Patents Assigned to Nobel AB
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Patent number: 5589447Abstract: A liquid dishwashing-detergent composition containing an anionic surfactant, at least two types of amphoteric compounds, and a nonionic surface active compound. The amphoteric compounds are characterized by general formula (I) and (III) or (IV): ##STR1## wherein R is a hydrocarbon group having 7-22 carbon atoms, n is 0 or 1, A is a carbonyl group (C(O)), a group (OCH.sub.2 CH.sub.2).sub.z or a group (OCH.sub.2 CH.sub.2 CH.sub.2).sub.z in which z is an integer from 1 to 5, R.sub.1 is hydrogen or a lower alkyl group, x is 2 or 3, y is an integer from 0 to 4, Q is the group --R.sub.2 COOM in which R.sub.2 is an alkylene group having 1-6 carbon atoms and M is hydrogen or an ion from the groups alkali metals, alkaline earth metals, ammonium and substituted ammonium, and B is hydrogen or a group Q as defined above; ##STR2## wherein R is a longer hydrophobic hydrocarbon group having at least 7 carbon atoms, R' is an alkyl or hydroxyalkyl group having 1-4 carbon atoms, n is 1 or 2, and M is hydrogen or a sodium ion.Type: GrantFiled: May 10, 1995Date of Patent: December 31, 1996Assignee: Berol Nobel ABInventor: Jadwiga Palicka
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Patent number: 5585119Abstract: An apparatus for producing expanded thermoplastic microspheres, including a belt conveyor (A) having an endless belt (1) for conveying microspheres. A device (B) for infrared (IR) heating, including a plurality of IR lamps (4) is located above the belt (1). A dosing device (C) for the dried unexpanded microspheres is located at one end of the belt conveyor and in conjunction with the belt (1). A collecting device (D) for expanded microspheres is located at the other end of the belt conveyor and in conjunction with the belt (1).Type: GrantFiled: June 7, 1995Date of Patent: December 17, 1996Assignee: Casco Nobel ABInventors: Jorgen Petersen, Lars-Olov Svedberg
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Patent number: 5584222Abstract: A method for charging explosives in substantially horizontal bore-holes, with a loading density reduced in relation to that corresponding to the complete fill up of the bore-hole diameter with the explosive in bulk form, comprising that a charging hose with an end opening is introduced into at least one bore-hole of a blasting round, that a pumpable and coherent bulk explosive is pumped through the charging hose at a controlled rate, that simultaneous with the pumping of explosive the hose is withdrawn at a controlled rate, that the pumping and withdrawal rates are adjusted to form a coherent string exiting from the hose end opening, said exiting string only partially filling up the bore-hole diameter.Type: GrantFiled: March 22, 1996Date of Patent: December 17, 1996Assignee: Nitro Nobel ABInventors: Bjorn Engsbr.ang.ten, Rolf Magnusson
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Patent number: 5578788Abstract: Explosive composition, and method for its manufacture, based on an essentially particulate mixture containing a solid oxidizing salt and optionally a fuel, wherein at least a part of the oxidizing salt contains ammonium ion. The mixture contains an additive of acid and may be used in environments with risk of ammonia liberation.Type: GrantFiled: September 8, 1995Date of Patent: November 26, 1996Assignee: Nitro Nobel ABInventor: Bjorn Engsbr.ang.ten
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Patent number: 5567911Abstract: An explosive in granulated or particulate form, wherein at least a part of the granules comprises an emulsion, having a continuous fuel phase and a discontinuous oxidizer phase containing oxidizing salts, and wherein the fuel phase is soft or deformable and at least a part of the oxidizing salts in the discontinuous phase is in solid crystalline or amorphous form. A method for the manufacture of an explosive in granular or particluate form comprises the steps of, forming an emulsion having a continuous fuel phase and a discontinuous oxidizing phase containing oxidizing salts, solidifying at least a part of the oxidizing salts in the discontinuous phase and granulating the emulsion. The granulated explosive may be charged, e.g. by blow-loading, into a hole in a material and initiated.Type: GrantFiled: December 15, 1994Date of Patent: October 22, 1996Assignee: Nitro Nobel ABInventor: Gunnar Ekman
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Patent number: 5552519Abstract: Surfactant obtainable by and method for the production thereof comprising (1) esterifying a rosin with an alcohol to an acid value of less than 30, (2a) grafting the rosin ester with an unsaturated carboxylic acid or anhydride, the mole ratio carboxylic acid or anhydride/rosin (calculated as each rosin associated with a rosin ester) being from 0.05:1-1.5:1, (3a) esterifying the grafted rosin ester with a polyethylene glycol with an Mw of 1000-20000 the mole ratio glycol/free carboxylic acid group being from 0.2:1-1:1 to an acid value of less than 30, alternatively (2b) esterifying an unsaturated carboxylic acid or anhydride with a polyethylene glycol with a Mw of 1000-20000 the mole ratio glycol/free carboxylic acid group or anhydride being from 0.2:1-1:1 to an acid value less than 30, (3b) grafting the rosin ester from (1) with the ester from (2b), the mole ratio ester from (2b)/rosin ester (calculated as in (2a)) being from 0.05:1-1.5:1.Type: GrantFiled: May 16, 1995Date of Patent: September 3, 1996Assignee: EKA Nobel, ABInventors: Paul N. Hemmings, Long Wang
