitrile group-containing highly saturated copolymer rubber and a fibrous material, which copolymer rubber is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and the copolymer rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80. This composite is useful for a belt.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: November 4, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Osamu Mori, Mitsugu Ishihara, Motofumi Oyama
  • Patent number: 5681900
    Abstract: A resin obtained by subjecting a norbornene type monomer having an aromatic ring structure (e.g. 5-phenyl-2-norbornene) to ring-opening polymerization and hydrogenating 95% or more of the unsaturated bonds in the backbone structure of the resulting polymer by the use of a catalyst composed of a combination of a transition metal compound and an alkyl metal compound, while leaving 80% or more of the aromatic ring structures, which resin has not only a high refractive index but also characteristics of a hydrogenated norbornene ring-opening polymerization product, i.e., excellent heat resistance, transparency, low birefringent properties, weather resistance, light resistance, low water absorption properties, moisture resistance, small dielectric constant, small dielectric loss, chemical resistance, etc., said resin being usable in optical materials, medical tools and materials, tools and materials for treating electronic parts, etc.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: October 28, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Toshihide Murakami, Teiji Kohara, Tadao Natsuume
  • Patent number: 5679485
    Abstract: A photosensitive composition comprising:(A) 35-80 weight parts of a phosphorus-containing hydrophilic copolymer made by copolymerization of a mixture of (a) 5-30 weight % of a phosphate ester group-containing unsaturated monomer, (b) 40-90 weight % of a conjugated diene monomer, and (c) 0-50 weight % of other monoolefinically unsaturated monomer;(B) 65-20 weight parts of a thermoplastic elastomer; the sum of (A) plus (B) being 100 weight parts;(C) 5-300 weight parts of a photopolymerizable ethylenically unsaturated monomer; and(D) 0.1-10 weight parts of a photopolymerization initiator.The photosensitive composition is useful for a photosensitive rubber plate and a flexographic printing plate.
    Type: Grant
    Filed: September 29, 1995
    Date of Patent: October 21, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Takao Suzuki, Fusayoshi Sakurai, Haruo Ueno, Ichiro Konishi, Tatsuo Usui
  • Patent number: 5665795
    Abstract: A resin composition comprising 30-95 parts by weight of a thermoplastic norbornene resin and 5-70 parts by weight of a spherical inorganic filler having an average particle diameter of 0.05-50 .mu.m; and a precision molding produced therefrom.
    Type: Grant
    Filed: June 26, 1995
    Date of Patent: September 9, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yuji Koushima, Teiji Kohara, Tadao Natsuume
  • Patent number: 5658987
    Abstract: The present invention provides a rubber composition which is balanced in wet skid resistance, low-temperature properties and low fuel consumption and which is suitable as a material for all-weather tire. This rubber composition comprises a random copolymer A having a glass transition temperature of -20.degree. C. or higher, a random copolymer B having a glass transition temperature of -50.degree. C. or lower, and a block copolymer C composed of said two copolymers as block units. The copolymers A, B and C can be produced by copolymerizing an aromatic vinyl compound and a conjugated diene using an alkali metal-based catalyst.
    Type: Grant
    Filed: September 29, 1995
    Date of Patent: August 19, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Masao Nakamura, Kiyoshi Tanaka, Fumitoshi Suzuki
  • Patent number: 5651995
    Abstract: A nitrile group-containing highly saturated copolymer rubber which is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atom, and the highly saturated copolymer rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80. The highly saturated copolymer rubber is produced copolymerizing an unsaturated nitrile, a conjugated diene and an optional copolymerizable monomer by using as a molecular weight modifier an alkylthiol compound having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and then, hydrogenating the thus-obtained copolymer.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: July 29, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Motofumi Oyama, Yoshiaki Aimura, Kazuyoshi Nakajima, Osamu Mori, Mitsugu Ishihara
  • Patent number: 5637179
    Abstract: A process for adhesion using an epoxy rein adhesive composition which comprises coating surfaces for adhesion with a two component epoxy resin adhesive composition prepared immediately before the coating by mixing a mixture containing (A) resin powder prepared by ionic crosslinking of resin particles by addition of a metal cation and (B) an epoxy resin with (C) a curing agent of a room temperature curing type for epoxy resins, bringing the coated surfaces for adhesion into contact with each other, and subsequently heating the surfaces for adhesion. The resin particle is constituted with (a) a core formed with a (meth)acrylate polymer and/or a diene polymer which has a glass transition temperature of -30.degree. C. or lower and (b) a shell formed with a copolymer of a (meth)acrylate monomer and a radical polymerizable unsaturated carboxylic acid monomer having carboxyl group and 3 to 8 carbon atoms which has a glass transition temperature of 70.degree. C. or higher.
    Type: Grant
    Filed: September 28, 1995
    Date of Patent: June 10, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Akira Nakayama, Toshio Nagase
  • Patent number: 5621076
    Abstract: Antigen proteins of Mycoplasma gallisepticum, genes encoding the antigen protein, recombinant vectors integrated with the gene and hosts transformed with the vector are provided. Diagnostics and vaccine using the antigen protein produced by such hosts are effective for poultry, especially chicken infected with Mycoplasma gallisepticum. Vaccination can maintain poultry free of Mycoplasma gallisepticum infection.
    Type: Grant
    Filed: September 2, 1994
    Date of Patent: April 15, 1997
    Assignees: Nippon Zeon Co., Ltd., Shionogi & Co., Ltd.
    Inventors: Kazumi Kodama, Shuji Saito, Noboru Yanagida, Kouichi Kamogawa, Yoshikazu Iritani, Shigemi Aoyama
  • Patent number: 5607772
    Abstract: A binder for coating materials containing dispersed inorganic powder comprises a polyurethane resin containing (a) 2.2 to 7.0 terminal epoxy groups in one molecule in average and (b) 0.1 to 5.0% by weight as SO.sub.3 -- of a sulfonic acid salt group, 0.05 to 3.0% by weight as COO-- of a carboxylic acid salt group, or 0.02 to 1.0% by weight as N.sup.+ of a quaternary ammonium salt group in the molecule, and having a number-average molecular weight of 2,000 to 10,000. A coating material containing dispersed inorganic powder and a magnetic recording medium both use this binder. In a recording medium comprising a magnetic layer placed on a non-magnetic substrate, the magnetic layer comprises polyurethane resin (A) as a binder, vinyl chloride polymer (B) containing 0.
    Type: Grant
    Filed: March 10, 1995
    Date of Patent: March 4, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Masahiro Yamakawa, Kenji Akimoto, Katsuya Nakamura, Fumio Takano, Takahiro Takasaki
  • Patent number: 5599882
    Abstract: The present invention discloses a polycyclic norbornene-based ring-opening polymer which comprises(A) 90-5% by mol of a repeating unit represented by the following formula [I] or the alkyl-substituted derivative thereof, and(B) 10-95% by mol of at least one repeating unit selected from a repeating unit represented by the following formula [II], the alkyl-substituted derivative thereof, a repeating unit represented by the following formula [III], the alkyl-substituted derivative thereof, or the alkylidene-substituted derivative thereof, and which has an intrinsic viscosity [.eta.] of 0.01-20 dl/g as determined in toluene at 25.degree. C., the hydrogenation products thereof, and a process for production thereof ##STR1## wherein ------ denotes a single bond or a double bond.
    Type: Grant
    Filed: February 13, 1990
    Date of Patent: February 4, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yoshikatsu Nishi, Masayoshi Ohshima, Teiji Kohara, Toshiyasu Matsui, Tadao Natsuume
  • Patent number: 5585989
    Abstract: Using a thermoplastic norbornene type plastic as a material for the magnetic disc substrate, a magnetic disc substrate having a small deformation and a high modulus of elasticity is prepared. By optimizing the thickness of the substrate, the resonance frequency of the magnetic disc can be elevated to a level higher than the servo band. As a result, a magnetic disc substrate can form a servo mark having a high positional precision, and can carry out tracking with high precision.
    Type: Grant
    Filed: November 23, 1994
    Date of Patent: December 17, 1996
    Assignees: Sony Corporation, Nippon Zeon Co., Ltd.
    Inventors: Miyuki Kuromiya, Hiroshi Takino, Masayoshi Oshima, Teiji Kohara
  • Patent number: 5583182
    Abstract: A block copolymer comprising a polymer block of an aromatic vinyl compound, a polymer block of butadiene and a polymer block of isoprene, having a weight average molecular weight of 10,000-500,000, containing 10-50 wt. % of a bound aromatic vinyl compound, 10-60 wt. % of bound butadiene, 10-60 wt. % of bound isoprene, at most 15 wt. % of 1,2-vinyl bonds in a butadiene segment and at most 10 wt. % of 3,4-vinyl bonds in an isoprene segment, and having a storage modulus (G') of 10.sup.6 -3.times.10.sup.8 Pa in a viscoelasticity measurement in a temperature range of from 0.degree. C. to 50.degree. C. and only one peak on loss tangent (tan .delta.) attributable to the butadiene polymer block and the isoprene polymer block in a temperature range of from -80.degree. C. to -50.degree. C. scarcely undergoes a change of melt viscosity with time. A pressure sensitive adhesive composition comprising the block copolymer and a tackifier is also provided.