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Patent number: 5547542Abstract: The invention relates to a process for treating a low-concentrated aqueous feed solution which includes at least one aqueous process stream from a pulp mill. The process includes concentrating the feed solution by evaporation to form an evaporation concentrate, and subjecting at least a part of the concentrate to a first electrodialysis treatment, thereby forming a first electrodialysis concentrate containing salt removed from the evaporation concentrate and at least one diluate depleted in the salt. The invention also relates to a plant for carrying out the above process.Type: GrantFiled: February 2, 1994Date of Patent: August 20, 1996Assignee: Eka Nobel ABInventor: Johan Landfors
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Patent number: 5547603Abstract: The invention concerns a solid alkalimetal silicate having a molar ratio SiO.sub.2 :M.sub.2 O from about 1.5 to about 3, in which M is an alkali metal and substantially consists of sodium and optionally potassium. The silicate contains from about 7 to about 20% by weight of sodium carbonate based on the dry material and has a water content from about 14 to about 22% by weight. Further, the invention concerns a method of preparing the silicate above, use of the same and cleaning agent compositions containing such a silicate.Type: GrantFiled: May 13, 1994Date of Patent: August 20, 1996Assignee: Eka Nobel ABInventors: Olle Sorensson, Krister Severinsson
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Patent number: 5545389Abstract: A process for the production of chlorine dioxide by reacting at least one of chloric acid and an alkali metal chlorate, and hydrogen peroxide as the reducing agent in such proportions that chlorine dioxide is produced in a reaction medium. A mixture comprising chlorine dioxide and oxygen is withdrawn from the reaction medium. Urea and/or one or more phosphonic acid based complexing agents are added to the reaction medium. The stabilizer is added in an amount of 0.01-5 weight % and serves to increase the reaction rate.Type: GrantFiled: September 12, 1994Date of Patent: August 13, 1996Assignee: Eka Nobel ABInventors: John R. Winters, John M. Gray, Joel D. Tenney
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Patent number: 5523470Abstract: A new class of surfactants exhibits properties, which make the surfactants suitable for use in surfactant flooding for enhanced oil recovery. The surfactants have the formulaXA.sub.r ORSO.sub.3.sup.- M.sup.+ (I)where R is a hydrocarbon or hydroxyl-substituted hydrocarbon group with 2-6 carbon atoms; A is an oxyalkylene group having 2-4 carbon atoms; r is a number from 0-10, preferably 0-5 and most preferably 1-4; X is an hydroxyl group or hydroxyl and ether group containing hydrophobic group, which comprises 2-6, preferably 2-4 end groups containing 3-22 carbon atoms; and M is a cation, preferably a monovalent cation; or a C.sub.1-4 -alkyl ether thereof. A method for the manufacture of the surfactants are also enclosed.Type: GrantFiled: April 5, 1994Date of Patent: June 4, 1996Assignees: Berol Nobel AB, Den norske stats oljeselskap a.s.Inventors: Leif Karlsson, Per-Erik Hellberg, Lena Eriksson, Stig Svennberg, Eimund Gilje, Siri Espedal, Trygve Maldal
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Patent number: 5523431Abstract: The present application relates to a method of producing an amide product mixture having a low content of secondary amines by reacting an amide product mixture having a high secondary amine content with an aliphatic alkylene oxide in the absence of an essential amount of any alkoxylation catalyst. The amide product mixture obtained contains a minor amount of tertiary amines and exhibits advantageous properties when used for the formulation of cosmetic products, such as shampoos and creams; foam cleaning compositions, e.g. for textiles and cars; and functional fluids, such as lubricants, metal working fluids and hydraulic fluids.Type: GrantFiled: October 29, 1993Date of Patent: June 4, 1996Assignees: Berol Nobel AB, Castrol Ltd.Inventor: Rolf Skold
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Patent number: 5520961Abstract: A coating composition suitable as an undercoating for cars contains vinyl-chloride-polymer-based plastisol and expandable thermoplastic microspheres. The expandable thermoplastic microspheres have a substantially halogen-free polymer shell which comprises a copolymer of halogen-free monomers and, in an amount of at least about 80% by weight, nitrile-containing monomers. Preferably, the polymer shell of the thermoplastic microspheres contains from about 85% by weight to about 97% by weight of nitrile-containing monomer. A method for spray-coating a surface with the coating composition by airless spraying is also disclosed.Type: GrantFiled: December 1, 1994Date of Patent: May 28, 1996Assignee: Casco Nobel ABInventors: Lennart Lysell, Lars Malmbom
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Patent number: 5512135Abstract: The present invention relates to a process for improved dewatering and retention in the production of paper, where an anionic retention agent based on starches, cellulose derivatives or guar gums having no cationic groups and an acidic solution of an aluminum compound are added to the stock containing lignocellulose-containing fibres and optionally fillers. The pH of the stock prior to the addition of the aluminium compound should be at least about 6 to obtain the desired cationic aluminium hydroxide complexes in the stock. The present invention is cost effective and insensitive to the content of calcium in the white water.Type: GrantFiled: January 3, 1994Date of Patent: April 30, 1996Assignee: Eka Nobel ABInventors: Bruno Carre, Ulf Carlson
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Patent number: 5510003Abstract: The invention relates to a method of sizing paper and similar cellulose products containing precipitated calcium carbonate as a filler. According to the method, an aqueous suspension of pulp is dewatered and dried in the presence of an aqueous dispersion of a rosin-based sizing agent, which comprises a rosin component and a rosin ester component, and an aqueous dispersion of a cellulose-reactive sizing agent. The invention also relates to an aqueous dispersion of sizing agents which comprises a rosin-based sizing agent, which contains a rosin component and a rosin ester component, and a cellulose-reactive sizing agent.Type: GrantFiled: July 20, 1994Date of Patent: April 23, 1996Assignee: Eka Nobel ABInventors: Anthony R. Colasurdo, Ian R. Hiskens, Nicholas S. Morgan, Karen J. Smith
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Patent number: 5502218Abstract: A process for the production of ketene dimers from fatty acid halides by reaction with tertiary amines. The process is operated batchwise and the reaction is started in the presence of an initial reaction mixture containing ketene dimer and pre-prepared crystals of tertiary amine hydrogen halide and is carried out in the substantial absence of additional solvents.Type: GrantFiled: September 15, 1994Date of Patent: March 26, 1996Assignee: Eka Nobel ABInventors: John F. Nicholass, Piotr Zettinger
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Water-soluble polyurethane and use thereof to thicken water-based systems such as water-based paints
Patent number: 5496908Abstract: A water-soluble polyurethane, including a polymer backbone; end groups provided on the ends of the polymer backbone and containing water-soluble oxyethylene groups having a molecular weight ranging from 400 to 15,000, and groups pendant from the polymer backbone and containing hydrocarbon groups having 8-22 carbon atoms, in a number of at least 0.1 per urethane bond. The water-soluble polyurethane has moderate viscosities in aqueous solution and is especially useful as a thickener, for instance, in alkyd- or latex-based paints.Type: GrantFiled: March 16, 1994Date of Patent: March 5, 1996Assignee: Berol Nobel ABInventors: Peter Bostrom, Annelie Askenbom, Eva Gottberg-Klingskog -
Patent number: 5496440Abstract: A process for improved dewatering and retention in the manufacture of paper, where a retention agent containing anionic groups and being based on a polysaccharide or being an acrylamide-based polymer and an alkaline solution of an aluminate are added to the stock containing lignocellulose-containing fibres and optionally fillers. The pH of the stock prior to the addition of the aluminate should be below about 7 to obtain the desired cationic aluminum hydroxide complexes in the stock. The present process is cost effective and insensitive to the content of calcium in the white water.Type: GrantFiled: January 3, 1994Date of Patent: March 5, 1996Assignee: Eka Nobel ABInventors: Bruno Carre/, Ulf Carlson
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Patent number: 5484815Abstract: The present invention relates to a method for producing expanded thermoplastic microspheres by heating. Unexpanded microspheres are dried under agitation to a dry solids content exceeding 98% by weight, preferably 99% by weight, before heating. The dried microspheres can be rewetted and then expanded by heating. The microspheres thus produced contain but minor amounts of agglomerates, The invention also comprises an apparatus for expanding the dried spheres. The apparatus has a belt conveyor (A), a device (B) for IR heating, a dosing device (C) for unexpanded spheres, and a collecting device (D) for expanded spheres.Type: GrantFiled: March 28, 1994Date of Patent: January 16, 1996Assignee: Casco Nobel ABInventors: Jorgen Petersen, Lars-Olov Svedberg
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Patent number: 5474938Abstract: The invention relates to a method of determining the content of hydrogen peroxide in an aqueous solution, which is brought to a pH below 3, supplied with an excess of I.sup.-, and irradiated with light, the absorbance being measured at a predetermined wavelength. The invention also relates to an analyser for carrying out the method. Further, the invention relates to a method and a system of controlling the supply of hydrogen peroxide to an aqueous solution.Type: GrantFiled: January 10, 1994Date of Patent: December 12, 1995Assignee: Eka Nobel ABInventors: Gunilla Jadesjo, Bertil Magnusson, Signar Sundstrand
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Patent number: 5447604Abstract: Silica sols which have a large alkali excess, i.e. a low molar ratio SiO.sub.2 to M.sub.2 O, and which contain silica particles with a high specific surface area. The silica sols can be prepared through acidification of a water glass solution and subsequent alkalization of the acid sol to the molar ratio in question. The sols are particularly suitable for use as additives, in combination with cationic polymers, in papermaking.Type: GrantFiled: May 8, 1992Date of Patent: September 5, 1995Assignee: Eka Nobel ABInventors: Hans E. Johansson, Bo V. Larsson