    Type: Grant
    Filed: March 2, 1995
    Date of Patent: December 10, 1996
    Assignee: Nippon Zeon Co. Ltd.
    Inventors: Itsuo Asahara, Minoru Takematsu
  • Patent number: 5580934
    Abstract: There are disclosed a polycyclic norbornene or its derivative hydrogenated copolymer which containsa repeating unit represented by the following formula [I] or the alkyl-substituted derivative thereof (A),a repeating unit represented by the following formula [II] or the alkyl-substituted derivative thereof (B) and, as desired,5-85% by mole of at least one repeating unit (C) selected from a repeating unit represented by the following formula [III], the alkyl-substituted derivative thereof, a repeating unit represented by the following formula [IV], the alkyl-substituted derivative and the alkylidene-substituted derivative thereof, and a process for producing the polycyclic norbornene or its derivative ring-opening hydrogenated copolymer ##STR1## wherein ------ represents either a single bond or a double bond.
    Type: Grant
    Filed: June 7, 1990
    Date of Patent: December 3, 1996
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yoshikatsu Nishi, Masayoshi Oshima, Teiji Kohara, Tadao Natsuume
  • Patent number: 5571859
    Abstract: A resin composition comprising 100 parts by weight of a thermoplastic resin and 1 to 50 parts by weight of an antistatic composition consisting essentially of 100 parts by weight of carbon fibers having a length of 0.01 to 100 mm and 5 to 70 parts by weight of carbon fibers having a length of 1/2 to 1/100 of the first carbon fibers is molded to obtain a molded article having an even antistatic effect over the surface in which molded article the antistatic agent (carbon fibers) does not bleed to the exterior and the antistatic effect is maintained for a long time.
    Type: Grant
    Filed: October 27, 1994
    Date of Patent: November 5, 1996
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Hidenori Yukishige, Yuji Koshima, Hajime Tanisho, Teiji Kohara
  • Patent number: 5569719
    Abstract: A vulcanizable rubber composition including a partially hydrogenated unsaturated nitrile-conjugated diene copolymer having an iodine value of smaller than 25, a sulfur vulcanizer and a tellurium dithiocarbamate compound as a vulcanization promotor. This rubber composition provides a vulcanizate having reduced heat build-up, reduced compression set and high mechanical strength.
    Type: Grant
    Filed: December 19, 1994
    Date of Patent: October 29, 1996
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Sachio Hayashi, Isamu Miyauchi, Motofumi Oyama
  • Patent number: 5569796
    Abstract: A fluorinated saturated hydrocarbon represented by the formula (2): ##STR1## wherein R and R' represent a perfluoroalkyl group or both R and R' are bonded together to form a perfluoroalkylene group which is a part of a ring, is industrially advantageously produced with good operating characteristics by reacting a fluorinated unsaturated hydrocarbon represented by the formula (1):R --CF.dbd.CF-R' (1)wherein R and R' are as defined above, with hydrogen in the presence of a platinum catalyst.
    Type: Grant
    Filed: March 29, 1995
    Date of Patent: October 29, 1996
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Toshiro Yamada, Yasuhiro Mitsuda
  • Patent number: 5561208
    Abstract: A polymer composition comprising a thermoplastic norbornene polymer which preferably has a number average molecular weight of 10,00-200,000 as determined by gel permeation chromatography in toluene solvent and calculated as styrene and a content of norbornene polymer components having a number average molecular weight of 2,000 or less of 1% by weight or less, and a compounding ingredient, such as a rubber-like polymer, wherein the compounding ingredient is preferably dispersed in the form of microdomains in the norbornene polymer; and medical implements and optical naturals formed essentially of the composition.
    Type: Grant
    Filed: August 2, 1995
    Date of Patent: October 1, 1996
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Nobukazu Takahashi, Tohru Hosaka, Koji Minami, Yuichiro Konishi, Teiji Kohara, Tadao Natsuume